CN101857776A - UV-curable adhesive composition for compact discs - Google Patents
UV-curable adhesive composition for compact discs Download PDFInfo
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- CN101857776A CN101857776A CN 201010200014 CN201010200014A CN101857776A CN 101857776 A CN101857776 A CN 101857776A CN 201010200014 CN201010200014 CN 201010200014 CN 201010200014 A CN201010200014 A CN 201010200014A CN 101857776 A CN101857776 A CN 101857776A
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Abstract
The invention provides a UV-curable adhesive composition for compact discs, which consists of bisphenol epoxy acrylate (A), acrylate compound (B) and photopolymerization initiator (C), wherein the acrylate compound (B) consists of iso-Bornyl acryl (B-1) and at least one of the following acrylate compounds: phenoxyethyl acrylate (B-2), tricyclodecane dihydroxymethyl diacrylate (B-3), ethoxylated trihydroxymethyl tricrylate (B-4), dipropylene glycol diacrylate (B-5) and enthyl hexyl acrylate (B-6). The composition can be utilized to bond two compact disc substrates together to produce a bonded compact disc.
Description
Technical field
The present invention relates to a kind of binder composition of CD, be specifically related to a kind of UV-curable adhesive composition of CD.
Background technology
Present digital versatile disc (DVD) can roughly be divided into DVD-ROM and blank DVD, DVD-ROM when making imprinting in the above information, and blank DVD does not have any information of imprinting when making, but by human consumer's own imprinting information on recording layer.DVD can be divided into according to structure and capacity: single-surface single-layer structure, capacity are the DVD5 of 5GB; Single-surface double-layer structure, capacity are the DVD9 of 9GB; Two-sided bilayer structure, capacity are the DVD10 of 10GB; Or the like.At present, that with the most use is DVD9, because it can write down 2.5 hours film.
DVD9 is placed on two-layer recording layer respectively two substrates up and down usually, and following recording layer is made semitransparent reflecting film, and top recording layer is made total reflection film, then two substrates is binded by tackiness agent.Laser head is when reading CD, and laser beam is the semitransparent reflecting film reading of data of arrival earlier; See through this semitransparent reflecting film again and arrive the total reflection film reading of data.
The material of total reflection film can be selected the silver or the silver alloys of higher reflectivity for use.Different with total reflection film is, semitransparent reflecting film must transmission laser, and therefore this film must be very thin, selects gold usually for use, because it is configured as film and relatively stable easily.Yet gold is very expensive material, and the material that therefore is used for semitransparent reflecting film turns to silicon or silicon compound from gold, and further turns to silver or silver alloys.But, because silver is oxidized easily, so very high to the requirement of tackiness agent.And, oxidized easily again though silver has higher reflectivity, so need layer protective layer.Although the protective layer that forms has the advantage of high-durability, easily cause the production efficiency of CD to descend, increase production cost and reduce production efficiency.
In patent documentation JP2003132, put down in writing the Photocurable adhesive that can be applicable to CD, but when the material of semitransparent reflecting film is silicon compound, the poor effect of this tackiness agent; And on the other hand, because two compact disc substrates are easy to generate bubble when bonding, so select for use the tackiness agent of high conductivity to avoid bubble usually.When using gold, silicon or silicon compound as semitransparent reflecting film, the resistance of the tackiness agent of selecting for use is 5.0 * 10
15Therefore Ω cm or littler when adopting conventional optical disc manufacturing apparatus, can be brought into bubble among the DVD of manufacturing hardly.But, when the material that is used for semitransparent reflecting film becomes the silver of easy oxidation or silver alloys, the binder ingredients that is used for this material is generally hydrophobic lower concentration ion, has very high resistance, when adopting conventional optical disc manufacturing apparatus to make DVD, the voltage that is applied can not provide the electric current that is enough to prevent to produce bubble, thereby is easy to generate bubble.
Therefore need a kind of tackiness agent of development, satisfying the effect of playing protection semitransparent reflector silver layer under the situation of bonding requirement simultaneously.
Summary of the invention
The UV-curable adhesive composition that the purpose of this invention is to provide a kind of CD, it is bonding to utilize this binder composition that two compact disc substrates are carried out, thus the preparation bonded optical disks.
A kind of UV-curable adhesive composition of CD, comprise: bisphenol type epoxy acrylate (A), acrylic compound (B) and Photoepolymerizationinitiater initiater (C), wherein, described acrylic compound (B) comprises at least a in isobornyl acrylate (B-1) and the following acrylic compound: benzene oxygen ethyl propylene acid esters (B-2), tristane dihydroxymethyl diacrylate (B-3), ethoxylation tri methylol triacrylate (B-4), propylene glycol diacrylate (B-5), Isooctyl acrylate monomer (B-6).
Described bisphenol type epoxy acrylate (A) is the bisphenol A diglycidyl ether diacrylate.
Described acrylic compound (B) comprises two kinds in isobornyl acrylate (B-1), benzene oxygen ethyl propylene acid esters (B-2) and the following acrylic compound: tristane dihydroxymethyl diacrylate (B-3), ethoxylation tri methylol triacrylate (B-4), propylene glycol diacrylate (B-5), Isooctyl acrylate monomer (B-6).
Described Photoepolymerizationinitiater initiater (C) is at least a in the following compound: 2,4, and the dimethacrylate phosphoric acid ester of 6-(trimethylbenzoyl) hexichol phosphine oxide, 1-hydroxy-cyclohexyl phenyl ketone or oxyethane modification.
Described composition further comprises silane coupling agent (D), and described silane coupling agent (D) is preferably γ-methacryloxypropyl trimethoxy silane.
The content of described bisphenol type epoxy acrylate (A) is 1-70 gross weight %, is preferably 35-50 gross weight %; The content of described acrylic compound (B) is 5-75 gross weight %, is preferably 45-60 gross weight %; The content of described Photoepolymerizationinitiater initiater (C) is 0.05-25 gross weight %, is preferably 0.1-6 gross weight %.
The content of described isobornyl acrylate (B-1) is 5-15 gross weight %, is preferably 9-10 gross weight %; The content 5-20 gross weight % of described benzene oxygen ethyl propylene acid esters (B-2) is preferably 9-15 gross weight %.
The content of described silane coupling agent (D) is 0.01-10 gross weight %, is preferably 0.9-1 gross weight %.
The invention provides the purposes of above-mentioned UV-curable adhesive composition as the CD tackiness agent.
The invention provides a kind of CD that comprises tackiness agent, described tackiness agent can obtain by solidifying above-mentioned UV-curable adhesive composition.
If the semitransparent reflecting film in two compact disc substrates is silver or silver alloys, when utilizing binder composition of the present invention to prepare bonded optical disks, between two compact disc substrates, do not produce bubble; The bonded optical disks of preparation has high moisture-proof heat, high ageing-resistant performance, and has and be equivalent to use the high reliability of gold as the conventional adhesive type CD of semitransparent reflecting film.
Embodiment
UV-curable adhesive composition according to a kind of CD of the present invention comprises following component: bisphenol type epoxy acrylate (A), acrylic compound (B) and Photoepolymerizationinitiater initiater (C).Wherein, acrylic compound (B) refers at least a following acrylic compound that is selected from: isobornyl acrylate (B-1), benzene oxygen ethyl propylene acid esters (B-2), tristane dihydroxymethyl diacrylate (B-3), ethoxylation tri methylol triacrylate (B-4), propylene glycol diacrylate (B-5), Isooctyl acrylate monomer (B-6).
The viscosity of composition of the present invention is 200-1000mPas.
Binder composition of the present invention can be as the tackiness agent of bonded optical disks, especially for the tackiness agent of bonded optical disks substrate.The total reflection film or the semitransparent reflecting film that have silver or silver alloys to constitute on arbitrary of the adherent compact disc substrate or two sides.Be preferred for using silver or silver alloys CD as semitransparent reflecting film.
The present invention also comprises the bonded optical disks that uses binder composition of the present invention to come the bonded optical disks substrate to make.Described CD comprises DVD-ROM (DVD9) and DVD-R etc.
Below, be described in more detail the present invention by embodiment, but the present invention is not subjected to the restriction of these embodiment.Among the embodiment, part refers to " weight part ", unless point out in addition.
Embodiment 1
In the reactor of being furnished with agitator and thermometer; 50 parts of bisphenol A diglycidyl ether diacrylate (trade(brand)name CNUVE151; Sartomer makes); 10 parts of isobornyl acrylate (IBOA; SR506); 5 parts of ethoxylated trimethylolpropane triacrylate (EO-TMPTA; SR454), and 25 parts of tristane dihydroxymethyl diacrylates (SR833S, R-684); 10 parts of benzene oxygen ethyl propylene acid esters (R-561); 3 part 2,4,6-(trimethylbenzoyl) hexichol phosphine oxide (TPO; DAROCUR TPO), 1 part of γ-methacryloxypropyl trimethoxy silane (Silquest
A-174 Silane), and in 60 ℃ the dissolving 1 hour, make UV-curable adhesive composition of the present invention.The UV-curable adhesive composition of the present invention that makes, 25 ℃ viscosity are 500MPas (by NDJ-5S type viscometer determining).
According to the conventional adhesion step 1-4 of following DVD9, utilize UV-curable adhesive composition of the present invention to protect the mineral membrane substrate bonding silver alloys semi-permeable membranes reflectance coating substrate and silicon-dioxide/zinc oxide, make the bonded optical disks of DVD9 type of the present invention.
1. silver alloys semitransparent reflector film substrate can be the silver alloys of 20nm by sputter average film thickness on the thick PC substrate of 0.6mm.Silicon-dioxide/zinc oxide protection substrate can be the inorganic silicon compound film of 5-6nm by sputter mean thickness on the thick PC substrate of 0.6mm.
2. the quantitative directly spin coating 1.5-1.8g UV-curable adhesive composition of the present invention of equipment that around the circular DVD substrate of sputter silicon-dioxide/zinc oxide protection mineral membrane, utilizes Anwell to make.
3. the ventricumbent silver alloys total reflection film of sputter substrate is placed on the supine silicon-dioxide of sputter/zinc oxide protection mineral membrane substrate, and carries out spin coating in 5 seconds with 2500rpm speed, so that they are bonding, the film thickness of composition is 40-50 μ m.The equipment that uses the Anwell manufacturing is as the CD binding appts.
4. use two xenon flash lamps up and down, use 6 flash of light irradiation that lamp carries out 1500V, lamp carries out 4 flash of light irradiation of 1500V under using, to be cured with bonding.In the irradiation process, DVD dish is placed to above the silver alloys semitransparent reflecting film is positioned at, and below the inorganic silicon compound film is positioned at.
Embodiment 2-6, comparative example 1-3
The UV-curable adhesive composition for preparing embodiment 2-6 and comparative example 1-3 according to the mode identical with embodiment 1.According to the mode bonded optical disks identical with embodiment 1.
Wherein, comparative example 1-3 is for industrially applying to bonding metal UV cure adhesive at present.
The ratio of each component of the UV-curable adhesive composition of each embodiment sees Table 1: the numeral umber in the table 1, and the abbreviation of each component is expressed as follows:
CNUVE151: the bisphenol A diglycidyl ether diacrylate, from Sartomer CO., LTD obtains
SR454: ethoxylated trimethylolpropane triacrylate, from Sartomer CO., LTD obtains
R-684: tristane dihydroxymethyl diacrylate, from NIPPON KAYAKU CO., LTD obtains
R-561: benzene oxygen ethyl propylene acid esters, from NIPPON KAYAKU CO., LTD obtains
DAROCUR TPO:2,4,6-(trimethylbenzoyl) hexichol phosphine oxide obtains from Ciba SpecialtyChemicals
IRGACURE 184:1-hydroxycyclohexylphenylketone obtains from Ciba Specialty Chemicals
SR506: isobornyl acrylate, from Sartomer CO., LTD obtains
SR508: propylene glycol diacrylate, from Sartomer CO., LTD obtains
SR440: Isooctyl acrylate monomer, from Sartomer CO., LTD obtains
PM-2: the dimethacrylate phosphoric acid ester of oxyethane modification, from NIPPON KAYAKUCO., LTD obtains
Silquest
A-174 Silane: γ-methacryloxypropyl trimethoxy silane obtains from GEAdvanced Materials
Estimate each UV-curable adhesive composition and the adhesive type CD that makes according to following method.
(1) resistivity
Use Xiang Tan China elegant demeanour device Manufacturing Co., Ltd to produce RT-1000 type resistivity tester, measure the resistivity of each UV-curable adhesive composition.The results are shown in table 2.
(2) bubble produces
Whether contain bubble with each adhesive type CD of microscopic examination.Be listed in table 2. according to following standard evaluation observations
G... find according to microscopic examination, do not contain bubble
P... find according to microscopic examination, contain bubble
(3) reflectance coating outward appearance before and after the endurance test
Each adhesive type CD was placed 500 hours and 700 hours in the environment of 80 ℃ and 85%RH.The visual inspection reflectance coating.Be listed in table 2. according to following standard evaluation observations
Observe total reflection film or semitransparent reflecting film after G...700 hour, with relatively not variation of bonding good CD just.
M... with just bonding good CD relatively, observe total reflection film after 500 hours or semitransparent reflecting film does not change, but observe total reflection film after 700 hours or semitransparent reflecting film has obvious variable color or pin hole.
P... compare with just bonding good CD, observation total reflection film or semitransparent reflecting film have obvious variable color or pin hole after 500 hours.
(4) electrical signal of CD before and after the endurance test
Each adhesive type CD was placed 700 hours in the environment of 80 ℃ and 85%RH.Electrical signal with the adhesive type CD after DVD data signal determinator DVD-2000 (AECO LTD manufacturing) the evaluation endurance test.
" thrashing " and " PI error " is the electrical signal from CD, be worth big more, adhesive type optical disc data save power poor more.
G... thrashing is not more than 8.0, and the PI error is not more than 250
M... thrashing is 8.1-9.0, and the PI error is 251-350
P... thrashing is not less than 9.1, and the PI error is not less than 351
(5) sunlight is transferred the reflectivity of the semitransparent reflecting film of postpone
Each adhesive type CD is in the 0.36W/m of 340nm
2UV illumination, blackboard temperature is 40 ℃, bathe 24 ℃ of temperature, following 200 hours of the condition of bath humidity 60%RH, the xenon WEATHER-OMETER Ci-4000. taking-up dish that uses Atlas Material TestingTechnology LLC to make uses DVD-2000 (AECO LTD. manufacturing) to measure the reflectivity of silver alloys semitransparent reflecting film then.
G... the reflectivity of silver alloys semitransparent reflecting film is not less than 18.1%
M... the reflectivity of silver alloys semitransparent reflecting film is 18.0-17.1%
P... the reflectivity of silver alloys semitransparent reflecting film is not more than 17.0%
By table 2 result as can be known, the bonded optical disks (described CD can be used for DVD-ROM (DVD9)) that uses binder composition of the present invention to take the bonded optical disks substrate to make avoid bubble to produce and endurance test after the performance excellence of aspects such as electrical signal.
Be exemplified as bisphenol A diglycidyl ether diacrylate (CNUVE151) according to the bisphenol type epoxy acrylate (A) in the UV-curable adhesive composition of various embodiments of the present invention at this.The content of bisphenol type epoxy acrylate (A) is generally 1-70 gross weight % in the present composition, is preferably 35-50 gross weight % at this.
Acrylic compound in the present composition (B) is exemplified as at this and comprises isobornyl acrylate (SR506), benzene oxygen ethyl propylene acid esters (R-561) and two kinds and be selected from following acrylic compound: tristane dihydroxymethyl diacrylate (R-684), ethoxylation tri methylol triacrylate (SR454), propylene glycol diacrylate (SR508), Isooctyl acrylate monomer (SR440).The content of acrylic compound in the present composition (B) is generally 5-75 gross weight %, is preferably 45-60 gross weight %.Wherein, the content of isobornyl acrylate (SR506) is generally 5-15 gross weight %, is preferably 9-10 gross weight %; The content of benzene oxygen ethyl propylene acid esters (R-561) is generally 5-20 gross weight %, is preferably 9-15 gross weight %.
Photoepolymerizationinitiater initiater (C) contained in the present composition is exemplified as at least a of following compound at this: 2; 4, the dimethacrylate phosphoric acid ester of 6-(trimethylbenzoyl) hexichol phosphine oxide, 1-hydroxy-cyclohexyl phenyl ketone or oxyethane modification.The content of Photoepolymerizationinitiater initiater in the present composition (C) is generally 0.05-20 gross weight %, is preferably 0.1-6 gross weight %.
The present composition can comprise further that silane coupling agent (D) is exemplified as γ-methacryloxypropyl trimethoxy silane (Silquest at this
A-174 Silane).The content of silane coupling agent in the present composition (D) is generally 0.01-10 gross weight %, is preferably 0.9-1 gross weight %.
Embodiment 7
According to following bonding DVD-R conventional steps 1-4, with bonding two substrates of UV-curing composition of embodiment 1 preparation.
1. according to ordinary method, on the thick PC substrate of 0.6mm, form the DVD-R coat of colo(u)r, and adopt the ordinary method of DVD-R standard to form groove thereon.
2. forming sputtering silver alloy TTP-40A on the substrate of coat of colo(u)r (obtaining), and forming coat of colo(u)r thereon, making that average film thickness is 50-60nm on the DVD-R coat of colo(u)r from Target TechnologyCompany LLC.
3. use the UV-curing composition of 1.5g embodiment 1 on by the circular substrate that forms above around the silver alloy reflective.Place the thick PC substrate of a 0.6mm on it, carry out spin coating in 4 seconds with 2000rpm, so that they are bonding.The film thickness that makes the UV-curing composition is 45-50 μ m.The equipment that uses OriginELECTRLC CO.LTD manufacturing is as the CD binding appts.
4. two xenon flash lamps about using are used 8 flashes of light that lamp carries out 1800V, and lamp carries out 4 flash of light placements of 1600V under using, to be cured with bonding.In the irradiation process, the DVD dish is placed to the thick PC substrate of 0.6mm up, and the silver alloys total reflection film down.
According to following method, the adhesive type CD of estimating each UV-curable adhesive composition and making.
(1) resistivity
According to measuring with top identical mode.
(2) bubble produces
According to measuring with top identical mode.
(3) reflectance coating outward appearance before and after the endurance test
After recorded information on the adhesive type CD that makes, in the environment of 80 ℃ and 85%RH, placed 200 hours and 400 hours.The visual inspection reflectance coating.According to following standard evaluation observations.
Observe total reflection film or semitransparent reflecting film after G...400 hour, with relatively not variation of bonding good CD just.
M... with just bonding good CD relatively, observe total reflection film after 200 hours or semitransparent reflecting film does not change, but observe total reflection film after 400 hours or semitransparent reflecting film has obvious variable color or pin hole.
P... compare with just bonding good CD, observation total reflection film or semitransparent reflecting film have obvious variable color or pin hole after 200 hours.
(4) electrical signal of CD before and after the endurance test
Behind the adhesive type cd-rom recording of information that makes, each adhesive type CD was placed 200 hours in the environment of 80 ℃ and 85%RH.Electrical signal with the adhesive type CD after the DVD data signal determinator evaluation endurance test.
" thrashing " and " PI error " is the electrical signal from CD, be worth big more, adhesive type data of optical disk save power poor more.
G... thrashing is not more than 8.0, and the PI error is not more than 250
M... thrashing is 8.1-9.0, and the PI error is 251-350
P... thrashing is not less than 9.1, and the PI error is not less than 351
The reflectivity of the semitransparent reflecting film after (5) sunlight stops down
According to measuring with top identical mode.
The result such as the table 3 that obtain above.
By table 3 result as can be known, the bonded optical disks (described CD can be used for DVD-R) that uses binder composition of the present invention to take the bonded optical disks substrate to make avoid bubble to produce and endurance test after the performance excellence of aspects such as electrical signal.
Claims (20)
1. the UV-curable adhesive composition of a CD, comprise: bisphenol type epoxy acrylate (A), acrylic compound (B) and Photoepolymerizationinitiater initiater (C), wherein, described acrylic compound (B) comprises at least a in isobornyl acrylate (B-1) and the following acrylic compound: benzene oxygen ethyl propylene acid esters (B-2), tristane dihydroxymethyl diacrylate (B-3), ethoxylation tri methylol triacrylate (B-4), propylene glycol diacrylate (B-5), Isooctyl acrylate monomer (B-6).
2. the UV-curable adhesive composition of CD as claimed in claim 1, described bisphenol type epoxy acrylate (A) is the bisphenol A diglycidyl ether diacrylate.
3. the UV-curable adhesive composition of CD as claimed in claim 1; described Photoepolymerizationinitiater initiater (C) is at least a in the following compound: 2; 4, the dimethacrylate phosphoric acid ester of 6-(trimethylbenzoyl) hexichol phosphine oxide, 1-hydroxy-cyclohexyl phenyl ketone or oxyethane modification.
4. the UV-curable adhesive composition of CD as claimed in claim 1, the content of described bisphenol type epoxy acrylate (A) is 1-70 gross weight %; The content of described acrylic compound (B) is 5-75 gross weight %; The content of described Photoepolymerizationinitiater initiater (C) is 0.05-25 gross weight %.
5. the UV-curable adhesive composition of CD as claimed in claim 4, the content of described bisphenol type epoxy acrylate (A) is 35-50 gross weight %; The content of described acrylic compound (B) is 45-60 gross weight %; The content of described Photoepolymerizationinitiater initiater (C) is 0.1-6 gross weight %.
6. the UV-curable adhesive composition of CD as claimed in claim 1 is characterized in that, described composition further comprises silane coupling agent (D).
7. the UV-curable adhesive composition of CD as claimed in claim 6, described silane coupling agent (D) is γ-methacryloxypropyl trimethoxy silane.
8. the UV-curable adhesive composition of CD as claimed in claim 6, the content of described silane coupling agent (D) is 0.01-10 gross weight %.
9. the UV-curable adhesive composition of CD as claimed in claim 8, the content of described silane coupling agent (D) is 0.9-1 gross weight %.
10. the UV-curable adhesive composition of a CD, comprise: bisphenol type epoxy acrylate (A), acrylic compound (B) and Photoepolymerizationinitiater initiater (C), wherein, described acrylic compound (B) comprises in isobornyl acrylate (B-1), benzene oxygen ethyl propylene acid esters (B-2) and the following acrylic compound two kinds: tristane dihydroxymethyl diacrylate (B-3), ethoxylation tri methylol triacrylate (B-4), propylene glycol diacrylate (B-5), Isooctyl acrylate monomer (B-6).
11. the UV-curable adhesive composition of CD as claimed in claim 10, described bisphenol type epoxy acrylate (A) is the bisphenol A diglycidyl ether diacrylate.
12. the UV-curable adhesive composition of CD as claimed in claim 10; described Photoepolymerizationinitiater initiater (C) is at least a in the following compound: 2; 4, the dimethacrylate phosphoric acid ester of 6-(trimethylbenzoyl) hexichol phosphine oxide, 1-hydroxy-cyclohexyl phenyl ketone or oxyethane modification.
13. the UV-curable adhesive composition of CD as claimed in claim 10, the content of described bisphenol type epoxy acrylate (A) are 1-70 gross weight %; The content of described acrylic compound (B) is 15-75 gross weight %; The content of described Photoepolymerizationinitiater initiater (C) is 0.05-25 gross weight %; The content of described isobornyl acrylate (B-1) is 5-15 gross weight %; The content of described benzene oxygen ethyl propylene acid esters (B-2) is 5-20 gross weight %.
14. the UV-curable adhesive composition of CD as claimed in claim 13, the content of described bisphenol type epoxy acrylate (A) are 35-50 gross weight %; The content of described acrylic compound (B) is 45-60 gross weight %; The content of described Photoepolymerizationinitiater initiater (C) is 0.1-6 gross weight %; The content of described isobornyl acrylate (B-1) is 9-10 gross weight %; The content of described benzene oxygen ethyl propylene acid esters (B-2) is 9-15 gross weight %.
15. the UV-curable adhesive composition of CD as claimed in claim 10 is characterized in that, described composition further comprises silane coupling agent (D).
16. the UV-curable adhesive composition of CD as claimed in claim 15, described silane coupling agent (D) is γ-methacryloxypropyl trimethoxy silane.
17. the UV-curable adhesive composition of CD as claimed in claim 15, the content of described silane coupling agent (D) are 0.01-10 gross weight %.
18. the UV-curable adhesive composition of CD as claimed in claim 17, the content of described silane coupling agent (D) are 0.9-1 gross weight %.
19. be used as the tackiness agent of CD as the UV-curable adhesive composition of each CD among the claim 1-18.
20. a CD that comprises tackiness agent, wherein said tackiness agent can each composition obtains among the claim 1-18 by solidifying.
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| CN 201010200014 CN101857776B (en) | 2010-06-11 | 2010-06-11 | UV-curable adhesive composition for compact discs |
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| CN 201010200014 CN101857776B (en) | 2010-06-11 | 2010-06-11 | UV-curable adhesive composition for compact discs |
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| CN101857776A true CN101857776A (en) | 2010-10-13 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292972A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | High-performance low-cost ultraviolet-curing water-based ink for metal base material |
| CN104312270A (en) * | 2014-10-28 | 2015-01-28 | 成都纳硕科技有限公司 | High-performance low-cost ultraviolet curing printing ink for base material |
| CN111732692A (en) * | 2020-05-22 | 2020-10-02 | 修德(溧阳)管道科技有限公司 | Light-cured resin adhesive for protective prepreg cloth of crossing pipeline and soaking method thereof |
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| CN101006151A (en) * | 2004-08-19 | 2007-07-25 | 日本化药株式会社 | Adhesive composition for optical disk, cured product and article |
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2010
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101006151A (en) * | 2004-08-19 | 2007-07-25 | 日本化药株式会社 | Adhesive composition for optical disk, cured product and article |
Non-Patent Citations (1)
| Title |
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| 《中国优秀博硕士学位论文全文数据库（硕士） 工程科技Ⅰ辑》 20061015 孙会宁 低能表面基材用UV固化胶粘剂的研制 第36页第3.3.2节、图22、第49页第3.7.1节、表28 1-9、19-20 , 第10期 2 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292972A (en) * | 2014-10-28 | 2015-01-21 | 成都纳硕科技有限公司 | High-performance low-cost ultraviolet-curing water-based ink for metal base material |
| CN104312270A (en) * | 2014-10-28 | 2015-01-28 | 成都纳硕科技有限公司 | High-performance low-cost ultraviolet curing printing ink for base material |
| CN104292972B (en) * | 2014-10-28 | 2016-08-24 | 成都纳硕科技有限公司 | A kind of metal base high-performance and low-cost UV-curable water-borne ink |
| CN111732692A (en) * | 2020-05-22 | 2020-10-02 | 修德(溧阳)管道科技有限公司 | Light-cured resin adhesive for protective prepreg cloth of crossing pipeline and soaking method thereof |
| CN111732692B (en) * | 2020-05-22 | 2023-05-12 | 修德(溧阳)管道科技有限公司 | Photocurable resin adhesive for protecting prepreg cloth through pipeline and soaking method thereof |
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| CN101857776B (en) | 2013-01-16 |
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