CN104209003B - 基于甲醚-三氟化硼络合物分离硼同位素产品的工业生产方法 - Google Patents
基于甲醚-三氟化硼络合物分离硼同位素产品的工业生产方法 Download PDFInfo
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- CN104209003B CN104209003B CN201410415624.XA CN201410415624A CN104209003B CN 104209003 B CN104209003 B CN 104209003B CN 201410415624 A CN201410415624 A CN 201410415624A CN 104209003 B CN104209003 B CN 104209003B
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- Prior art keywords
- methyl ether
- tower
- boron trifluoride
- boron
- trifluoride complex
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- KTPWETRNSUKEME-UHFFFAOYSA-N methoxymethane;trifluoroborane Chemical compound COC.FB(F)F KTPWETRNSUKEME-UHFFFAOYSA-N 0.000 title claims abstract description 54
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229910052796 boron Inorganic materials 0.000 title claims abstract description 36
- 238000000926 separation method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 claims abstract description 52
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000007921 spray Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 239000002826 coolant Substances 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 40
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 229910015900 BF3 Inorganic materials 0.000 claims description 17
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 11
- 239000012071 phase Substances 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 230000004907 flux Effects 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 2
- 238000005372 isotope separation Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 description 9
- ZOXJGFHDIHLPTG-BJUDXGSMSA-N Boron-10 Chemical compound [10B] ZOXJGFHDIHLPTG-BJUDXGSMSA-N 0.000 description 8
- 238000004821 distillation Methods 0.000 description 7
- 230000000903 blocking effect Effects 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- ZOXJGFHDIHLPTG-IGMARMGPSA-N boron-11 atom Chemical compound [11B] ZOXJGFHDIHLPTG-IGMARMGPSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229910000792 Monel Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000006837 decompression Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- -1 methyl phenyl ethers anisole-boron trifluoride Chemical class 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UYAGPULHTNCMOT-UHFFFAOYSA-N [B].FB(F)F Chemical compound [B].FB(F)F UYAGPULHTNCMOT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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CN201410415624.XA CN104209003B (zh) | 2014-08-16 | 2014-08-16 | 基于甲醚-三氟化硼络合物分离硼同位素产品的工业生产方法 |
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CN104209003A CN104209003A (zh) | 2014-12-17 |
CN104209003B true CN104209003B (zh) | 2016-07-06 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109942005B (zh) * | 2019-03-29 | 2020-09-15 | 刘禹超 | 一种硼-10同位素的工业生产方法 |
CN111389224A (zh) * | 2020-03-30 | 2020-07-10 | 辽宁鸿昊化学工业股份有限公司 | 一种蒸馏法富集硼-10同位素抗堵塔方法 |
CN111423461A (zh) * | 2020-04-01 | 2020-07-17 | 辽宁鸿昊化学工业股份有限公司 | 一种三氟化硼甲醚络合物抗水解方法 |
CN111282438B (zh) * | 2020-04-01 | 2023-08-22 | 辽宁鸿昊化学工业股份有限公司 | 一种高丰度10b同位素富集方法 |
CN114409686B (zh) * | 2022-01-27 | 2023-11-07 | 上海化工研究院有限公司 | 一种用于制备三氟化硼络合物的系统及方法 |
CN116832615B (zh) * | 2023-08-29 | 2023-11-21 | 天津天和盛新材料科技有限公司 | 一种硅同位素连续化生产工艺方法 |
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US5419887A (en) * | 1994-01-25 | 1995-05-30 | Research & Development Institute, Inc. | Separation of the isotopes of boron by chemical exchange reactions |
CN100457240C (zh) * | 2006-04-18 | 2009-02-04 | 天津大学 | 三塔串联单塔累积全回流批采交替操作分离硼-10的方法 |
CN101502758A (zh) * | 2009-03-23 | 2009-08-12 | 大连泰瑞化学工业有限公司 | 用异径塔分离硼-10同位素的方法 |
CN102773016A (zh) * | 2012-07-06 | 2012-11-14 | 天津大学 | 多塔串联分离生产富集硼-10的方法及装置 |
CN103950950B (zh) * | 2014-05-20 | 2015-11-11 | 方治文 | 高丰度硼-11酸的制备方法 |
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