Improve boron doped p-type monocrystalline silicon battery photo attenuation device and using method thereof
Technical field
The present invention relates to one and improve boron doped p-type monocrystalline silicon battery photo attenuation device and using method thereof, belong to technical field of solar cells.
Background technology
At present, photo attenuation (light-induceddegradation:LID) refers to the crystal silicon solar batteries phenomenon that battery efficiency declines after illumination, the most obvious in P type single crystal battery, attenuation ratio can reach the 3%-5% that compares, particularly efficient p type single crystal silicon battery, its decay can be increased to 5 ~ 7%, the IEC standard-required more than 5%, thus seriously limits its commercial applications.Current general approved explanation is owing to causing in B-O complex centre, and elimination known at present or the method reducing this decay mainly reduce B or O content in silicon chip, and gallium or indium replace B as P-type dopant, or adopts P as N-type dopant.But these methods all also exist the shortcoming that production cost increases, and are therefore unfavorable for suitability for industrialized production.Propose one in the Chinese patent of application number CN20091002812.9 and first cell piece is carried out annealing in process, and then carry out the method for illumination heating, but need 4 hours, processing time is long is not suitable for volume production, the method adopting energising heating is refer in the patent of application number CN201410022208.3 in addition, same needs 30 ~ 180min, has difficulties equally in volume production process.
Summary of the invention
Technical problem to be solved by this invention is the defect overcoming prior art, and provide one to improve boron doped p-type monocrystalline silicon battery photo attenuation device, it can effectively shorten the Battery disposal time, thus reduces costs, and realizes industrialization and produces.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: one improves boron doped p-type monocrystalline silicon battery photo attenuation device, it comprises casing, light source, probe row, heating station and power supply, and the positive pole of power supply and heating station are electrically connected, and the negative pole of power supply and probe are arranged and be electrically connected; When pending battery is placed on heating station, described light source is positioned at the top of pending battery for use in the pending battery of illumination, and probe row pressure is on the main grid of pending battery front side.
Further, described light source is at least one in LED, Halogen lamp LED and Flash lamp.
Further, described heating station is that copper material or aluminium are made.
Present invention also offers a kind of using method improving boron doped p-type monocrystalline silicon battery photo attenuation device, it comprises following steps:
A pending battery is placed on heating station and heats it by ();
(b) by probe row pressure on the main grid in the front of pending battery;
C () is opened light source and is treated treatment of battery and carry out illumination, and treat treatment of battery by power supply simultaneously and carry out being energized and add illumination a period of time;
D battery after process is cooled to room temperature by ();
E () carries out test and classify.
Further, the irradiance of described light source is 0.1kW/m
2~ 10kW/m
2.
Further, described power supply is DC constant current power supply, and the current density treating the direct current that treatment of battery applies is 10 ~ 1000mA/cm
2.
Further, in described step (c), the processing time is 0.01 ~ 60min.
After have employed technique scheme, the light source of apparatus of the present invention is mainly used in treating treatment of battery and carries out illumination, heating station is used for treating treatment of battery and heats, power supply, pending battery, heating station and probe row's formation conductive loops is used for treating treatment of battery and is energized, by combining in conjunction with illumination, energising and heating three kinds thus effectively shortening the Battery disposal time, make it to be less than 60min, thus reduce costs, realize industrialization and produce.
Accompanying drawing explanation
Fig. 1 is the structural representation improving boron doped p-type monocrystalline silicon battery photo attenuation device of the present invention.
Embodiment
In order to make content of the present invention more easily be clearly understood, below according to specific embodiment also by reference to the accompanying drawings, the present invention is further detailed explanation.
As shown in Figure 1, one improves boron doped p-type monocrystalline silicon battery photo attenuation device, and it comprises casing 6, light source 1, probe row 2, heating station 4 and power supply 5, and positive pole and the heating station 4 of power supply 5 are electrically connected, and the negative pole of power supply 5 and probe are arranged 2 and be electrically connected; When pending battery 3 is placed on heating station 4, light source 1 is positioned at the top of pending battery 3 for use in the pending battery 3 of illumination, and probe row pressure is on the main grid of pending battery front side.
Light source 1 is at least one in LED, Halogen lamp LED and Flash lamp.
Heating station 4 is made for copper material or aluminium.
The using method of this improvement boron doped p-type monocrystalline silicon battery photo attenuation device comprises following steps:
A pending battery 3 is placed on heating station 4 and heats it by ();
B probe row 2 is pressed on the main grid in the front of pending battery 3 by ();
C () is opened light source 1 and is treated treatment of battery 3 and carry out illumination, and treat treatment of battery 3 by power supply 5 simultaneously and carry out being energized and add illumination a period of time;
D battery after process is cooled to room temperature by ();
E () carries out test and classify.
The irradiance of light source 1 is 0.1kW/m
2~ 10kW/m
2.
Power supply 5 is DC constant current power supply, and the current density treating the direct current that treatment of battery 3 applies is 10 ~ 1000mA/cm
2.
In step (c), the processing time is 0.01 ~ 60min.
The heating of heating station 4 can adopt any mode of heating, as Resistant heating.
Operation principle of the present invention is as follows:
The light source 1 of apparatus of the present invention is mainly used in treating treatment of battery 3 and carries out illumination, heating station 4 heats for treating treatment of battery, power supply 5, pending battery 3, a heating station 4 and probe row 2 formation conductive loops is used for treating treatment of battery 3 and is energized, by combining in conjunction with illumination, energising and heating three kinds thus effectively shortening the Battery disposal time, make it to be less than 60min, thus reduce costs, realize industrialization and produce.
Above-described specific embodiment; technical problem, technical scheme and beneficial effect that the present invention solves are further described; be understood that; the foregoing is only specific embodiments of the invention; be not limited to the present invention; within the spirit and principles in the present invention all, any amendment made, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.