CN104194906A - Aqueous lubricant composition for processing metallic material - Google Patents
Aqueous lubricant composition for processing metallic material Download PDFInfo
- Publication number
- CN104194906A CN104194906A CN201410437665.9A CN201410437665A CN104194906A CN 104194906 A CN104194906 A CN 104194906A CN 201410437665 A CN201410437665 A CN 201410437665A CN 104194906 A CN104194906 A CN 104194906A
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- Prior art keywords
- acid
- metal
- salt
- water
- component
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- 239000000314 lubricant Substances 0.000 title claims abstract description 78
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 238000012545 processing Methods 0.000 title claims abstract description 44
- 239000007769 metal material Substances 0.000 title claims abstract description 42
- -1 boric acid ester Chemical class 0.000 claims abstract description 87
- 150000003839 salts Chemical class 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000004327 boric acid Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 239000002253 acid Substances 0.000 claims description 38
- 238000005555 metalworking Methods 0.000 claims description 33
- 229910052783 alkali metal Inorganic materials 0.000 claims description 31
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 27
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 15
- 235000010338 boric acid Nutrition 0.000 claims description 12
- 229960002645 boric acid Drugs 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 11
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 9
- 239000012964 benzotriazole Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 8
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 7
- 238000005260 corrosion Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 4
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 4
- 150000004867 thiadiazoles Chemical class 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000007669 thermal treatment Methods 0.000 claims description 3
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims description 2
- KNRLJBCKGKUPOO-UHFFFAOYSA-N 2-(6-ethylpentadecyl)propanedioic acid Chemical compound CCCCCCCCCC(CC)CCCCCC(C(O)=O)C(O)=O KNRLJBCKGKUPOO-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 claims description 2
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 claims description 2
- 229940038384 octadecane Drugs 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 238000005238 degreasing Methods 0.000 abstract description 16
- 239000004033 plastic Substances 0.000 abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052749 magnesium Inorganic materials 0.000 abstract description 5
- 239000011777 magnesium Substances 0.000 abstract description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract description 3
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 16
- 239000002585 base Substances 0.000 description 16
- 239000001103 potassium chloride Substances 0.000 description 16
- 235000011164 potassium chloride Nutrition 0.000 description 16
- 239000003513 alkali Substances 0.000 description 11
- 159000000000 sodium salts Chemical class 0.000 description 8
- 229910003002 lithium salt Inorganic materials 0.000 description 7
- 159000000002 lithium salts Chemical class 0.000 description 7
- 235000019602 lubricity Nutrition 0.000 description 7
- 239000004411 aluminium Substances 0.000 description 6
- JTZWKIGVOZOHDD-UHFFFAOYSA-N 7-ethylhexadecane Chemical compound CCCCCCCCCC(CC)CCCCCC JTZWKIGVOZOHDD-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 159000000009 barium salts Chemical class 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 159000000003 magnesium salts Chemical class 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910001069 Ti alloy Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical compound CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 150000001261 hydroxy acids Chemical group 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
- HXQHRUJXQJEGER-UHFFFAOYSA-N 1-methylbenzotriazole Chemical compound C1=CC=C2N(C)N=NC2=C1 HXQHRUJXQJEGER-UHFFFAOYSA-N 0.000 description 1
- XYHKNCXZYYTLRG-UHFFFAOYSA-N 1h-imidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1 XYHKNCXZYYTLRG-UHFFFAOYSA-N 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-M 3-Methylbutanoic acid Natural products CC(C)CC([O-])=O GWYFCOCPABKNJV-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- YTMGLVBZNZLLIF-UHFFFAOYSA-N C(C)P(O)(O)O Chemical compound C(C)P(O)(O)O YTMGLVBZNZLLIF-UHFFFAOYSA-N 0.000 description 1
- BBGQARREKZWTAT-UHFFFAOYSA-N C(CCC)P(O)(O)O Chemical compound C(CCC)P(O)(O)O BBGQARREKZWTAT-UHFFFAOYSA-N 0.000 description 1
- QKFSMXLZDRRYNC-UHFFFAOYSA-N C(CCCCC)P(O)(O)O Chemical compound C(CCCCC)P(O)(O)O QKFSMXLZDRRYNC-UHFFFAOYSA-N 0.000 description 1
- IQUXCWMIGNNXLZ-UHFFFAOYSA-N C(CCCCCCCCC)C1(N=C(SC1)OP(O)(O)=O)CCCCCCCCCC Chemical compound C(CCCCCCCCC)C1(N=C(SC1)OP(O)(O)=O)CCCCCCCCCC IQUXCWMIGNNXLZ-UHFFFAOYSA-N 0.000 description 1
- OHIQVKSVQKMXMU-UHFFFAOYSA-N C(CCCCCCCCC)C1(N=C(SC1)P(O)(O)O)CCCCCCCCCC Chemical compound C(CCCCCCCCC)C1(N=C(SC1)P(O)(O)O)CCCCCCCCCC OHIQVKSVQKMXMU-UHFFFAOYSA-N 0.000 description 1
- OHZKZLDEKHDBPI-UHFFFAOYSA-N C(CCCCCCCCC)P(O)(O)O Chemical compound C(CCCCCCCCC)P(O)(O)O OHZKZLDEKHDBPI-UHFFFAOYSA-N 0.000 description 1
- YHOKOCFZNYBCKX-UHFFFAOYSA-N C(CCCCCCCCCCC)P(O)(O)O Chemical compound C(CCCCCCCCCCC)P(O)(O)O YHOKOCFZNYBCKX-UHFFFAOYSA-N 0.000 description 1
- OXXLWOJOCLPJAE-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)P(O)(O)O Chemical compound C(CCCCCCCCCCCCCCC)P(O)(O)O OXXLWOJOCLPJAE-UHFFFAOYSA-N 0.000 description 1
- SFLOGAKKIOVVRY-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCCC)P(O)(O)O Chemical compound C(CCCCCCCCCCCCCCCCC)P(O)(O)O SFLOGAKKIOVVRY-UHFFFAOYSA-N 0.000 description 1
- GFMYEVPBEJFZHH-UHFFFAOYSA-N CP(O)(O)O Chemical compound CP(O)(O)O GFMYEVPBEJFZHH-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N beta-methyl-butyric acid Natural products CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- FBCOERCPMMDNIL-UHFFFAOYSA-N bis(prop-2-enyl) hydrogen phosphate Chemical compound C=CCOP(=O)(O)OCC=C FBCOERCPMMDNIL-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- SCIGVHCNNXTQDB-UHFFFAOYSA-N decyl dihydrogen phosphate Chemical compound CCCCCCCCCCOP(O)(O)=O SCIGVHCNNXTQDB-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- WLUODQDXJNAOEQ-UHFFFAOYSA-N dibutyl(trihydroxy)-$l^{5}-phosphane Chemical compound CCCCP(O)(O)(O)CCCC WLUODQDXJNAOEQ-UHFFFAOYSA-N 0.000 description 1
- QHAUASBJFFBWMY-UHFFFAOYSA-N didecyl hydrogen phosphate Chemical compound CCCCCCCCCCOP(O)(=O)OCCCCCCCCCC QHAUASBJFFBWMY-UHFFFAOYSA-N 0.000 description 1
- CBAXKGZPFRYMIV-UHFFFAOYSA-N didecyl(trihydroxy)-$l^{5}-phosphane Chemical compound CCCCCCCCCCP(O)(O)(O)CCCCCCCCCC CBAXKGZPFRYMIV-UHFFFAOYSA-N 0.000 description 1
- JTXUVYOABGUBMX-UHFFFAOYSA-N didodecyl hydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(=O)OCCCCCCCCCCCC JTXUVYOABGUBMX-UHFFFAOYSA-N 0.000 description 1
- PTQOVJJYEBOGBW-UHFFFAOYSA-N didodecyl(trihydroxy)-$l^{5}-phosphane Chemical compound CCCCCCCCCCCCP(O)(O)(O)CCCCCCCCCCCC PTQOVJJYEBOGBW-UHFFFAOYSA-N 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
- CPUDLRLOFJLISR-UHFFFAOYSA-N diethyl(trihydroxy)-$l^{5}-phosphane Chemical compound CCP(O)(O)(O)CC CPUDLRLOFJLISR-UHFFFAOYSA-N 0.000 description 1
- NSSQXCMBLFTYKH-UHFFFAOYSA-N dihexyl(trihydroxy)-lambda5-phosphane Chemical compound CCCCCCP(O)(O)(O)CCCCCC NSSQXCMBLFTYKH-UHFFFAOYSA-N 0.000 description 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
- QVKQJEWZVQFGIY-UHFFFAOYSA-N dipropyl hydrogen phosphate Chemical compound CCCOP(O)(=O)OCCC QVKQJEWZVQFGIY-UHFFFAOYSA-N 0.000 description 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CAAULPUQFIIOTL-UHFFFAOYSA-N methyl dihydrogen phosphate Chemical compound COP(O)(O)=O CAAULPUQFIIOTL-UHFFFAOYSA-N 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- GMTCPFCMAHMEMT-UHFFFAOYSA-N n-decyldecan-1-amine Chemical compound CCCCCCCCCCNCCCCCCCCCC GMTCPFCMAHMEMT-UHFFFAOYSA-N 0.000 description 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- CMSWHGFRLICZCA-UHFFFAOYSA-N trihydroxy(dimethyl)-$l^{5}-phosphane Chemical compound CP(C)(O)(O)O CMSWHGFRLICZCA-UHFFFAOYSA-N 0.000 description 1
- NHKGNFMVYVLYHW-UHFFFAOYSA-N trihydroxy(dioctyl)-$l^{5}-phosphane Chemical compound CCCCCCCCP(O)(O)(O)CCCCCCCC NHKGNFMVYVLYHW-UHFFFAOYSA-N 0.000 description 1
- XXYFVMZNUFEQAI-UHFFFAOYSA-N trihydroxy(dipropyl)-$l^{5}-phosphane Chemical compound CCCP(O)(O)(O)CCC XXYFVMZNUFEQAI-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21J—FORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
- B21J3/00—Lubricating during forging or pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/201—Work-pieces; preparation of the work-pieces, e.g. lubricating, coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/18—Lubricating, e.g. lubricating tool and workpiece simultaneously
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0239—Lubricating
- B21B45/0242—Lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/085—Phosphorus oxides, acids or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
- C10M2213/062—Polytetrafluoroethylene [PTFE]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/042—Metal salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Forging (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Mounting, Exchange, And Manufacturing Of Dies (AREA)
Abstract
The present invention relates to an aqueous lubricant composition for processing a metallic material. It discloses an aqueous lubricant composition for metal material working which is excellent in workability, degreasing property and working condition. The aqueous lubricant composition is suitably used in the field of plastic working, particularly in warm press forming of various metal materials, particularly magnesium-based or aluminum-based nonferrous metal materials. The aqueous lubricant composition for processing metallic materials comprises a solid lubricant, (B) at least one member selected from the group consisting of (i) an organic metal carboxylate and (ii) a metal salt of an organic phosphoric acid ester or boric acid ester, and if necessary, (C) a nitrogen-containing compound.
Description
The application is that application number is the dividing an application of PCT application in 200580009714.8 (international filing date is on March 29th, 2005), denomination of invention country's stage that enters that is " aqueous lubricant composition for metal material working ".
Technical field
The present invention relates to Water-based Lubricant for Metal Working composition and adopt this water-based lubricant composition to produce the method for the metallic substance of temperature and pressure processing.More particularly, the present invention relates to such Water-based Lubricant for Metal Working composition, it has excellent machining property, degreasing performance, processing environment etc., and be preferably used for plastic working field, be particularly preferred for various metallic substance, specifically, the temperature and pressure manufacture field of magnesium base or aluminium base non-ferrous metal material, and relate to the method that adopts this water-based lubricant composition to produce efficiently the metallic substance of temperature and pressure processing.
Background technology
Therefore the plastic working that, lubricant is used to metal is to reach following purpose: reduce the friction between metallic substance and instrument or mould; Make metal plastic deformation carry out more steadily; And promotion instrument or mould cooling and it is shielded and the disengaging of metallic substance from instrument or mould.
Meanwhile, because magnesium alloy is alloy the lightest in the middle of practical metal and have excellent properties as electromagnetic wave shielding performance thereby be used widely in recent years.Magnesium alloy is at present mainly by die casting with touch and to melt molding and process, but points out, this kind of processing technology requires after processing, to carry out surface finish, and this kind of processing technology almost cannot be applied to thin-wall product.
And using after magnesium alloy plate can be applied to thin-wall product and not require processing as the press working of material to be processed, carry out surface finish., magnesium alloy is very poor in processability at normal temperatures, therefore generally the temperature of 200～300 ℃, carries out press working.During press working, suppress the fracture that oily lubricity deficiency can cause machined material, its adhesion on mould or like that.Therefore, press working adopts special lubricant.
As mentioned above, the lubricant that the plastic working of magnesium alloy plate is used must have, in warm temperature, generally between the temperature range of 100 ℃～300 ℃, the lubricity that suppresses machined material fracture and adhere on mould, just can show high working property energy, and must remove by general degreasing method.
Solid-film lubricant has been applied to the temperature processing of magnesium alloy plate at present.Yet this kind of working condition requirement implemented striping and processed after processing, and can not implement simple skimming treatment.Therefore, productivity inevitably declines.
Meanwhile, there is environmental problem in oil lubricant, because die temperature is during pressing elevated to approximately 300 ℃, causes oil smoke, very poor in processability, and may cause manufacturing deficiency or crackle.Visible, oil lubricant exists the problem that runs into all difficulties in application.
For example, JP2003-89797A discloses a kind of plastic working lubricant of magnesium alloy, it has excellent degreasing performance and can prevent that processing environment from worsening, by a kind of aqueous solution, formed, the alkaline earth salt of an alkali metal salt that this solution contains 7～20wt%10～18 carbon atom fatty acid, 2～6wt%12～18 carbon atom fatty acid, and specified quantity provides the alkali metal hydroxide of 12～14 pH value.Yet this magnesium alloy lubricant for plastic working, not containing solid lubricant, therefore differs sufficient plastic working is provided surely.
Summary of the invention
In such cases, the object of this invention is to provide a kind of Water-based Lubricant for Metal Working composition, it has excellent machining property, degreasing performance, processing environment etc., and be preferably used for plastic working field, particularly preferably in various metallic substance, the temperature and pressure manufacture field of magnesium base or aluminium base non-ferrous metal material particularly; And adopt this water-based lubricant composition to produce the method for temperature and pressure processing metallic.
The inventor conducts in-depth research and finds for reaching above object, the aqueous composition that contains solid lubricant and specific compound can reach the object as Water-based Lubricant for Metal Working composition, and the metallic substance of temperature and pressure processing can be by being applied to above-described composition metal material surface to be processed and this metallic substance to be processed being implemented pressing treatment and produced efficiently.The inventor has completed of the present invention based on these discoveries exactly.
In other words, the invention provides following (1)～(15).
(1) a Water-based Lubricant for Metal Working composition, it comprises solid lubricant as component (A); And at least one metal-salt is as component (B), the latter is selected from the metal-salt (i) of organic carboxyl acid and the metal-salt (ii) of organophosphate or organic boric acid ester.
(2), with the Water-based Lubricant for Metal Working composition of begin a project (1), also comprise that nitrogenous compound is as component (C).
(3) with the Water-based Lubricant for Metal Working composition of begin a project (1) or (2), wherein the solid lubricant as component (A) is at least one powder, is selected from tetrafluoroethylene, calcium carbonate, zinc oxide, molybdenumdisulphide and graphite.
(4) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(3), wherein the metal salt of organic carboxylic acid (i) of component (B) is at least one metal-salt, be selected from monocarboxylic an alkali metal salt and alkaline earth salt, and polycarboxylic an alkali metal salt and alkaline earth salt.
(5) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(3), wherein the metal-salt (ii) of the organophosphate of component (B) or organic boric acid ester is at least one metal-salt, be selected from an alkali metal salt and the alkaline earth salt of phosphoric acid or phosphorous acid, and an alkali metal salt of ortho-boric acid and alkaline earth salt.
(6) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(5), wherein the nitrogenous compound as component (C) is that at least one is selected from benzotriazole, thiadiazoles, amine, acid amides and imido compound.
(7) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(6), also comprise at least one additive as component (D), be selected from corrosion inhibitor, antioxidant, sterilant and defoamer.
(8), with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(7), wherein component (A) is 10:90～95:5 with the ratio of the content of component (B), in mass ratio.
(9) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(8), wherein water-content is 10～50wt%.
(10) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(9), it has the pH value between 3～12.
(11) with any one Water-based Lubricant for Metal Working composition in begin a project (1)～(10), it for temperature and pressure processing, cold presswork, forging process, roll, thin, crooked, element rolling or calendering.
(12) with the Water-based Lubricant for Metal Working composition of begin a project (11), it is for the temperature and pressure processing of non-ferrous metal material.
(13) with any one Water-based Lubricant for Metal Working composition in begin a project (11) or (12), wherein non-ferrous metal material is magnesium alloy.
(14) produce a method for the metallic substance of temperature and pressure processing, comprise and will be applied on metal material surface to be processed with the lubricant compositions of any one in begin a project (1)～(10); By thermal treatment evaporating off water; And treat processing metallic and implement pressing treatment.
(15) method of the metallic substance of processing with the production temperature and pressure of begin a project (14), the water being wherein applied in the lubricant compositions on metal material surface to be processed evaporates on heating compacting tool set; And treat on the spot processing metallic and implement pressing treatment.
The invention provides a kind of Water-based Lubricant for Metal Working composition, it has excellent machining property, degreasing performance, processing environment and the like, and be preferably used for plastic working field, particularly preferably in various metallic substance, particularly in the processing of the temperature and pressure of magnesium base or aluminium base non-ferrous metal material.
In addition, according to the inventive method, owing to adopting this lubricant compositions, can produce efficiently the metallic substance of temperature and pressure processing.
the preferred forms of invention
Water-based Lubricant for Metal Working composition of the present invention is such aqueous composition, and it comprises solid lubricant as component (A); At least one metal-salt is as component (B), and the latter is selected from the metal-salt (i) of organic carboxyl acid and the metal-salt (ii) of organic phosphoric acid or organic boric acid ester; Nitrogenous compound is as component (C) and/or at least one additive as component (D), and the latter, as requested, is selected from corrosion inhibitor, antioxidant, sterilant and defoamer; And water medium.
The example of the solid lubricant of the component in lubricant compositions of the present invention (A) comprises powder, for example, and tetrafluoroethylene, calcium carbonate, zinc oxide, molybdenumdisulphide or graphite.Can use separately a kind of types of powders, or the combination of use 2 or more kinds of type powder.Consideration based on processing environment, non-black powder than black powder as molybdenumdisulphide or graphite more preferably, and tetrafluoroethylene (Teflon) powder, from the viewpoint of processing environment, lubricity etc., particularly preferably.The mean particle size of solid lubricant powder, but generally between approximately 0.1～20 μ m, preferably 0.2～7 μ m, considers from viewpoints such as dispersiveness, lubricities.The example of tetrafluoroethylene (Teflon) powder is a kind of product " LUBRONL-2 " (trade(brand)name is manufactured by Daikin industrial) of available commercial.
The content of component (A), preferably between 5～80wt%, for the total amount of composition, is considered from the angle of lubricity.
Meanwhile, the metal-salt (i) of the organic carboxyl acid of component (B) has the function of giving degreasing performance, can use monocarboxylic acid or polycarboxylic an alkali metal salt and alkaline earth salt.A kind of types of metals salt that can be used alone, or can by 2 or more kinds of type be used in combination.
The example of an alkali metal salt comprises sodium salt, sylvite and lithium salts.The example of alkaline earth salt comprises calcium salt, barium salt and magnesium salts.
In the metal-salt of organic carboxyl acid, the hydrocarbyl group except hydroxy-acid group preferably contains 17 or carbon atom still less, and more preferably 12 or each hydroxy-acid group of carbon atom still less, from the angle of degreasing performance, consider.The example of hydrocarbyl group comprises alkyl group, kiki alkenyl group, aromatic yl group and aromatic alkyl group.In the middle of these, alkyl group and kiki alkenyl group are preferred.Alkyl group and kiki alkenyl group can be line style, branching or ring-type.From the angle of degreasing performance, consider, an alkali metal salt than alkaline-earth metal more preferably.
The example of the metal-salt of organic carboxyl acid (for example comprises sour an alkali metal salt, sodium salt, sylvite or lithium salts): aliphatic monocarboxylic acid's (acetic acid for example, propionic acid, lactic acid, different lactic acid, valeric acid, isovaleric acid, PIVALIC ACID CRUDE (25), caproic acid, enanthic acid, sad, 2 ethyl hexanoic acid, capric acid, lauric acid, tetradecanoic acid, palmitinic acid, stearic acid, vinylformic acid, methacrylic acid, β-crotonic acid, octylenic acid, decylenic acid or oleic acid) or aliphatic polycarboxylic acid (for example, oxalic acid, propanedioic acid, succsinic acid, pentanedioic acid, hexanodioic acid, pimelic acid, suberic acid, sebacic acid, dodecanedioic acid, tetradecane diacid, Thapsic acid, octadecane diacid, 7-ethyl hexadecane dicarboxylic acid or BTCA), and their alkaline earth salt (for example, calcium salt, barium salt or magnesium salts).In the middle of these, an alkali metal salt is preferred.
When adopting an alkali metal salt (i) as component (B), organic carboxyl acid and alkali-metal mol ratio are preferably between 0.5:1～1:0.5.
The metal-salt (ii) of the organic phosphoric acid of component (B) or organic boric acid ester has the function of giving degreasing performance.Can use an alkali metal salt or the alkaline earth salt of phosphoric acid or phosphorous acid (phosphonic acids) ester, an alkali metal salt of ortho-boric acid ester or alkaline earth salt and the like.A kind of types of metals salt or the combination of use 2 or more kinds of types can be used alone.
The example of an alkali metal salt comprises sodium salt, sylvite and lithium salts.The example of alkaline earth salt comprises calcium salt, barium salt and magnesium salts.
The example that forms the hydrocarbyl group of ester comprises alkyl group, kiki alkenyl group, aromatic yl group and aromatic alkyl group, and each preferably altogether has and is equal to or less than 32 carbon atoms, is more preferably equal to or less than 24 carbon atoms.In the middle of these, alkyl group and kiki alkenyl group are preferred.This alkyl group and kiki alkenyl group can be line style, branching or ring-type.From the angle of degreasing performance, consider, an alkali metal salt than alkaline earth salt more preferably.
The example of the metal-salt of phosphoric acid ester comprises: sodium salt, sylvite or the lithium salts of dialkyl group or two alkenyl phosphoric acid ester (for example, dimethyl phosphoric acid, diethyl phosphoric acid, dipropyl phosphoric acid, dibutylphosphoric acid, DHP dihexylphosphoric acid, dioctyl phosphoric acid, didecyl phosphoric acid, dilauryl phosphoric acid, diallyl phosphoric acid, two octenyl phosphoric acid or didecyl thiazolinyl phosphoric acid); The ester of one alkyl or an alkenyl phosphoric acid (for example, monomethyl phosphoric acid, an ethyl phosphonic acid, a propyl group phosphoric acid, monobutyl phosphoric acid, a hexyl phosphoric acid, an octyl group phosphoric acid, a decyl phosphoric acid, a lauryl phosphoric acid, a palmityl phosphoric acid, a stearyl phosphoric acid, an allyl group phosphoric acid, an octenyl phosphoric acid, a decene base phosphoric acid or an oil base phosphoric acid) a sodium salt, a sylvite or a lithium salts, for example, an alkyl or alkenyl phosphoric acid hydrogen one an alkali metal salt; And disodium salt, di-potassium or the dilithium salt of alkyl or an alkenyl phosphoric acid ester, for example, an alkyl or an alkenyl di(2-ethylhexyl)phosphate an alkali metal salt.
The example of the metal-salt of phosphorous acid ester (phosphorusester) comprising: sodium salt, sylvite or the lithium salts of dialkyl group or two alkenyl phosphorous acid esters (for example, dimethyl phosphorous acid, diethyl phosphorous acid, dipropyl phosphorous acid, dibutyl phosphorous acid, dihexyl phosphorous acid, dioctyl phosphorous acid, didecyl phosphorous acid, dilauryl phosphorous acid, diallyl phosphorous acid, two octenyl phosphorous acid or didecyl thiazolinyl phosphorous acid); One alkyl or an alkenyl phosphorous acid ester are (for example, monomethyl phosphorous acid, an ethyl phosphorous acid, a propyl group phosphorous acid, monobutyl phosphorous acid, a hexyl phosphorous acid, an octyl group phosphorous acid, a decyl phosphorous acid, a lauryl phosphorous acid, a palmityl phosphorous acid, a stearyl phosphorous acid, an allyl group phosphorous acid, an octenyl phosphorous acid, a decene base phosphorous acid or an oil base phosphorous acid) a sodium salt, a sylvite or a lithium salts, for example, an alkyl or alkenyl hydrogen phosphite one an alkali metal salt; And disodium salt, di-potassium or the dilithium salt of alkyl or an alkenyl phosphorous acid ester, for example, two an alkali metal salts of an alkyl or an alkenyl phosphorous acid (ester).
The example of the metal-salt of ortho-boric acid ester comprises: the various an alkali metal salts of dialkyl group or two alkenyl ortho-boric acid esters; And various two an alkali metal salts or an an alkali metal salt of alkyl or an alkenyl ortho-boric acid ester.
When an alkali metal salt (ii) is used as component (B), the mol ratio between phosphoric acid ester, phosphorous acid ester or ortho-boric acid ester (acid) and basic metal is preferably between 0.5:1～1:0.5.
With regard to the present composition, an alkali metal salt (i) or an alkali metal salt (ii) can be used independently or with the form of the appropriate combination between each component.Component (A) is with the ratio of component (B) content preferably between 10:90～95:5, and more preferably 15:85～95:5, counts in mass ratio, from lubricity (processibility), degreasing performance equal angles, considers.
Nitrogenous compound as component (C) has the function of giving corrosion resistance nature, can use benzotriazole, thiadiazoles, amine, acid amides etc.Can be used alone a kind of type compound or with its 2 or more kinds of being used in combination.
The example of benzotriazole comprises benzotriazole, N-dialkyl amino methyl isophthalic acid, 2,3-benzotriazole and N-Methylbenzotriazole.The example of thiadiazoles comprises: two (the n-nonyl dithio)-1,3 of 2,5-, 4-thiadiazoles; With two (1,1,3, the 3-tetramethyl butyl dithio)-1,3 of 2,5-, 4-thiadiazoles.
The example of amine comprises primary, secondary or tertiary alkylamine or alkenyl amine and Cycloalkyl amine.Its concrete example comprises butylamine, dibutylamine, tributylamine, hexyl amine, dihexyl amine, three hexyl amines, cyclo-hexylamine, dicyclohexylamine, thricyclohexyl amine, octyl amine, dioctylamine, trioctylphosphine amine, decyl amine, didecylamine, three decyl amine, lauryl amine, dilauryl amine, three lauryl amines, palmityl amine, two palmityl amines, three palmityl amines, stearic amine, distearyl amine, three stearic amines, oil base amine, two oil base amine and three oil base amine.
The example of acid amides comprises dioctyl acid amides and N-oil base sarkosine.Imido example comprises polybutylene-based succinimide.In the middle of these, benzotriazole and amine are preferred, and benzotriazole and dioctylamine are particularly preferred.
The content of component (C) is preferably between 0.1～10wt%, and more preferably 0.5～5wt%, for the total amount of said composition, considers from erosion resistance and efficiency.
The present composition can optionally contain, and as component (D), metal processing is used, the normally used various additives of traditional water-based lubricant composition, for example, as requested, corrosion inhibitor, antioxidant, sterilant and defoamer.
The pH value of the present composition preferably, in 3～12 scope, more preferably 6～10, is considered from viewpoints such as processibility, degreasing performances.Water-content is preferably between 10～50wt%, more preferably within the scope of 15～40wt%, for the total amount of composition.The water-content being adjusted in above scope can be formed on lubricant film appropriate on lubricated surface, and favourable lubricity and favourable operability are provided.
Lubricant compositions of the present invention can be used for plastic working field, for example, and temperature and pressure processing, cold presswork, forging processing, calendering, ironing, bending, element rolling or calendering.Material to be processed can adopt various metals or its alloy, for example, and steel, stainless steel, magnesium alloy, aluminium, aluminium alloy, titanium, titanium alloy and copper.
Lubricant compositions of the present invention is preferred for, non-ferrous metal material especially, for example, the processing of the temperature and pressure of magnesium alloy, aluminium, aluminium alloy, titanium, titanium alloy or copper.
The invention provides a kind of method of producing temperature and pressure processing metallic, comprise lubricant compositions of the present invention is applied on metal material surface to be processed; By thermal treatment evaporating off water; And treat processing metallic and implement pressing treatment.
In the method for mentioning in the above, the water being applied in the lubricant compositions that metal material surface gets on can evaporate in the compacting tool set of heating, then treats on the spot processing metallic and implements pressing treatment.
Embodiment
Below, in connection with embodiment, describe in more detail the present invention, but the present invention is not limited to these embodiment from any sense.
The performance of lubricant compositions is assessed by described program below.
(1) oilness
(a) degree of depth calenderability test
Degree of depth calenderability test, the magnesium alloy plate that adopts thick 1mm carries out under the condition of 250 ℃ of cavity rate 10mm/s, punching press diameter 32mm, mould diameter 34.4mm and temperature, the defect that detects by an unaided eye and crackle.
(b) Bowden test
Bowden test adopts magnesium alloy plate to carry out under the temperature condition of SUJ2 steel ball (3/16 inch (4.8mm)), the load of 49N, the sleeve distance of the speed of 20mm/s, 50mm and 200 ℃, to determine frictional coefficient.
(2) degreasing performance
Sample paint magnesium alloy plate (80mmx60mm) is upper, and whole assembly is dry 5min at 200 ℃.Then, the assembly of acquisition washes 10min with water, and the area percentage of definite non-fat portion.
(3) processing environment
AA representative does not cause the processing property problem of lubricant compositions or by the situation of the contamination of machine periphery.CC representative causes the situation of this respect problem.
(4) anti-corrosion test
Sample is lubricated to magnesium alloy plate, then implements exposure test and in sheet surface, whether has corrosion with after assessing 1 month.
Embodiment 1～11, and comparative example 1～3
Prepare every kind of lubricant compositions that its composition is loaded in table 1 and 2 for use in assessed for performance.Table 1 and 2 shows result.
(note)
A-1:Teflon powder (LUBRONL-2, Daikin industrial manufactures, mean particle size is equal to or less than 5 μ m)
A-2: calcium carbonate
A-3: zinc oxide
A-4: molybdenumdisulphide
A-5: graphite
(the acid: the mol ratio=1:0.9 of alkali) of i-1:7-ethyl hexadecane dicarboxylic acid sylvite
I-2: the sodium salt of capric acid (acid: the mol ratio=1:0.9 of alkali)
(the acid: the mol ratio=1:0.9 of alkali) of the sylvite of i-3 palmitinic acid
I-4: the sylvite of oleic acid (acid: the mol ratio=1:0.9 of alkali)
Table 1 shows, because embodiment 7 and 8 adopts respectively molybdenumdisulphide and graphite as component (A), therefore they show bad processing environment.Table 2 demonstration, embodiment 10 and 11 is used the lipid acid of many carbonatomss separately, therefore they have bad degreasing performance.Comparative example 4 causes white cigarette, because have mist of oil and show disaster on fire.
Embodiment 12～21
Prepare each composition lubricant compositions as shown in Tables 3 and 4 for assessment of performance.Table 3 and 4 shows result.
(note)
(the acid: the mol ratio=1:0.5 of alkali) of i-5:7-ethyl hexadecane dicarboxylic acid sylvite
(the acid: the mol ratio=1:0.7 of alkali) of i-6:7-ethyl hexadecane dicarboxylic acid sylvite
(the acid: the mol ratio=1:1.3 of alkali) of i-7:7-ethyl hexadecane dicarboxylic acid sylvite
(the acid: the mol ratio=1:1.15 of alkali) of i-8:7-ethyl hexadecane dicarboxylic acid sylvite
Ii-1: single, (the acid: the mol ratio=1:0.9 of alkali) of dioctyl potassium phosphate salt
Ii-2: the sylvite of phosphoric acid one Lauryl Ester (acid: the mol ratio=1:0.9 of alkali)
Ii-3: the sylvite of phosphoric acid monobutyl ester (acid: the mol ratio=1:0.9 of alkali)
C-1: benzotriazole
C-2: dioctylamine
The same with table 1 and 2 of the definition of A-1～A-5 and i-1～i-4.
industrial application
Water-based Lubricant for Metal Working composition of the present invention has excellent machining property, degreasing performance and processing environment etc. and is preferably used for plastic working field, particularly at various metallic substance, the temperature and pressure manufacture field of magnesium base or aluminium base non-ferrous metal material especially.
Claims (16)
1. a Water-based Lubricant for Metal Working composition, it is for the temperature and pressure processing of non-ferrous metal material, and comprise solid lubricant as component (A), metal-salt is as component (B), and the water of 10～50wt%, wherein said metal-salt is the metal-salt (i) of organic carboxyl acid, or the metal-salt (ii) of the metal-salt of organic carboxyl acid (i) and organophosphate or organic boric acid ester, above-mentioned organic carboxyl acid is for being selected from oxalic acid, propanedioic acid, succsinic acid, pentanedioic acid, hexanodioic acid, pimelic acid, suberic acid, sebacic acid, dodecanedioic acid, tetradecane diacid, Thapsic acid, octadecane diacid, aliphatic polycarboxylic acid in 7-ethyl hexadecane dicarboxylic acid and BTCA, and described non-ferrous metal material is magnesium alloy.
2. the Water-based Lubricant for Metal Working composition of claim 1, also comprises that nitrogenous compound is as component (C).
3. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein as the solid lubricant of component (A) by least one powder constituent, described powder is selected from this group of tetrafluoroethylene, calcium carbonate, zinc oxide, molybdenumdisulphide and graphite.
4. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein the metal salt of organic carboxylic acid (i) of component (B) is comprised of at least one metal-salt, and it is selected from polycarboxylic an alkali metal salt and alkaline earth salt.
5. the Water-based Lubricant for Metal Working composition of claim 4, wherein the metal salt of organic carboxylic acid (i) of component (B) is polycarboxylic an alkali metal salt, organic carboxyl acid and alkali-metal mol ratio are in the scope of 0.5:1～1:0.5.
6. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein the alkyl except carboxyl of the metal salt of organic carboxylic acid (i) of component (B) is alkyl or the alkenyl of branching.
7. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein the metal-salt (ii) of the organophosphate of component (B) or organic boric acid ester is comprised of at least one metal-salt, it is selected from an alkali metal salt and the alkaline earth salt of phosphoric acid or phosphorous acid, and an alkali metal salt of ortho-boric acid and alkaline earth salt.
8. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein comprise at least one as the nitrogenous compound of component (C) and be selected from benzotriazole, thiadiazoles, amine, acid amides and imido compound.
9. claim 1 or 2 Water-based Lubricant for Metal Working composition, wherein the content as component (C) is 0.1～10wt%.
10. claim 1 or 2 Water-based Lubricant for Metal Working composition, also comprise at least one additive as component (D), and it is selected from corrosion inhibitor, antioxidant, sterilant and defoamer.
11. claims 1 or 2 Water-based Lubricant for Metal Working composition, wherein component (A) is 10:90～95:5 with the ratio of the content of component (B), in mass ratio.
12. claims 1 or 2 Water-based Lubricant for Metal Working composition, it has the pH value between 3～12.
The Water-based Lubricant for Metal Working composition of 13. claims 1, it comprises component (A) solid lubricant, component (B) metal salt of organic carboxylic acid (i), and water.
14. 1 kinds of methods of producing the metallic substance of temperature and pressure processing, comprise the lubricant compositions of any one in claim 1～13 are applied on metal material surface to be processed; By thermal treatment evaporating off water; And the metallic substance that will process is carried out to pressing treatment.
The method of the metallic substance of the production temperature and pressure processing of 15. claims 11, the water being wherein applied in the lubricant compositions on metal material surface to be processed evaporates on the compacting tool set of heating; And on the spot the metallic substance that will process is carried out to pressing treatment.
The method of the metallic substance of the production temperature and pressure processing of 16. claims 14 or 15, the processing temperature of described temperature and pressure processing is between the temperature range of 100 ℃～300 ℃.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004105740A JP4880880B2 (en) | 2004-03-31 | 2004-03-31 | Lubricant composition for processing water-based metal materials |
| JP2004-105740 | 2004-03-31 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800097148A Division CN1938411A (en) | 2004-03-31 | 2005-03-29 | Aqueous lubricant composition for processing metallic material |
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| CN104194906A true CN104194906A (en) | 2014-12-10 |
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| CN201410437665.9A Pending CN104194906A (en) | 2004-03-31 | 2005-03-29 | Aqueous lubricant composition for processing metallic material |
| CNA2005800097148A Pending CN1938411A (en) | 2004-03-31 | 2005-03-29 | Aqueous lubricant composition for processing metallic material |
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| JP (1) | JP4880880B2 (en) |
| CN (2) | CN104194906A (en) |
| MY (1) | MY176897A (en) |
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| WO (1) | WO2005095564A1 (en) |
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| CN107532109A (en) * | 2015-05-15 | 2018-01-02 | 日本帕卡濑精株式会社 | Water-based lubricant, metal material and metal work |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP4828498B2 (en) * | 2007-10-02 | 2011-11-30 | トヨタ紡織株式会社 | Lubricating oil evaluation method and die for lubricating oil evaluation |
| ES2731903T3 (en) * | 2009-06-29 | 2019-11-19 | Nihon Parkerizing | Water-based lubricant for plastic processing that has excellent corrosion resistance and metal material that has excellent plastic workability |
| JP2013209625A (en) * | 2012-02-27 | 2013-10-10 | Kobe Steel Ltd | Water-soluble lubricating agent for plastic working, metal material for plastic working, and worked metal article |
| CN102703171B (en) * | 2012-05-16 | 2014-02-19 | 沧州华海炼油化工有限责任公司 | Aluminum material rolling oil additive and preparation method thereof |
| CN103509640A (en) * | 2012-06-26 | 2014-01-15 | 江南大学 | Water-based lubricant containing MoS2 and preparation method thereof |
| CN103666662A (en) * | 2012-09-24 | 2014-03-26 | 天津博克尼科技发展有限公司 | Waste oil prepared lubricating oil for metal pressure process |
| CN103480650A (en) * | 2013-10-09 | 2014-01-01 | 重庆市科学技术研究院 | Magnesium alloy sheet rolling technology |
| CN104560303B (en) * | 2014-12-17 | 2017-08-01 | 宁波蓝润能源科技股份有限公司 | Nano metal processing oil and preparation method thereof |
| CN105754698A (en) * | 2016-03-11 | 2016-07-13 | 东莞市纳晟润滑油科技有限公司 | Water-soluble magnesium alloy machining fluid |
| CN107384567B (en) * | 2017-08-15 | 2020-12-04 | 广州杜朗介质科技有限公司 | High-performance water-based lubricating oil for copper-zinc alloy cold stamping |
| JP2020180179A (en) * | 2019-04-23 | 2020-11-05 | ユシロ化学工業株式会社 | Lubricant for warm or hot forging |
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| JP2920218B2 (en) * | 1990-03-14 | 1999-07-19 | 大同化学工業株式会社 | Water-soluble hot lubricant composition |
| JPH0873883A (en) * | 1994-08-31 | 1996-03-19 | Sky Alum Co Ltd | Lubricating material for hot working of aluminum material |
| JPH1088171A (en) * | 1996-09-18 | 1998-04-07 | Yushiro Chem Ind Co Ltd | Water-soluble lubricant stock solution for capping |
| JPH10316989A (en) * | 1997-03-18 | 1998-12-02 | Kyodo Yushi Kk | Water-dispersion-type lubricant for plastic working |
| JPH11158485A (en) * | 1997-11-26 | 1999-06-15 | Sky Alum Co Ltd | Lubricating release agent for superplastic molding |
| JP2000144167A (en) * | 1998-11-05 | 2000-05-26 | Asahi Denka Kogyo Kk | Aqueous lubricating composition |
| JP2001081495A (en) * | 1999-09-17 | 2001-03-27 | Yuukou Shoji Kk | Aqueous lubricant for plastic working of metal |
| TW587096B (en) * | 2000-08-11 | 2004-05-11 | Nihon Parkerizing | Greases component containing in aqueous composition for forming protective membranes |
| JP2002361302A (en) * | 2001-05-31 | 2002-12-17 | Nippon Parkerizing Co Ltd | Method for rolling metal material plate |
| JP4754125B2 (en) * | 2001-09-18 | 2011-08-24 | コスモ石油ルブリカンツ株式会社 | Plastic processing lubricant for magnesium alloy |
| JP2003193088A (en) * | 2001-12-26 | 2003-07-09 | Kansai Paint Co Ltd | Surface-finishing composition for metallic material |
| JP2003253290A (en) * | 2002-02-27 | 2003-09-10 | Yushiro Chem Ind Co Ltd | Water-based lubricating oil composition for plastically working non-ferrous metal |
| JP3967692B2 (en) * | 2002-05-23 | 2007-08-29 | 三洋化成工業株式会社 | Lubricant for metal processing |
| JP4110378B2 (en) * | 2002-07-23 | 2008-07-02 | 株式会社カサタニ | Lubricant for warm plastic working of magnesium and magnesium alloy and processing method using the lubricant |
| JP4456817B2 (en) * | 2003-02-03 | 2010-04-28 | 本田技研工業株式会社 | Water-soluble metal processing lubricant |
-
2004
- 2004-03-31 JP JP2004105740A patent/JP4880880B2/en not_active Expired - Fee Related
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2005
- 2005-03-29 WO PCT/JP2005/005933 patent/WO2005095564A1/en active Application Filing
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| CN107532109A (en) * | 2015-05-15 | 2018-01-02 | 日本帕卡濑精株式会社 | Water-based lubricant, metal material and metal work |
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| Publication number | Publication date |
|---|---|
| CN1938411A (en) | 2007-03-28 |
| JP4880880B2 (en) | 2012-02-22 |
| JP2005290154A (en) | 2005-10-20 |
| MY176897A (en) | 2020-08-26 |
| TW200536934A (en) | 2005-11-16 |
| WO2005095564A1 (en) | 2005-10-13 |
| TWI354019B (en) | 2011-12-11 |
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Application publication date: 20141210 |