1354019 (1) 九、發明說明 【發明所屬之技術領域】 本發明係關於一種金屬處理用水基潤滑劑組成物，及 關於一種採用此水基潤滑劑組成物以製造溫壓處理的金屬 材料之方法。本發明更明確係關於金屬處理用水基潤滑劑 組成物，其具有優異的可處理性、除油脂特性、操作環境 與類似者，且較佳使用於塑性處理領域、特別是較佳用於 # 各種金屬材料的溫壓處理領域，更明確而言，用於鎂基或 鋁基之非鐵金屬材料，及關於一種採用此水基潤滑劑組成 物以有效地製造經溫壓處理的金屬材料之方法。 【先前技術】 迄今用於金屬的塑性處理之潤滑劑，其用途有：降低 金屬材料及工具或模具之間的摩擦；讓金屬的塑性變形更 順利；及促進工具或模具的冷卻與保護，並讓金屬材料自 # 工具或模具中釋出。 同時，近來廣泛使用鎂合金，因爲在實用的金屬中， 鎂合金是最輕的合金，並具有諸如電磁波遮蔽特性的優異 特性。最近鎂合金主要以壓鑄及觸變成型 (thixomolding )處理，但已指出該處理技術在處理後需 要表面拋光，且該處理技術難以施用於薄壁的產品。 同時，採用鎂合金薄片作爲待處理材料的壓製處理可 施用於薄壁的產品，且在處理後不需要表面拋光。然而， 鎂合金在一般溫度下的可處理性不佳，因此通常在200至 -5- (2) 1354019 300 °C的溫度下進行壓製處理。壓製油在壓製處理期間的 潤滑成效若不足，會導致待處理的材料斷裂、其與模具黏 結、或類似情況。因此，壓製處理要使用專用的潤滑劑。 如上所述，用於鎂合金薄片的塑性處理之潤滑劑在一 般自10(TC至300 °c溫度範圍內的溫熱溫度下，必須具有 抑制待處理材料之斷裂及其與模具黏結的潤滑性能，以展 現高的處理性能，且必須能以一般的除油脂程序去除。 φ 固體膜潤滑劑迄今已使用於鎂合金薄片的溫熱處理。 然而，此情況需要在處理後進行除膜處理，且無法進行簡 單的除油脂處理。因此，不可避免地降低了生產力。 同時，油基潤滑劑具有環境問題，因爲在壓製期間模 具的溫度增加至約3 OOt，會導致油霧，處理性不佳，且 可能導致操作的裂隙或裂縫。因此，油基潤滑劑在使用上 具有困難度的問題。 例如，JP 2003-89797A揭示一種用於鎂合金的塑性處 # 理之潤滑劑，其具有優異的除油脂特性且可防止操作環境 的惡化，其係由含有7至20質量％之具1〇至18個碳原子 脂肪酸的鹼金屬鹽、2至6質量％之具12至18個碳原子 脂肪酸的鹼土金屬鹽、及提供pH爲12至14的預定量之 鹼金屬氫氧化物之基溶液所構成。然而’該用於鎂合金的 塑性處理之潤滑劑不含固體潤滑劑’因此不一定提供足夠 的塑性可處理性。 【發明內容】 -6 - (3) 1354019 在此情形下，本發明的目標係提供一種金屬處理用水 '基潤滑劑組成物，其具有優異的可處理性、除油脂特性、 操作環境與類似者，且較佳使用於塑性處理領域、特別是 較佳用於各種金屬材料的溫壓處理領域，更明確而言，用 於鎂基或鋁基之非鐵金屬材料，及提供一種採用此水基潤 滑劑組成物以製造經溫壓處理的金屬材料之方法。 本發明的發明者已進行深入的的硏究，以達成上述目 φ 標，且已發現含有固體潤滑劑及特定化合物的水基組成物 可達成作爲用於金屬處理的水基潤滑劑組成物的目標；且 將上述的組成物施加於待處理的金屬材料表面上，以熱處 理將水蒸發，且將待處理的金屬材料進行壓製處理，而可 有效地製造經溫壓處理的金屬材料。本發明的發明者已完 成以這些發現爲基礎的本發明。 亦即，本發明提供以下的（1 )至（15 )。 (1 ) 一種金屬處理用之水基潤滑劑組成物，其包含 # 固體潤滑劑作爲成分（A );以及至少一種金屬鹽作爲成 分（B)，其係選自有機羧酸的金屬鹽（i)及有機磷酸酯 或有機硼酸酯的金屬鹽（ii)。 (2 )如上述項目（1 )之金屬處理用水基潤滑劑組成 物，其進一步包含含氮化合物作爲成分（C)。 (3)如上述項目（1)或（2)之金屬處理用水基潤 滑劑組成物，其中作爲成分（A )的固體潤滑劑爲至少一 種選自包括聚四氟乙烯、碳酸鈣、氧化鋅、二硫化鉬及石 墨之群組的粉末。 (5) 1354019 用水基潤滑劑組成物’其具有PH在3至12的範圍內。 ' (11)如上述項目（1)至（10)中任一項之金屬處 理用水基潤滑劑組成物，其係用於溫壓處理、冷壓處理、 鍛造處理、拉製、壓扁、彎曲、元件輥軋或壓延。 (12) 如上述項目（11)之金屬處理用水基潤滑劑組 成物，其用於非鐵金屬材料的溫壓處理。 (13) 如上述項目（11)至（12)中之金屬處理用水 • 基潤滑劑組成物，其中非鐵金屬材料爲鎂合金。 (14) 一種製造經溫壓處理的金屬材料之方法，其包 含：將如上述項目（1)至（10)中任一項之潤滑劑組成 物施加於待處理的金屬材料表面上；以熱處理將水蒸發； 且將待處理的金屬材料進行壓製處理。 (15) 如上述項目（14)之製造經溫壓處理的金屬材 料之方法，其中施加於待處理的金屬材料表面上的潤滑劑 組成物中的水係於經加熱的壓模上蒸發；且將此待處理的 ® 金屬材料直接進行壓製處理。 依據本發明，提供金屬處理用水基潤滑劑組成物，其 具有優異的可處理性、除油脂特性、操作環境與類似者， &較佳使用於塑性處理領域、特別是較佳用於各種金屬材 Μ的溫壓處理領域，更明確而言，用於鎂基或鋁基之非鐵 金屬材料。 而且，依據本發明的方法，其採用此水基潤滑劑組成 % ’可有效地製造經溫壓處理的金屬材料。 (6) 1354019 實施本發明之最佳模式 依據本發明的金屬處理用水基潤滑劑組成物，其包含 固體潤滑劑作爲成分（A):至少一種金屬鹽作爲成分 (B)，其係選自有機羧酸的金屬鹽（i)及有機磷酸酯或 有機硼酸酯的金屬鹽（ii);含氮化合物作爲成分（C) 及/或視需要至少一種藥劑作爲成份（D)，其係選自包括 腐蝕抑制劑、抗氧化劑、殺蟲劑、及消泡劑之群組；以及 • 水介質。 在本發明的潤滑劑組成物中，成份（A )的固體潤滑 劑實例包括諸如聚四氟乙烯、碳酸鈣、氧化鋅、二硫化鉬 或石墨的粉末。可單獨使用一種粉末，或其二種或多種組 合使用。從操作環境的觀點而言，非黑色粉末較諸如二硫 化鉬或石墨的黑色粉末爲佳；且從操作環境、潤滑成效等 的觀點而言，聚四氟乙烯（鐵氟龍）粉末特別佳。固體潤 滑劑粉末的平均粒徑不受特別限制，但從可分散性、潤滑 Φ 成效等觀點而言，一般約爲0.1至20；tzm，較佳在〇·2至 0_7//m範圍內。聚四氟乙烯（鐵氟龍）粉末的實例有商業 可得的產品”LUBRON L-2”（商標名，由Daikin工業有限 公司製造）。 且從潤滑成效的觀點而言，成份（A)對於組成物的 總量之含量較佳爲5至8 0質量％。 同時’成分（B)的有機羧酸金屬鹽（i)具有賦予除 油脂特性的功能，且可使用一元羧酸或多元羧酸的鹼金屬 鹽或鹼土金屬鹽。可單獨使用一種金屬鹽，或其二種或多 -10- (7) 1354019 種組合使用。 鹼金屬鹽的實例包括鈉鹽、鉀鹽及鋰鹽。鹼土金屬鹽 的實例包括鈣鹽、鋇鹽及鎂鹽。 在有機羧酸的金屬鹽中，從除油脂的觀點而言，除了 羧酸官能基以外的碳氫化物官能基較佳以每羧酸官能基含 有17個或更少的碳原子，更佳爲12個或更少的碳原子。 碳氫化物官能基的實例包括烷基' 烷烯基、芳基及芳院 φ 基。在那些之中，較佳爲烷基及烷烯基。烷基及烷烯基可 爲直鏈、分支鏈或環狀。從除油脂特性的觀點而言，鹼金 屬鹽比鹼土金屬鹽更佳。 有機羧酸金屬鹽的實例包括：脂族一元羧酸（諸如醋 酸、丙酸、乳酸、異乳酸、戊酸、異戊酸、三甲基乙酸、 己酸、庚酸、辛酸、2 -乙基己酸、癸酸、十二酸、十四 酸、十六酸、硬脂酸、丙烯酸、甲基丙烯酸、丁烯酸、辛 烯酸、癸辛酸或油酸）或脂族多元羧酸（諸如草酸、丙二 # 酸、丁二酸、戊二酸、己二酸、庚二酸、辛二酸、癸二 酸、十二二酸、十四二酸、十六二酸、十八二酸、7-乙基 十六二羧酸或丁四羧酸）的鹼金屬鹽（諸如鈉鹽、鉀鹽或 鋰鹽）：及彼之鹼土金屬鹽（鈣鹽、鋇鹽或鎂鹽）。在那 些之中，較佳爲鹼金屬鹽。 當使用鹼金屬鹽（i)作爲成份（B)時，有機羧酸對 鹼金屬的莫耳比例較佳落在0.5:1至1:0.5的範圍內。 成份（B)的有機磷酸酯或有機硼酸酯金屬鹽（ii) 具有賦予除油脂特性的功能。可使用磷酸或亞磷酸（膦 -11 - (8) 1354019 酸）酯的鹼金屬鹽或鹼土金屬鹽、原硼酸酯的鹼金屬鹽或 鹼土金屬鹽、及類似者。可單獨使用一種金屬鹽，或其二 種或多種組合使用》 鹼金屬鹽的實例包括鈉鹽、鉀鹽及鋰鹽。鹼土金屬鹽 的實例包括鈣鹽、鋇鹽及鎂鹽。 構成酯的碳氫化物官能基包括烷基、烯基、芳基及芳 烷基，其較佳總共具有32個或更少的碳原子，更佳爲24 φ 個或更少的碳原子。其中，較佳爲烷基及烷烯基。烷基及 烯基可爲直鏈、分支鏈或環狀。從除油脂特性的觀點而 言，鹼金屬鹽比鹼土金屬鹽更佳。 磷酸酯金屬鹽的實例包括：磷酸二烷酯或二烯酯（諸 如磷酸二甲酯、磷酸二乙酯 '磷酸二丙酯、磷酸二丁酯、 磷酸二己酯、磷酸二辛酯、磷酸二癸酯、磷酸二月桂酯、 磷酸二烯丙酯、磷酸二辛烯酯、或磷酸二癸烯酯）的鈉 鹽、鉀鹽或鋰鹽；磷酸單烷酯或單烯酯（諸如磷酸單甲 φ 酯、磷酸單乙酯、磷酸單丙酯、磷酸單丁酯、磷酸單己 酯、磷酸單辛酯、磷酸單癸酯、磷酸單月桂酯、磷酸單十 六烷酯、磷酸單十八烷酯、磷酸單烯丙酯、磷酸單辛烯 酯、磷酸單癸烯酯、或磷酸單油醯酯諸如磷酸氫單烷酯或 單烯酯的單鹼金屬鹽的）的單鈉鹽、單鉀鹽或單鋰鹽；及 磷酸單烷酯或單烯酯的二鈉鹽、二鉀鹽或二鋰鹽諸如磷酸 單烷酯或單烯酯的二鹼金屬鹽。 亞磷酸酯金屬鹽的實例包括：亞磷酸二烷酯或二烯酯 (諸如亞磷酸二甲酯、亞磷酸二乙酯、亞磷酸二丙酯、亞 -12- (10) 1354019 單獨使用一種化合物，或其二種或多種組合使用。 苯并三唑的實例包括苯并三唑、N·二烷基胺弓 1，2,3 -苯并三唑及N -甲基苯并三唑。噻二唑的實例 2,5-雙（正-壬基二硫）-1,3,4-噻二唑及2,5-雙（1，1 四甲基丁基二硫）-1，3，4-噻二唑。 胺的實例包括一級、二級或三級烷基胺或烷烯基 及環狀烷基胺。其特殊的實例包括丁胺、二丁胺、 φ 胺、己胺、二己胺、三己胺、環己胺、二環己胺、三 胺、辛胺、二辛胺、三辛胺、癸胺'二癸胺'三癸胺 桂胺、二月桂胺、三月桂胺、棕櫚胺、二棕櫚胺、三 胺、硬脂醯胺、二硬脂醯胺、三硬脂醯胺、油胺、 胺、及三油胺。 醯胺的實例包括二辛基醯胺及N-十八烯基肌胺 亞胺的實例包括聚丁烯基丁二醯亞胺》在那些之中， 爲苯并三唑及胺，且特別佳爲苯并三唑及二辛胺。 Φ 從抗腐蝕特性及效率的觀點而言，成份（C)對 物總量的的含量較佳爲0.1至10質量％，更佳爲0.5 質量％。 本發明的組成物可隨意含有各種常用在習用金屬 用水基潤滑劑組成物的添加物作爲成份（D )，諸如 要有腐蝕抑制劑、抗氧化劑、殺蟲劑、及消泡劑。 從可處理性、除油脂特性等觀點而言，本發明組 的pH較佳在3至12的範圍內，更佳在6至1〇的 內。水對於組成物的總量之含量較佳落在1〇至50賃 3基_ 包括 ,3,3- 胺、 三丁 環己 、月 棕_ 二油 酸。 較佳 化合 至5 處理 視需 成物 範圍 '量％ -14- (11) 1354019 的範圍內，更佳在15至40質量％的範圍內。將水的含量 調整在上述範圍內會產生有利的潤滑成效，以及有利的操 作特性。 本發明的潤滑劑組成物可用於諸如溫壓處理、冷壓處 理、鍛造處理、拉製、壓扁、彎曲、元件輥軋或壓延的塑 性處理領域。可採用各種金屬及其合金作爲待處理的材 料，諸如鋼、不銹鋼、鎂合金、鋁、鋁合金、鈦、鈦合 鲁 金、及銅。 本發明的潤滑劑組成物較佳用於更明確而言諸如鎂合 金、鋁、鋁合金、鈦、鈦合金、或銅之非鐵金屬的溫壓處 理。 本發明提供一種製造經溫壓處理的金屬材料之方法， 藉由將本發明的潤滑劑組成物施加於待處理的金屬材料表 面上；以熱處理將水蒸發：且將待處理的金屬材料進行壓 製處理。 φ 在上述方法中，施加於待處理的金屬材料表面上的潤 滑劑組成物中的水可在加熱的壓製模具上蒸發，且待處理 的金屬材料可直接進行壓製處理。 【實施方式】 實例 下之將參考實例更詳細說明本發明，但本發明絕不受 限於該等實例。 藉由下述的程序，評估潤滑劑組成物的特性。 -15- (12) 1354019 (1 )潤滑性 (a )深度可拉製性測試 使用厚度爲1 mm的鎂合金薄片材料進行深度可拉製 性測試’其條件爲衝擊速率爲1〇 mm/s、衝頭直徑爲32 mm、模具直徑爲34.4 mm、及溫度爲250。(：，以目視觀察 裂隙與裂縫。 (b)堡登（Bowden)測試 使用鎂合金薄片材料進行堡登測試，其條件爲SUJ2 鋼球（3/16央吋（4.8 mm))、承載49 N、速率爲20 mm/s、內襯距離爲50 mm、及溫度爲200。(：，以決定摩擦 係數。 (2 )除油脂特性 將樣品施加在鎂合金薄片材料（80 mmx60 mm)上， 且整個在200°C下乾燥5分鐘。然後，所獲得的薄片以水 淸洗1 〇分鐘，並決定經除油脂部位的面積％。 (3 )操作環境 AA代表對於潤滑劑組成物的操作特性或機器周邊上 的污染不會導致問題的情況。CC代表其中會產生問題的 淸況。 -16- (13) (13)1354019 (4 )抗腐蝕測試 將樣品在鎂合金薄片材料上潤滑，進行暴露測試，以 評估薄片的表面在1個月後出現或不出現腐蝕。 實例1至1 1，以及比較性實例1至3 製備用於特性評估的每一種潤滑劑組成物的組成如表 1及2所示。表1及2顯示此結果。1354019 (1) IX. Description of the Invention [Technical Field of the Invention] The present invention relates to a metal-based water-based lubricant composition, and a method for using the water-based lubricant composition to produce a warm-pressure treated metal material . The present invention is more specifically directed to a metal-based water-based lubricant composition which has excellent handleability, grease removal characteristics, operating environment and the like, and is preferably used in the field of plastic treatment, particularly preferably for various Field of temperature and pressure treatment of metallic materials, more specifically, non-ferrous metal materials for magnesium or aluminum, and a method for efficiently producing a temperature-treated metal material using the water-based lubricant composition . [Prior Art] Lubricants which have heretofore been used for the plastic treatment of metals have the following applications: reducing friction between metal materials and tools or molds; smoothing plastic deformation of metals; and promoting cooling and protection of tools or molds, and Let the metal material be released from the #tool or mold. Meanwhile, magnesium alloys have recently been widely used because among practical metals, magnesium alloys are the lightest alloys and have excellent characteristics such as electromagnetic wave shielding properties. Recently, magnesium alloys have been mainly subjected to die casting and thixomolding treatment, but it has been pointed out that the treatment technique requires surface polishing after treatment, and the treatment technique is difficult to apply to thin-walled products. At the same time, the pressing treatment using the magnesium alloy flakes as the material to be treated can be applied to the thin-walled product, and no surface polishing is required after the treatment. However, magnesium alloys have poor handleability at normal temperatures, and therefore are usually subjected to a press treatment at a temperature of 200 to -5 - (2) 1354019 300 °C. Insufficient lubrication of the pressed oil during the pressing process can result in breakage of the material to be treated, adhesion to the mold, or the like. Therefore, a special lubricant is used for the pressing process. As described above, the lubricant for the plastic treatment of the magnesium alloy flakes must have a lubricating property for suppressing the fracture of the material to be treated and its adhesion to the mold at a warm temperature ranging from 10 (TC to 300 ° C). In order to exhibit high processing performance, and must be removed by a general grease removal procedure. φ Solid film lubricant has been used for the thermal treatment of magnesium alloy flakes. However, this situation requires removal of the film after treatment, and It is impossible to carry out simple degreasing treatment. Therefore, productivity is inevitably lowered. At the same time, oil-based lubricants have environmental problems because the temperature of the mold increases to about 30,000 tons during pressing, which causes oil mist and poor handleability. It may cause cracks or cracks in operation. Therefore, oil-based lubricants have problems in use. For example, JP 2003-89797 A discloses a plastics for magnesium alloys, which has excellent removal. It is a grease characteristic and can prevent deterioration of the operating environment, and is composed of 7 to 20% by mass of an alkali metal salt having 1 to 18 carbon atoms, 2 to 6 5% by weight of an alkaline earth metal salt of a fatty acid having 12 to 18 carbon atoms, and a base solution providing a predetermined amount of an alkali metal hydroxide having a pH of 12 to 14. However, the lubrication for plastic treatment of a magnesium alloy The agent does not contain a solid lubricant. Therefore, it does not necessarily provide sufficient plastic treatability. [Invention] -6 - (3) 1354019 In this case, the object of the present invention is to provide a metal treatment water-based lubricant composition. It has excellent handleability, grease removal characteristics, operating environment and the like, and is preferably used in the field of plastic treatment, particularly in the field of temperature and pressure treatment of various metal materials, and more specifically, a magnesium-based or aluminum-based non-ferrous metal material, and a method of using the water-based lubricant composition to produce a temperature-treated metal material. The inventors of the present invention have conducted intensive research to achieve the above目目, and it has been found that a water-based composition containing a solid lubricant and a specific compound can achieve the goal of being a water-based lubricant composition for metal treatment; and the above composition Applied to the surface of the metal material to be treated, the water is evaporated by heat treatment, and the metal material to be treated is subjected to a pressing treatment, and the temperature-treated metal material can be efficiently produced. The inventors of the present invention have completed these findings. In the present invention, the present invention provides the following (1) to (15). (1) A water-based lubricant composition for metal treatment comprising #solid lubricant as the component (A); At least one metal salt is used as the component (B) selected from the metal salt (i) of an organic carboxylic acid and the metal salt (ii) of an organic phosphate or an organic boronic acid ester. (2) A metal as in the above item (1) A water-based lubricant composition further comprising a nitrogen-containing compound as the component (C). (3) A metal-based water-based lubricant composition according to the above item (1) or (2), wherein the component (A) is used as the component (A) The solid lubricant is at least one powder selected from the group consisting of polytetrafluoroethylene, calcium carbonate, zinc oxide, molybdenum disulfide, and graphite. (5) 1354019 A water-based lubricant composition' having a pH in the range of 3 to 12. (11) A metal-based water-based lubricant composition according to any one of the above items (1) to (10), which is used for warming treatment, cold pressing treatment, forging treatment, drawing, flattening, bending , component rolling or calendering. (12) A metal-based water-based lubricant composition according to the above item (11), which is used for temperature-pressure treatment of a non-ferrous metal material. (13) The metal treatment water according to the above items (11) to (12) • The base lubricant composition, wherein the non-ferrous metal material is a magnesium alloy. (14) A method of producing a temperature-treated metal material, comprising: applying a lubricant composition according to any one of items (1) to (10) above to a surface of a metal material to be treated; The water is evaporated; and the metal material to be treated is subjected to a pressing treatment. (15) The method of producing a temperature-treated metal material according to the above item (14), wherein the water applied to the lubricant composition on the surface of the metal material to be treated is evaporated on the heated stamper; The treated metal material is directly pressed. According to the present invention, there is provided a metal-based water-based lubricant composition which has excellent handleability, grease removal characteristics, operating environment and the like, and is preferably used in the field of plastic treatment, particularly preferably for various metals. The field of temperature and pressure treatment of materials, more specifically, non-ferrous metal materials for magnesium or aluminum. Moreover, according to the method of the present invention, the water-based lubricant composition % ' is effective for producing a temperature-treated metal material. (6) 1354019 BEST MODE FOR CARRYING OUT THE INVENTION The metal-treated water-based lubricant composition according to the present invention comprises a solid lubricant as the component (A): at least one metal salt as the component (B) selected from organic a metal salt of a carboxylic acid (i) and a metal salt of an organic phosphate or an organic boronic acid ester (ii); a nitrogen-containing compound as a component (C) and/or optionally at least one agent as a component (D) selected from the group consisting of Includes groups of corrosion inhibitors, antioxidants, pesticides, and defoamers; and • Aqueous media. In the lubricant composition of the present invention, examples of the solid lubricant of the component (A) include powders such as polytetrafluoroethylene, calcium carbonate, zinc oxide, molybdenum disulfide or graphite. One type of powder may be used alone or in combination of two or more kinds thereof. From the viewpoint of the operating environment, the non-black powder is preferable to a black powder such as molybdenum disulfide or graphite; and the polytetrafluoroethylene (Teflon) powder is particularly preferable from the viewpoints of the operating environment, lubrication effect, and the like. The average particle diameter of the solid lubricant powder is not particularly limited, but is generally from about 0.1 to 20; tzm, preferably from 〇·2 to 0_7/m, from the viewpoints of dispersibility, lubrication Φ effect, and the like. An example of a polytetrafluoroethylene (Teflon) powder is the commercially available product "LUBRON L-2" (trade name, manufactured by Daikin Industrial Co., Ltd.). Further, the content of the component (A) for the total amount of the composition is preferably from 5 to 80% by mass from the viewpoint of the lubricating effect. Meanwhile, the organic carboxylic acid metal salt (i) of the component (B) has a function of imparting grease-removing properties, and an alkali metal salt or an alkaline earth metal salt of a monocarboxylic acid or a polyvalent carboxylic acid can be used. A metal salt may be used alone or in combination of two or more of -10 (7) 1354019. Examples of the alkali metal salt include a sodium salt, a potassium salt, and a lithium salt. Examples of the alkaline earth metal salt include a calcium salt, a barium salt, and a magnesium salt. In the metal salt of the organic carboxylic acid, the hydrocarbon functional group other than the carboxylic acid functional group preferably contains 17 or less carbon atoms per carboxylic acid functional group from the viewpoint of fat removal, and more preferably 12 or fewer carbon atoms. Examples of the hydrocarbon functional group include an alkyl 'alkenyl group, an aryl group, and a aryl group. Among those, an alkyl group and an alkenyl group are preferred. The alkyl group and the alkenyl group may be a straight chain, a branched chain or a cyclic group. The alkali metal salt is more preferable than the alkaline earth metal salt from the viewpoint of degreasing properties. Examples of the organic carboxylic acid metal salt include: aliphatic monocarboxylic acids (such as acetic acid, propionic acid, lactic acid, isolactic acid, valeric acid, isovaleric acid, trimethylacetic acid, caproic acid, heptanoic acid, octanoic acid, 2-ethyl group). Caproic acid, citric acid, dodecanoic acid, tetradecanoic acid, palmitic acid, stearic acid, acrylic acid, methacrylic acid, crotonic acid, octenoic acid, octanoic acid or oleic acid) or an aliphatic polycarboxylic acid (such as Oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, dodecanoic acid, tetradecanoic acid, hexadecanic acid, octadedioic acid An alkali metal salt (such as a sodium salt, a potassium salt or a lithium salt) of 7-ethylhexadecandioic acid or tetrabutyl carboxylic acid: and an alkaline earth metal salt (calcium, barium or magnesium salt). Among them, an alkali metal salt is preferred. When the alkali metal salt (i) is used as the component (B), the molar ratio of the organic carboxylic acid to the alkali metal preferably falls within the range of from 0.5:1 to 1:0.5. The organic phosphate or the organic borate metal salt (ii) of the component (B) has a function of imparting grease removal characteristics. An alkali metal salt or an alkaline earth metal salt of phosphoric acid or phosphorous acid (phosphine-11 - (8) 1354019 acid) ester, an alkali metal salt of an orthoborate or an alkaline earth metal salt, and the like can be used. A metal salt may be used alone or in combination of two or more thereof. Examples of the alkali metal salt include a sodium salt, a potassium salt, and a lithium salt. Examples of the alkaline earth metal salt include a calcium salt, a barium salt, and a magnesium salt. The hydrocarbon functional group constituting the ester includes an alkyl group, an alkenyl group, an aryl group and an aralkyl group, which preferably has a total of 32 or less carbon atoms, more preferably 24 φ or less. Among them, an alkyl group and an alkenyl group are preferred. The alkyl and alkenyl groups may be straight chain, branched chain or cyclic. The alkali metal salt is more preferable than the alkaline earth metal salt from the viewpoint of degreasing properties. Examples of the phosphate metal salt include: a dialkyl phosphate or a diene ester (such as dimethyl phosphate, diethyl phosphate 'dipropyl phosphate, dibutyl phosphate, dihexyl phosphate, dioctyl phosphate, phosphoric acid di a sodium, potassium or lithium salt of decyl ester, dilauryl phosphate, diallyl phosphate, dioctyl phosphate or dinonyl phosphate; monoalkyl or monoethyl phosphate (such as monomethyl phosphate) φ ester, monoethyl phosphate, monopropyl phosphate, monobutyl phosphate, monohexyl phosphate, monooctyl phosphate, monodecyl phosphate, monolauryl phosphate, monohexadecyl phosphate, monooctadecane phosphate Monosodium salt, monopotassium salt of ester, monoallyl phosphate, monooctyl phosphate, monoterpene phosphate, or monoolein phosphate such as monoalkyl phosphate or monoalkali metal salt of monoethyl ester a salt or a monolithium salt; and a disodium salt, a dipotassium salt or a dilithium salt of a monoalkyl or monoalkyl phosphate such as a monoalkyl or monoalkyl phosphate. Examples of the metal phosphite salt include: a dialkyl phosphite or a diene ester (such as dimethyl phosphite, diethyl phosphite, dipropyl phosphite, -12-(10) 1354019, a compound alone. Or two or more combinations thereof. Examples of benzotriazoles include benzotriazole, N.dialkylamine 1,2,3-benzotriazole and N-methylbenzotriazole. Examples of oxadiazoles 2,5-bis(n-decyldithio)-1,3,4-thiadiazole and 2,5-bis(1,1 tetramethylbutyldisulfide)-1,3, 4-thiadiazoles Examples of the amines include primary, secondary or tertiary alkylamines or alkenyl groups and cyclic alkylamines. Specific examples thereof include butylamine, dibutylamine, φ amine, hexylamine, and Hexylamine, trihexylamine, cyclohexylamine, dicyclohexylamine, triamine, octylamine, dioctylamine, trioctylamine, decylamine diamine, triammine amide, dilaurylamine, trilaurylamine , palmamine, dipalmitamine, triamine, stearylamine, distearylamine, tristearylamine, oleylamine, amine, and trioleylamine. Examples of indoleamine include dioctyldecylamine and N Examples of octadecyl myosine imine include polybutenyl diacetyl Among them, imine is benzotriazole and amine, and particularly preferably benzotriazole and dioctylamine. Φ From the viewpoint of corrosion resistance and efficiency, the total amount of the component (C) The content of the present invention is preferably from 0.1 to 10% by mass, more preferably 0.5% by mass. The composition of the present invention may optionally contain, as component (D), various additives commonly used in water-based lubricant compositions of conventional metals, such as corrosion. Inhibitor, antioxidant, insecticide, and antifoaming agent. The pH of the present invention is preferably in the range of 3 to 12, more preferably 6 to 1 观点 from the viewpoints of handleability, grease removal characteristics, and the like. The content of water for the total amount of the composition preferably falls between 1 and 50 ounces of 3 bases, including, 3,3-amine, tributylcyclohexyl, and leuco-dioleic acid. Depending on the desired range of the amount '%% -14- (11) 1354019, more preferably in the range of 15 to 40% by mass. Adjusting the water content within the above range will produce favorable lubrication results, and favorable Operating characteristics The lubricant composition of the present invention can be used for, for example, warm pressing, cold pressing, forging Plastic processing in the treatment, drawing, flattening, bending, component rolling or calendering. Various metals and their alloys can be used as materials to be treated, such as steel, stainless steel, magnesium alloy, aluminum, aluminum alloy, titanium, titanium alloy. Lujin, and copper. The lubricant composition of the present invention is preferably used for warm-pressure treatment of a non-ferrous metal such as magnesium alloy, aluminum, aluminum alloy, titanium, titanium alloy, or copper, more specifically. A method of producing a temperature-treated metal material by applying a lubricant composition of the present invention to a surface of a metal material to be treated; evaporating water by heat treatment: and subjecting the metal material to be treated to a pressing treatment. In the above method, water applied to the lubricant composition on the surface of the metal material to be treated may be evaporated on the heated press mold, and the metal material to be treated may be directly subjected to press treatment. [Embodiment] The present invention will be described in more detail with reference to examples, but the present invention is by no means limited to the examples. The characteristics of the lubricant composition were evaluated by the following procedure. -15- (12) 1354019 (1) Lubricity (a) Depth drawability test The depth drawability test is carried out using a magnesium alloy sheet material having a thickness of 1 mm. The condition is that the impact rate is 1 mm/s. The punch has a diameter of 32 mm, a die diameter of 34.4 mm, and a temperature of 250. (:, visually observe the cracks and cracks. (b) The Bowden test uses the magnesium alloy sheet material for the Fortress test under the condition that the SUJ2 steel ball (3/16 吋 (4.8 mm)), bearing 49 N The rate is 20 mm/s, the lining distance is 50 mm, and the temperature is 200. (:, to determine the coefficient of friction. (2) The sample is applied to the magnesium alloy sheet material (80 mm x 60 mm) in addition to the grease characteristics, and The whole was dried at 200 ° C for 5 minutes. Then, the obtained sheet was rinsed with water for 1 minute and determined by the area % of the grease removal portion. (3) The operating environment AA represents the operational characteristics of the lubricant composition or Contamination on the periphery of the machine does not cause problems. CC represents a problem that can cause problems. -16- (13) (13) 1354019 (4) Corrosion resistance test Lubricate the sample on magnesium alloy sheet material for exposure Test to evaluate whether the surface of the sheet appeared or did not corrode after 1 month. Examples 1 to 1 1, and Comparative Examples 1 to 3 The composition of each of the lubricant compositions prepared for property evaluation is shown in Tables 1 and 2. Shown. Tables 1 and 2 show this result.
-17- (14)1354019-17- (14) 1354019
實例 00 I I 1 1 (N 1 1 1 ^T) <Ν ν〇 〇〇 0.06 100 〇 U 卜 I I 1 沄 1 (N 1 1 1 (Ν VO 00 ¥: 0.05 100 U U Ό I I 芝 1 1 (N 1 1 1 CN 00 1 ν=ί 〇 100 ΑΑ I 1 1 1 CN 1 1 1 CN VO 00 葚 m 0.13 100 ΑΑ 寸 〇 I 1 1 1 1 1 1 *Τί (Ν oo 层 0.07 100 ΑΑ m 〇 I 1 1 1 艺 1 1 1 Ο VO 00 蓥 揉 0.07 100 ΑΑ CN I 1 1 1 1 1 1 m m VO oo 薜 璀 0.05 100 ΑΑ I 1 1 1 <N 1 1 1 (Ν 00 0.05 100 ΑΑ A-1 CN 1 < m 1 < 寸 1 < yr\ 1 < r—^ (N 1 «^ m 1 寸 1 潤滑劑組成物的pH 1 出現或未出現裂隙 出現或未出現裂縫 摩擦係數 油脂去除率（％) 操作環境 成份（A)固體潤滑劑 成份（B) (i)有 機羧酸的金屬鹽 深度可拉製 性測試 堡登測試 除油脂測試 潤滑劑組成物 (質量％) 潤滑性 除油脂特性 -18 - 1354019 鬥(N® Li<«w <υ _, m运 葚 葚 0.05 〇 ΑΑ u JJ (N 礦物油(運 動黏度在 40°C下爲 450 mm2/s) M： rv^ 0.35 1 m CQ 1 1 1 1 1 s 1 1 1 Ό 00 聛 0.09 100 AA 實例 1 1 1 1 1 1 1 in (N u-> (N »n 00 葚 0.05 AA Ο 1 1 1 1 1 1 (N 1 (N ό 00 蕻 揉 0.05 AA ON 1 1 1 1 1 (N 1 1 iT) (N 00 鹿 0.07 100 AA A-1 A-2 m 1 < A-4 in 1 < 1—^ (N 1 m 1 • —M 寸 1 • mm * 潤滑劑組成物的pH 出現或未出現裂隙 出現或未出現裂縫 摩擦係數 油脂去除率（％) 操作環境 成份（A)固體潤滑劑 1 C n s s S經 a搲 深度可拉製性測試 堡登測試 除油脂測試 潤滑劑組成物 (質量％) 潤滑性 除油脂特性 -19- (16) 1354019 (註） A-1:鐵氟龍粉末（Diakin工業有 LUBRON L-2，平均粒徑5以m或更小） Α-2:碳酸鈣 A - 3 :氧化辞 A - 4 :二硫化鉬 A-5 :石墨 φ i-1 : 7-乙基十六烷二羧酸的鉀鹽（莫 1:0.9) i-2:癸酸的鈉鹽（莫耳比例酸：鹼= i-3:棕櫚酸的鉀鹽（莫耳比例酸：驗 i-4:油酸的鉀鹽（莫耳比例酸：鹼= 表1顯示因爲實例7及8分別採用二 爲成份（A) ’它們表現不良的操作環境， ® 10及11皆採用具有大數目碳原子的脂肪 們具有不良的除油脂特性。比較性實例4 煙霧，並表現有起火的危害。 實例1 2至2 1 製備如表3及4所示組成的每一種潤 於特性評估。表3及4顯示此結果。 限公司所製的 耳比例酸：鹼= 1:0.9) =1:0.9) 1:0.9) 硫化鉬及石墨作 表2顯示實例 酸鹼金屬鹽，它 因爲油霧而導致 滑劑組成物，用 -20- 1354019Example 00 II 1 1 (N 1 1 1 ^T) <Ν ν〇〇〇0.06 100 〇U 卜II 1 沄1 (N 1 1 1 (Ν VO 00 ¥: 0.05 100 UU Ό II 芝 1 1 (N 1 1 1 CN 00 1 ν=ί 〇100 ΑΑ I 1 1 1 CN 1 1 1 CN VO 00 葚m 0.13 100 ΑΑ inch 〇 I 1 1 1 1 1 1 *Τί (Ν oo layer 0.07 100 ΑΑ m 〇I 1 1 1 Art 1 1 1 Ο VO 00 蓥揉0.07 100 ΑΑ CN I 1 1 1 1 1 1 mm VO oo 薜璀0.05 100 ΑΑ I 1 1 1 <N 1 1 1 (Ν 00 0.05 100 ΑΑ A-1 CN 1 < m 1 < inch 1 < yr\ 1 < r—^ (N 1 «^ m 1 inch 1 Lubricant composition pH 1 appears or does not appear cracks or does not appear crack friction coefficient grease removal rate (%) Operating environment components (A) Solid lubricant component (B) (i) Metal salt of organic carboxylic acid Depthability test Forkden test Degreasing test Lubricant composition (% by mass) Lubricity and grease removal characteristics -18 - 1354019 Bucket (N® Li<«w <υ _, m运葚葚 0.05 〇ΑΑ u JJ (N mineral oil (motion viscosity is 450 mm2/s at 40 °C) M: rv^ 0.35 1 m CQ 1 1 1 1 1 s 1 1 1 Ό 00 聛0.09 100 AA Example 1 1 1 1 1 1 1 1 in (N u-> (N »n 00 葚0.05 AA Ο 1 1 1 1 1 1 (N 1 (N ό 00 蕻揉0.05 AA ON 1 1 1 1 1 (N 1 1 iT) (N 00 deer 0.07 100 AA A-1 A-2 m 1 < A-4 in 1 < 1—^ (N 1 m 1 • —M 1 1 • mm * Lubricant composition The pH appears or does not appear cracks or cracks are not present. Friction coefficient of grease removal rate (%) Operating environment composition (A) Solid lubricant 1 C nss S by a depth Depthability test Fortenberg test Degreasing test lubricant Composition (% by mass) Lubricity and grease removal characteristics -19- (16) 1354019 (Note) A-1: Teflon powder (Diakin industry has LUBRON L-2, average particle size 5 or less) Α- 2: Calcium carbonate A - 3 : Oxidation A - 4 : Molybdenum disulfide A-5 : Graphite φ i-1 : Potassium salt of 7-ethylhexadecanedicarboxylic acid (Mo 1:0.9) i-2: Sodium salt of citric acid (mole ratio acid: base = i-3: potassium salt of palmitic acid (mole ratio acid: test i-4: potassium salt of oleic acid (mole ratio acid: base = Table 1 shows Examples 7 and 8 use two components (A) respectively. They exhibit poor operating environments, ® 10 and 11 Fats with a large number of carbon atoms have poor degreasing properties. Comparative example 4 is smog and exhibits a fire hazard. Example 1 2 to 2 1 Each of the characteristics of the compositions shown in Tables 3 and 4 was evaluated. Tables 3 and 4 show this result. The ratio of the ear made by the company is: acid = 1:0.9) =1:0.9) 1:0.9) Molybdenum sulfide and graphite are shown in Table 2. The acid-base metal salt is used as a slip agent composition due to oil mist. -20- 1354019
【ε ¥ 實例 卜 〇 1 1 1 1 1 1 1 VO 1 1 寸 1 m (N 〇〇 0.05 100 AA 良好 VO 〇 XT) 1 1 1 1 1 1 1 寸 1 1 1 (N 00 葚 | 0.05 1 loo 1 AA 1良好1 〇 1 i i 1 CN 1 1 1 1 1 1 CN Ό 〇〇 蓥 乐； | 0.09 1 loo 1 AA 1良好1 寸 〇 1 1 1 1 1 1 1 1 1 1 (Ν 1 1 CN (N 00 0.05 100 1 AA 1 〇 1 1 1 1 1 1 1 1 1 ο 1 1 1 〇 寸 <N oo 揉 0.09 100 AA 1 CN 〇 «〇 1 1 1 1 1 1 1 1 (N 1 I 1 1 (Ν m 00 摧 摧 | 0.05 1 1QQ 1 AA 1 A-1 A-2 m 1 < A-4 A-5 1 (N 1 •— m 1 寸 1 •— 1 « (Ν I •— • —Ν ϋ-3 C-l C-2 潤滑劑組成物的pH 出現或未出現裂隙 出現或未出現裂縫 摩擦係數 油脂去除率（％) 操作環境 抗腐蝕測試 成份（A)固體潤滑劑 C I® S經 φ；您 成份（B) (ii) 磷酸酯的金屬鹽 成份（C)含氮化合物 深度可拉製 性測試 堡登測試 除油脂測試 潤滑劑組成物 (質量°/。） 潤滑性 除油脂特性 -21 - 1354019[ε ¥ Example 〇 1 1 1 1 1 1 1 VO 1 1 inch 1 m (N 〇〇 0.05 100 AA Good VO 〇 XT) 1 1 1 1 1 1 1 inch 1 1 1 (N 00 葚 | 0.05 1 loo 1 AA 1 good 1 〇 1 ii 1 CN 1 1 1 1 1 1 CN Ό 〇〇蓥乐; | 0.09 1 loo 1 AA 1 good 1 inch 〇 1 1 1 1 1 1 1 1 1 1 (Ν 1 1 CN ( N 00 0.05 100 1 AA 1 〇1 1 1 1 1 1 1 1 1 ο 1 1 1 &inch<N oo 揉0.09 100 AA 1 CN 〇«〇1 1 1 1 1 1 1 1 (N 1 I 1 1 (Ν m 00 Destroy | 0.05 1 1QQ 1 AA 1 A-1 A-2 m 1 < A-4 A-5 1 (N 1 •– m 1 inch 1 •— 1 « (Ν I •— • — Ν Cl-3 Cl C-2 Lubricant composition pH appears or no cracks appear or no crack coefficient of friction Grease removal rate (%) Operating environment corrosion test component (A) solid lubricant CI® S φ; Your ingredients (B) (ii) Phosphate metal salt components (C) Nitrogen compounds Deep drawability test Fortenberg test Degreaser test Lubricant composition (mass ° /.) Lubricity Degreasing properties - 21 - 1354019
【寸m】 實例 <N ο (Ν 1 1 1 1 1 1 to iT) 〇〇 0.09 100 ΑΑ Ο Ol Ο CN 1 ! 1 ! I 1 ! iT) cn 卜 Os ΐ=3； ί=3ί 0.07 100 ΑΑ 〇\ Ο (Ν 1 1 1 1 1 to 1 1 m 璀 0.05 100 ΑΑ 00 Ο (Ν 1 1 1 1 »η 1 1 1 »n (N v〇 璀 摧 0.07 100 ΑΑ Α-1 (Ν I < 1 < Α-4 1 < I 1 ♦— 卜 1 會-Η οο I » K Λ S 出現或未出現裂隙 出現或未出現裂縫 摩擦係數 油脂去除率(％) 操作環境 成份(Α)固體潤滑劑 犖顬 3姻 « S 5 m m 蘅 ,7-r 深度可拉 製性測試 堡登測試 除油脂測試 链$ Enj =_ s _ 潤滑性 除油脂 特性 -22- (19) 1354019 (註） i-5: 7·乙基十六烷二羧 1:0.5) 卜6: 7-乙基十六烷二羧 1:0.7) i_7: 7-乙基十六烷二羧 1:1.3) i- 8: 7·乙基十六烷二羧 1:1.15) ii- 1··磷酸二辛酯的單鉀 ii-2:磷酸單月桂酯的鉀 ii-3:磷酸單丁酯的鉀鹽 C-1 :苯并三唑 C-2:二辛胺 酸的鉀鹽（莫耳比例酸：鹼= 酸的鉀鹽（莫耳比例酸：鹼= 酸的鉀鹽（莫耳比例酸：鹼= 酸的鉀鹽（莫耳比例酸：鹼= 菌（莫耳比例酸：鹼=1:0.9) 鹽（莫耳比例酸：鹼=1:0.9) (莫耳比例酸：鹼=1:0.9)[inch m] example <N ο (Ν 1 1 1 1 1 1 to iT) 〇〇0.09 100 ΑΑ Ο Ol Ο CN 1 ! 1 ! I 1 ! iT) cn 卜 Os ΐ=3; ί=3ί 0.07 100 ΑΑ 〇\ Ο (Ν 1 1 1 1 1 to 1 1 m 璀0.05 100 ΑΑ 00 Ο (Ν 1 1 1 1 »η 1 1 1 »n (N v〇璀〇璀0.07 100 ΑΑ Α-1 (Ν I < 1 < Α-4 1 < I 1 ♦ — 卜 1 会 -Η οο I » K Λ S Appears or does not appear cracks or cracks Friction coefficient Grease removal rate (%) Operating environment composition (Α) solid Lubricant 荦顬3 marriage « S 5 mm 蘅, 7-r Depth pullability test Fortress test degreasing test chain $ Enj =_ s _ Lubricity degreasing characteristics -22- (19) 1354019 (Note) i -5: 7·ethylhexadecane dicarboxyl 1:0.5) Bu 6: 7-ethylhexadecanedicarboxylate 1:0.7) i_7: 7-ethylhexadecanedicarboxylate 1:1.3) i- 8 : 7 · Ethylhexadecane dicarboxyl 1:1.15) ii- 1 ··Dioctyl phosphate monopotassium ii-2: Potassium phosphate monoethyl citrate ii-3: Potassium salt C-1 of monobutyl phosphate : benzotriazole C-2: potassium salt of dioctylamine (mole ratio acid: base = potassium salt of acid (mole ratio acid: base = potassium salt of acid (morbi ratio Acid: base = potassium salt of acid (mole ratio acid: base = bacteria (mole ratio acid: base = 1:0.9) salt (mole ratio acid: base = 1:0.9) (mole ratio acid: base = 1:0.9)
對於A-1至A-5及i-1 相同。 至i-4的定義與在表1及2中 工業上的應用性 依據本發明之金屬處理 優異的可處理性、除油脂特 佳使用於塑性處理領域、特 溫壓處理領域，更明確而言 材料。 用水基潤滑劑組成物，其具有 性、操作環境與類似者，且較 別是較佳用於各種金屬材料的 ，用於鎂基或鋁基之非鐵金屬 -23-The same is true for A-1 to A-5 and i-1. The definition of i-4 and the industrial applicability in Tables 1 and 2 are excellent in handleability according to the metal treatment of the present invention, particularly in the field of plastic treatment, and in the field of special temperature treatment, more specifically material. Water-based lubricant composition, its properties, operating environment and the like, and more preferably used for various metal materials, for magnesium-based or aluminum-based non-ferrous metals -23-