CN104169259B - 从己二酸产生己内酰胺 - Google Patents

从己二酸产生己内酰胺 Download PDF

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Publication number
CN104169259B
CN104169259B CN201380009620.5A CN201380009620A CN104169259B CN 104169259 B CN104169259 B CN 104169259B CN 201380009620 A CN201380009620 A CN 201380009620A CN 104169259 B CN104169259 B CN 104169259B
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China
Prior art keywords
adipic acid
ammonia
caprolactam
reaction
solvent
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CN201380009620.5A
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English (en)
Chinese (zh)
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CN104169259A (zh
Inventor
E·L·迪亚斯
V·J·墨菲
J·朗迈尔
H·蒋
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Archer Daniels Midland Co
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Rennovia Inc
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201380009620.5A 2012-02-23 2013-02-13 从己二酸产生己内酰胺 Active CN104169259B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261602533P 2012-02-23 2012-02-23
US61/602,533 2012-02-23
PCT/US2013/025846 WO2013126250A1 (en) 2012-02-23 2013-02-13 Production of caprolactam from adipic acid

Publications (2)

Publication Number Publication Date
CN104169259A CN104169259A (zh) 2014-11-26
CN104169259B true CN104169259B (zh) 2016-09-21

Family

ID=47748790

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380009620.5A Active CN104169259B (zh) 2012-02-23 2013-02-13 从己二酸产生己内酰胺

Country Status (12)

Country Link
US (1) US8946411B2 (enExample)
EP (1) EP2817293A1 (enExample)
JP (1) JP2015517977A (enExample)
KR (1) KR20140129076A (enExample)
CN (1) CN104169259B (enExample)
AR (1) AR089980A1 (enExample)
BR (1) BR112014020642B1 (enExample)
HK (1) HK1205121A1 (enExample)
IN (1) IN2014DN07028A (enExample)
SA (1) SA113340296B1 (enExample)
SG (1) SG11201405045YA (enExample)
WO (1) WO2013126250A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2791104B1 (en) 2011-12-14 2018-01-10 Rennovia Inc. Water concentration reduction process
CA2858822A1 (en) 2011-12-14 2013-06-20 Rennovia, Inc. Process for the separation of mono- and di-carboxylic acid compounds
CN104557705B (zh) * 2013-10-15 2017-06-09 中国石油化工股份有限公司 一种己内酰胺精制的方法和装置
SG11201701141PA (en) 2014-09-29 2017-03-30 Rennovia Inc Preparation and separation of a dicarboxylic acid-containing mixture using a dicarboxylate form of an anion exchange chromatogrpahy resin
JP6672792B2 (ja) * 2014-10-30 2020-03-25 東レ株式会社 ε−カプロラクタムの製造方法
US10364218B2 (en) 2015-09-11 2019-07-30 Toray Industries, Inc. Method of producing epsilon-caprolactam
CN110023285B (zh) * 2016-12-06 2023-01-17 东丽株式会社 ε-己内酰胺的制造方法
KR102739203B1 (ko) * 2018-08-28 2024-12-05 현대자동차주식회사 바이오 나일론 원료의 중간체 물질인 아디프아마이드 제조방법
CN114160120B (zh) * 2021-12-24 2024-01-26 郑州中科新兴产业技术研究院 一种用于己二酸酯生产己二腈的催化剂的制备方法

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GB778253A (en) * 1955-02-02 1957-07-03 Inventa Ag Process for the manufacture of -e-caprolactam
US3652549A (en) * 1968-07-18 1972-03-28 Kanegafuchi Spinning Co Ltd Production of epsilon-caprolactam
JPS4919250B1 (enExample) * 1969-01-09 1974-05-16
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US4800227A (en) 1984-08-20 1989-01-24 Phillips Petroleum Company Process for the production of lactams
IT1214622B (it) 1985-07-10 1990-01-18 Montedipe Spa Processo catalitico per laproduzione di cicloesanonossima.
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DE19548289A1 (de) * 1995-12-22 1997-06-26 Basf Ag Verfahren zur gleichzeitigen Herstellung von Caprolactam und Hexamethylendiamin
US5780623A (en) 1996-02-23 1998-07-14 Dsm N.V. Process to prepare ε-caprolactam from 6-aminocaproic acid
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CA2763777C (en) * 2009-06-13 2017-10-17 Rennovia Inc. Production of adipic acid and derivatives from carbohydrate-containing materials
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CA2858822A1 (en) 2011-12-14 2013-06-20 Rennovia, Inc. Process for the separation of mono- and di-carboxylic acid compounds
EP2791104B1 (en) 2011-12-14 2018-01-10 Rennovia Inc. Water concentration reduction process
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SG11201408289UA (en) 2012-06-11 2015-01-29 Rennovia Inc Process for production of adipic acid from 1,6-hexanediol

Also Published As

Publication number Publication date
BR112014020642A2 (pt) 2019-09-10
JP2015517977A (ja) 2015-06-25
AR089980A1 (es) 2014-10-01
EP2817293A1 (en) 2014-12-31
US8946411B2 (en) 2015-02-03
WO2013126250A1 (en) 2013-08-29
SA113340296B1 (ar) 2015-09-06
SG11201405045YA (en) 2014-09-26
KR20140129076A (ko) 2014-11-06
HK1205121A1 (en) 2015-12-11
BR112014020642B1 (pt) 2020-12-29
IN2014DN07028A (enExample) 2015-04-10
CN104169259A (zh) 2014-11-26
US20130225785A1 (en) 2013-08-29

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Effective date of registration: 20180521

Address after: Illinois State

Patentee after: Archer Daniels Midland Co.,Ltd.

Address before: American California

Patentee before: RENNOVIA, INC.