CN104151902B - Quick-drying powdery paints used by a kind of pottery - Google Patents

Quick-drying powdery paints used by a kind of pottery Download PDF

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CN104151902B
CN104151902B CN201410431517.6A CN201410431517A CN104151902B CN 104151902 B CN104151902 B CN 104151902B CN 201410431517 A CN201410431517 A CN 201410431517A CN 104151902 B CN104151902 B CN 104151902B
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parts
pottery
quick
powdery paints
drying
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CN104151902A (en
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陈进国
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Langfang Yanmei Chemical Co ltd
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Wenzhou Xingtai Technology Co Ltd
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Abstract

The invention discloses a kind of pottery quick-drying powdery paints, raw material is: glutaric acid methyl esters, polysiloxanes, diethanol amine, ammoniacal liquor, potassium hydroxide, propoxy propanol, pigment, cobalt naphthenate, neopentyl glycol, zirconium naphthenate, plasticizer, ethylene glycol monobutyl ether, trimethylolpropane, rutile type titanium white and hexahydro phthalic anhydride;Product fusing point 180 200 DEG C, pliability 1 5mm, glossiness 90% 110%;Hot strength 20 30MPa, percentage elongation 150 250%, solidification temperature 130 150 DEG C, drying time 10,20min, soaked 25 35d without exception in 5% hydrochloric acid solution;Adhesive force 12 grades, impact strength 80 100N/cm, soaks in saturated calcium hydroxide that 30 40d are non-foaming, elephant skin;Pencil hardness 3 5H, soaks nothing foaming, obscission after 45 55d in water.

Description

Quick-drying powdery paints used by a kind of pottery
Technical field
The application belongs to paint field, particularly relates to a kind of pottery quick-drying powdery paints.
Background technology
Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays become name in the world Secondary Production of Ceramics big country in fact, consumption big country.The domestic ceramics yield of domestic product accounts for full generation About the 70% of boundary, display art ceramic yield is the 65% of the whole world, and architectural pottery yield also accounts for Gross World Product half of the country.China industry occupies very important ground in world's building material industry Position.Development due to ceramic science technology.And the demand day that market is to pottery new product Benefit increases, and forces Ceramics Enterprises to want development new product, and must consider the variation of product Problem that rationalization's production process is brought by this factor and the impact of generation.Suitable in order to strengthen Ying Xing, Ceramics Enterprises not only needs to improve science and technology application level and the research of new product energetically Ability, constantly makes model change, it is necessary to use program evaluation and review technique, GT and many The production organization method that kind mixes line production etc. are advanced, use adaptable machinery equipment and Flexible production manufactures system, to adapt to produce the needs of variation.
Coating, English name: coating products defines: be applied to body surface energy shape Become and there is the one of the solid-state film protecting decoration or property (such as insulation, anticorrosion, mark etc.) Class I liquid I or the general name of solid material.Coating type is various, purposes is the widest.In national economy and People's lives play an important role.Year use coating content is the weight of a national living standard per capita Want index.Coating is typically based on resin or oil, and adds or be not added with face, filler, with organic Solvent or the thick liquid of water modulation, also occur in that the coating new product existed with solid forms Plant such as powdery paints.No matter the form (liquid or solid) of all kinds of coating coating varieties, At least should be made up of two or three basis.I.e. it is divided into main film forming substance;Secondary film forming Material and auxiliary film forming matter.Coating can be coated on surface of bottom material and form tough and tensile continuous film The liquid or solid macromolecular material of (paint film).It is once called as paint, paint.It is mainly used to being coated with Decoration and protective effect are played in surface.Some coating also has specific function, as high temperature resistant, Cold-resistant, radiation proof etc..Coating is widely used in the sides such as building, boats and ships, vehicle, metallic article Face.
Powdery paints is that a kind of 100% solid that contains divides, and carries out the painting of coating film forming with powder morphology Material, it is using air as decentralized medium.Epoxide powder coating is that one has corrosion resistance and heavily fortified point The thermosetting powder coating of toughness, application is the earliest, fast-developing, by epoxy resin, color stuffing, Additive and curing agent composition.The preparation of epoxide powder coating is to use international production thermosetting Property powdery paints unique method, i.e. melting mixing extrusion molding mixing, melting mixing extrusion, Finely divided.Ceramic coating weatherability and processing characteristics are excellent, bear dirty and resistant to damage.Conventional Although ceramic coating resistant to damage, but if the parts after application are curved processing, easily Crack, and fluorine resin paints and organic coating, easily damaged by sandstone, dust etc.. Therefore, the appearance of ceramic coating, receive the favor of ceramic industry, and forward other industry is oozed Thoroughly, promise well.And popularizing along with humanity concept, and the composition of novel harmonious society, Design a kind of have good flexibility, tack and have excellent anti-corruptibility, resistance to water, The pottery quick-drying powdery paints of acid resistance and alkali resistance is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that quick-drying powdery paints used by a kind of pottery, solves The skills such as existing pottery quick-drying powdery paints adhesive force is low, and alkali resistance, resistance to water and acid resistance are poor Art problem.
Technical scheme:
Quick-drying powdery paints used by a kind of pottery, and the raw material of described pottery quick-drying powdery paints is by weight Amount number proportioning is as follows: glutaric acid methyl esters 100 parts;Polysiloxanes 0.4-0.8 part;Diethanol Amine 40-80 part;Ammoniacal liquor 1-5 part;Potassium hydroxide 10-15 part;Propoxy propanol 10-20 part; Pigment 5-15 part;Cobalt naphthenate 2-8 part;Neopentyl glycol 80-90 part;Zirconium naphthenate 2-6 Part;Plasticizer 1-10 part;Ethylene glycol monobutyl ether 15-25 part;Trimethylolpropane 10-30 Part;Rutile type titanium white 30-40 part;Hexahydro phthalic anhydride 50-60 part.
As a preferred technical solution of the present invention: described pottery quick-drying powdery paints former Expect that proportioning is as follows by weight: glutaric acid methyl esters 100 parts;Polysiloxanes 0.6 part;Diethyl Hydramine 60 parts;Ammoniacal liquor 3 parts;13 parts of potassium hydroxide;Propoxy propanol 15 parts;Pigment 10 Part;Cobalt naphthenate 5 parts;Neopentyl glycol 85 parts;Zirconium naphthenate 4 parts;5 parts of plasticizer; Ethylene glycol monobutyl ether 20 parts;Trimethylolpropane 20 parts;Rutile type titanium white 35 parts; Hexahydro phthalic anhydride 55 parts.
As a preferred technical solution of the present invention: described pigment uses phthalocyanine blue or ultramarine.
As a preferred technical solution of the present invention: described plasticizer uses DOP or DBP.
Beneficial effect:
A kind of pottery quick-drying powdery paints of the present invention uses above technical scheme with existing Technology is compared, and has following technical effect that 1, product fusing point 180-200 DEG C, pliability 1-5mm, Glossiness 90%-110%;2, hot strength 20-30MPa, percentage elongation 150-250%, solidification Temperature 130-150 DEG C, drying time, 10-20min, soaked 25-35d in 5% hydrochloric acid solution Without exception;3, adhesive force 1-2 level, impact strength 80-100N/cm, at saturated calcium hydroxide Middle immersion 30-40d is non-foaming, elephant skin;4, pencil hardness 3-5H, soaks 45-55d in water Afterwards without foaming, obscission, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
Quick-drying powdery paints used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: glutaric acid Methyl esters 100 parts;Polysiloxanes 0.4 part;Diethanol amine 40 parts;Ammoniacal liquor 1 part;Hydroxide 10 parts of potassium;Propoxy propanol 10 parts;5 parts of ultramarine;Cobalt naphthenate 2 parts;Neopentyl glycol 80 parts;Zirconium naphthenate 2 parts;DOP1 part;Ethylene glycol monobutyl ether 15 parts;Trimethylolpropane 10 parts;Rutile type titanium white 30 parts;Hexahydro phthalic anhydride 50 parts.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, Being warmed up to 130 DEG C under nitrogen protection, insulation reaction 3h mixes, with pulverizing after cooling Machine is pulverized, and is sieved through sieve with 140mg, prepares coating.
Product fusing point 180 DEG C, pliability 1mm, glossiness 90%;Hot strength 20MPa, stretches Long rate 150%, solidification temperature 130 DEG C, drying time, 20min, soaked in 5% hydrochloric acid solution 25d is without exception;Adhesive force 2 grades, impact strength 80N/cm, soak in saturated calcium hydroxide 30d is non-foaming, elephant skin;Pencil hardness 3H, soaks nothing foaming, obscission after 45d in water.
Embodiment 2:
Quick-drying powdery paints used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: glutaric acid Methyl esters 100 parts;Polysiloxanes 0.8 part;Diethanol amine 80 parts;Ammoniacal liquor 5 parts;Hydroxide 15 parts of potassium;Propoxy propanol 20 parts;Phthalocyanine blue 15 parts;Cobalt naphthenate 8 parts;New penta 2 Alcohol 90 parts;Zirconium naphthenate 6 parts;DOP10 part;Ethylene glycol monobutyl ether 25 parts;Trihydroxy methyl 30 parts of propane;Rutile type titanium white 40 parts;Hexahydro phthalic anhydride 60 parts.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, Being warmed up to 150 DEG C under nitrogen protection, insulation reaction 5h mixes, with pulverizing after cooling Machine is pulverized, and is sieved through sieve with 160mg, prepares coating.
Product fusing point 190 DEG C, pliability 3mm, glossiness 100%;Hot strength 25MPa, Percentage elongation 200%, solidification temperature 140 DEG C, drying time, 15min, soaked in 5% hydrochloric acid solution 30d is without exception for bubble;Adhesive force 2 grades, impact strength 90N/cm, in saturated calcium hydroxide Immersion 35d is non-foaming, elephant skin;Pencil hardness 4H, without bubbling, taking off after soaking 50d in water Fall phenomenon.
Embodiment 3:
Quick-drying powdery paints used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: glutaric acid Methyl esters 100 parts;Polysiloxanes 0.6 part;Diethanol amine 60 parts;Ammoniacal liquor 3 parts;Hydroxide 13 parts of potassium;Propoxy propanol 15 parts;Phthalocyanine blue 10 parts;Cobalt naphthenate 5 parts;New penta 2 Alcohol 85 parts;Zirconium naphthenate 4 parts;DBP5 part;Ethylene glycol monobutyl ether 20 parts;Trihydroxy methyl 20 parts of propane;Rutile type titanium white 35 parts;Hexahydro phthalic anhydride 55 parts.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, Being warmed up to 140 DEG C under nitrogen protection, insulation reaction 4h mixes, with pulverizing after cooling Machine is pulverized, and is sieved through sieve with 150mg, prepares coating.
Product fusing point 200 DEG C, pliability 5mm, glossiness 110%;Hot strength 30MPa, Percentage elongation 250%, solidification temperature 140 DEG C, drying time, 15min, soaked in 5% hydrochloric acid solution 30d is without exception for bubble;Adhesion 1 grade, impact strength 90N/cm, in saturated calcium hydroxide Immersion 35d is non-foaming, elephant skin;Pencil hardness 4H, without bubbling, taking off after soaking 50d in water Fall phenomenon.
Composition all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of This any change in the implication suitable with claims of the present invention and scope, all should It is considered to be included within the scope of the claims.

Claims (3)

1. quick-drying powdery paints used by a pottery, it is characterised in that the described fast dry powder of pottery The raw materials by weight portion proportioning of coating is as follows: glutaric acid methyl esters 100 parts;Polysiloxanes 0.4-0.8 part;Diethanol amine 40-80 part;Ammoniacal liquor 1-5 part;Potassium hydroxide 10-15 part; Propoxy propanol 10-20 part;Pigment 5-15 part;Cobalt naphthenate 2-8 part;Neopentyl glycol 80-90 part;Zirconium naphthenate 2-6 part;Plasticizer 1-10 part;Ethylene glycol monobutyl ether 15-25 Part;Trimethylolpropane 10-30 part;Rutile type titanium white 30-40 part;Hexahydro is adjacent Phthalate anhydride 50-60 part;
Described pigment uses phthalocyanine blue or ultramarine.
A kind of pottery quick-drying powdery paints the most according to claim 1, its feature exists As follows in the raw materials by weight portion proportioning of described pottery quick-drying powdery paints: glutaric acid methyl esters 100 parts;Polysiloxanes 0.6 part;Diethanol amine 60 parts;Ammoniacal liquor 3 parts;Potassium hydroxide 13 parts;Propoxy propanol 15 parts;Pigment 10 parts;Cobalt naphthenate 5 parts;Neopentyl glycol 85 parts;Zirconium naphthenate 4 parts;5 parts of plasticizer;Ethylene glycol monobutyl ether 20 parts;Three hydroxyl first 20 parts of base propane;Rutile type titanium white 35 parts;Hexahydro phthalic anhydride 55 parts.
A kind of pottery quick-drying powdery paints the most according to claim 1, its feature exists In: described plasticizer uses DOP or DBP.
CN201410431517.6A 2014-08-28 2014-08-28 Quick-drying powdery paints used by a kind of pottery Active CN104151902B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129724A (en) * 2017-05-12 2017-09-05 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint quick-drying anti-dropout powder and preparation method thereof
CN107142042A (en) * 2017-05-12 2017-09-08 安徽阜南县向发工艺品有限公司 Furniture paint reinforcing quick-drying primer and preparation method thereof
CN107418470A (en) * 2017-05-12 2017-12-01 安徽阜南县向发工艺品有限公司 Furniture paint strengthens anti-dropout primer and preparation method thereof
CN107163690A (en) * 2017-05-12 2017-09-15 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint strengthens fast dry powder and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6103835A (en) * 1998-11-11 2000-08-15 Shell Oil Company Epoxy-functional polyester advanced with carboxyl-functional polyester or dicarboxylic acid (anhydride)
CN1456620A (en) * 2002-05-10 2003-11-19 德古萨公司 Modified polyester powder coating based on polyester and thermosetting material
CN103642014A (en) * 2013-12-11 2014-03-19 浙江天松新材料股份有限公司 Polyester resin for epoxy-cured powder coating with high glossiness and high leveling property and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6103835A (en) * 1998-11-11 2000-08-15 Shell Oil Company Epoxy-functional polyester advanced with carboxyl-functional polyester or dicarboxylic acid (anhydride)
CN1456620A (en) * 2002-05-10 2003-11-19 德古萨公司 Modified polyester powder coating based on polyester and thermosetting material
CN103642014A (en) * 2013-12-11 2014-03-19 浙江天松新材料股份有限公司 Polyester resin for epoxy-cured powder coating with high glossiness and high leveling property and preparation method thereof

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Inventor after: Chen Jinguo

Inventor before: Ma Zhiming

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Effective date of registration: 20160815

Address after: Longwan District of Wenzhou City, Zhejiang province Yongzhong street village of 325000 new road

Applicant after: Wenzhou Xingtai Technology Co., Ltd.

Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu Province Tianlong 215101 No. 378 building room 4722

Applicant before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY CO., LTD.

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Effective date of registration: 20181107

Address after: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee after: Huzhou You Yan Intellectual Property Service Co., Ltd.

Address before: 325000 New Exhibition Road, Zhejiang, Wenzhou, Longwan

Patentee before: Wenzhou Xingtai Technology Co., Ltd.

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Effective date of registration: 20220530

Address after: 065000 No.1, Yimin Road, Guangyang District, Langfang City, Hebei Province

Patentee after: LANGFANG YANMEI CHEMICAL Co.,Ltd.

Address before: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee before: Huzhou You Yan Intellectual Property Service Co.,Ltd.