CN104151902A - Quick-drying powder coating used for ceramic - Google Patents

Quick-drying powder coating used for ceramic Download PDF

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Publication number
CN104151902A
CN104151902A CN201410431517.6A CN201410431517A CN104151902A CN 104151902 A CN104151902 A CN 104151902A CN 201410431517 A CN201410431517 A CN 201410431517A CN 104151902 A CN104151902 A CN 104151902A
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parts
powder coating
quick
drying powder
pottery
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CN201410431517.6A
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CN104151902B (en
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马志明
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Langfang Yanmei Chemical Co ltd
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Suzhou Luotelan New Material Technology Co Ltd
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Abstract

The invention discloses a quick-drying powder coating used for ceramics. Raw materials comprise methyl glutarate, polysiloxane, diethanol amine, ammonia water, potassium hydroxide, propoxyl propanol, a pigment, cobalt naphthenate, neopentyl glycol, zirconium naphthenate, a plasticizer, ethylene glycol monobutyl ether, trimethylolpropane, rutile type titanium dioxide and hexahydrophthalic anhydride. A melting point of a product is 180-200 DEG C; toughness is 1-5 mm; glossiness is 90-110%; tensile strength is 20-30 MPa; elongation is 150-250%; a curing temperature is 130-150 DEG C; a drying time is 10-20 min; the product has no abnormity after being immersed for 25-35 d in a 5% hydrochloric acid solution; an adhesive force is 1-2 level; impact strength is 80-100 N/cm; the product does not blister or wrinkle after being immersed for 30-40 d in a saturated calcium hydroxide solution; pencil hardness is 3-5H; and the product has no blistering or shedding phenomena after being immersed for 45-55 d in water.

Description

A kind of pottery quick-drying powder coating
Technical field
The application belongs to paint field, relates in particular to a kind of pottery quick-drying powder coating.
Background technology
Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays becomes genuine Production of Ceramics big country, consumption big country in the world.The domestic ceramics output of domestic product accounts for global 70% left and right, and display art ceramic yield is 65% of the whole world, and architectural pottery output also accounts for Gross World Product half of the country.Pottery industry is occupied very important status in world's building material industry.Due to the development of ceramic science technology.And market increases day by day to the demand of ceramic product innovation, force Ceramics Enterprises to want development product innovation, and must consider problem that this factor of variation of product is brought rationalization's production process and the impact of generation.In order to strengthen adaptability, Ceramics Enterprises not only needs to improve energetically the Research Ability of scientific and technical application level and product innovation, constantly make model change, also must adopt the advanced production organization method such as program evaluation and review technique, group technology and the production of many kinds mixed flow, adopt adaptable machinery equipment and flexible production manufacturing system, to adapt to produce the needs of variation.
Coating, English name: coating products definition: be applied to body surface and can form and there is protection decoration or property one class I liquid I of solid-state film of (as insulated, anticorrosion, mark etc.) or the general name of solid material.Coating type is various, purposes is extremely wide.In national economy and people's lives, play an important role.A year use coating content is the important indicator of a national standard of living per capita.Coating is normally taking resin or oil as main, and adds or do not add face, filler, modulates with organic solvent or water the thick liquid forming, and also occurred that the coating new variety that exist with solid form are as powder coating.No matter the form of all kinds of coating coating varieties (liquid or solid) how, at least should be formed by two or three basal component.Be divided into main film forming substance; Film forming subsidiary material matter and auxiliary film forming matter.Coating can be coated on substrate surface and form the liquid or solid macromolecular material of tough and tensile continuous film (paint film).Be once called as paint, paint.Be mainly used to be played decoration and provide protection to being coated with surface.Some coating also has specific function, as high temperature resistant, cold-resistant, radioprotective etc.Coating is widely used in the aspects such as building, boats and ships, vehicle, metal products.
Powder coating is that a kind of 100% solid that contains divides, and carries out the coating of coating film forming with powder morphology, and it is using air as dispersion medium.Epoxide powder coating is a kind of thermosetting powder coating(s) with erosion resistance and tenacity, and the earliest, fast development, is made up of epoxy resin, color stuffing, additive and solidifying agent in application.The preparation of epoxide powder coating is the unique method that adopts international production thermosetting powder coating(s), i.e. melting mixing extrusion molding---mixing, melting mixing are extruded, fine powder is broken.Ceramic coating weathering resistance and processing characteristics excellence, bear dirty and resistance to damage.Although the resistance to damage of ceramic coating in the past, if the parts after application are carried out to bending machining, easily cracks, and fluorine resin paints and organic coating, easily by the damage such as sandstone, dust.Therefore, the appearance of ceramic coating, has been subject to the favor of ceramic industry, and the infiltration of forward other industry, promise well.And universal along with humanity concept, and the formation of novel harmonious society, design a kind of have good flexibility, tack and there is good anti-putridness, water tolerance, acid resistance and alkali-proof pottery quick-drying powder coating be very important.
Summary of the invention
The technical problem solving:
The technical problems such as the application, for above-mentioned technical problem, provides a kind of pottery to use quick-drying powder coating, solves existing pottery quick-drying powder coating sticking power low, and alkali resistance, water tolerance and acid resistance are poor.
Technical scheme:
A kind of pottery quick-drying powder coating, described pottery is as follows by the raw materials by weight portion proportioning of quick-drying powder coating: 100 parts of pentanedioic acid methyl esters; Polysiloxane 0.4-0.8 part; Diethanolamine 40-80 part; Ammoniacal liquor 1-5 part; Potassium hydroxide 10-15 part; Propoxy-propyl alcohol 10-20 part; Pigment 5-15 part; Cobalt naphthenate 2-8 part; Neopentyl glycol 80-90 part; Zirconium naphthenate 2-6 part; Softening agent 1-10 part; Ethylene glycol monobutyl ether 15-25 part; TriMethylolPropane(TMP) 10-30 part; Rutile type Titanium Dioxide 30-40 part; Hexahydro phthalic anhydride 50-60 part.
As a preferred technical solution of the present invention: described pottery is as follows by the raw materials by weight portion proportioning of quick-drying powder coating: 100 parts of pentanedioic acid methyl esters; 0.6 part of polysiloxane; 60 parts of diethanolamine; 3 parts of ammoniacal liquor; 13 parts, potassium hydroxide; 15 parts of propoxy-propyl alcohol; 10 parts of pigment; 5 parts of cobalt naphthenates; 85 parts of neopentyl glycol; 4 parts of zirconium naphthenates; 5 parts, softening agent; 20 parts of ethylene glycol monobutyl ethers; 20 parts of TriMethylolPropane(TMP)s; 35 parts of Rutile type Titanium Dioxides; 55 parts of hexahydro phthalic anhydrides.
As a preferred technical solution of the present invention: described pigment adopts phthalocyanine blue or ultramarine.
As a preferred technical solution of the present invention: described softening agent adopts DOP or DBP.
Beneficial effect:
A kind of pottery of the present invention adopts above technical scheme compared with prior art with quick-drying powder coating, has following technique effect: 1, product fusing point 180-200 DEG C, snappiness 1-5mm, glossiness 90%-110%; 2, tensile strength 20-30MPa, elongation 150-250%, solidification value 130-150 DEG C, time of drying, 10-20min soaked 25-35d without extremely in 5% hydrochloric acid soln; 3, sticking power 1-2 level, shock strength 80-100N/cm, soaks in saturated calcium hydroxide that 30-40d is non-foaming, elephant skin; 4, pencil hardness 3-5H, soaks after 45-55d without bubbling, obscission in water, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
A kind of pottery is used quick-drying powder coating, and its raw materials by weight portion proportioning is as follows: 100 parts of pentanedioic acid methyl esters; 0.4 part of polysiloxane; 40 parts of diethanolamine; 1 part of ammoniacal liquor; 10 parts, potassium hydroxide; 10 parts of propoxy-propyl alcohol; 5 parts, ultramarine; 2 parts of cobalt naphthenates; 80 parts of neopentyl glycol; 2 parts of zirconium naphthenates; DOP1 part; 15 parts of ethylene glycol monobutyl ethers; 10 parts of TriMethylolPropane(TMP)s; 30 parts of Rutile type Titanium Dioxides; 50 parts of hexahydro phthalic anhydrides.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 130 DEG C under nitrogen protection, insulation reaction 3h mixes, and cooling pulverize with pulverizer afterwards sieved with 140mg sieve, makes coating.
180 DEG C of product fusing points, snappiness 1mm, glossiness 90%; Tensile strength 20MPa, elongation 150%, 130 DEG C of solidification values, time of drying, 20min soaked 25d without extremely in 5% hydrochloric acid soln; 2 grades of sticking power, shock strength 80N/cm, soaks in saturated calcium hydroxide that 30d is non-foaming, elephant skin; Pencil hardness 3H, soaks after 45d without bubbling, obscission in water.
Embodiment 2:
A kind of pottery is used quick-drying powder coating, and its raw materials by weight portion proportioning is as follows: 100 parts of pentanedioic acid methyl esters; 0.8 part of polysiloxane; 80 parts of diethanolamine; 5 parts of ammoniacal liquor; 15 parts, potassium hydroxide; 20 parts of propoxy-propyl alcohol; 15 parts of phthalocyanine blues; 8 parts of cobalt naphthenates; 90 parts of neopentyl glycol; 6 parts of zirconium naphthenates; DOP10 part; 25 parts of ethylene glycol monobutyl ethers; 30 parts of TriMethylolPropane(TMP)s; 40 parts of Rutile type Titanium Dioxides; 60 parts of hexahydro phthalic anhydrides.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 150 DEG C under nitrogen protection, insulation reaction 5h mixes, and cooling pulverize with pulverizer afterwards sieved with 160mg sieve, makes coating.
190 DEG C of product fusing points, snappiness 3mm, glossiness 100%; Tensile strength 25MPa, elongation 200%, 140 DEG C of solidification values, time of drying, 15min soaked 30d without extremely in 5% hydrochloric acid soln; 2 grades of sticking power, shock strength 90N/cm, soaks in saturated calcium hydroxide that 35d is non-foaming, elephant skin; Pencil hardness 4H, soaks after 50d without bubbling, obscission in water.
Embodiment 3:
A kind of pottery is used quick-drying powder coating, and its raw materials by weight portion proportioning is as follows: 100 parts of pentanedioic acid methyl esters; 0.6 part of polysiloxane; 60 parts of diethanolamine; 3 parts of ammoniacal liquor; 13 parts, potassium hydroxide; 15 parts of propoxy-propyl alcohol; 10 parts of phthalocyanine blues; 5 parts of cobalt naphthenates; 85 parts of neopentyl glycol; 4 parts of zirconium naphthenates; DBP5 part; 20 parts of ethylene glycol monobutyl ethers; 20 parts of TriMethylolPropane(TMP)s; 35 parts of Rutile type Titanium Dioxides; 55 parts of hexahydro phthalic anhydrides.
Above-mentioned raw materials is added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 140 DEG C under nitrogen protection, insulation reaction 4h mixes, and cooling pulverize with pulverizer afterwards sieved with 150mg sieve, makes coating.
200 DEG C of product fusing points, snappiness 5mm, glossiness 110%; Tensile strength 30MPa, elongation 250%, 140 DEG C of solidification values, time of drying, 15min soaked 30d without extremely in 5% hydrochloric acid soln; Adhesion 1 grade, shock strength 90N/cm, soaks in saturated calcium hydroxide that 35d is non-foaming, elephant skin; Pencil hardness 4H, soaks after 50d without bubbling, obscission in water.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.

Claims (4)

1. pottery is used a quick-drying powder coating, it is characterized in that the raw materials by weight portion proportioning of described pottery quick-drying powder coating is as follows: 100 parts of pentanedioic acid methyl esters; Polysiloxane 0.4-0.8 part; Diethanolamine 40-80 part; Ammoniacal liquor 1-5 part; Potassium hydroxide 10-15 part; Propoxy-propyl alcohol 10-20 part; Pigment 5-15 part; Cobalt naphthenate 2-8 part; Neopentyl glycol 80-90 part; Zirconium naphthenate 2-6 part; Softening agent 1-10 part; Ethylene glycol monobutyl ether 15-25 part; TriMethylolPropane(TMP) 10-30 part; Rutile type Titanium Dioxide 30-40 part; Hexahydro phthalic anhydride 50-60 part.
2. a kind of pottery according to claim 1 is used quick-drying powder coating, it is characterized in that the raw materials by weight portion proportioning of described pottery quick-drying powder coating is as follows: 100 parts of pentanedioic acid methyl esters; 0.6 part of polysiloxane; 60 parts of diethanolamine; 3 parts of ammoniacal liquor; 13 parts, potassium hydroxide; 15 parts of propoxy-propyl alcohol; 10 parts of pigment; 5 parts of cobalt naphthenates; 85 parts of neopentyl glycol; 4 parts of zirconium naphthenates; 5 parts, softening agent; 20 parts of ethylene glycol monobutyl ethers; 20 parts of TriMethylolPropane(TMP)s; 35 parts of Rutile type Titanium Dioxides; 55 parts of hexahydro phthalic anhydrides.
3. a kind of pottery according to claim 1 is used quick-drying powder coating, it is characterized in that: described pigment adopts phthalocyanine blue or ultramarine.
4. a kind of pottery according to claim 1 is used quick-drying powder coating, it is characterized in that: described softening agent adopts DOP or DBP.
CN201410431517.6A 2014-08-28 2014-08-28 Quick-drying powdery paints used by a kind of pottery Active CN104151902B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129724A (en) * 2017-05-12 2017-09-05 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint quick-drying anti-dropout powder and preparation method thereof
CN107142042A (en) * 2017-05-12 2017-09-08 安徽阜南县向发工艺品有限公司 Furniture paint reinforcing quick-drying primer and preparation method thereof
CN107163690A (en) * 2017-05-12 2017-09-15 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint strengthens fast dry powder and preparation method thereof
CN107418470A (en) * 2017-05-12 2017-12-01 安徽阜南县向发工艺品有限公司 Furniture paint strengthens anti-dropout primer and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
US6103835A (en) * 1998-11-11 2000-08-15 Shell Oil Company Epoxy-functional polyester advanced with carboxyl-functional polyester or dicarboxylic acid (anhydride)
CN1456620A (en) * 2002-05-10 2003-11-19 德古萨公司 Modified polyester powder coating based on polyester and thermosetting material
CN103642014A (en) * 2013-12-11 2014-03-19 浙江天松新材料股份有限公司 Polyester resin for epoxy-cured powder coating with high glossiness and high leveling property and preparation method thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
US6103835A (en) * 1998-11-11 2000-08-15 Shell Oil Company Epoxy-functional polyester advanced with carboxyl-functional polyester or dicarboxylic acid (anhydride)
CN1456620A (en) * 2002-05-10 2003-11-19 德古萨公司 Modified polyester powder coating based on polyester and thermosetting material
CN103642014A (en) * 2013-12-11 2014-03-19 浙江天松新材料股份有限公司 Polyester resin for epoxy-cured powder coating with high glossiness and high leveling property and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129724A (en) * 2017-05-12 2017-09-05 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint quick-drying anti-dropout powder and preparation method thereof
CN107142042A (en) * 2017-05-12 2017-09-08 安徽阜南县向发工艺品有限公司 Furniture paint reinforcing quick-drying primer and preparation method thereof
CN107163690A (en) * 2017-05-12 2017-09-15 安徽阜南县向发工艺品有限公司 A kind of woodwork underwater paint strengthens fast dry powder and preparation method thereof
CN107418470A (en) * 2017-05-12 2017-12-01 安徽阜南县向发工艺品有限公司 Furniture paint strengthens anti-dropout primer and preparation method thereof

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Inventor after: Chen Jinguo

Inventor before: Ma Zhiming

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Effective date of registration: 20160815

Address after: Longwan District of Wenzhou City, Zhejiang province Yongzhong street village of 325000 new road

Applicant after: Wenzhou Xingtai Technology Co., Ltd.

Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu Province Tianlong 215101 No. 378 building room 4722

Applicant before: SUZHOU LUOTELAN NEW MATERIAL TECHNOLOGY CO., LTD.

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Effective date of registration: 20181107

Address after: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee after: Huzhou You Yan Intellectual Property Service Co., Ltd.

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Patentee before: Wenzhou Xingtai Technology Co., Ltd.

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Effective date of registration: 20220530

Address after: 065000 No.1, Yimin Road, Guangyang District, Langfang City, Hebei Province

Patentee after: LANGFANG YANMEI CHEMICAL Co.,Ltd.

Address before: 313000 room 1020, science and Technology Pioneer Park, 666 Chaoyang Road, Nanxun Town, Nanxun District, Huzhou, Zhejiang.

Patentee before: Huzhou You Yan Intellectual Property Service Co.,Ltd.

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