CN104293063A - Thermosetting acrylic resin powder coating for ceramic - Google Patents
Thermosetting acrylic resin powder coating for ceramic Download PDFInfo
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- CN104293063A CN104293063A CN201410542680.XA CN201410542680A CN104293063A CN 104293063 A CN104293063 A CN 104293063A CN 201410542680 A CN201410542680 A CN 201410542680A CN 104293063 A CN104293063 A CN 104293063A
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- acrylic resin
- powder coating
- resin powder
- thermosetting acrylic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Abstract
The invention discloses a thermosetting acrylic resin powder coating for ceramic. The thermosetting acrylic resin powder coating comprises the following raw materials: butyl acrylate, zinc naphthenate, crylic acid, isobutanol, n-butyl acrylate, ethyl acrylate, an initiator, methylbenzene, acrylic acid-2-phthalic acid ester, normal butanol, a flatting agent, pentaerythritol, isobutyl methacrylate, benzoic acid and lauryl methacrylate, wherein the melting point of the product is 140-160 DEG C; the density is 130-150g/cm<3>; the glossiness is 130%-150%; after artificial accelerated aging for 500 hours, the gloss retention rate is 94%-96%; the tensile strength is 25-35MPa; the elongation rate is 150%-250%; the drying time is 10-30 minutes; the adhesive force is 1-2 grades; the impact strength is 450-550N/cm; the thermosetting acrylic resin powder coating does not blister or wrinkle after being soaked in water for 40-60 days; the scrub resistance of the product is 1300-1500 times; and the shore hardness is 55-65H.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of pottery thermosetting acrylic resin powder coating.
Background technology
The various goods that pottery is is the material that main raw material is mixing, shaping through pulverizing and calcining is obtained with natural clay and various natural mineral.People were called pottery the article of high-temperature firing in special kiln be made into potter's clay in the past, and pottery is the general name of pottery and porcelain.The traditional concept of pottery refers to all artificial Industrial products being raw material with Inorganic nonmetal mineral such as clays.It comprises by clay or containing the mixture of clay through mixing, be shaped, calcining and the various goods made.All belonged to its scope to the meticulousst fine pottery and porcelain by the most coarse earthenware.Main raw material for it takes from natural silicate minerals (as clay, quartz etc.), therefore with industry such as glass, cement, enamel, refractory materialss, belongs to the category of " silicate industry ".Special cermacis is along with Modern appliances, and the developing by leaps and bounds of top science technology such as the industry such as wireless, aviation, nuclear power, metallurgy, machinery, chemistry and robot calculator, space technology, new energy development grow up.These potteries main raw material used is no longer clay, feldspar, quartz, and some bases not also use some clays or feldspar, but is more the raw material adopting pure oxide compound and have property, and manufacturing process and performance requriements are also different.
Coating, is be applied to body surface can be formed and have protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.Coating normally based on resin or oil, and adds or does not add face, filler, the thick liquid modulated with organic solvent or water, has also occurred with the coating new variety of solid form existence as powder coating.No matter the form (liquid or solid) of all kinds of coating coating variety, at least should be made up of two or three basal component.Namely main film forming substance is divided into; Film forming subsidiary material matter and auxiliary film forming matter.Coating can be coated on substrate surface and form the liquid or solid macromolecular material of tough and tensile continuous film (paint film).Be once called as paint, paint.Be mainly used to play decoration and provide protection to by painting surface.Some coating also has specific function, as high temperature resistant, cold-resistant, radioprotective etc.Coating is widely used in the aspects such as building, boats and ships, vehicle, metal products.
Reform and open up to the outside world over 30 years, Chinese pottery industrial boom, nowadays become genuine Production of Ceramics big country, consumption big country in the world.The domestic ceramics output of domestic product accounts for global about 70%, and display art ceramic yield is 65% of the whole world, and architectural pottery output also accounts for Gross World Product half of the country.China industry occupies very important status in world's building material industry.Ceramic coating is that one can make organism and inorganics react, thus has had both the novel ceramic coating of both advantages.Ceramic coating weathering resistance and processing characteristics excellence, bear dirty and resistant to damage.Although ceramic coating resistant to damage in the past, if carry out bending machining to the parts after application, easily cracks, and fluorine resin paints and organic coating, easily by the damage such as sandstone, dust.Therefore, the appearance of ceramic coating, receives the favor of ceramic industry, and the infiltration of forward other industry, promise well.And universal along with humanity concept, and the formation of novel harmonious society, designs that a kind of tensile strength is high, elongation at break is high, the shock-resistant and pottery thermosetting acrylic resin powder coating that scrub resistance is good is very important.
Summary of the invention
The technical problem solved:
The application, for above-mentioned technical problem, provides a kind of pottery thermosetting acrylic resin powder coating, solves existing pottery thermosetting acrylic resin powder coating tensile strength and elongation at break is low, not shock-resistant, the not technical problem such as scrubbing resistance.
Technical scheme:
Thermosetting acrylic resin powder coating used by a kind of pottery, and the raw materials by weight portion proportioning of described pottery thermosetting acrylic resin powder coating is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.1-0.5 part; Vinylformic acid 10-20 part; Isopropylcarbinol 50-60 part; N-butyl acrylate 20-30 part; Ethyl propenoate 30-40 part; Initiator 5-15 part; Toluene 80-100 part; Ethyl acrylate 20-40 part; Propyl carbinol 15-35 part; Flow agent 1-10 part; Tetramethylolmethane 10-20 part; Propenoic acid, 2-methyl, isobutyl ester 40-60 part; Phenylformic acid 15-25 part; Lauryl methacrylate(LMA) 10-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery thermosetting acrylic resin powder coating is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.3 part; 15 parts, vinylformic acid; Isopropylcarbinol 55 parts; N-butyl acrylate 25 parts; Ethyl propenoate 35 parts; Initiator 10 parts; Toluene 90 parts; Ethyl acrylate 30 parts; Propyl carbinol 25 parts; Flow agent 5 parts; Tetramethylolmethane 15 parts; Propenoic acid, 2-methyl, isobutyl ester 50 parts; 20 parts, phenylformic acid; Lauryl methacrylate(LMA) 20 parts.
As a preferred technical solution of the present invention: described initiator adopts azo dicyano valeric acid initiator or benzophenone.
As a preferred technical solution of the present invention: described flow agent adopts polyether polyester modified organic silicon oxygen alkane or urea-formaldehyde resin.
Beneficial effect:
A kind of pottery thermosetting acrylic resin powder coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product fusing point 140-160 DEG C, density 130-150g/cm
3, glossiness 130%-150%, after artificial accelerated aging 500h, protects light rate 94-96%; 2, tensile strength 25-35MPa, elongation 150-250%, time of drying 10-30min; 3, sticking power 1-2 level, shock strength 450-550N/cm, elephant skin non-foaming at water soaking 40-60d; 4, product scrub resistance 1300-1500 time, shore hardness 55-65H, the widespread production not division of history into periods can replace current material.
Embodiment
Embodiment 1:
Thermosetting acrylic resin powder coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.1 part; 10 parts, vinylformic acid; Isopropylcarbinol 50 parts; N-butyl acrylate 20 parts; Ethyl propenoate 30 parts; Benzophenone 5 parts; Toluene 80 parts; Ethyl acrylate 20 parts; Propyl carbinol 15 parts; 1 part, polyether polyester modified organic silicon oxygen alkane; Tetramethylolmethane 10 parts; Propenoic acid, 2-methyl, isobutyl ester 40 parts; 15 parts, phenylformic acid; Lauryl methacrylate(LMA) 10 parts.
Butyl acrylate, isopropylcarbinol, n-butyl acrylate and ethyl propenoate are added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 80 degrees Celsius, insulation reaction 6h mixes, and pulverizes after cooling with pulverizer, with the sieved sieve of 20mg, obtained coating.
Product fusing point 140 DEG C, density 130g/cm
3, glossiness 130%, after artificial accelerated aging 500h, protects light rate 94%; Tensile strength 25MPa, elongation 150%, time of drying 30min; Sticking power 2 grades, shock strength 450N/cm, elephant skin non-foaming at water soaking 40d; Product scrub resistance 1300 times, shore hardness 55H.
Embodiment 2:
Thermosetting acrylic resin powder coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.5 part; 20 parts, vinylformic acid; Isopropylcarbinol 60 parts; N-butyl acrylate 30 parts; Ethyl propenoate 40 parts; Benzophenone 15 parts; Toluene 100 parts; Ethyl acrylate 40 parts; Propyl carbinol 35 parts; Urea-formaldehyde resin 10 parts; Tetramethylolmethane 20 parts; Propenoic acid, 2-methyl, isobutyl ester 60 parts; 25 parts, phenylformic acid; Lauryl methacrylate(LMA) 30 parts.
Butyl acrylate, isopropylcarbinol, n-butyl acrylate and ethyl propenoate are added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 100 degrees Celsius, insulation reaction 8h mixes, and pulverizes after cooling with pulverizer, with the sieved sieve of 80mg, obtained coating.
Product fusing point 150 DEG C, density 140g/cm
3, glossiness 140%, after artificial accelerated aging 500h, protects light rate 95%; Tensile strength 30MPa, elongation 200%, time of drying 20min; Sticking power 2 grades, shock strength 500N/cm, elephant skin non-foaming at water soaking 50d; Product scrub resistance 1400 times, shore hardness 60H.
Embodiment 3:
Thermosetting acrylic resin powder coating used by a kind of pottery, and its raw materials by weight portion proportioning is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.3 part; 15 parts, vinylformic acid; Isopropylcarbinol 55 parts; N-butyl acrylate 25 parts; Ethyl propenoate 35 parts; Azo dicyano valeric acid initiator 10 parts; Toluene 90 parts; Ethyl acrylate 30 parts; Propyl carbinol 25 parts; 5 parts, polyether polyester modified organic silicon oxygen alkane; Tetramethylolmethane 15 parts; Propenoic acid, 2-methyl, isobutyl ester 50 parts; 20 parts, phenylformic acid; Lauryl methacrylate(LMA) 20 parts.
Butyl acrylate, isopropylcarbinol, n-butyl acrylate and ethyl propenoate are added in the reactor with agitator, thermometer and reflux condensing tube, be warmed up to 90 degrees Celsius, insulation reaction 7h mixes, and pulverizes after cooling with pulverizer, with the sieved sieve of 50mg, obtained coating.
Product fusing point 160 DEG C, density 150g/cm
3, glossiness 150%, after artificial accelerated aging 500h, protects light rate 96%; Tensile strength 35MPa, elongation 250%, time of drying 10min; Adhesion 1 grade, shock strength 550N/cm, elephant skin non-foaming at water soaking 60d; Product scrub resistance 1500 times, shore hardness 65H.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.
Claims (3)
1. a thermosetting acrylic resin powder coating used by pottery, it is characterized in that the raw materials by weight portion proportioning of described pottery thermosetting acrylic resin powder coating is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.1-0.5 part; Vinylformic acid 10-20 part; Isopropylcarbinol 50-60 part; N-butyl acrylate 20-30 part; Ethyl propenoate 30-40 part; Initiator 5-15 part; Toluene 80-100 part; Ethyl acrylate 20-40 part; Propyl carbinol 15-35 part; Flow agent 1-10 part; Tetramethylolmethane 10-20 part; Propenoic acid, 2-methyl, isobutyl ester 40-60 part; Phenylformic acid 15-25 part; Lauryl methacrylate(LMA) 10-30 part.
2. a kind of pottery thermosetting acrylic resin powder coating according to claim 1, is characterized in that the raw materials by weight portion proportioning of described pottery thermosetting acrylic resin powder coating is as follows: butyl acrylate 100 parts; Zinc naphthenate 0.3 part; 15 parts, vinylformic acid; Isopropylcarbinol 55 parts; N-butyl acrylate 25 parts; Ethyl propenoate 35 parts; Initiator 10 parts; Toluene 90 parts; Ethyl acrylate 30 parts; Propyl carbinol 25 parts; Flow agent 5 parts; Tetramethylolmethane 15 parts; Propenoic acid, 2-methyl, isobutyl ester 50 parts; 20 parts, phenylformic acid; Lauryl methacrylate(LMA) 20 parts.
3. a kind of pottery thermosetting acrylic resin powder coating according to claim 1, is characterized in that: described initiator adopts azo dicyano valeric acid initiator or benzophenone.A kind of pottery thermosetting acrylic resin powder coating according to claim 1, is characterized in that: described flow agent adopts polyether polyester modified organic silicon oxygen alkane or urea-formaldehyde resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410542680.XA CN104293063A (en) | 2014-10-14 | 2014-10-14 | Thermosetting acrylic resin powder coating for ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410542680.XA CN104293063A (en) | 2014-10-14 | 2014-10-14 | Thermosetting acrylic resin powder coating for ceramic |
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| Publication Number | Publication Date |
|---|---|
| CN104293063A true CN104293063A (en) | 2015-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410542680.XA Pending CN104293063A (en) | 2014-10-14 | 2014-10-14 | Thermosetting acrylic resin powder coating for ceramic |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104693950A (en) * | 2015-03-12 | 2015-06-10 | 湖州中辰建设有限公司 | Acid-resistant acrylic resin powder paint for new ceramics |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1123302A (en) * | 1994-11-25 | 1996-05-29 | 中国石化齐鲁石油化工公司 | Acrylic acid powder coatings and production method thereof |
| CA2412191A1 (en) * | 2002-02-01 | 2003-08-01 | Atofina Chemicals, Inc. | Improved high-solids coatings resins via controlled radical polymerization |
| CN101705040A (en) * | 2009-11-05 | 2010-05-12 | 中国科学院宁波材料技术与工程研究所 | Fluorine-modified methacrylic acid epoxy powder paint and preparation method thereof |
| CN103642353A (en) * | 2013-11-28 | 2014-03-19 | 六安科瑞达新型材料有限公司 | Thermosetting acrylic resin powder paint composition and preparation method thereof |
| CN103865015A (en) * | 2014-03-24 | 2014-06-18 | 合肥工业大学 | High-Tg low-softening-point carboxyl-containing acrylic resin for weather-resisting powder coating |
-
2014
- 2014-10-14 CN CN201410542680.XA patent/CN104293063A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1123302A (en) * | 1994-11-25 | 1996-05-29 | 中国石化齐鲁石油化工公司 | Acrylic acid powder coatings and production method thereof |
| CA2412191A1 (en) * | 2002-02-01 | 2003-08-01 | Atofina Chemicals, Inc. | Improved high-solids coatings resins via controlled radical polymerization |
| CN101705040A (en) * | 2009-11-05 | 2010-05-12 | 中国科学院宁波材料技术与工程研究所 | Fluorine-modified methacrylic acid epoxy powder paint and preparation method thereof |
| CN103642353A (en) * | 2013-11-28 | 2014-03-19 | 六安科瑞达新型材料有限公司 | Thermosetting acrylic resin powder paint composition and preparation method thereof |
| CN103865015A (en) * | 2014-03-24 | 2014-06-18 | 合肥工业大学 | High-Tg low-softening-point carboxyl-containing acrylic resin for weather-resisting powder coating |
Non-Patent Citations (1)
| Title |
|---|
| 周学良: "《精细化工产品手册 涂料》", 31 May 2002, article "精细化工产品手册 涂料", pages: 392-395 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104693950A (en) * | 2015-03-12 | 2015-06-10 | 湖州中辰建设有限公司 | Acid-resistant acrylic resin powder paint for new ceramics |
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Application publication date: 20150121 |
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