CN104140646A - 一种无卤抗氧化pbt材料 - Google Patents
一种无卤抗氧化pbt材料 Download PDFInfo
- Publication number
- CN104140646A CN104140646A CN201410340750.3A CN201410340750A CN104140646A CN 104140646 A CN104140646 A CN 104140646A CN 201410340750 A CN201410340750 A CN 201410340750A CN 104140646 A CN104140646 A CN 104140646A
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- CN
- China
- Prior art keywords
- parts
- halogen
- raw material
- pbt material
- polydimethylsiloxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 18
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 24
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 13
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 8
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229960002887 deanol Drugs 0.000 claims abstract description 7
- 239000012972 dimethylethanolamine Substances 0.000 claims abstract description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims abstract description 7
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010262 sodium metabisulphite Nutrition 0.000 claims abstract description 4
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 claims abstract description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 235000006708 antioxidants Nutrition 0.000 claims description 13
- 229910052736 halogen Inorganic materials 0.000 claims description 13
- 150000002367 halogens Chemical class 0.000 claims description 13
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 6
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 claims description 6
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910021534 tricalcium silicate Inorganic materials 0.000 claims description 6
- 235000019976 tricalcium silicate Nutrition 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 6
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims description 3
- 235000004298 Tamarindus indica Nutrition 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
- 240000004584 Tamarindus indica Species 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 abstract description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 abstract 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004296 sodium metabisulphite Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000596504 Tamarindus Species 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 229920004449 Halon® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
Abstract
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CN201410340750.3A CN104140646B (zh) | 2014-07-17 | 2014-07-17 | 一种无卤抗氧化pbt材料 |
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CN201410340750.3A CN104140646B (zh) | 2014-07-17 | 2014-07-17 | 一种无卤抗氧化pbt材料 |
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CN104140646A true CN104140646A (zh) | 2014-11-12 |
CN104140646B CN104140646B (zh) | 2016-05-18 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519601A (zh) * | 2016-10-26 | 2017-03-22 | 安徽飞达电气科技有限公司 | 一种电容器用改性塑料外壳 |
CN110122496A (zh) * | 2019-06-19 | 2019-08-16 | 中国农业科学院植物保护研究所 | 一种含二氯异氰尿酸钠和喹啉铜的药物组合物及其应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101955636A (zh) * | 2010-10-12 | 2011-01-26 | 江苏安格特新材料科技有限公司 | 抗黄变增强热塑性聚酯及其制备方法 |
CN102321346A (zh) * | 2011-08-16 | 2012-01-18 | 河北中联塑胶科技发展有限公司 | 一种可辐照交联耐高温无卤阻燃聚酯弹性体材料及其制备方法 |
CN102443152A (zh) * | 2011-09-19 | 2012-05-09 | 江苏中鲈科技发展股份有限公司 | 一种具有复合功能的聚酯切片的制备方法 |
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2014
- 2014-07-17 CN CN201410340750.3A patent/CN104140646B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101955636A (zh) * | 2010-10-12 | 2011-01-26 | 江苏安格特新材料科技有限公司 | 抗黄变增强热塑性聚酯及其制备方法 |
CN102321346A (zh) * | 2011-08-16 | 2012-01-18 | 河北中联塑胶科技发展有限公司 | 一种可辐照交联耐高温无卤阻燃聚酯弹性体材料及其制备方法 |
CN102443152A (zh) * | 2011-09-19 | 2012-05-09 | 江苏中鲈科技发展股份有限公司 | 一种具有复合功能的聚酯切片的制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519601A (zh) * | 2016-10-26 | 2017-03-22 | 安徽飞达电气科技有限公司 | 一种电容器用改性塑料外壳 |
CN110122496A (zh) * | 2019-06-19 | 2019-08-16 | 中国农业科学院植物保护研究所 | 一种含二氯异氰尿酸钠和喹啉铜的药物组合物及其应用 |
CN110122496B (zh) * | 2019-06-19 | 2020-10-13 | 中国农业科学院植物保护研究所 | 一种含二氯异氰尿酸钠和喹啉铜的药物组合物及其应用 |
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CN104140646B (zh) | 2016-05-18 |
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Inventor after: Gong Shujun Inventor before: Meng Yong |
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TR01 | Transfer of patent right |
Effective date of registration: 20170630 Address after: 528305 Guangdong Province, Foshan city Shunde District Lunjiao Village Official Version Shilong Industrial Zone of Yongcheng Road No. 4 Patentee after: Foshan Yuanyang Plastic Technology Co.,Ltd. Address before: 239236 Anhui city of Chuzhou province Nanjing Pu Lu Cha River Economic Development Zone No. 3 County Patentee before: CHUZHOU YOUSHENG HIGH POLYMER MATERIAL Co.,Ltd. |
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Effective date of registration: 20240122 Address after: 529729 No.8-5 Longxiang Road, Zhushan Town, Heshan City, Jiangmen City, Foshan City, Guangdong Province Patentee after: Jiangmen Yuanyang Rubber Technology Co.,Ltd. Country or region after: China Address before: 528305, No. 4 Yongcheng Road, Shilong Industrial Zone, Lunjiao Shibian Village Committee, Shunde District, Foshan City, Guangdong Province Patentee before: Foshan Yuanyang Plastic Technology Co.,Ltd. Country or region before: China |