CN104119731B - A kind of chlorinated rubber building coating - Google Patents
A kind of chlorinated rubber building coating Download PDFInfo
- Publication number
- CN104119731B CN104119731B CN201410381860.4A CN201410381860A CN104119731B CN 104119731 B CN104119731 B CN 104119731B CN 201410381860 A CN201410381860 A CN 201410381860A CN 104119731 B CN104119731 B CN 104119731B
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- CN
- China
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- parts
- chlorinated rubber
- titanium dioxide
- building coating
- chlorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 36
- 239000005060 rubber Substances 0.000 title claims abstract description 36
- 239000011248 coating agent Substances 0.000 title claims abstract description 31
- 238000000576 coating method Methods 0.000 title claims abstract description 31
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- JHIVVAPYMSGYDF-UHFFFAOYSA-N Cyclohexanone Chemical group O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 11
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004927 clay Substances 0.000 claims abstract description 11
- 229910052570 clay Inorganic materials 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- HPSUPGAVFFFPMQ-UHFFFAOYSA-N 1,2,3,4,6,7,10-heptachlorododecane Chemical compound CCC(Cl)CCC(Cl)C(Cl)CC(Cl)C(Cl)C(Cl)CCl HPSUPGAVFFFPMQ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 231100000716 Acceptable daily intake Toxicity 0.000 claims abstract description 9
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 8
- KREXGRSOTUKPLX-UHFFFAOYSA-N octadecanoic acid;zinc Chemical compound [Zn].CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O KREXGRSOTUKPLX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract description 6
- JLTDJTHDQAWBAV-UHFFFAOYSA-N Dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims abstract description 3
- DOIRQSBPFJWKBE-UHFFFAOYSA-N Dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 7
- 229940088417 PRECIPITATED CALCIUM CARBONATE Drugs 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 7
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000002791 soaking Methods 0.000 abstract 1
- 238000000498 ball milling Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003973 paint Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000002633 protecting Effects 0.000 description 2
- 230000001681 protective Effects 0.000 description 2
- -1 Butyl ester Chemical class 0.000 description 1
- 240000008528 Hevea brasiliensis Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 210000004080 Milk Anatomy 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N Phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000607 poisoning Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910001929 titanium oxide Inorganic materials 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Abstract
A kind of chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorinated rubber 100 parts；Anhydrous Ketohexamethylene 40 50 parts；Chlorinated paraffin 25 35 parts；Trimethylolpropane 15 25 parts；Rutile titanium dioxide 15 35 parts；Toluene di-isocyanate(TDI) 25 35 parts；Deionized water 70 80 parts；Zinc stearate 5 15 parts；Extender pigment 20 30 parts；Titanium dioxide 30 40 parts；20 40 parts of potter's clay；Pulvis Talci 30 40 parts；Plasticizer 5 15 parts；Organobentonite 35 45 parts；Ethanol 25 45 parts；N, N dimethylaniline 20 30 parts；Product viscosity 45 55s, adhesion strength 40 50MPa；At 600 DEG C, 5 8h are without exception；After soaking 60 90d in water without exception；The resistance to wiping of film 2,800 3000 times, can be with the widespread production not division of history into periods for current material.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of chlorinated rubber building coating.
Background technology
Coating, at the entitled paint of Chinese tradition.So-called coating is to be coated in be protected or filled
The body surface of decorations, and can be with the continuous film of coated article formation firm attachment, it is common that with tree
Fat or oil or emulsion are main, add or without extender pigment, filler, add and help accordingly
Agent, with the formulated thick liquid of organic solvent or rutile titanium dioxide.Chlorinated rubber
It is the rubber derived product obtained after chlorination modified by natural rubber or synthetic rubber, is rubber
1st industrialized rubber derivative in field, according to ICI Imperial Chemical Industries of Britain (ICI)
Data, in the commercial Application of by a definite date 30 years, did not occur a cause to connect with chlorinated rubber
The poisoning touched and cause.Chlorinated rubber relative density is 1.596, and its water absorption rate is 0.1
To 0.3, thermal stable temperature is 130 DEG C, dissolve in aromatic hydrocarbon, esters, ketone, ethers,
In vegetable and animals oils and chlorinated hydrocarbon solution, but insoluble in aliphatic hydrocarbon, alcohols and water.Coating and paint
It it is the identical concept.Paint is people's custom used for a long time titles, after introducing China, the most always
Utilize in building trade.The effect of coating may be summarized to be three aspects: protective effect, dress
Decorations effect, specific function effect.The general composition of coating: comprise film forming matter, color stuffing,
Solvent, auxiliary agent.
Coating refers to be applied to body surface and can form the general name of the material of tough and tensile protecting film, builds
Building coating is an important class in coating, in China, typically will be used for inner wall of building,
Exterior wall, ceiling, ground, the coating of toilet is referred to as building coating.Building coating has decoration
Function, defencive function and livability improve function.Proportion shared by various functions is because of application target
Different and be not quite similar.Decoration functions is to improve its appearance value by beautifying of building
Function.Mainly include the concept in terms of plane color, pattern and gloss and three-dimensional pattern
Concept.But to match with the size and shape of the moulding of building itself and base material itself
Close, just can fully play out.Defencive function refers to protect building the most protected from environmental
With the function destroyed.Different types of content defencive function required by protective also each not phase
With.The index difference reached as required by indoor and outdoor application is the biggest.Building coating conduct
One class is mainly used in the coating products of house decoration, and its market development develops close with real estate industry
Cut is closed.
Industrial chlorinated rubber is the most white or milk yellow powder, lamellar or threadiness, chlorine
Mass fraction, between 62～65, has preferable thermostability.From " the tightest real estate in history
Policy " put into effect since, market of real estate development be absorbed in low ebb, especially into 2012
Since Nian, intended policy loosens and does not occur before, is that firmly the portion of building explicitly indicates that short on the contrary
In time, policy of regulation and control will not change.Some buildings are to mildew-resistant, fire prevention, insulation, resistance to
Corrosion etc. has particular/special requirement.Livability improves function mainly for indoor application, it is simply that have
Help improve the function of living environment, such as sound-proofing, sound absorption properties, anti-condensation etc..And along with
Popularizing of humanity concept, and the composition of novel harmonious society, a kind of viscosity of design is high, heat-resisting
Property good, resistance to water and the excellent chlorinated rubber building coating of resistance to wiping be very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of chlorinated rubber building coating, solves existing
Have that chlorinated rubber building coating viscosity is low, the technology such as poor heat resistance, resistance to water and resistance to wiping difference
Problem.
Technical scheme:
A kind of chlorinated rubber building coating, the raw material of described chlorinated rubber building coating is by weight
Number proportioning is as follows: chlorinated rubber 100 parts；Anhydrous Ketohexamethylene 40-50 part；Chlorinated paraffin 25-35
Part；Trimethylolpropane 15-25 part；Rutile titanium dioxide 15-35 part；Toluene two is different
Cyanate 25-35 part；Deionized water 70-80 part；Zinc stearate 5-15 part；Extender pigment
20-30 part；Titanium dioxide 30-40 part；Potter's clay 20-40 part；Pulvis Talci 30-40 part；Increase
Mould agent 5-15 part；Organobentonite 35-45 part；Ethanol 25-45 part；N, N-dimethyl benzene
Amine 20-30 part.
As a preferred technical solution of the present invention: the raw material of described chlorinated rubber building coating
Proportioning by weight is as follows: chlorinated rubber 100 parts；Anhydrous Ketohexamethylene 45 parts；Chlorination stone
30 parts of wax；Trimethylolpropane 20 parts；Rutile titanium dioxide 25 parts；Toluene two is different
Cyanate 30 parts；Deionized water 75 parts；Zinc stearate 10 parts；Extender pigment 25 parts；Two
Titanium oxide 35 parts；30 parts of potter's clay；Pulvis Talci 35 parts；Plasticizer 10 parts；Organobentonite
40 parts；Ethanol 35 parts；DMA 25 parts.
As a preferred technical solution of the present invention: described extender pigment uses lightweight carbonic acid
Calcium.
As a preferred technical solution of the present invention: described plasticizer uses phthalic acid two
Butyl ester.
Beneficial effect:
A kind of chlorinated rubber building coating of the present invention uses above technical scheme and existing skill
Art is compared, and has following technical effect that 1, product viscosity 45-55s, adhesion strength 40-50MPa；
2,5-8h is without exception at 600 DEG C；Water soak after 60-90d without exception；3, film is resistance to
Wiping 2800-3000 time, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
A kind of chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorinated rubber
100 parts；Anhydrous Ketohexamethylene 40 parts；Chlorinated paraffin 25 parts；Trimethylolpropane 15 parts；
Rutile titanium dioxide 15 parts；Toluene di-isocyanate(TDI) 25 parts；Deionized water 70 parts；
Zinc stearate 5 parts；Precipitated calcium carbonate 20 parts；Titanium dioxide 30 parts；20 parts of potter's clay；Sliding
Stone powder 30 parts；Dibutyl phthalate 5 parts；Organobentonite 35 parts；Ethanol 25 parts；
DMA 20 parts.
Anhydrous Ketohexamethylene is added after deionized water dissolves, add chlorinated rubber, chlorinated paraffin,
Rutile titanium dioxide, precipitated calcium carbonate, dibutyl phthalate, potter's clay, ethanol,
With ball mill ball milling 30min, add trimethylolpropane, toluene di-isocyanate(TDI) and residue
Raw material, ball milling 30min had both obtained finished product.
Product viscosity 45s, adhesion strength 40MPa；At 600 DEG C, 5h is without exception；Water soaks
Bubble 60d after without exception；The resistance to wiping of film 2800 times.
Embodiment 2:
A kind of chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorinated rubber
100 parts；Anhydrous Ketohexamethylene 50 parts；Chlorinated paraffin 35 parts；Trimethylolpropane 25 parts；
Rutile titanium dioxide 35 parts；Toluene di-isocyanate(TDI) 35 parts；Deionized water 80 parts；
Zinc stearate 15 parts；Precipitated calcium carbonate 30 parts；Titanium dioxide 40 parts；40 parts of potter's clay；Sliding
Stone powder 40 parts；Dibutyl phthalate 15 parts；Organobentonite 45 parts；Ethanol 45 parts；
DMA 30 parts.
Anhydrous Ketohexamethylene is added after deionized water dissolves, add chlorinated rubber, chlorinated paraffin,
Rutile titanium dioxide, precipitated calcium carbonate, dibutyl phthalate, potter's clay, ethanol,
With ball mill ball milling 30min, add trimethylolpropane, toluene di-isocyanate(TDI) and residue
Raw material, ball milling 30min had both obtained finished product.
Product viscosity 50s, adhesion strength 45MPa；At 600 DEG C, 7h is without exception；Water soaks
Bubble 80d after without exception；The resistance to wiping of film 2900 times.
Embodiment 3:
A kind of chlorinated rubber building coating, its raw materials by weight portion proportioning is as follows: chlorinated rubber
100 parts；Anhydrous Ketohexamethylene 45 parts；Chlorinated paraffin 30 parts；Trimethylolpropane 20 parts；
Rutile titanium dioxide 25 parts；Toluene di-isocyanate(TDI) 30 parts；Deionized water 75 parts；
Zinc stearate 10 parts；Precipitated calcium carbonate 25 parts；Titanium dioxide 35 parts；30 parts of potter's clay；Sliding
Stone powder 35 parts；Dibutyl phthalate 10 parts；Organobentonite 40 parts；Ethanol 35 parts；
DMA 25 parts.
Anhydrous Ketohexamethylene is added after deionized water dissolves, add chlorinated rubber, chlorinated paraffin,
Rutile titanium dioxide, precipitated calcium carbonate, dibutyl phthalate, potter's clay, ethanol,
With ball mill ball milling 30min, add trimethylolpropane, toluene di-isocyanate(TDI) and residue
Raw material, ball milling 30min had both obtained finished product.
Product viscosity 55s, adhesion strength 50MPa；At 600 DEG C, 8h is without exception；Water soaks
Bubble 90d after without exception；The resistance to wiping of film 3000 times.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of
This any change in the implication suitable with claims of the present invention and scope, all should
It is considered to be included within the scope of the claims.
Claims (2)
1. a chlorinated rubber building coating, it is characterised in that described chlorinated rubber building coating
Raw materials by weight portion proportioning as follows: chlorinated rubber 100 parts；Anhydrous Ketohexamethylene 40-50 part；
Chlorinated paraffin 25-35 part；Trimethylolpropane 15-25 part；Rutile titanium dioxide 15-35
Part；Toluene di-isocyanate(TDI) 25-35 part；Deionized water 70-80 part；Zinc stearate 5-15
Part；Extender pigment 20-30 part；Titanium dioxide 30-40 part；Potter's clay 20-40 part；Pulvis Talci
30-40 part；Plasticizer 5-15 part；Organobentonite 35-45 part；Ethanol 25-45 part；N,
Accelerine 20-30 part；
Described extender pigment uses precipitated calcium carbonate；
Described plasticizer uses dibutyl phthalate.
A kind of chlorinated rubber building coating the most according to claim 1, it is characterised in that
The raw materials by weight portion proportioning of described chlorinated rubber building coating is as follows: chlorinated rubber 100
Part；Anhydrous Ketohexamethylene 45 parts；Chlorinated paraffin 30 parts；Trimethylolpropane 20 parts；Golden red
Stone-type titanium dioxide 25 parts；Toluene di-isocyanate(TDI) 30 parts；Deionized water 75 parts；Stearic
10 parts of zinc of acid；Extender pigment 25 parts；Titanium dioxide 35 parts；30 parts of potter's clay；Pulvis Talci
35 parts；Plasticizer 10 parts；Organobentonite 40 parts；Ethanol 35 parts；N, N-dimethyl
Aniline 25 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410381860.4A CN104119731B (en) | 2014-08-06 | A kind of chlorinated rubber building coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410381860.4A CN104119731B (en) | 2014-08-06 | A kind of chlorinated rubber building coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119731A CN104119731A (en) | 2014-10-29 |
| CN104119731B true CN104119731B (en) | 2016-11-30 |
Family
ID=
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109085A (en) * | 1994-03-24 | 1995-09-27 | 丁铁龙 | Special waterproof coating for both dry and wet applications |
| CN101113295A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Waterproofing paint capable of constructing on building damp and moisture-free basis |
| CN102898900A (en) * | 2012-09-28 | 2013-01-30 | 启东市华亚工业配套有限公司 | Rubber paint |
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109085A (en) * | 1994-03-24 | 1995-09-27 | 丁铁龙 | Special waterproof coating for both dry and wet applications |
| CN101113295A (en) * | 2006-07-28 | 2008-01-30 | 中宏（天津）实业有限公司 | Waterproofing paint capable of constructing on building damp and moisture-free basis |
| CN102898900A (en) * | 2012-09-28 | 2013-01-30 | 启东市华亚工业配套有限公司 | Rubber paint |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160929 Address after: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Applicant after: Gu Yukui Address before: Wujiang City, Suzhou City, 215299 Song Ling Zhen Wu in Jiangsu province with the side of the road Applicant before: Suzhou Jing Yu novel material company limited |
|
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Pan Yimin Inventor before: Qian Yuzhu |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20170608 Address after: Haizhuqu District Jianji road Guangzhou city Guangdong province 510000 66 No. 701 (east of self) (only for office buildings function) Patentee after: Guangzhou beauty Architectural Decoration Engineering Co., Ltd. Address before: 266000 Licang, Qingdao, No. nine East water road, No. 320, No. Patentee before: Gu Yukui |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161130 Termination date: 20190806 |