CN104109470A - Strong permeability waterproof agent and preparation method thereof - Google Patents
Strong permeability waterproof agent and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a strong permeability waterproof agent and a preparation method thereof. The strong permeability waterproof agent comprises the following raw materials by following mass fraction: 1.8-2.5 parts of organosilicon polymer, 0.1-0.3 parts of osmotic agent, 0.1-0.3 parts of levelling agent, 0.1-0.3 parts of antifoaming agent, 0.1-0.3 parts of dispersing agent and 96-98 parts of cosolvent. The waterproof agent is prepared by adding the ingredients in a container one by one and then stirring, controlling the temperature and filtering under normal pressure condition. The strong permeability waterproof agent has the advantages of production technology simplification, prevention of high temperature/high pressure synthesis risk, and no three wastes generation of composition; and has the beneficial effects of strong high-temperature resistance, strong permeability, fast drying and no change of color of original product. The strong permeability waterproof agent can be widely used for moisture and mildew resistant treatment before interior decoration, and used for water repellent treatment in stone industry, woodwork and textile industry, and is especially suitable for rapid construction under special environment.
Description
Technical field
The present invention relates to a kind of water-resisting agent, particularly relate to a kind of strong osmotic water-resisting agent and preparation method thereof.
Background technology
1 organosilicon
Organosilicon, be silicoorganic compound, refer to that containing Si-O key and having an organic radical at least is the compound being directly connected with Siliciumatom, also often makes the compound that organic radical is connected with Siliciumatom also be used as silicoorganic compound by oxygen, sulphur, nitrogen etc. those traditionally.Wherein, the polysiloxane of composition taking siloxane bond (Si-0-Si-) as skeleton, is maximum for counting in silicoorganic compound, studies dark, a most most widely used class, accounts for the more than 90% of total consumption.
The basic structural unit of organosilicon product is made up of silicon-oxygen chain link, and side chain is connected by the various organic groups of Siliciumatom and other.Therefore, both contained " organic group " in the structure of organosilicon product, and contained again " inorganic structure ", this special composition and molecular structure make it integrate the function of organic characteristic and inorganics.
Organosilicon material has unique structure:
(1) on Si atom, sufficient methyl shields high-octane polysiloxane backbone;
(2) C-H is nonpolarity, makes intermolecular interaction very faint;
(3) Si-O bond distance is longer, and Si-O-Si key bond angle is large.
(4) Si-O key is the covalent linkage (covalent linkage has directivity, and ionic linkage is non-directional) with 50% ionic linkage feature.
First silicoorganic compound be 1863 by french chemist Fu charles in Dare (Friedel C) and Americanized scholar James Kerafyrm thatch (Crafts J) jointly find.They obtain tetraethyl silicane with silicon tetrachloride and zinc ethyl reaction.It is simple that carbon-silicon compound---silicon carbide is mineral compound.
Organosilicon material, by the difference of its form, can be divided into: silane coupling agent (organosilicon chemical reagent), biological active organic silicon, silicone oil (silicone grease, silicon emulsion, Silicon surfactant), high-temperature silicon disulfide rubber, liquid silastic, silicone resin, mixture etc.
2 organosilicon performances
Organosilicon product is taking silicon-oxygen (Si-O) key as backbone structure, the bond energy of C-C key is 82.6 kilocalories/mol, the bond energy of Si-O key is 121 kilocalories/mol in organosilicon, so the thermostability of organosilicon product is high, under high temperature, the chemical bond of (or radiation irradiation) molecule does not rupture, does not decompose.Organosilicon not only can be high temperature resistant, and low temperature resistant, can in a very wide temperature range, use.No matter be chemical property or physical and mechanical properties, variation with temperature is all very little.
The main chain of organosilicon product is-Si-O-that unparalleled key exists, and is therefore difficult for being decomposed by UV-light and ozone.Organosilicon has than the better thermostability of other macromolecular materials and resistance to irradiation and weather-proof ability.Can reach decades the work-ing life in organosilicon under physical environment.
Organosilicon product all has good electrical insulation capability, its dielectric loss, proof voltage, resistance to electric arc, resistance to corona, volume resistivity and surface resistivity etc. all come out at the top in insulating material, and their electric property is subject to the impact of temperature and frequency very little.Therefore, they are a kind of stable electrically insulating materials, are widely used in electronics, electrical industry.Organosilicon, except having good thermotolerance, also has excellent water repellency, and this is that electric installation uses the guarantee with high reliability under hygrometric state condition.
Biological active organic silicon is a kind of nutrient substance of needed by human.Organosilicon is to form tissue and participate in metabolic important element.Be stored in the middle of each cell of human body, as the support of cell construction, help other important substance as magnesium, phosphorus, the absorptions such as calcium simultaneously.Human body can only constantly obtain organosilicon by food.
Scientists thinks, organosilicon is mainly present in human body with three kinds of forms:
(1) solubility organosilicon, accounts for 10% of weight;
(2) percent 30 are present in various cell matrixs;
(3) 60% be used for synthetic protein this illustrate that our every days, required organosilicon was quite high.
If keep 5 years, within 10 years, be even the young degree of 30 years, the organosilicon of taking in organosilicon 20-30 milligram every day is particularly important.
3 organic silicon water-proofings
Organosilyl main chain is very submissive, its intermolecular reactive force a little less than than hydrocarbon polymer many, therefore, low than the hydrocarbon polymer viscosity of same molecular weight, a little less than surface tension, surface can be little, film forming ability is strong.This low surface tension and low surface energy are the major causes that its obtains many-sided application: every excellent properties such as hydrophobic, froth breaking, foam stabilization, antiseized, lubricated, glazing.Primary study waterproof of the present invention.
Waterproofing agent of organosilicon has two types of water-based and oiliness.
The waterproofing agent of organosilicon of water-based is colourless or light yellow, and it is mixed in sand-cement slurry, also can play retardant, water reducer and toughener effect.Therefore it is applicable to being applied to the waterproof on building trade, exterior wall finish, underground works, archaized architecture, pond, brick and tile, cement, plastering and the lagging material taking perlite as major ingredient and roof, rural area, moistureproof, anti-pollution processing.
The waterproofing agent of organosilicon of oiliness is transparent, is generally used for glaze, ceramic tile, floor tile, pottery etc., can suitably add partial solvent dilution, easy to use.
4 organic silicon water-proofing principles
Organosilyl the waterproof principle: in the time that poly-silicon breast is heated to more than 140 DEG C, polysiloxane aligns on fabric, hydrophobic group---CH3 outwardly, some atom on Siliciumatom, Sauerstoffatom and the fiber of silicone oil emulsion forms dative bond and hydrogen bond, thereby water vapor, air can pass through fabric, the globule but can not see through.The hydroxyl on silicone oil emulsion chain top and containing hydrogen silicone oil grafting, in containing hydrogen silicone oil, Si.H key is hydrolyzed into Si.H, and it and silicone oil terminal hydroxy group dehydration grafting form long chain molecule, and molecular change obtains larger, more soft, can increase water repellency.Silicone oil and containing hydrogen silicone oil 150-180 DEG C is cross-linked to form water insoluble and organopolysiloxane resin molding solvent at fabric face.In silane structure, methyl, produces water repellency outwardly, the discontinuous and ventilation property of film.
5 organosilicon purposes
Due to the structure of organosilicon uniqueness, have both the performance of inorganic materials and organic materials, there is surface tension low, temperature coefficient of viscosity is little, compressibility is high, the high essential property that waits of gas permeability, and there is high-low temperature resistant, electric insulation, resistance to oxidation stability, weathering resistance, difficult combustion, hydrophobic, corrosion-resistant, the excellent specific properties such as nonpoisonous and tasteless and physiology inertia, be widely used in aerospace, electric, building, transport, chemical industry, weaving, food, light industry, the industries such as medical treatment, wherein organosilicon is mainly used in sealing, bonding, lubricated, coating, surfactivity, the demoulding, froth breaking, press down bubble, waterproof, moistureproof, inertia filling etc.Along with the sustainable growth of organosilicon quantity and kind, Application Areas is constantly widened, and forms the new chemical materials circle staple product system of taking the course of its own, and many kinds are that other chemical cannot substitute and requisite.
Organism metabolism also needs organosilicon to participate in, and this type of organosilicon chemical formula shows as CH3 (SiOH) 3 conventionally.Organosilicon plays an important role for health various functions and has direct relation with the absorption of mineral substance.Human body on average has approximately seven grams of silicon, and its quantity is considerably beyond other important minerals, as iron.Iron and silicon are needed by human, are very important effects to maintaining normal metabolism.
Organosilyl water-proof function, be widely used in the interior exterior wall of various buildingss, especially can solve the ubiquitous Dong Qiang in civilian room, the north wall indoor problem of going mouldy causing that seeps water. it can also be widely used in the moistureproof and mildewproof processing before upholstery in addition, in industrial premises the antipollution of exterior wall keep a public place clean, weathering resistance, acid rain preventing processing, and the waterproofing work of reservoir, water tower, water reservoir, sewage work and agricultural drainage and irrigation channel; Also all applicable for ancient building, stone tablet, ceramic tile, book and file chamber, precision instrument room and computer room, change power distribution room, warehouse etc.
6 organosilicon industry prospects
China has become the maximum country of consumption of organosilicon material.Due to weaving, the thriving demands of industry to organosilicon material such as a large amount of outlets of electronics, electric equipment products and domestic construction, weaving, automobile, daily use chemicals, promote and have promoted the development of China's organosilicon material.2010 China's siloxanes consumptions reach 55.5 ten thousand tons, account for 36% of global total amount, become the organosilyl maximum country of consumption in the whole world; China, taking processing manufacturing industry as main industrial pattern, has caused Chinese organosilicon consumption structure and other countries and regions, the whole world to have very big difference, and other countries and regions silicon rubber and silicone oil accounting are average, and China is taking silicon rubber as main.
During " 12 ", China's organosilicon consumption average growth rate per annum is estimated to remain on 18% left and right, and siloxanes consumption in 2015 is estimated to reach approximately 1,300,000 tons, amounts to approximately 2,600,000 tons of organosilane monomers.2010, approximately 410,000 tons of Chinese organosilicon (folding siloxanes) output; 55.5 ten thousand tons of consumptions.Organosilicon continues to keep steady-state growth in traditional Application Areas on the one hand, continually develop at aspects such as new forms of energy, energy-conserving and environment-protective, health care and high-end manufactures the purposes making new advances on the other hand, particularly, aspect solar cell, LED, personal-care supplies, track traffic and petroleum replacing base product, its application is rapidly developed.Owing to having the wide market space, organosilicon has been put into novel material " 12 " planning.More than 20 organosilicon product listed the products catalogue of novel material " 12 " planning in.
Organosilicon " 12 " is planned strict access threshold, controls production capacity and increases, and 2015 annual capacities reach 3,000,000 tons, meets domestic needs slightly outlet outward.Planning proposes, and forms the organosilane monomer leading enterprise of 3-5 family's international competitiveness by 2015.Planning demonstration, silane coupling agent will build up the enterprise that 2-3 scale exceedes 30,000 tons/year, adopts green environmental protection technique production, and 2015 gross annual output amounts reach 400,000 tons, and kind quantity exceedes 100.The plant of biological active organic silicon is purified and only has so far developed country's grasps such as French.Organosilicon makes organosilicon product have huge application prospect to the vital role of organism.Within the coming years, utilize the organosilicon product that vegetable active extracts at medicine, to improve looks, the field explosive types such as health care are expanded.The consumption of organosilicon product in all trades and professions, than row, is depended on the industrial structure at that time.Taking Japan as example, be assigned as in 1988: electronic apparatus accounts for 25%-30%, building accounts for 15%-20%, automobile accounts for 10%-15%, food medical treatment accounts for 10%, and office machinery accounts for 10%, and all the other (comprising fiber, paper, plastics, coating etc.) account for 15%-30%.Visible, the three large pillars in electronic apparatus, building and automobile Shi Gai state's organosilicon market.Market trend in recent years, electric tempo still ranks first, and the reliability of organosilicon material and weather resistance make its application in building and automobile industry be continued to increase; Because the physiology inertia of siloxanes and safety, reliability to human body are further confirmed, thereby the number of applications sharp increase of organosilicon in medical treatment and makeup.
7 organosilicon supply and demand situations
Between 6 years of 2002～2008, along with the high speed development in China's Room temperature silicone rubber market, organosilicon manufacturing enterprise of foreign country arranges production base one after another at home, and domestic production producer also significantly carries out production capacity expansion, industry production capacity average growth rate per annum is 17.9%, and average annual growth of output is 17.3%.Cut-off was to 2008, and China's Room temperature silicone rubber aggregated capacity reaches 350,000 tons, and ultimate production reaches 260,000 tons.And consumption reaches 27.5 ten thousand tons, there is certain supply breach.
Coming 10 years is the important period of China's socio-economic development; for realizing the objective of the struggle of off; China is optimizing structure, is increasing the benefit, is reducing on the basis of consumption, protection of the environment; steadily improve ratio of consumption, improve the people's livelihood comprehensively, form save energy resource and the industrial structure of preserving the ecological environment, growth pattern, consumption mode, the utilisation technology exploitation that this is Room temperature silicone rubber and further develop the market space and the opportunity to develop that provide huge.The following further increase along with China's silicone intermediate supply, China's Room temperature silicone rubber product will enter into common people house, estimate that its demand will remain on average annual 13.2% rapid growth at the five-year, its market impellent is still mainly at building and industrial circle.Room temperature silicone rubber is because the function difference of various product is larger, and Application Areas is also not quite similar, and therefore aspect the market supply and demand, also embodies different characteristics.
(1) market supply and demand situation on building field
The consumer objects of Room temperature silicone rubber maximum is building trade.No matter in the U.S., Japan or European, construction industry all occupy the first with the consumption of silicon rubber always, accounted for respectively 44%, 38% and 40% (data source: organosilicon material, 2008,22 (5) 261～267) of each department aggregate consumption in 2006.Along with the in-depth development of China's urbanization, construction industry will be in the development trend of long-term growth, and Room temperature silicone rubber also will present long-term growth situation in the demand of construction industry.
Room temperature silicone rubber mainly comprises aspect three of the sealing of building curtain wall, building construction and the processing of door and window energy-saving glass at present in the application of building field.2008, approximately 6.1 ten thousand tons of the Room temperature silicone rubbers that building curtain wall field consumes, accounted for 22.2% of the whole Room temperature silicone rubber consumptions of China, and 5 years average growth rates per annum of future are 5%; The Room temperature silicone rubber that doors and windows sealing and decorations field consume adds up to 6.1 ten thousand tons, accounts for 22.2% of the whole Room temperature silicone rubber consumptions of China, is the Application Areas of market capacity maximum, and 5 years average growth rates per annum of future are 10.6%; The Room temperature silicone rubber that double glazing manufacture field consumes adds up to 2.4 ten thousand tons, accounts for 8.7% of the whole Room temperature silicone rubber consumptions of China, and 5 years average growth rates per annum of future are 20%.Double glazing processing will become the application that Room temperature silicone rubber demand growth in building field is the fastest.Building field has been concentrated the traditional bulk product of Room temperature silicone rubber, and manufacturer is numerous, and technology is generally ripe, and competition fully.The coming five years, the Room temperature silicone rubber output in this field and consumption all increase to some extent, but increase of production will be faster, since China's field for building room temperature silicon rubber in 2011, totally by the situation that occurs that supply exceed demand, some product will export to world market.
(2) supply and demand situation on major industry field
Manufacture field at automobile and other transportation means.China's auto output in 2008 has reached 934.5 ten thousand 2001～2008 average growth rates per annum and has reached 22.7%, and China's auto output has exceeded the U.S. and occupied the second in the world.According to external current research, increase the consumption of organosilicon material aspect automobile component, can increase substantially the safety performance of automobile, in the U.S., on every automobile, organosilicon material has the purposes more than exceeding 40, therefore all increases to Room temperature silicone rubber demand by propelling vehicle industry of raising of auto output and bicycle consumption level.The Room temperature silicone rubber of automotive field consumption in 2008 adds up to 20,000 tons, accounts for 7.3% of the whole Room temperature silicone rubber consumptions of China, and 5 years average growth rates per annum of future are 30%.
In electronics and radio industry field.China is the maximum electronic product producing country in the whole world at present, and all over the world, since 1999, the average growth rate per annum of electronic devices and components professional income remains on more than 30% Product Marketing.The Room temperature silicone rubber of electronic applications consumption in 2008 adds up to 2.2 ten thousand tons, accounts for 8% of the whole Room temperature silicone rubber consumptions of China, and 5 years average growth rates per annum of future are 23%.
At power domain.The Room temperature silicone rubber of power domain consumption in 2008 adds up to 1.2 ten thousand tons, accounts for 4.4% of the whole Room temperature silicone rubber consumptions of China, and 5 years average growth rates per annum of future are 25%.In major industry Application Areas, performance and the technical requirement of client to Room temperature silicone rubber product varies, require manufacturing enterprise to there is very strong research and development technology strength, domestic Jin You minority local enterprise can provide such product, therefore mainly relies on import or is produced by foreign capital affiliate magnificent.Due to otherness and the existence situation that supply falls short of demand of product, therefore client has higher ability to bear conventionally to the product price that can meet its requirement.
Up to now, on market, sell water-resisting agent of all kinds, but all have its defect: can not be high temperature resistant, dry slow, poor permeability, change original color, water-repellancy be poor, preparation method's complexity, can not meet the demand in market.
Summary of the invention
The object of the invention is to change the synthetic thinking of tradition, make up prior art deficiency, a kind of strong osmotic water-resisting agent and preparation method thereof is provided.
To achieve these goals, technical scheme of the present invention is such:
A kind of strong osmotic water-resisting agent, described water-resisting agent is under condition of normal pressure, and each component is added in container successively one by one, makes by stirring, temperature control, filtration step; Described water-resisting agent comprises following component and mass parts thereof: organosilicon macromolecule 1.8-2.5; Permeate agent 0.1-0.3; Flow agent 0.1-0.3; Defoamer 0.1-0.3; Dispersion agent 0.1-0.3; Solubility promoter 96-98.
In technique scheme, described water-resisting agent comprises following component and mass parts thereof: organosilicon macromolecule 2.2; Permeate agent 0.2; Flow agent 0.2; Defoamer 0.2; Dispersion agent 0.2; Solubility promoter 97.
In technique scheme, described organosilicon macromolecule is a kind of of tri-methyl-chlorosilane, dimethyldichlorosilane(DMCS) and METHYL TRICHLORO SILANE or 2～3 kinds.
In technique scheme, described permeate agent is sulfated castor oil, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium, Seconary Alkane Sulphonate Sodium, secondary alkyl sulphate sodium, a mono-sodium olefin sulfonate, sodium alkyl naphthalene sulfonate, succsinic acid alkyl ester sodium sulfonate, Igepon T, thionamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphate compounds, and alcohol compound, ketone, ethers a kind of or 2～3 kinds.
In technique scheme, described flow agent is polysiloxane-based (U.S. Dow Corning Co.), cellulose acetate butyrate class (U.S. Eastman Co.), acrylate copolymer (U.S. Rohm & Hass Co., Monsanto Co.), flow agent for emulsion paint (Diamond-Shamrock), solvent-thinned paint flow agent (Germany BYK-Mallinck-rodt), cellulose acetate butyrate class flow agent, acrylate copolymer flow agent a kind of or 2～3 kinds.
In technique scheme, described defoamer is the one of lower alcohol system as methyl alcohol, ethanol, Virahol, sec-butyl alcohol, propyl carbinol or 2～3 kinds.
In technique scheme, described dispersion agent is a kind of of non-ionic type and ionogenic surfactant, 2-amino-2-methyl-1-propanol (AMP-95) or 2～3 kinds.
In technique scheme, described solubility promoter is a kind of of ethanol, ethyl acetate, No. 120 solvent oils, No. 180 solvent oils, No. 200 solvent oils or 2～3 kinds.
A preparation method for strong osmotic water-resisting agent, described preparation method comprises following processing step: one, get organosilicon macromolecule 1.8-2.5kg and insert in container, add solubility promoter 96-98kg under stirring, temperature control 15-50 DEG C is reacted 1 hour, for subsequent use; Two, treat that in step 1, reactant is bright, add permeate agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use; Three, treat that in step 2, reactant is bright, add flow agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use; Four, treat that in step 3, reactant is bright, add defoamer 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use; Five, treat that in step 4, reactant is bright, add dispersion agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use; Six, the reactant in step 5 is filtered to packaging warehouse-in through 300 order stainless (steel) wires.
In technique scheme, described organosilicon molecule content is that 2.2kg, solubility promoter content are that 97kg, permeate agent content are that 0.2kg, flow agent content are that 0.2kg, antifoam content are that 0.2kg, dispersant are 0.2kg; Described temperature control is 30 DEG C.
The present invention has following advantage and positively effect:
(1) the present invention adopts the mode of synthesis under normal pressure to synthesize, and has avoided the synthetic risk of High Temperature High Pressure;
(2) production method is simple;
(3) synthetics of the present invention produces without " three wastes ", synthetic ratio 100%;
(4) resistance to temperature resistance strong (high and low temperature all can), strong osmotic can reach 3-5mm, fast drying (5 minutes is visual effects, 6 hours complete dryinies), not change the advantages such as original color, nontoxic pollution-free;
(5) described water-resisting agent viscosity adjustment can be become below 1mPa.s (25 DEG C) according to height infiltration requirement;
Owing to solving in time the interior exterior wall of various buildingss, especially can solve the ubiquitous Dong Qiang in civilian room, the north wall indoor problem of going mouldy causing that seeps water.Therefore have broad application prospects.
The present invention can be widely used in the moistureproof and mildewproof processing before upholstery, in industrial premises the antipollution of exterior wall keep a public place clean, weathering resistance, acid rain preventing processing, and the waterproofing work of reservoir, water tower, water reservoir, sewage work and agricultural drainage and irrigation channel; Also all applicable for ancient building, stone tablet, ceramic tile, book and file chamber, precision instrument room and computer room, change power distribution room, warehouse etc.This product is also widely used in the WATER REPELLENT of stone material industry, woodwork, textiles.
Embodiment
Further illustrate below by embodiment.
Embodiment 1
1. the interior exterior wall strong osmotic water-resisting agent proportioning (mass ratio) of buildings
2. preparation method
(1) get organosilicon macromolecule 2.0kg, under stirring, add solubility promoter 97.6kg, 30 DEG C of reactions of temperature control 1 hour;
(2) question response thing is bright, adds permeate agent 0.11kg under stirring, 30 DEG C of reactions of temperature control 0.5 hour;
(3) question response thing is bright, adds flow agent 0.11kg under stirring, 30 DEG C of reactions of temperature control 0.5 hour;
(4) question response thing is bright, adds defoamer 0.11kg under stirring, 30 DEG C of reactions of temperature control 0.5 hour;
(5) question response thing is bright, adds dispersion agent 0.11kg under stirring, 30 DEG C of reactions of temperature control 0.5 hour;
(6) filter packaging warehouse-in through 300 order stainless (steel) wires.
Embodiment 2
1. ancient building strong osmotic water-resisting agent proportioning (mass ratio)
2. preparation method
(1) get organosilicon macromolecule 1.9kg, under stirring, add solubility promoter 97.5kg, 25 DEG C of reactions of temperature control 1 hour; (2) question response thing is bright, adds permeate agent 0.2kg under stirring, 25 DEG C of reactions of temperature control 0.5 hour;
(3) question response thing is bright, adds flow agent 0.2kg under stirring, 25 DEG C of reactions of temperature control 0.5 hour;
(4) question response thing is bright, adds defoamer 0.15kg under stirring, 25 DEG C of reactions of temperature control 0.5 hour;
(5) question response thing is bright, adds dispersion agent 0.15kg under stirring, 25 DEG C of reactions of temperature control 0.5 hour;
(6) filter packaging warehouse-in through 300 order stainless (steel) wires.
The examining report (seeing appendix) of the strong osmotic water-resisting agent of preparing according to embodiment 1.
Claims (10)
1. a strong osmotic water-resisting agent, is characterized in that: described water-resisting agent is under condition of normal pressure, and each component is added in container successively one by one, makes by stirring, temperature control, filtration step; Described water-resisting agent comprises following component and mass parts thereof:
2. strong osmotic water-resisting agent according to claim 1, is characterized in that: described water-resisting agent comprises following component and mass parts thereof:
3. strong osmotic water-resisting agent according to claim 1 and 2, is characterized in that: described organosilicon macromolecule is a kind of of tri-methyl-chlorosilane, dimethyldichlorosilane(DMCS) and METHYL TRICHLORO SILANE or 2～3 kinds.
4. strong osmotic water-resisting agent according to claim 1 and 2, it is characterized in that: described permeate agent is sulfated castor oil, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, alkyl sulfuric ester sodium, Seconary Alkane Sulphonate Sodium, secondary alkyl sulphate sodium, a mono-sodium olefin sulfonate, sodium alkyl naphthalene sulfonate, succsinic acid alkyl ester sodium sulfonate, Igepon T, thionamic acid sodium, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyethers, phosphate compounds, and alcohol compound, ketone, ethers a kind of or 2～3 kinds.
5. strong osmotic water-resisting agent according to claim 1 and 2, is characterized in that: described flow agent is polysiloxane-based, cellulose acetate butyrate class, acrylate copolymer, flow agent for emulsion paint, solvent-thinned paint flow agent, cellulose acetate butyrate class flow agent, acrylate copolymer flow agent a kind of or 2～3 kinds.
6. strong osmotic water-resisting agent according to claim 1 and 2, is characterized in that: described defoamer is the one of lower alcohol system as methyl alcohol, ethanol, Virahol, sec-butyl alcohol, propyl carbinol or 2～3 kinds.
7. strong osmotic water-resisting agent according to claim 1 and 2, is characterized in that: described dispersion agent is a kind of of non-ionic type and ionogenic surfactant, 2-amino-2-methyl-1-propanol or 2～3 kinds.
8. strong osmotic water-resisting agent according to claim 1 and 2, is characterized in that: described solubility promoter is a kind of of ethanol, ethyl acetate, No. 120 solvent oils, No. 180 solvent oils, No. 200 solvent oils or 2～3 kinds.
9. a preparation method for strong osmotic water-resisting agent, is characterized in that: described preparation method comprises following processing step:
One, get organosilicon macromolecule 1.8-2.5kg and insert in container, add solubility promoter 96-98kg under stirring, temperature control 15-50 DEG C is reacted 1 hour, for subsequent use;
Two, treat that in step 1, reactant is bright, add permeate agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use;
Three, treat that in step 2, reactant is bright, add flow agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use;
Four, treat that in step 3, reactant is bright, add defoamer 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use;
Five, treat that in step 4, reactant is bright, add dispersion agent 0.1-0.3kg under stirring, temperature control 15-50 DEG C is reacted 0.5 hour, for subsequent use;
Six, the reactant in step 5 is filtered to packaging warehouse-in through 300 order stainless (steel) wires.
10. the preparation method of strong osmotic water-resisting agent according to claim 9, is characterized in that: described organosilicon molecule content is that 2.2kg, solubility promoter content are that 97kg, permeate agent content are that 0.2kg, flow agent content are that 0.2kg, antifoam content are that 0.2kg, dispersant are 0.2kg; Described temperature control is 30 DEG C.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313913A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Penetrating agent with high adsorption capacity for leather |
| CN105155306A (en) * | 2015-07-23 | 2015-12-16 | 百宁纺织化工(中山)有限公司 | Formula for osmotic agent |
| CN107189654A (en) * | 2017-07-20 | 2017-09-22 | 合肥安力电力工程有限公司 | A kind of power equipment anti-oxidant insulated paint of waterproof |
| CN109094134A (en) * | 2018-06-28 | 2018-12-28 | 福田实业有限公司 | A kind of composite material-feeding |
| CN111117329A (en) * | 2019-12-13 | 2020-05-08 | 河南普绿环保科技有限公司 | Environment-friendly building construction and decoration coating and preparation method thereof |
| CN112239954A (en) * | 2020-09-17 | 2021-01-19 | 江苏吉良新材料科技有限公司 | Preparation method and equipment of fluoride-free waterproof agent |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1394931A (en) * | 2001-07-05 | 2003-02-05 | 张友新 | Tiangong permeable water-proofing agent |
| CN101386780A (en) * | 2007-09-11 | 2009-03-18 | 嘉兴联合化学有限公司 | Water proof anti-seepage agent for maritime building and structure |
| CN101624501A (en) * | 2009-08-11 | 2010-01-13 | 伍少欢 | Inorganic-organic colored waterproofing agent |
| CN102161864A (en) * | 2011-01-18 | 2011-08-24 | 天津游龙科技发展有限公司 | Preparation method and use of organic fIuorosiIane waterproofing agent |
| JP2011213813A (en) * | 2010-03-31 | 2011-10-27 | Cci Corp | Water repellent coating composition for glass |
-
2014
- 2014-06-25 CN CN201410291047.8A patent/CN104109470B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1394931A (en) * | 2001-07-05 | 2003-02-05 | 张友新 | Tiangong permeable water-proofing agent |
| CN101386780A (en) * | 2007-09-11 | 2009-03-18 | 嘉兴联合化学有限公司 | Water proof anti-seepage agent for maritime building and structure |
| CN101624501A (en) * | 2009-08-11 | 2010-01-13 | 伍少欢 | Inorganic-organic colored waterproofing agent |
| JP2011213813A (en) * | 2010-03-31 | 2011-10-27 | Cci Corp | Water repellent coating composition for glass |
| CN102161864A (en) * | 2011-01-18 | 2011-08-24 | 天津游龙科技发展有限公司 | Preparation method and use of organic fIuorosiIane waterproofing agent |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104313913A (en) * | 2014-10-25 | 2015-01-28 | 合肥市安山涂层织物有限公司 | Penetrating agent with high adsorption capacity for leather |
| CN105155306A (en) * | 2015-07-23 | 2015-12-16 | 百宁纺织化工(中山)有限公司 | Formula for osmotic agent |
| CN107189654A (en) * | 2017-07-20 | 2017-09-22 | 合肥安力电力工程有限公司 | A kind of power equipment anti-oxidant insulated paint of waterproof |
| CN109094134A (en) * | 2018-06-28 | 2018-12-28 | 福田实业有限公司 | A kind of composite material-feeding |
| CN111117329A (en) * | 2019-12-13 | 2020-05-08 | 河南普绿环保科技有限公司 | Environment-friendly building construction and decoration coating and preparation method thereof |
| CN112239954A (en) * | 2020-09-17 | 2021-01-19 | 江苏吉良新材料科技有限公司 | Preparation method and equipment of fluoride-free waterproof agent |
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