CN104313913A - Penetrating agent with high adsorption capacity for leather - Google Patents
Penetrating agent with high adsorption capacity for leather Download PDFInfo
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- CN104313913A CN104313913A CN201410575552.5A CN201410575552A CN104313913A CN 104313913 A CN104313913 A CN 104313913A CN 201410575552 A CN201410575552 A CN 201410575552A CN 104313913 A CN104313913 A CN 104313913A
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- penetrating agent
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- moss
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- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a penetrating agent with high adsorption capacity for leather. The penetrating agent with high adsorption capacity for leather is prepared from the following raw materials in parts by weight: 40-50 parts of phenethyl naphthol polyoxyethylene ether, 6-8 parts of ethylene glycol monobutyl ether, 25-30 parts of rosin resin, 4-5 parts of linear alkyl benzene sulphonic acid, 8-10 parts of phthalic anhydride, 2-4 parts of cyclohexanone, 4-6 parts of sodium formate, 7-8 parts of p-tert-butyl benzoic acid, 15-20 parts of modified moss and 45-55 parts of water. The penetrating agent with high adsorption capacity for leather has a good osmotic effect and an emulsifying effect and also has low-foam and anti-foaming functions, so that the penetrating agent with high adsorption capacity is environmentally friendly; the obtained penetrating agent does not contain environmentally harmful substances and also has good penetration performance; and the prepared penetrating agent has large specific surface area and strong adsorption capacity by virtue of modification treatment on the moss.
Description
Technical field
The present invention relates to textile printing and dyeing technology, be specifically related to a kind of high absorption capacity leather bleeding agent.
Background technology
More in current bleeding agent is adopt the surfactant of anionic, nonionic surface active agent and different ions type to carry out composite use, to reach comparatively ideal synergy; But great majority are in order to consider cost and result of use, sodium alkyl benzene sulfonate (ABS) and the alkylphenol polyoxyethylene (APEO) of anion is mostly have employed in formula, everyly need chemosmotic place and all will add bleeding agent, its Main Function reduces interfacial tension, is applied to all trades and professions such as weaving, printing and dyeing, leather, papermaking, agricultural chemicals, chemical industry.
Summary of the invention
The object of the present invention is to provide a kind of high absorption capacity leather bleeding agent.
The present invention adopts following technical scheme to achieve these goals:
High absorption capacity leather bleeding agent, the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 40-50, different glycol monobutyl ether 6-8, abietic resin 25-30, linear alkyl benzene sulphonic acid 4-5, phthalic anhydride 8-10, cyclohexanone 2-4, sodium formate 4-6, p-tert-butyl benzoic acid 7-8, modification moss 15-20 and water 45-55.
High absorption capacity leather bleeding agent, the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
The preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate again, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven.
Beneficial effect of the present invention:
High absorption capacity bleeding agent provided by the invention not only has good osmosis and emulsifying effectiveness, and also having low bubble, press down bubble function, is a kind of environmental type bleeding agent; The bleeding agent of gained is not containing environmentally harmful material and permeance property is good, and by the modification to moss, made bleeding agent specific area is large, high adsorption capacity.
Detailed description of the invention
Embodiment 1: high absorption capacity leather bleeding agent, the weight portion (kg) of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
The preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 5% acrylic acid, 2.5% ammonium persulfate again, stir 3-4h at 85 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2 times amount, after mixing, be placed on 105 DEG C of oven dry 35min in baking oven.
Bleeding agent pH value of the present invention is 6.8, cloud point is 34.8 DEG C, water-soluble and the organic solvent of energy, sedimentation time is 65s, and there is very high adsorption capacity and permeability, bleeding agent of the present invention mixes formation dye liquor, in whole dyeing course with water, KOH, dyestuff etc., obvious lamination is there is not, the fabric uniform in color dyed in dye vat.
Claims (3)
1. a high absorption capacity leather bleeding agent, is characterized in that the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 40-50, different glycol monobutyl ether 6-8, abietic resin 25-30, linear alkyl benzene sulphonic acid 4-5, phthalic anhydride 8-10, cyclohexanone 2-4, sodium formate 4-6, p-tert-butyl benzoic acid 7-8, modification moss 15-20 and water 45-55.
2. high absorption capacity leather bleeding agent according to claim 1, is characterized in that the weight portion of its constitutive material is: phenethyl naphthols polyoxyethylene ether 45, different glycol monobutyl ether 7, abietic resin 28, linear alkyl benzene sulphonic acid 4.5, phthalic anhydride 9, cyclohexanone 3, sodium formate 5, p-tert-butyl benzoic acid 7.5, modification moss 18 and water 50.
3. high absorption capacity leather bleeding agent according to claim 1, it is characterized in that: the preparation of described modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, then put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575552.5A CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575552.5A CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104313913A true CN104313913A (en) | 2015-01-28 |
Family
ID=52369214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410575552.5A Pending CN104313913A (en) | 2014-10-25 | 2014-10-25 | Penetrating agent with high adsorption capacity for leather |
Country Status (1)
| Country | Link |
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| CN (1) | CN104313913A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521992A (en) * | 2016-11-24 | 2017-03-22 | 肇庆高新区飞越信息科技有限公司 | High temperature resistant penetrant for leather dyeing |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827668A (en) * | 1994-07-13 | 1996-01-30 | Sanyo Chem Ind Ltd | Penetrant |
| US20020198287A1 (en) * | 2001-03-12 | 2002-12-26 | Seiko Epson Corporation | Ink for ink jet printing process and printed matter obtained using the same |
| CN103030966A (en) * | 2012-12-24 | 2013-04-10 | 建德市顺发化工助剂有限公司 | Preparation method of high-efficiency penetrant for PU synthetic leather |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
| CN104109470A (en) * | 2014-06-25 | 2014-10-22 | 武汉黑豹防漏技术开发有限公司 | Strong permeability waterproof agent and preparation method thereof |
-
2014
- 2014-10-25 CN CN201410575552.5A patent/CN104313913A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0827668A (en) * | 1994-07-13 | 1996-01-30 | Sanyo Chem Ind Ltd | Penetrant |
| US20020198287A1 (en) * | 2001-03-12 | 2002-12-26 | Seiko Epson Corporation | Ink for ink jet printing process and printed matter obtained using the same |
| CN103030966A (en) * | 2012-12-24 | 2013-04-10 | 建德市顺发化工助剂有限公司 | Preparation method of high-efficiency penetrant for PU synthetic leather |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
| CN104109470A (en) * | 2014-06-25 | 2014-10-22 | 武汉黑豹防漏技术开发有限公司 | Strong permeability waterproof agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521992A (en) * | 2016-11-24 | 2017-03-22 | 肇庆高新区飞越信息科技有限公司 | High temperature resistant penetrant for leather dyeing |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |