CN104107689A - 一种大孔径纳米复合材料及其制备方法 - Google Patents
一种大孔径纳米复合材料及其制备方法 Download PDFInfo
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- CN104107689A CN104107689A CN201310135715.3A CN201310135715A CN104107689A CN 104107689 A CN104107689 A CN 104107689A CN 201310135715 A CN201310135715 A CN 201310135715A CN 104107689 A CN104107689 A CN 104107689A
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- Prior art keywords
- zinc oxide
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- composite material
- epoxy resin
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- 239000002114 nanocomposite Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 97
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000011787 zinc oxide Substances 0.000 claims abstract description 36
- 239000003822 epoxy resin Substances 0.000 claims abstract description 27
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 27
- 239000000243 solution Substances 0.000 claims abstract description 24
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 20
- 239000013078 crystal Substances 0.000 claims abstract description 19
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 9
- IWLXWEWGQZEKGZ-UHFFFAOYSA-N azane;zinc Chemical compound N.[Zn] IWLXWEWGQZEKGZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007864 aqueous solution Substances 0.000 claims abstract description 5
- 239000011148 porous material Substances 0.000 claims description 32
- 239000002070 nanowire Substances 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000002202 Polyethylene glycol Substances 0.000 claims description 19
- 239000012528 membrane Substances 0.000 claims description 19
- 229920001223 polyethylene glycol Polymers 0.000 claims description 19
- 239000002131 composite material Substances 0.000 claims description 18
- 239000011701 zinc Substances 0.000 claims description 18
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 15
- 239000011159 matrix material Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 239000000741 silica gel Substances 0.000 claims description 12
- 229910002027 silica gel Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- 238000005352 clarification Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000002955 isolation Methods 0.000 claims description 5
- 230000014759 maintenance of location Effects 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 5
- 229920002959 polymer blend Polymers 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 4
- 229940007718 zinc hydroxide Drugs 0.000 claims description 4
- 229910021511 zinc hydroxide Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical compound [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 17
- 239000000758 substrate Substances 0.000 abstract description 10
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 8
- 229910052681 coesite Inorganic materials 0.000 abstract description 5
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 5
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 5
- 229910052682 stishovite Inorganic materials 0.000 abstract description 5
- 229910052905 tridymite Inorganic materials 0.000 abstract description 5
- 239000012876 carrier material Substances 0.000 abstract description 2
- 102000004190 Enzymes Human genes 0.000 abstract 2
- 108090000790 Enzymes Proteins 0.000 abstract 2
- 239000011942 biocatalyst Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 239000011941 photocatalyst Substances 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 238000003980 solgel method Methods 0.000 abstract 1
- 229960001296 zinc oxide Drugs 0.000 description 11
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229960003511 macrogol Drugs 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 229960001124 trientine Drugs 0.000 description 3
- 239000000428 dust Substances 0.000 description 2
- 239000011807 nanoball Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000002207 thermal evaporation Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000004549 pulsed laser deposition Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Silicon Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
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CN201310135715.3A CN104107689B (zh) | 2013-04-18 | 2013-04-18 | 一种大孔径纳米复合材料及其制备方法 |
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CN201310135715.3A CN104107689B (zh) | 2013-04-18 | 2013-04-18 | 一种大孔径纳米复合材料及其制备方法 |
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CN104107689A true CN104107689A (zh) | 2014-10-22 |
CN104107689B CN104107689B (zh) | 2016-06-29 |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104628411A (zh) * | 2015-02-05 | 2015-05-20 | 宁波大学 | 一种负载氧化铜纳米线的超大孔材料 |
CN107020055A (zh) * | 2017-06-10 | 2017-08-08 | 安徽工程大学 | 一种SiO2@ZnO核壳结构多足小球纳米复合材料的制备方法及其应用 |
CN108567988A (zh) * | 2018-03-26 | 2018-09-25 | 闽南师范大学 | 一种具有增强香药材有机分子功能的无机活性材料及其制备和应用 |
CN108940363A (zh) * | 2017-05-19 | 2018-12-07 | 宁波大学 | 一种大孔/介孔复合型光催化剂及其制备方法 |
CN108940228A (zh) * | 2017-05-19 | 2018-12-07 | 宁波大学 | 一种能清除空气中颗粒物质的聚合物吸附材料及其制备方法 |
CN113993366A (zh) * | 2021-11-02 | 2022-01-28 | 西安电子科技大学 | 磁控可重构的银纳米线电磁屏蔽膜及制备方法 |
CN115301223A (zh) * | 2022-08-15 | 2022-11-08 | 诺丁汉大学卓越灯塔计划(宁波)创新研究院 | 一种氧化锌或氧化镍光催化剂及其制备方法 |
-
2013
- 2013-04-18 CN CN201310135715.3A patent/CN104107689B/zh not_active Expired - Fee Related
Non-Patent Citations (4)
Title |
---|
JINWOONG KIM ET AL.: "Patterned horizontal growth of ZnO nanowires on SiO2 surface", 《CURRENT APPLIED PHYSICS》 * |
LINGLING WANG ET AL.: "Bioinspired Preparation of Ultrathin SiO2 Shell on ZnO Nanowire Array for Ultraviolet-Durable Superhydrophobicity", 《LANGMUIR》 * |
T. K. SHING ET AL.: "Growth and Patterning of ZnO Nanowires on Silicon and LiNbO3 Substrates", 《TAMKANG JOURNAL OF SCIENCE AND ENGINEERING》 * |
YUNG-KUAN TSENG ET AL.: "Characterization and Field-Emission Properties of Needle-like Zinc Oxide Nanowires Grown Vertically on Conductive Zinc Oxide Films", 《ADV.FUNCT.MATER.》 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104628411A (zh) * | 2015-02-05 | 2015-05-20 | 宁波大学 | 一种负载氧化铜纳米线的超大孔材料 |
CN104628411B (zh) * | 2015-02-05 | 2020-02-11 | 宁波大学 | 一种负载氧化铜纳米线的超大孔材料 |
CN108940363A (zh) * | 2017-05-19 | 2018-12-07 | 宁波大学 | 一种大孔/介孔复合型光催化剂及其制备方法 |
CN108940228A (zh) * | 2017-05-19 | 2018-12-07 | 宁波大学 | 一种能清除空气中颗粒物质的聚合物吸附材料及其制备方法 |
CN108940228B (zh) * | 2017-05-19 | 2020-12-18 | 宁波大学 | 一种能清除空气中颗粒物质的聚合物吸附材料及其制备方法 |
CN108940363B (zh) * | 2017-05-19 | 2021-01-01 | 宁波大学 | 一种大孔/介孔复合型光催化剂及其制备方法 |
CN107020055A (zh) * | 2017-06-10 | 2017-08-08 | 安徽工程大学 | 一种SiO2@ZnO核壳结构多足小球纳米复合材料的制备方法及其应用 |
CN108567988A (zh) * | 2018-03-26 | 2018-09-25 | 闽南师范大学 | 一种具有增强香药材有机分子功能的无机活性材料及其制备和应用 |
CN108567988B (zh) * | 2018-03-26 | 2020-07-10 | 闽南师范大学 | 一种具有增强香药材有机分子功能的无机活性材料及其制备和应用 |
CN113993366A (zh) * | 2021-11-02 | 2022-01-28 | 西安电子科技大学 | 磁控可重构的银纳米线电磁屏蔽膜及制备方法 |
CN115301223A (zh) * | 2022-08-15 | 2022-11-08 | 诺丁汉大学卓越灯塔计划(宁波)创新研究院 | 一种氧化锌或氧化镍光催化剂及其制备方法 |
CN115301223B (zh) * | 2022-08-15 | 2023-11-21 | 诺丁汉大学卓越灯塔计划(宁波)创新研究院 | 一种氧化锌或氧化镍光催化剂及其制备方法 |
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CN104107689B (zh) | 2016-06-29 |
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Effective date of registration: 20190819 Address after: Room 1,020, Nanxun Science and Technology Pioneering Park, No. 666 Chaoyang Road, Nanxun District, Huzhou City, Zhejiang Province, 313000 Patentee after: Huzhou You Yan Intellectual Property Service Co.,Ltd. Address before: 315211 School of materials science and chemical engineering, Ningbo University, 818 Fenghua Road, Zhenhai District, Zhejiang, Ningbo Patentee before: Ningbo University |
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Effective date of registration: 20201126 Address after: 313000 No. 818 Xinhui Road, Lianshi Town, Nanxun District, Huzhou City, Zhejiang Province Patentee after: ZHEJIANG SANXING ELECTRICAL TECHNOLOGY Co.,Ltd. Address before: Room 1,020, Nanxun Science and Technology Pioneering Park, No. 666 Chaoyang Road, Nanxun District, Huzhou City, Zhejiang Province, 313000 Patentee before: Huzhou You Yan Intellectual Property Service Co.,Ltd. |
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