CN1041018A - The fabric preparation and the application of antibacterial finishing agent - Google Patents
The fabric preparation and the application of antibacterial finishing agent Download PDFInfo
- Publication number
- CN1041018A CN1041018A CN 88105618 CN88105618A CN1041018A CN 1041018 A CN1041018 A CN 1041018A CN 88105618 CN88105618 CN 88105618 CN 88105618 A CN88105618 A CN 88105618A CN 1041018 A CN1041018 A CN 1041018A
- Authority
- CN
- China
- Prior art keywords
- finishing agent
- agent
- fabric
- dihydroxy diphenyl
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention is preparation and the application of a kind of fabric with anti-bacteium deodorization finishing agent.It is with fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene as emulsifying agent, chlorinated paraffin be auxiliary agent to 2,4,4 '-three oxygen-2 '-dihydroxy diphenyl ether carries out emulsification and the stability that obtains anti-bacteium deodorization finishing agent preferably.It can be put in order with bathing with other finishing agent of fabric, and the textiles after the arrangement not only has tangible anti-bacterial anti-foul function and washability preferably, and does not influence textiles original physical properties and outward appearance thereof, and is nontoxic to human body skin, non-stimulated and irritated.
Description
The present invention is preparation and the application thereof of a kind of fabric with antibacterial finishing agent, belongs to textiles is carried out the chemical finishing field.
When textiles was carried out anti-bacterial purifying finish, the selection of antiseptic was comparatively crucial.Though the kind of antiseptic is a lot of at present, the antiseptic that can be used for the arrangement of antibacterial textile deodorization is few in number.Because the antibacterial finishing agent that fabric is used requires except that antimicrobial spectrum and antibacterial ability that common antiseptic has, also must have following characteristics: (1) is non-stimulated to human body, does not have irritated; (2) fabric through antibiotic finish has durability (through washing, sterilization etc. are not lost antibiotic property after handling); (3) do not damage the processing material, without detriment to textile appearance; (4) processing method is simple, and is cheap; (5) antibacterial effect is easily differentiated.With 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether (be called for short HD244) as the antibiotic finish antiseptic, can satisfy above-mentioned requirements substantially.But, must be made into earlier and be applicable to that the finishing agent of processing on the conventional equipment is just easy to use because this medicament is water-fast flour.It is more to use the HD244 machining textile, with surfactant HD244 is made O/W type emulsion earlier usually, and then finish fabric, to this, and Japan Patent JP60-90564, JP59-43172, JP59-100766 all have report.But the emulsion stability that makes like this is good inadequately, places one day even a few hours, will the breakdown of emulsion layering, need now with the currently, and brought trouble to use.
The objective of the invention is to propose a kind of higher stability that has, be convenient to antibacterial textile processing, and do not influence the antibacterial finishing agent of anti-microbial property and appearance of fabrics.
Technical characterictic of the present invention is to adopt fatty alcohol-polyoxyethylene ether
(C
nH
2n-1-(OCH
2CH
2)
m-OH n=10-20, m=8-30) and alkylphenol polyoxyethylene
R=C
5～C
20, m=5-15) and as emulsifying agent, with chlorinated paraffin (C
nH
mCL
pN=20-30, m=35-55, p=5-12) be auxiliary agent, with this HD244 is carried out emulsification, obtain stability antibacterial finishing agent preferably.Wherein the preparation of finishing agent be by
HD244: fatty alcohol-polyoxyethylene ether: alkylphenol polyoxyethylene: chlorinated paraffin: water=1: (0.5-4): (0.3-2): (0.2-1): (10-50) under 20-70 ℃ of temperature, HD244 is mixed with various auxiliary agents, add water to ormal weight under stirring and be made into.
Based on 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether is water-fast powder at normal temperatures, be made into stable O/W type emulsion, must select suitable emulsifying agent and proper assistant for use.Be convenient to use with bathing processing for making the emulsion made from other finishing agent, again to be formulated as suitable with non-ionic surfactant and auxiliary agent, the present invention selects fatty alcohol-polyoxyethylene ether for use for this reason, and non-ionic surface active agent such as alkylphenol polyoxyethylene and chlorinated paraffin and auxiliary agent carry out emulsification to HD244.
As if 5～10 times of the finishing agent dilute with waters that will contain HD244 5%, be made into the dressing liquid that contains active material 0.5～1%, outward appearance is creamy white, and stores above not stratified breakdown of emulsion half a year under the room temperature, stable performance.Stable at PH≤12 o'clock finishing agent, finishing agent is also stable when the electrolyte degree of depth in the liquid≤10%.If with other finishing agent one-bath finishing, then dilution proportion 5% finishing agent that contains HD244 is made into dressing liquid equally.
This antibacterial finishing agent can be added in bleaching, dyeing, and resin arrangement, sizing finish adds in the manufacturing procedure such as white arrangement, carries out one-bath finishing with them.Processing object is various natural fabrics such as cotton, hair, silk, fiber crops, or various synthetic fabrics such as terylene, polyamide fibre, acrylic fibers, and their BLENDED FABRIC.The arrangement back does not have influence to original various physical properties of fabric and outward appearance.
The present invention has following outstanding feature:
1. the antibacterial finishing agent excellent storage stability that proposes of the present invention, the resistance to acids and bases scope is bigger, and ionic strength affect is little, is easy to carry out with bathing with other arrangement.
2. this antibiotic finish agent compounding method is easy, and converted goods can be on conventional equipment, to carry out under the common processing conditions.
3. processing object is in extensive range, all can process various textiless.Every physical properties such as the original coloured light of arrangement back fabric, feel, brute force, whiteness have no adverse effects.
4. the fabric after the arrangement of this antibacterial finishing agent has good washability and significant anti-microbial property.By U.S. AATCC-90 standard testing, the textiles after the arrangement is soaped through 50 times and is still had anti-microbial property; By U.S. AATCC-100 standard testing, the textiles after the arrangement is soaped through 50 times, still keeps the bacteriostasis rate more than 90%.
5. the fabric of this antibacterial finishing agent arrangement is non-stimulated and irritated to skin, can be for the human body safe handling.
Below in conjunction with example, the invention will be further elaborated.
1) preparation of antibacterial finishing agent:
HD244 1kg
Fatty alcohol-polyoxyethylene ether 1kg
Alkylphenol polyoxyethylene 1kg
Chlorinated paraffin 0.5kg
Water 16.5kg
Under 25 ℃, stir and form the antibacterial finishing agent 20kg that contains HD244 5%
2) antibiotic finish on the polyester-cotton blend bleaching machine fabric:
Dosing: get above-mentioned finishing agent 10kg, add water 50kg, get dressing liquid 60kg
Padding finishing liquid-dry-bake
Finishing technique: 60% 100 ℃ 180 ℃ of pick-ups
2 minutes 30 seconds
3) polyamide fibre socks antibiotic finish:
Dosing: get the finishing agent 10kg that contains HD244 5% and add water 40kg, get dressing liquid 50kg
Arrangement process: dipping socks product-centrifugal dewatering-drying typing
50% 120 ℃ of liquid carrying rates 20 minutes
Through the fabric of above-mentioned arrangement, test after 50 washings by the method for U.S. AATCC-90, still keep suitable antibacterial effect.
Claims (3)
1, a kind of fabric is carried out the finishing agent of anti-bacterial purifying finish, it is characterized in that it be with fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene as emulsifying agent, be auxiliary agent with chlorinated paraffin, to 2,4,4 '-three chloro-2 ' dihydroxy diphenyl ethers carry out emulsification and form.
2, by the described finishing agent of claim 1, it is characterized in that it prepares in following ratio: 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether: poly alkyl alcohol vinyl chloride ether: alkylphenol polyoxyethylene: water=1: (0.5-4): (0.3-2): (0.2-1): (10-50).
3, by claim 1 or 2 described finishing agents, it is characterized in that it be under 20～70 ℃ with 2,4,4 '-three chloro-2 ' dihydroxy diphenyl ethers mix with various auxiliary agents, add water under the stirring and form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105618 CN1015291B (en) | 1988-12-21 | 1988-12-21 | Fabric antibacterial finishing agent and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88105618 CN1015291B (en) | 1988-12-21 | 1988-12-21 | Fabric antibacterial finishing agent and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1041018A true CN1041018A (en) | 1990-04-04 |
| CN1015291B CN1015291B (en) | 1992-01-08 |
Family
ID=4833795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88105618 Expired CN1015291B (en) | 1988-12-21 | 1988-12-21 | Fabric antibacterial finishing agent and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1015291B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057807C (en) * | 1996-08-29 | 2000-10-25 | 舒军 | Prodn process of physically antiseptic non-woven fabric |
| CN1088557C (en) * | 1999-12-30 | 2002-08-07 | 王雪平 | Persistent disinfectant and preparation process thereof |
| CN100344822C (en) * | 2004-10-19 | 2007-10-24 | 东华大学 | Polycomponent fiber product composite nano antibacterial agent, its preparing method and use |
| CN101144247B (en) * | 2006-09-15 | 2011-05-11 | 高德康 | Special-purpose avian influenza resisting finishing agent for eiderdown and preparation method thereof |
| CN102505467A (en) * | 2011-09-30 | 2012-06-20 | 天津市中科健新材料技术有限公司 | Finishing liquor for realizing antibiosis of fabrics and preparation method of finishing liquor |
| CN103498247A (en) * | 2013-09-09 | 2014-01-08 | 上海婉静纺织科技有限公司 | Chitin fiber and bamboo fiber blended fabric |
| CN103498248A (en) * | 2013-09-09 | 2014-01-08 | 上海婉静纺织科技有限公司 | Tencel bamboo fiber shirt fabric |
| CN103668949A (en) * | 2013-12-18 | 2014-03-26 | 江苏波波熊纺织品有限公司 | Antibacterial emulsion of wool and nylon blended fabric |
| CN104328657A (en) * | 2014-10-20 | 2015-02-04 | 苏州庄爵服饰有限公司 | Antibacterial finishing method used for clothes |
| CN105442312A (en) * | 2015-12-01 | 2016-03-30 | 南通强生安全防护科技有限公司 | Antibacterial cloth as well as preparation method and application thereof |
-
1988
- 1988-12-21 CN CN 88105618 patent/CN1015291B/en not_active Expired
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057807C (en) * | 1996-08-29 | 2000-10-25 | 舒军 | Prodn process of physically antiseptic non-woven fabric |
| CN1088557C (en) * | 1999-12-30 | 2002-08-07 | 王雪平 | Persistent disinfectant and preparation process thereof |
| CN100344822C (en) * | 2004-10-19 | 2007-10-24 | 东华大学 | Polycomponent fiber product composite nano antibacterial agent, its preparing method and use |
| CN101144247B (en) * | 2006-09-15 | 2011-05-11 | 高德康 | Special-purpose avian influenza resisting finishing agent for eiderdown and preparation method thereof |
| CN102505467A (en) * | 2011-09-30 | 2012-06-20 | 天津市中科健新材料技术有限公司 | Finishing liquor for realizing antibiosis of fabrics and preparation method of finishing liquor |
| CN102505467B (en) * | 2011-09-30 | 2016-01-20 | 天津市中科健新材料技术有限公司 | A kind of dressing liquid for antibacterial fabric and preparation method thereof |
| CN103498248A (en) * | 2013-09-09 | 2014-01-08 | 上海婉静纺织科技有限公司 | Tencel bamboo fiber shirt fabric |
| CN103498248B (en) * | 2013-09-09 | 2015-03-18 | 上海婉静纺织科技有限公司 | Tencel bamboo fiber shirt fabric |
| CN103498247A (en) * | 2013-09-09 | 2014-01-08 | 上海婉静纺织科技有限公司 | Chitin fiber and bamboo fiber blended fabric |
| CN103668949A (en) * | 2013-12-18 | 2014-03-26 | 江苏波波熊纺织品有限公司 | Antibacterial emulsion of wool and nylon blended fabric |
| CN104328657A (en) * | 2014-10-20 | 2015-02-04 | 苏州庄爵服饰有限公司 | Antibacterial finishing method used for clothes |
| CN104328657B (en) * | 2014-10-20 | 2016-08-31 | 苏州庄爵服饰有限公司 | Antibiotic finishing method for clothes |
| CN105442312A (en) * | 2015-12-01 | 2016-03-30 | 南通强生安全防护科技有限公司 | Antibacterial cloth as well as preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1015291B (en) | 1992-01-08 |
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