CN104094948A - Ternary pesticide compound containing thiamethoxam and fludioxonil - Google Patents

Ternary pesticide compound containing thiamethoxam and fludioxonil Download PDF

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CN104094948A
CN104094948A CN201410303730.9A CN201410303730A CN104094948A CN 104094948 A CN104094948 A CN 104094948A CN 201410303730 A CN201410303730 A CN 201410303730A CN 104094948 A CN104094948 A CN 104094948A
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fludioxonil
diacloden
tmtd
effective content
ziram
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CN104094948B (en
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刘连盟
黄世文
王玲
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China National Rice Research Institute
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China National Rice Research Institute
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Abstract

A ternary pesticide compound containing thiamethoxam and fludioxonil belongs to the technical field of pesticide compounds. The ternary pesticide compound contains effective components A, B and C, wherein the effective component A is the thiamethoxam; the effective component B is fludioxonil; the effective component C is thiram or ziram, and the effective components A, B and C are at a weight ratio of (1-60):(1-30):(1-60). The ternary pesticide compound containing the thiamethoxam and the fludioxonil, provided by the invention, has a remarkable synergy effect, can expand the prevention and treatment range and improve the pesticide efficacy, can be used as a seed soaking agent, a seed coating agent and a pesticide for preventing and treating diseases and insect pests in the crop seedling period or other periods, efficiently prevents and controls seed and soil spread diseases and insect pest in the seedling period at one time, and can be applied to field crops including paddy rice, wheat and maize, as well as other crops such as vegetables, fruit trees and nursery stocks.

Description

A kind of ternary built agricultural chemicals containing Diacloden, fludioxonil
Technical field
The invention belongs to technical field of compounded pesticide, be specifically related to a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil.
Background technology
Diacloden (Thiamethoxam), chemical name is that (2-chloro-1 for 3-, 3-thiazole-5-ylmethyl)-5-methyl isophthalic acid, 3,5-oxadiazines-4-base fork (nitro) amine is a kind of second generation nicotinoids high-efficient low toxicity insecticide of brand new, its mechanism of action is similar to Imidacloprid, alternative inhibition insect central nervous system nicotinic acid nAChR ligands, and then the normal conduction of blocking-up insect central nervous system, cause insect to occur paralysis death in time.Not only have tag, stomach toxicity, systemic activity, and there is higher activity, better safety, wider insecticidal spectrum and the feature such as speed of action is fast, the lasting period is long, and to person poultry safety.After its dispenser, can in crop, be inhaled rapidly, and be transmitted to each position of plant, can effectively be prevented and treated Homoptera, Lepidoptera, coleoptera, thrips insect.Wherein to Homoptera special efficacy, as various aphids, leafhopper, aleyrodid, plant hopper etc.
Fludioxonil, has another name called fluorine fludioxonil (Fludioxonil), and chemical name is 4-(2, and 2-bis-is fluoro-1,3-benzo dioxy-4-yl) pyrroles-3-nitrile is a kind of pyroles bactericide.The mechanism of action of this bactericide suppresses the relevant transfer of glucose phosphorylated for passing through, and the mycelial growth of Antifungi, finally causes germ dead.The mechanism of action is unique, with existing bactericide without cross resistance.Although interior absorption is not good, its action spectrum is wide, and the term of validity is long, and the microbial kind biography of many cause of diseases such as sac fungi, basidiomycetes, imperfect fungus and soil-borne disease are had to extraordinary preventive effect, is suitable as very much seed coat agent.
Tmtd (Thiram), chemical name is tetramethyl thiuram disulfide, is a kind of protective fungicide.Seed treatment can effectively be prevented and treated, the diseases such as seedling blight, Cereal apple scab, and to mouse and insect pest in seedling stage walk quickly and keep away, preventive and therapeutic effect.Ziram (Ziram); chemical name is zine dimethyldithiocarbamate; compare tmtd, its character is unstable, tool protective effect; the diseases such as sprout term disease and fruit tree anthracnose are had to good control efficiency; insect pest is also had to certain effect, and the two is all good fortune U.S.A is bactericide, and its Main Function mechanism is for destroying coacetylase; thereby affect tricarbonic acid cycle, suppress the growth of mycelia.
Crop from seed seedling stage be a most weak period of resistance, be easy to suffer various native biographies, seed-borne disease and various sucking pest damage, cause dead seedling, be short of seedling, also can cause various virus diseases.Will there is the harm of bakanae disease of rice, damping off, small brown rice planthopper, white-backed planthopper in the rice seedling bed phase for example.Seed chemicals treatment is the efficient means of this prevention and elimination of disease and pests in period, but this period should be with insecticide, use bactericide, Multiple Pesticides to use again likely to cause drug effect to decline, even cause poisoning simultaneously.Therefore, be necessary to there is synergistic effect medicament and mix several, be made into built agent, can greatly save reagent cost.
Summary of the invention
The problem existing for prior art, the object of the invention is to the technical scheme that design provides a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, it is characterized in that containing effective constituents A, active ingredient B and active ingredient C, described effective constituents A is Diacloden, described active ingredient B is fludioxonil, described active ingredient C is tmtd or ziram, and the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 1~60:1~30:1~60.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 1~50:1~25:1~50.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 5~40:2~20:5~40.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 10~35:5~15:10~35.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 15~30:8~12:15~30.
Described a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 20~25:8~12:20~25.
Ternary built agricultural chemicals provided by the invention has remarkable synergistic effect, can expand chemical control scope, improve drug effect, can be used as the medicament of seed soaking agent, seed coat agent and crops seedling stage or other prevention and elimination of disease and pests in period, disposable efficient prevention and control kind biography, soil-borne disease and insect pest in seedling stage, can be used on and comprise on other crops such as the field crop of paddy rice, wheat, corn and vegetables, fruit tree, nursery stock.
Embodiment
Below in conjunction with embodiment, further illustrate the present invention.
The ratio of embodiment 1 Diacloden, fludioxonil and three kinds of medicaments of tmtd (or ziram) can be any ratio between 1~60:1~30:1~60, can make the formulation allowing in the various agriculturals such as water dispersible granules, wetting powder, suspension seed-coating agent.
Embodiment 2 medicament active constituent contents 80%, wherein Diacloden effective content 70%, fludioxonil effective content 5%, tmtd (or ziram) effective content 5%.
Embodiment 3 medicament active constituent contents 80%, wherein Diacloden effective content 70%, fludioxonil effective content 2.5%, tmtd (or ziram) effective content 7.5%.
Embodiment 4 medicament active constituent contents 60%, wherein Diacloden effective content 60%, fludioxonil effective content 5%, tmtd (or ziram) effective content 15%.
Embodiment 5 medicament active constituent contents 80%, wherein Diacloden effective content 60%, fludioxonil effective content 10%, tmtd (or ziram) effective content 10%.
Embodiment 6 medicament active constituent contents are 80%, and wherein Diacloden effective content 50%, fludioxonil effective content 20%, tmtd (or ziram) effective content 10%.
Embodiment 7 medicament active constituent contents are 80%, and wherein Diacloden effective content 40%, fludioxonil effective content 30%, tmtd (or ziram) effective content 10%.
Embodiment 8 medicament active constituent contents are 80%, and wherein Diacloden effective content 40%, fludioxonil effective content 25%, tmtd (or ziram) effective content 15%.
Embodiment 9 medicament active constituent contents are 80%, and wherein Diacloden effective content 30%, fludioxonil effective content 40%, tmtd (or ziram) effective content 10%.
Embodiment 10 medicament active constituent contents are 80%, and wherein Diacloden effective content 20%, fludioxonil effective content 50%, and tmtd (or ziram) effective content is 10%.
Embodiment 11 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 60%, and tmtd (or ziram) effective content is 10%.
Embodiment 12 medicament active constituent contents are 80%, and wherein Diacloden effective content is 5%, and fludioxonil effective content is 65%, and tmtd (or ziram) effective content is 10%.
Embodiment 13 medicament active constituent contents 80%, wherein Diacloden effective content is 50%, and fludioxonil effective content is 10%, and tmtd (or ziram) effective content is 20%.
Embodiment 14 medicament active constituent contents are 80%, and wherein Diacloden effective content is 40%, and fludioxonil effective content is 20%, and tmtd (or ziram) effective content is 20%.
Embodiment 15 medicament active constituent contents are 80%, and wherein Diacloden effective content is 30%, and fludioxonil effective content is 30%, and tmtd (or ziram) effective content is 20%.
Embodiment 16 medicament active constituent contents are 80%, and wherein Diacloden effective content is 20%, and fludioxonil effective content is 40%, and tmtd (or ziram) effective content is 20%.
Embodiment 17 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 50%, and tmtd (or ziram) effective content is 20%.
Embodiment 18 medicament active constituent contents are 80%, and wherein Diacloden effective content is 5%, and fludioxonil effective content is 55%, and tmtd (or ziram) effective content is 20%.
Embodiment 19 medicament active constituent contents 80%, wherein Diacloden effective content is 40%, and fludioxonil effective content is 10%, and tmtd (or ziram) effective content is 30%.
Embodiment 20 medicament active constituent contents are 80%, and wherein Diacloden effective content is 30%, and fludioxonil effective content is 20%, and tmtd (or ziram) effective content is 30%.
Embodiment 21 medicament active constituent contents are 80%, and wherein Diacloden effective content is 20%, and fludioxonil effective content is 30%, and tmtd (or ziram) effective content is 30%.
Embodiment 22 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 40%, and tmtd (or ziram) effective content is 30%.
Embodiment 23 medicament active constituent contents are 80%, and wherein Diacloden effective content is 30%, and fludioxonil effective content is 10%, and tmtd (or ziram) effective content is 40%.
Embodiment 24 medicament active constituent contents are 80%, and wherein Diacloden effective content is 20%, and fludioxonil effective content is 20%, and tmtd (or ziram) effective content is 40%.
Embodiment 25 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 30%, and tmtd (or ziram) effective content is 40%.
Embodiment 26 medicament active constituent contents 80%, wherein Diacloden effective content is 5%, and fludioxonil effective content is 35%, and tmtd (or ziram) effective content is 40%.
Embodiment 27 medicament active constituent contents are 80%, and wherein Diacloden effective content is 20%, and fludioxonil effective content is 10%, and tmtd (or ziram) effective content is 50%.
Embodiment 28 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 20%, and tmtd (or ziram) effective content is 50%.
Embodiment 29 medicament active constituent contents are 80%, and wherein Diacloden effective content is 5%, and fludioxonil effective content is 25%, and tmtd (or ziram) effective content is 50%.
Embodiment 30 medicament active constituent contents are 80%, and wherein Diacloden effective content is 10%, and fludioxonil effective content is 10%, and tmtd (or ziram) effective content is 60%.
The compound drug of embodiment 31 Diaclodens, fludioxonil and tmtd (or ziram), total active ingredient can be made any concentration between 3%~90%, ratio between three kinds of medicaments is close with embodiment 1~embodiment 30 or identical, but is not limited to aforementioned proportion.
Embodiment 32 Diaclodens, fludioxonil and the control efficiency of the composite seed dressing of tmtd (ziram) to rice seedling damage by disease and insect in seedling stage
1, experimental cultivar
Conventional japonica rice show water 09
2, test is processed and is arranged
Process 1 80% Diacloden fludioxonil tmtd (60%2%18%) 1:400 seed dressing;
Process 2 80% Diacloden fludioxonil ziram (50%2%28%) 1:400 seed dressings;
Process 3 80% Diacloden fludioxonil tmtd (50%2%28%) 1:400 seed dressings;
Process 4 80% Diacloden fludioxonil ziram (40%2%38%) 1:400 seed dressings;
Process 5 80% Diacloden fludioxonil tmtd (40%2.5%37.5%) 1:400 seed dressings;
Process 6 80% Diacloden fludioxonil ziram (40%2.5%37.5%) 1:400 seed dressings;
Process 7 80% Diacloden fludioxonil tmtd (30%3%47%) 1:400 seed dressings;
Process 8 80% Diacloden fludioxonil ziram (40%3%37%) 1:400 seed dressings;
Process 9 80% Diacloden fludioxonil tmtd (40%3%37%) 1:400 seed dressings;
Process 10 80% Diacloden fludioxonil ziram (40%3%37%) 1:400 seed dressings;
Contrast 1 50% Diacloden 1:400 seed dressing;
Contrast 2 3% fludioxonil 1:400 seed dressings;
Contrast 3 3% fludioxonil 37% tmtd 1:400 seed dressings;
Contrast 4 2.5% fludioxonil 37.5% ziram 1:400 seed dressings;
Contrasting 5 clear water processes
4, investigation
Paddy rice 4 leaf 1 heart stage investigation bakanaes disease of rice, rice seedling blight and rice fulgorid, a situation arises, according to blank, calculates preventive effect.
5, result of the test
The present embodiment is prevented and treated result, as shown in the table:
From to the preventive effect of bakanae disease of rice, Diacloden is to bakanae disease of rice control efficiency extreme difference, fludioxonil is to bakanae disease special efficacy, tmtd and ziram have certain control efficiency to bakanae disease of rice, the preventive effect that three's compounded combination is processed 1~processing 10 has all surpassed contrast medicament, illustrates that three is composite to having synergistic effect in bakanae disease of rice control.
From to the preventive effect of rice seedling blight, Diacloden is poor to damping off control efficiency, fludioxonil and tmtd (zinc) control efficiency is better, three's compounded combination processes 1~and process 10 preventive effect and all surpassed each treatment agent, illustrate that three is composite and there is synergistic effect in the control of rice seedling blight.
From to the preventive effect of plant hopper, the preventive effect of Diacloden is higher, and fludioxonil preventive effect is not obvious, and tmtd (zinc) has certain preventive effect.And three's compounded combination processes 1~and process 10 preventive effect the preventive effect of plant hopper has been reached more than 90%, be greater than contrast Diacloden or quite illustrate with it that three is composite there is synergistic effect in the control of rice fulgorid.
The 33 rice tillering Sheng phases of embodiment spray the control efficiency of Diacloden fludioxonil tmtd (ziram) pesticide combination to rice sheath blight disease and rice fulgorid.
1, experimental cultivar
Super hybridized rice " state rice No. six ".
2, process and arrange
Process 1 40% Diacloden fludioxonil tmtd (30%1.5%8.5%) 3ml/ mu spraying.
Process 2 40% Diacloden fludioxonil ziram (30%1.5%8.5%) 3ml/ mu sprayings.
Process 3 40% Diacloden fludioxonil tmtd (30%2%8%) 3ml/ mu sprayings.
Process 4 40% Diacloden fludioxonil tmtd (30%3%7%) 3ml/ mu sprayings.
Process 5 40% Diacloden fludioxonil ziram (30%5%5%) 3ml/ mu sprayings.
Process 6 40% Diacloden fludioxonil ziram (28%2%10%) 3ml/ mu sprayings.
Process 7 40% Diacloden fludioxonil tmtd (25%3%12%) 3ml/ mu sprayings.
Process 8 40% Diacloden fludioxonil tmtd (25%5%10%) 3ml/ mu sprayings.
Process 9 40% Diacloden fludioxonil ziram (22%3%15%) 3ml/ mu sprayings.
Process 10 40% Diacloden fludioxonil ziram (20%3%17%) 3ml/ mu sprayings.
Process 11 40% Diacloden fludioxonil tmtd (20%5%15%) 3ml/ mu sprayings.
Process 12 40% Diacloden fludioxonil tmtd (18%8%14%) 3ml/ mu sprayings.
Contrast 1 25% Diacloden 4ml/ mu spraying.
Contrast 25% fludioxonil 4ml/ mu spraying.
Contrast 3 25% tmtd 4ml/ mu sprayings
Contrast 4 25% ziram 4ml/ mu sprayings
Contrast 5 clear water contrasts
3, investigation
Plant hopper adopts the investigation of bat dish method.
Banded sclerotial blight is according to following standard survey.
Rice sheath blight disease grade scale
Sick level Symptom Disease index Evaluation of resistance
0 grade Plant leaf sheath and blade have no symptom Disease refers to be 0 (immunity) (HR)
1 grade Rice strain base portion has a small amount of fragmentary scab Disease refers to be 0.1~20 (disease-resistant) (R)
3 grades Scab extends to down 3 leaves (sword-like leave is for falling 0 leaf) Disease refers to be 20.1~40 (in anti-) (MR)
5 grades Scab extends to down 2 leaves Disease refers to be 40.1~60 (middle sense) (MS)
7 grades Scab extends to down 1 leaf Disease refers to be 60.1~80 (susceptible) (S)
9 grades Scab extends to sword-like leave or complete stool is withered Disease refers to be 80.1~100 (high sense) (HS)
4, result of the test
The rice tillering Sheng phase sprays the control efficiency of Diacloden fludioxonil tmtd pesticide combination to rice sheath blight disease and rice fulgorid, as shown in the table:
From to the preventive effect of rice sheath blight disease, the preventive effect of removing fludioxonil reaches 82.13%, the preventive effect of another two single doses is all below 70%, and the preventive effect of each Recompounded pesticide combination all surpasses or approaches 90%, explanation is on to the preventive effect of rice sheath blight disease, and Diacloden fludioxonil tmtd (ziram) compound drug combination table reveals strong synergistic effect.
From to the preventive effect of rice fulgorid, the preventive effect of fludioxonil is only 11.59, illustrates that this medicament is little to plant hopper effect.And the preventive effect of tmtd, ziram has surpassed 50%, illustrate that Corozate also has certain effect to plant hopper.And preventive effect the best of Diacloden has reached 86.67%, but still the control efficiency of too late each complex treatment.Illustrate, on to the preventive effect of rice fulgorid, the combination of Diacloden fludioxonil tmtd (ziram) compound drug shows strong synergistic effect equally.
Embodiment 34 Diacloden fludioxonil tmtd are composite to fusarium moniliforme indoor biometrics.
1, test strain
Fusarium moniliforme.
2, test method
With reference to < < farm-chemical indoor determination test rule > >, suppress disease fungus mycelial growth test Plating.
3, result of the test
Because Diacloden is insecticide, therefore first investigate the variation of fludioxonil and the composite bactericidal activity of tmtd.
Fludioxonil and tmtd composite bactericide activity change, as shown in the table:
Reagent agent Actual EC 50(ppm) Theoretical EC 50(ppm) Coefficient of synergism
Fludioxonil 0.174 / /
Tmtd 19.327 / /
Cough up good fortune proportioning 1:4 0.523 0.840 1.61
Cough up good fortune proportioning 3:7 0.224 0.568 2.53
Cough up good fortune proportioning 2:3 0.130 0.429 3.31
Cough up good fortune proportioning 1:1 0.126 0.345 2.73
Cough up good fortune proportioning 3:2 0.118 0.288 2.43
Cough up good fortune proportioning 7:3 0.128 0.248 1.94
Cough up good fortune proportioning 4:1 0.112 0.217 1.94
From result of the test, the coefficient of synergism of composite each formula of fludioxonil and tmtd, between 1.61~3.31, has all surpassed 1.5, illustrates that fludioxonil and tmtd are composite to show strong synergistic effect.
Select two formulas wherein to cough up good fortune proportioning 3:7 and cough up good fortune proportioning 3:2, investigate the composite impact on bactericidal activity of three with Thiamethoxam compound.
Table a coughs up good fortune proportioning 3:7 and the impact of Thiamethoxam compound on bactericidal activity
Reagent agent Actual EC 50(ppm) Theoretical EC 50(ppm) Coefficient of synergism
Diacloden 875.11 / /
Fludioxonil tmtd 3:7 0.224 / /
Diacloden fludioxonil tmtd 3:7:90 0.163 0.249 1.53
Diacloden fludioxonil tmtd 3:7:40 0.139 0.280 2.01
Diacloden fludioxonil tmtd 9:21:70 0.127 0.320 2.52
Diacloden fludioxonil tmtd 3:7:15 0.228 0.373 1.64
Diacloden fludioxonil tmtd 3:7:10 0.197 0.448 2.27
Diacloden fludioxonil tmtd 9:21:20 0.240 0.560 2.33
Diacloden fludioxonil tmtd 21:49:30 0.401 0.746 1.86
Diacloden fludioxonil tmtd 6:14:5 0.636 1.119 1.76
Diacloden fludioxonil tmtd 27:63:10 1.338 2.235 1.67
Table b coughs up good fortune proportioning 3:2 and the impact of Thiamethoxam compound on bactericidal activity
Reagent agent Actual EC 50(ppm) Theoretical EC 50(ppm) Coefficient of synergism
Diacloden 875.11 / /
Fludioxonil tmtd 3:2 0.118 / /
Diacloden fludioxonil tmtd 3:2:45 0.082 0.131 1.59
Diacloden fludioxonil tmtd 3:2:20 0.077 0.147 1.91
Diacloden fludioxonil tmtd 9:6:35 0.080 0.169 2.11
Diacloden fludioxonil tmtd 6:4:15 0.087 0.197 2.27
Diacloden fludioxonil tmtd 3:2:5 0.118 0.236 2.00
Diacloden fludioxonil tmtd 9:6:10 0.117 0.295 2.53
Diacloden fludioxonil tmtd 21:14:15 0.242 0.393 1.62
Diacloden fludioxonil tmtd 12:8:5 0.335 0.590 1.76
Diacloden fludioxonil tmtd 27:18:5 0.765 1.179 1.54
From table a cough up good fortune proportioning 3:7 and Thiamethoxam compound to the coefficient of synergism of fusarium moniliforme activity between 1.53~2.52, all shown synergistic effect.
From table b, cough up good fortune proportioning 3:2 and Thiamethoxam compound to the coefficient of synergism of fusarium moniliforme activity between 1.54~2.53, also all shown synergistic effect.
Therefore other formula and Thiamethoxam compound, to also all having shown synergistic effect in fusarium moniliforme activity, illustrate, Diacloden fludioxonil tmtd three composite on bactericidal activity synergistic effect remarkable.

Claims (6)

1. the ternary built agricultural chemicals containing Diacloden, fludioxonil, it is characterized in that containing effective constituents A, active ingredient B and active ingredient C, described effective constituents A is Diacloden, described active ingredient B is fludioxonil, described active ingredient C is tmtd or ziram, and the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 1~60:1~30:1~60.
2. a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil as claimed in claim 1, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 1~50:1~25:1~50.
3. a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil as claimed in claim 1, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 5~40:2~20:5~40.
4. a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil as claimed in claim 1, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 10~35:5~15:10~35.
5. a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil as claimed in claim 1, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 15~30:8~12:15~30.
6. a kind of ternary built agricultural chemicals containing Diacloden, fludioxonil as claimed in claim 1, is characterized in that the weight ratio of described effective constituents A, active ingredient B and active ingredient C is 20~25:8~12:20~25.
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WO2007141010A1 (en) * 2006-06-08 2007-12-13 Syngenta Participations Ag, A method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs
CN101647337A (en) * 2008-08-15 2010-02-17 上海农业科技种子有限公司 Novel anti-pest seed coating agent for waxy corn
CN102017954A (en) * 2010-12-22 2011-04-20 陕西韦尔奇作物保护有限公司 Fludioxonil-containing bactericidal composition
CN102726434A (en) * 2011-03-31 2012-10-17 山东海利尔化工有限公司 Multi-effect flowable concentrate for seed coating

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