CN103992724B - A kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses - Google Patents
A kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses Download PDFInfo
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- CN103992724B CN103992724B CN201410214565.XA CN201410214565A CN103992724B CN 103992724 B CN103992724 B CN 103992724B CN 201410214565 A CN201410214565 A CN 201410214565A CN 103992724 B CN103992724 B CN 103992724B
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Abstract
The present invention relates to a kind of floor paint, specifically, relate to a kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses. Its preparation method comprises the following steps: (1) prepares nano material dispersion liquid; (2) prepare water-based floor paint: make water-based floor paint A component; Make water-based floor paint B component; Water-based floor paint A component is mixed according to the mass ratio ratio of 1: 5 with water-based floor paint B component, stir, make finished product. The alternative oil product of the present invention, organic solvent uses and discharge greatly reduces, and workmen's physical impairment is reduced greatly, reaches the object that reduces VOC discharge, green, environmental protection; Meanwhile, the present invention possesses stronger wear-resisting, anti-pollution characteristic, and application property improves, and surface is more easy to clean, does not stay water stainly, and use cost and oil product are suitable, have good market value.
Description
Technical field
The present invention relates to a kind of floor paint, specifically, relate to and a kind ofly use nano-material modified water-based anti-Dirty abrasion-proof terrace paint.
Background technology
At present, floor coatings is mainly taking epoxide terrace and polyurethane floor as main. Epoxide terrace can be divided into solventType and no-solvent type, no matter any, all more or less contain organic solvent, and indivedual solvent-free terrace paintMiddle used reactive diluent contains toxic component. And polyurethane floor is in work progress, can there is tripDivorced cyanate, these all can bring harm to environmental and human health impacts.
Solvent-borne type floor coatings is had relatively high expectations to base material humidity and ambient humidity in the time of construction; Water-based terrace is to baseThe not too large requirement of material and ambient humidity, because it does not fire not quick-fried character, is producing, is transporting, is storing, is executingThe links such as work safety and environmental protection more, still, compares solvent-borne type floor coatings, and water-based terrace has paint film densificationThe shortcoming such as property is low, application property is poor, the market share is less.
In floor paint industry, water paint has inborn safety and environmental protection advantage, and what need solution is to improve itPerformance is to meet the requirement of environment for use, by the development of modern nanometer technology, by high performance nano materialProcess through special, water-based floor paint carried out to modification, can increase substantially paint film property, thus meet itsThe requirement of application link, acceleration advances the process of floor coatings Water-borne modification.
Summary of the invention
The object of the invention is to, a kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses is provided,To solve above-mentioned technical problem.
The present invention is achieved through the following technical solutions:
Use the antifouling abrasion-proof terrace paint of nano-material modified water-based, it is characterized in that: its preparation methodComprise the following steps:
(1) prepare nano material dispersion liquid
(1.1) get the raw materials ready: nano aluminium oxide 10-12 part, nano barium sulfate 5-6 part, nano zircite 2-3 part,80 parts of nonionic wetting dispersing agent 0.3-0.6 part, deionized waters;
(1.2) various raw materials described in step (1.1) are dropped into basket type sand mills, with 1500 revs/minSpeed is disperseed 120 minutes, is prepared into uniform and stable concentration and is 20% nano material dispersion liquid;
(2) prepare water-based floor paint
(2.1) 1 part of aqueous epoxy resins 15-18 part and cosolvent are uniformly dispersed, and make water-based floor paint AComponent is for subsequent use;
(2.2) aqueous epoxy curing agent 20-22 part, deionized water 25-30 part, polysiloxanes defoamer0.5 part, 1.5 parts of polycarboxylate wetting dispersing agents, rutile titanium dioxide 10-12 part, nanometer titanium dioxideTitanium 10-12 part, 1 part, polytetrafluoroethylene (PTFE) wax powder, 0.2 part of organically-modified dimethyl silicone polymer levelling agent, form0.3 part of mould assembly acrylate rheological agent through high speed dispersion, grind after, then under stirring, slowly add step(1) 10 parts of nano material dispersion liquids, stir, and make water-based floor paint B component for subsequent use;
(2.3) by mixed according to the mass ratio ratio of 1: 5 to water-based floor paint A component and water-based floor paint B componentClose, stir, make finished product.
Beneficial effect: owing to having adopted above-mentioned technical scheme, the alternative oil product of the present invention, You JirongAgent is used and discharge greatly reduces, and workmen's physical impairment is reduced greatly, reaches and reduces VOC dischargeObject, green, environmental protection; Meanwhile, the present invention possesses stronger wear-resisting, anti-pollution characteristic, and application property improves,Surface is more easy to clean, does not stay water stainly, and use cost and oil product are suitable, have good market value.
Detailed description of the invention
Below with reference to detailed description of the invention, the present invention is described further.
Embodiment 1:
Described in the present embodiment, use the antifouling abrasion-proof terrace paint of nano-material modified water-based, its preparation method comprisesFollowing steps:
(1) prepare nano material dispersion liquid
(1.1) get the raw materials ready: 12 parts of nano aluminium oxides, 6 parts of nano barium sulfates, 3 parts of nano zircites, non-from0.6 part of subtype wetting dispersing agent, 80 parts of deionized waters;
(1.2) various raw materials described in step (1.1) are dropped into basket type sand mills, with 1500 revs/minSpeed is disperseed 120 minutes, is prepared into uniform and stable concentration and is 20% nano material dispersion liquid;
(2) prepare water-based floor paint
(2.1) 18 parts of aqueous epoxy resins are uniformly dispersed with 1 part of cosolvent, make water-based floor paint A groupDivide for subsequent use;
(2.2) 22 parts of aqueous epoxy curing agents, 30 parts of deionized waters, 0.5 part of polysiloxanes defoamer,1.5 parts of polycarboxylate wetting dispersing agents, 12 parts of rutile titanium dioxides, 12 parts of nano titanium oxides, poly-1 part, tetrafluoroethene wax powder, 0.2 part of organically-modified dimethyl silicone polymer levelling agent, association type acrylate streamBecome 0.3 part of agent through high speed dispersion, grind after, then under stirring, slowly add the nanometer material of step (1)10 parts of material dispersion liquids, stir, and make water-based floor paint B component for subsequent use;
(2.3) by mixed according to the mass ratio ratio of 1: 5 to water-based floor paint A component and water-based floor paint B componentClose, stir, make finished product.
Embodiment 2:
Described in the present embodiment, use the antifouling abrasion-proof terrace paint of nano-material modified water-based, its preparation method comprisesFollowing steps:
(1) prepare nano material dispersion liquid
(1.1) get the raw materials ready: 11 parts of nano aluminium oxides, 5.5 parts of nano barium sulfates, 2.5 parts of nano zircites,0.5 part of nonionic wetting dispersing agent, 80 parts of deionized waters;
(1.2) various raw materials described in step (1.1) are dropped into basket type sand mills, with 1500 revs/minSpeed is disperseed 120 minutes, is prepared into uniform and stable concentration and is 20% nano material dispersion liquid;
(2) prepare water-based floor paint
(2.1) 17 parts of aqueous epoxy resins are uniformly dispersed with 1 part of cosolvent, make water-based floor paint A groupDivide for subsequent use;
(2.2) 21 parts of aqueous epoxy curing agents, 28 parts of deionized waters, 0.5 part of polysiloxanes defoamer,1.5 parts of polycarboxylate wetting dispersing agents, 11 parts of rutile titanium dioxides, 11 parts of nano titanium oxides, poly-1 part, tetrafluoroethene wax powder, 0.2 part of organically-modified dimethyl silicone polymer levelling agent, association type acrylate streamBecome 0.3 part of agent through high speed dispersion, grind after, then under stirring, slowly add the nanometer material of step (1)10 parts of material dispersion liquids, stir, and make water-based floor paint B component for subsequent use;
(2.3) by mixed according to the mass ratio ratio of 1: 5 to water-based floor paint A component and water-based floor paint B componentClose, stir, make finished product.
[experimental data]
According to national standard " terrace coating material " (GB/T22374-2008) to use nanometer of the present inventionThe antifouling abrasion-proof terrace paint of water-based of material modification carries out experiment test, the performance indications requirement that is all up to state standards,Particularly outstanding aspect hardness, anti-wear performance. By the test aspect water contact angle, the present invention's performanceGo out excellent anti-pollution characteristic.
The nano-material modified antifouling abrasion-proof terrace paint of water-based of use of the present invention with do not use nano material to changeThe water-based terrace of property, oiliness terrace the correction data of hardness, wear-resisting, three key indexs of water contact angle asUnder:
By test data, can find that the present invention has following characteristics:
(1) performance advantage is obvious, alternative oil product, and organic solvent uses and discharge greatly reduces, rightWorkmen's physical impairment reduces greatly, reaches the object that reduces VOC discharge, green, environmental protection.
(2) possess the performance of stronger wear-resisting and resistant, application property improves simultaneously, and surface is more easy to clean, noStay water stainly, use cost and oil product are suitable, have good market value.
Claims (1)
1. use the nano-material modified antifouling abrasion-proof terrace paint of water-based, it is characterized in that: its preparation sideMethod comprises the following steps:
(1) prepare nano material dispersion liquid
(1.1) get the raw materials ready: nano aluminium oxide 10-12 part, nano barium sulfate 5-6 part, nano zircite 2-3 part,80 parts of nonionic wetting dispersing agent 0.3-0.6 part, deionized waters;
(1.2) various raw materials described in step (1.1) are dropped into basket type sand mills, with 1500 revs/minSpeed is disperseed 120 minutes, is prepared into uniform and stable concentration and is 20% nano material dispersion liquid;
(2) prepare water-based floor paint
(2.1) 1 part of aqueous epoxy resins 15-18 part and cosolvent are uniformly dispersed, and make water-based floor paint AComponent is for subsequent use;
(2.2) aqueous epoxy curing agent 20-22 part, deionized water 25-30 part, polysiloxanes defoamer0.5 part, 1.5 parts of polycarboxylate wetting dispersing agents, rutile titanium dioxide 10-12 part, nanometer titanium dioxideTitanium 10-12 part, 1 part, polytetrafluoroethylene (PTFE) wax powder, 0.2 part of organically-modified dimethyl silicone polymer levelling agent, form0.3 part of mould assembly acrylate rheological agent through high speed dispersion, grind after, then under stirring, slowly add step(1) 10 parts of nano material dispersion liquids, stir, and make water-based floor paint B component for subsequent use;
(2.3) by mixed according to the mass ratio ratio of 1: 5 to water-based floor paint A component and water-based floor paint B componentClose, stir, make finished product.
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| CN201410214565.XA CN103992724B (en) | 2014-05-14 | 2014-05-14 | A kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses |
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| CN201410214565.XA CN103992724B (en) | 2014-05-14 | 2014-05-14 | A kind of antifouling abrasion-proof terrace paint of nano-material modified water-based that uses |
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| CN103992724A CN103992724A (en) | 2014-08-20 |
| CN103992724B true CN103992724B (en) | 2016-05-25 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104212308A (en) * | 2014-09-18 | 2014-12-17 | 江苏海晟涂料有限公司 | Waterborne epoxy self-leveling floor coating and preparation method thereof |
| CN104403510A (en) * | 2014-12-29 | 2015-03-11 | 苏州奥莱鑫建材有限公司 | Corrosion-resistant terrace |
| CN106554652A (en) * | 2015-09-25 | 2017-04-05 | 青岛瑞利特新材料科技有限公司 | Modified graphene additive and its application in floor paint |
| CN106189827A (en) * | 2016-08-26 | 2016-12-07 | 安徽建邦建材有限公司 | A kind of wear-resisting epoxy coating of insulated wall |
| CN106349883A (en) * | 2016-09-21 | 2017-01-25 | 苏州瑞斯格电子科技有限公司 | Heavy-load-resistant nanometer epoxy floor paint |
| CN106280907A (en) * | 2016-09-21 | 2017-01-04 | 苏州瑞斯格电子科技有限公司 | A kind of high abrasion nanometer epoxide terrace paint |
| CN106147537A (en) * | 2016-09-21 | 2016-11-23 | 苏州瑞斯格电子科技有限公司 | A kind of environment-protecting color nanometer epoxide terrace paint |
| CN106700759A (en) * | 2016-12-05 | 2017-05-24 | 江西龙正科技发展有限公司 | Environment-friendly floor paint |
| CN107365547B (en) * | 2017-08-17 | 2021-05-07 | 珠海市盛西源机电设备有限公司 | Bright water-based epoxy floor paint and preparation method thereof |
| CN107868614A (en) * | 2017-12-14 | 2018-04-03 | 广东顺德三阳化学有限公司 | A kind of environment-protection nano haze tallow fluid composition and preparation method thereof |
| CN109355050A (en) * | 2018-10-17 | 2019-02-19 | 天津米科技有限公司 | A kind of cement base terrace bonding agent |
| CN115746709A (en) * | 2022-11-07 | 2023-03-07 | 龙岩市宝丽建材科技有限公司 | Preparation method of water-based floor paint |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI287115B (en) * | 2005-10-07 | 2007-09-21 | Eternal Chemical Co Ltd | Brightness enhancement film |
| CN101143986A (en) * | 2007-08-07 | 2008-03-19 | 何良金 | Terrace paint |
| CN101210149A (en) * | 2007-12-21 | 2008-07-02 | 浙江中成建工集团有限公司 | Antiskid ventilating epoxide terrace paint |
| CN102234447A (en) * | 2010-12-08 | 2011-11-09 | 张锦碧 | Ultraviolet (UV) floor finishing paint |
| CN102108235B (en) * | 2010-12-31 | 2016-04-27 | 亚士漆(上海)有限公司 | Solvent type epoxy picking finish coat |
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Effective date of registration: 20190531 Address after: 271100 No. 191 Wudangshan Road, Laiwu High-tech Zone, Shandong Province Patentee after: Laiwu Yida New Material Technology Co., Ltd. Address before: 271100 West Hongbuling Village, Yanzhuang Town, Laiwu City, Shandong Province Patentee before: Shandong Gu Naite novel material company limited |
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