CN103992437A - 一种三元乙丙橡胶用大分子硅烷偶联剂的制备与应用 - Google Patents
一种三元乙丙橡胶用大分子硅烷偶联剂的制备与应用 Download PDFInfo
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- CN103992437A CN103992437A CN201410190882.2A CN201410190882A CN103992437A CN 103992437 A CN103992437 A CN 103992437A CN 201410190882 A CN201410190882 A CN 201410190882A CN 103992437 A CN103992437 A CN 103992437A
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- Prior art keywords
- coupling agent
- silane coupling
- preparation
- macromole
- rubber
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- Granted
Links
- 239000006087 Silane Coupling Agent Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920002943 EPDM rubber Polymers 0.000 title abstract description 19
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims abstract description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 14
- 238000010559 graft polymerization reaction Methods 0.000 claims abstract description 7
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 31
- 229920001971 elastomer Polymers 0.000 claims description 22
- 229920001897 terpolymer Polymers 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 abstract description 22
- 239000011159 matrix material Substances 0.000 abstract description 22
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000011256 inorganic filler Substances 0.000 abstract description 3
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 238000005457 optimization Methods 0.000 abstract description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 36
- 239000000377 silicon dioxide Substances 0.000 description 18
- 238000004381 surface treatment Methods 0.000 description 12
- 229960001866 silicon dioxide Drugs 0.000 description 10
- 235000012239 silicon dioxide Nutrition 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000012764 mineral filler Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- 150000003384 small molecules Chemical class 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000002329 infrared spectrum Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- -1 γ-methacryloxypropyl Chemical group 0.000 description 1
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- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
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CN201410190882.2A CN103992437B (zh) | 2014-05-07 | 2014-05-07 | 一种三元乙丙橡胶用大分子硅烷偶联剂的制备与应用 |
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CN201410190882.2A CN103992437B (zh) | 2014-05-07 | 2014-05-07 | 一种三元乙丙橡胶用大分子硅烷偶联剂的制备与应用 |
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CN103992437A true CN103992437A (zh) | 2014-08-20 |
CN103992437B CN103992437B (zh) | 2017-01-25 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105504729A (zh) * | 2016-02-04 | 2016-04-20 | 浙江海正生物材料股份有限公司 | 一种用于3d打印的聚乳酸改性材料 |
CN107746568A (zh) * | 2017-11-08 | 2018-03-02 | 安徽省瑞发复合材料制造有限公司 | 一种电路板用抗菌性聚氨酯复合材料 |
CN107778842A (zh) * | 2017-11-08 | 2018-03-09 | 安徽省瑞发复合材料制造有限公司 | 一种电路板专用耐老化聚氨酯复合材料 |
CN109943017A (zh) * | 2019-03-29 | 2019-06-28 | 广东榕泰实业股份有限公司 | 粒状三聚氰胺-甲醛塑料偶联剂的制备方法 |
-
2014
- 2014-05-07 CN CN201410190882.2A patent/CN103992437B/zh active Active
Non-Patent Citations (3)
Title |
---|
付锦锋等: ""EPDM- g-MMA对MS树脂的增韧作用"", 《弹性体》, vol. 17, no. 6, 25 December 2007 (2007-12-25), pages 13 - 16 * |
崔小明: ""原位溶胶-凝胶法改性三元乙丙橡胶的制备及其表征"", 《橡胶科技市场》, no. 10, 15 October 2012 (2012-10-15), pages 52 * |
李金玲等: ""乙丙橡胶接枝改性技术"", 《弹性体》, vol. 16, no. 3, 25 June 2006 (2006-06-25), pages 61 - 64 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105504729A (zh) * | 2016-02-04 | 2016-04-20 | 浙江海正生物材料股份有限公司 | 一种用于3d打印的聚乳酸改性材料 |
CN107746568A (zh) * | 2017-11-08 | 2018-03-02 | 安徽省瑞发复合材料制造有限公司 | 一种电路板用抗菌性聚氨酯复合材料 |
CN107778842A (zh) * | 2017-11-08 | 2018-03-09 | 安徽省瑞发复合材料制造有限公司 | 一种电路板专用耐老化聚氨酯复合材料 |
CN109943017A (zh) * | 2019-03-29 | 2019-06-28 | 广东榕泰实业股份有限公司 | 粒状三聚氰胺-甲醛塑料偶联剂的制备方法 |
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Effective date of registration: 20151028 Address after: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Applicant after: Changzhou University Applicant after: CHANGZHOU UNIVERSITY HUAIDE COLLEGE Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Applicant before: Changzhou University |
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Inventor after: Pan Haigang Inventor before: Zhang Hongwen Inventor before: Zhang Yang Inventor before: Jiang Yan Inventor before: Ren Yurong Inventor before: Liu Qiaoyun Inventor before: Yu Qiang |
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Effective date of registration: 20171208 Address after: 253400 Shandong province Dezhou city Ningjin County galactic economic and Technological Development Zone Liaohe Street Patentee after: Shandong Ningjin County Hao run science and Technology Co., Ltd. Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Co-patentee before: CHANGZHOU UNIVERSITY HUAIDE COLLEGE Patentee before: Changzhou University |
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Address after: Yinhe street, Ningjin economic and Technological Development Zone, Dezhou City, Shandong Province 253000 Patentee after: Shandong Yuanhe New Material Technology Co.,Ltd. Address before: 253400 Liaohe Street, Yinhe economic and Technological Development Zone, Ningjin County, Dezhou City, Shandong Province Patentee before: SHANDONG NINGJIN HAORUN TECHNOLOGY Co.,Ltd. |
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