CN103988989B - A kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect - Google Patents

A kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect Download PDF

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CN103988989B
CN103988989B CN201410155705.0A CN201410155705A CN103988989B CN 103988989 B CN103988989 B CN 103988989B CN 201410155705 A CN201410155705 A CN 201410155705A CN 103988989 B CN103988989 B CN 103988989B
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feedstuff
mildew preventive
liquid
surfactant
liquid mildew
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CN103988989A (en
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韩康印
陆克文
郑云峰
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Shanghai Bangcheng Biological Engineering Co ltd
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Shanghai Bang Cheng Bioengineering Co Ltd
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Abstract

The invention provides a kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect, including the component of following mass fraction: propanoic acid 25 50%, formic acid 10 25%, propionate 10 35%, surfactant 1 5%, water 10 30%.During use, by liquid mildew preventive and water with 1:(15 20) quality than mixed diluting, be then added in feedstuff.The bactericidal effect of liquid mildew preventive of the present invention is more preferable, and in feedstuff, the quantity of mycete significantly reduces, thus reduces the risk gone mouldy;Meanwhile, compared with the liquid mildew preventive conventional with existing market, addition significantly reduces, and is about the addition of 1200g/ ton relative to other liquid mildew preventive, and the addition of the present invention has only to 500 600g/ tons.

Description

A kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect
Technical field
The present invention relates to field of fodder, particularly relate to a kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect.
Background technology
Worldwide, grain and feedstuff all also exist serious mould contamination.According to research reports, the whole world Grain and the feedstuff of annual average loss are about the 20% of total output, and wherein more than half is owing to feedstuff is mould Become caused.
Feed mold can cause its nutritional labeling to reduce, and can not obtain corresponding nutritional amt after feed intake;Feedstuff Going mouldy and also result in the decline of feedstuff palatability, the searching for food property of animal reduces or anorexia;Cause the mycete of feed mold also Can produce a large amount of mycotoxin, the most then the animal production that makes to search for food declines, heavy then cause and adopt zoophagous death; Many mycotoxins have the highest residual rate in animal body, not only directly animal can be caused murder by poisoning, also can lead to Cross food chain and transfer to human body from animal, human body is produced injury.
At present, prevent going mouldy of feedstuff from mainly being realized by interpolation Midew preventive for feed.Wherein, granule is raised Material, its internal moisture is a very important quality index, and it directly influences the product of pellet Matter and the economic benefit of Feed Enterprise, control effectively to it and be to ensure that the crucial skill of feed product quality safety One of art.Moisture exceedes the standard of regulation, the easy moldy metamorphism of pellet, is unfavorable for preserving, also can The content making nutritional labeling reduces relatively;But if product moisture content is too low, it is unnecessary to cause enterprise again Loss, and the moisture that height is uneven, also result in the instability of product quality, have influence on the product of product Board reputation.During feed manufacturing, suitable moisture can reduce cost, is conducive to pelletizing, reduces Energy consumption, raising produce.
Currently used antifungus agent mostly is solid antifungus agent, as Chinese patent CN1692725A discloses one Solid antifungus agent, is mixed with 3-methoxy-4-hydroxybenzaldehyde by monomethyl fumarate and/or dimethyl fumarate Configuration forms.But solid antifungus agent and the effect of solid feed are difficult to reach uniform, and leave mildew-resistant dead angle.
For the problems referred to above, the liquid mildew preventive occurred the most on the market, antifungus agent and solid feed can be made Effect is more uniform, and it is mainly composed of organic acid and acylate, water compound, such as patent application CN102657281A discloses a kind of liquid mildew preventive, by propanoic acid, propanoic acid ammonium and polymeric guanidine compounding and Become.
But during Shi Yonging, the free water of solid feed increases, the mouldy probability of feedstuff is greatly increased, and it is former It is the free water of feed surface because of be that fungus growth process utilizes.And some liquid mildew preventive has the most anti- Mould effect, but the polarity of water can not be reduced, it is impossible to reducing the surface tension of water, the free water of feed surface is very Easily being utilized by mycete and cause feedstuff mouldy, some liquid mildew preventive can well reduce the polarity of water, reduces Water activity in feedstuff, reduces the potential risk that feedstuff is mouldy, but both products furthermore is less.Meanwhile, existing Some liquid mildew preventive additions are relatively big, directly increase Feed Manufacturing cost.
Summary of the invention
For above-mentioned technical problem, it is an object of the invention to provide a kind of mildew-resistant ability strong, and can significantly drop The surface tension of low water and the extremely low liquid mildew preventive of consumption.
The present invention is achieved by the following technical programs:
One aspect of the present invention is to provide a kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect, by quality Mark meter, including:
Preferably, described feedstuff liquid mildew preventive, in parts by weight, including:
It is highly preferred that described feedstuff liquid mildew preventive, in parts by weight, including:
Wherein, any one or several in the ammonium salt or slaine of propanoic acid of described propionate, wherein, described Metal in slaine is selected from periodic table of elements IA, IIA, IB, the 2-5 cycle of Group IIB, it is preferable that Described propionate is selected from any one or a few in ammonium salt or alkali metal salt, it is highly preferred that described propionate For propanoic acid ammonium or the propionate mixture that at least contains propanoic acid ammonium.
Wherein, described surfactant is selected from anion surfactant, cationic surfactant, nonionic Surfactant, amphoteric surfactant any one or a few, wherein, described anion surfactant Such as potassium oleate, aluminium stearate etc., described cationic surfactant such as Dodecyl trimethyl ammonium chloride, 16 Alkyl trimethyl ammonium chloride etc., described nonionic surfactant such as tween 20, Tween-40, polysorbate60, Polyoxyethylene castor oil, polyglycol distearate, polyoxyethylene ether 60 castor oil hydrogenated, Polyethylene Glycol are sweet Grease etc., described amphoteric surfactant such as lecithin class, amino acid pattern, betaine type etc..
Another aspect of the present invention also provides for the preparation method of described feedstuff liquid mildew preventive, is mixed by liquid component, Then solid constituent is joined in liquid component, mixing.
Further aspect of the present invention additionally provides the using method of a kind of described feedstuff liquid mildew preventive, by described feedstuff Liquid mildew preventive and water are with 1:(15-20) quality than mixed diluting, be then added in feedstuff.
Further aspect of the present invention additionally provides a kind of feedstuff, and it is 0.01-0.2%'s that described feedstuff contains mass fraction Described feedstuff liquid mildew preventive.
Preferably, described feedstuff contains the described feedstuff liquid mildew preventive that mass fraction is 0.01-0.08%.
Liquid mildew preventive of the present invention, component formic acid, propanoic acid can penetrate fungal cell wall, discharge H+, Make mycotic spore finally dead because of energy exhaustion, mycete is had the strongest killing action;Propanoic acid and propionate shape Become powerful buffer system, extend the sterilizing time of propanoic acid;It addition, free water is the essential condition of fungus growth, In order to control water activity, add surfactant, make the polarity of water reduce, help water and feed surface firm In conjunction with, forming the combination water with electronics weak bond form, the combination in conjunction with water and feedstuff is tightr, it is not easy to wave Send out, can not allow mycete utilization, thus limit the growth of mycete.
Liquid mildew preventive of the present invention can make vapours be easier to penetrate into inside feedstuff, and bactericidal effect is more preferable, In feedstuff, the quantity of mycete significantly reduces, thus reduces the risk gone mouldy;Meanwhile, commonly use with existing market Liquid mildew preventive is compared, and the addition of liquid mildew preventive of the present invention substantially reduces, other liquid mildew-resistant existing Agent is about the addition of 1200g/ ton, and liquid mildew preventive addition of the present invention has only to 500-600g/ Ton, and then reduce Feed Manufacturing cost.
Detailed description of the invention
Embodiment 1
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Embodiment 2
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Embodiment 3
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Embodiment 4
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Embodiment 5
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Embodiment 6
Liquid mildew preventive described in the present embodiment, by weight, including:
Aforesaid liquid component is initially charged in mixer, is subsequently adding solid constituent, mix.
Test case
This test case is tested by the following method.
1, test material
Feed formula: 63% Semen Maydis, 25% bean cake, 8% wheat bran, 4% premix material
Antifungus agent sample: embodiment 1,2,3, common liq antifungus agent (main component after tested on market 40% propionate, 20% propanoic acid, 10% lactic acid, 5% phosphoric acid, 15% moisture), it is reported, on market the most mostly Number common liq antifungus agent water content is after tested between 15-30%.
2, test method:
(1), the liquid mildew preventive of common liq antifungus agent and embodiment 1-3 on market is added to by 0.05% Mix homogeneously in feedstuff, respectively as contrast groups, test group 1-3, to be not added with the antifungus agent blank as comparison Group.
(2), prepare the beaker of 1 liter and the little plastic cup of 200 milliliters, feedstuff be placed in big cup, Noggin is placed in feedstuff middle position.
(3), in noggin, inject 60ml distilled water, and water is not scattered in the sample, protect by two-layer The sealing of big cup is sealed by fresh film with the whole big cup of guarantee.
(4), will be equipped with under the warm conditions that cup is placed in the calorstat of 30 ° of C or other is similar of feedstuff. Observe sample every day once, seen whether that mycete (silk) grows, and test is carried out record.
3, result of the test
The result of the test of liquid mildew preventive anti-mold effect test sees subordinate list 1.
Subordinate list 1 liquid mildew preventive anti-mold effect test table
Experiment natural law/sky Blank group Contrast groups Test group 1 Test group 2 Test group 3
1-7 - - - - -
8 + - - - -
9 ++ - - - -
10 +++ + + - -
11 ++++ ++ ++ + -
12 ++++ +++ ++++ ++ +
Wherein, in table 1, "-" is mouldy for not having, "+" for gathering mould, " ++ " is that moderate is mouldy, " +++ " Mouldy for major part, " ++++" it is the most mouldy.
From the data of table 1 it is obvious that under the conditions of hot and humid, blank group test the 8th day is mouldy, Common liq antifungus agent on market, test group 1 the 10th day are mouldy, and test group 2 the 11st day is mouldy, test Organize 3 the 12nd days mouldy, anti-mold effect is best.
For Zong He, liquid mildew preventive of the present invention can arrive and be better than common liq antifungus agent on market Prevention effect, and with water retaining function, meanwhile, usage amount is greatly reduced, liquid mildew preventive of the present invention Have only to the addition of 500-600g/ ton, far below the interpolation of common liquid mildew preventive about 1200g/ ton Amount, and then reduce Feed Manufacturing cost.
Being described in detail the specific embodiment of the present invention above, but it is intended only as example, the present invention is also It is not restricted to particular embodiments described above.To those skilled in the art, any the present invention is carried out Equivalent modifications and substitute the most all among scope of the invention.Therefore, without departing from the spirit of the present invention and model Enclose lower made impartial conversion and amendment, all should contain within the scope of the invention.

Claims (3)

1. the using method of a feedstuff liquid mildew preventive with mildew-resistant, water conservation effect, it is characterised in that Described feedstuff liquid mildew preventive in parts by weight, including:
Described surfactant is selected from anion surfactant, cationic surfactant, amphoteric surfactant Any one or a few, wherein, described anion surfactant is potassium oleate or aluminium stearate, described sun from Sub-surface activating agent is Dodecyl trimethyl ammonium chloride or hexadecyltrimethylammonium chloride, described amphoteric surface Activating agent is lecithin class, amino acid pattern or betaine type;
Wherein, first liquid component is mixed, then solid constituent is joined in liquid component, mixing, prepare feedstuff Liquid mildew preventive;Then by described feedstuff liquid mildew preventive and water with 1:(15-20) quality than mixed diluting, It is then added in feedstuff.
The using method of feedstuff liquid mildew preventive the most according to claim 1, it is characterised in that described Surfactant is selected from any one or a few in anion surfactant, cationic surfactant.
3. a feedstuff, it is characterised in that described feedstuff comprise mass fraction be 0.01-0.08% such as right Require feedstuff liquid mildew preventive described in 1-2 any one.
CN201410155705.0A 2014-04-17 2014-04-17 A kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect Active CN103988989B (en)

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CN105341360A (en) * 2015-12-07 2016-02-24 重庆华睿隆生物科技有限公司 Carrier-free propionic acid solid feed mildew preventive and preparation and use thereof
CN106036035A (en) * 2016-06-13 2016-10-26 江苏盐城源耀生物科技有限公司 Water-retaining agent having mold-proof function and preparation method thereof
CN106819764A (en) * 2016-12-27 2017-06-13 新昌县拜瑞珂生物技术有限公司 It is a kind of with mould proof, water conservation effect feed liquid mildew preventive
CN106819395A (en) * 2017-01-24 2017-06-13 上海邦成生物工程有限公司 A kind of composite mildew inhibitor with acidifying feed effect and preparation method thereof
CN108935983A (en) * 2018-06-20 2018-12-07 刘吉生 A kind of milk cow fully mixed diet additive

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997010724A1 (en) * 1995-09-18 1997-03-27 Basf Aktiengesellschaft Aqueous solutions of formic acid, propionic acid and ammonia and their use
CN101156598A (en) * 2007-09-20 2008-04-09 成都枫澜科技有限公司 Mould inhibitor with mildew resistant and mold toxin adsorption dual behavior as well as preparation method
CN102657281A (en) * 2012-04-12 2012-09-12 广汉隆达饲料有限公司 Dispersion type liquid mildew inhibitor and preparation method thereof
CN102919515A (en) * 2012-11-16 2013-02-13 安佑(中国)动物营养研发有限公司 Liquid mildew preventive
CN103168974A (en) * 2013-03-25 2013-06-26 重庆民泰香料化工有限责任公司 Liquid mildewproof agent for feed and method for avoiding mildew of feed

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997010724A1 (en) * 1995-09-18 1997-03-27 Basf Aktiengesellschaft Aqueous solutions of formic acid, propionic acid and ammonia and their use
CN101156598A (en) * 2007-09-20 2008-04-09 成都枫澜科技有限公司 Mould inhibitor with mildew resistant and mold toxin adsorption dual behavior as well as preparation method
CN102657281A (en) * 2012-04-12 2012-09-12 广汉隆达饲料有限公司 Dispersion type liquid mildew inhibitor and preparation method thereof
CN102919515A (en) * 2012-11-16 2013-02-13 安佑(中国)动物营养研发有限公司 Liquid mildew preventive
CN103168974A (en) * 2013-03-25 2013-06-26 重庆民泰香料化工有限责任公司 Liquid mildewproof agent for feed and method for avoiding mildew of feed

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