CN103988989A - Feed liquid mildew inhibitor with mildew inhibition and water retention efficacies - Google Patents

Feed liquid mildew inhibitor with mildew inhibition and water retention efficacies Download PDF

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Publication number
CN103988989A
CN103988989A CN201410155705.0A CN201410155705A CN103988989A CN 103988989 A CN103988989 A CN 103988989A CN 201410155705 A CN201410155705 A CN 201410155705A CN 103988989 A CN103988989 A CN 103988989A
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mould inhibitor
feed
feed liquid
liquid mould
liquid
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CN103988989B (en
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韩康印
陆克文
郑云峰
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Shanghai Bangcheng Biological Engineering Co ltd
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SHANGHAI BANGCHENG BIOTECHNOLOGY CO Ltd
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Abstract

The invention provides a feed liquid mildew inhibitor with mildew inhibition and water retention efficacies. The feed liquid mildew inhibitor comprises, by mass, 25-50% of propionic acid, 10-25% of formic acid, 10-35% of propionate, 1-5% of a surfactant and 10-30% of water. When the liquid mildew inhibitor is used, the liquid mildew inhibitor is mixed and diluted with water according to a ratio of 1:(15-20), and the obtained solution is added to a feed. The liquid mildew inhibitor has a good sterilization effect, and can obviously reduces the quantity of moulds in the feed, so the moldy risk is reduced; and the addition (500-600g/t) of the liquid mildew inhibitor provided by the invention is substantially lower than the addition (1200g/t) of liquid mildew inhibitors frequently used in the present market.

Description

A kind of feed liquid mould inhibitor with mildew-resistant, water conservation effect
Technical field
The present invention relates to field of fodder, relate in particular to a kind of feed liquid mould inhibitor with mildew-resistant, water conservation effect.
Background technology
Worldwide, grain and feed all exist serious mould contamination.According to research reports, the grain of the annual average loss in the whole world and feed are about 20% of total output, and wherein over half be due to due to feed mold.
Feed mold can cause its nutritional labeling to reduce, and after feed intake, can not obtain corresponding nutritional amt; Feed mold also causes feed palatability to decline, and the searching for food property of animal reduces or apocleisis; Cause the mould of feed mold also can produce a large amount of mycotoxins, the animal production that gently makes to search for food declines, heavy cause and adopt zoophagous death; Many mycotoxins have very high residual rate in animal body, not only can directly to animal, cause murder by poisoning, also can from animal, transfer to human body by food chain, and human body is produced to injury.
At present, prevent that going mouldy mainly of feed from realizing by adding Midew preventive for feed.Wherein, for pellet, its inner moisture is a very important quality index, and it directly has influence on the quality of pellet and the economic benefit of Feed Enterprise, and it is control effectively is one of key technology guaranteeing feed product quality safety.Moisture surpasses specified standard, and the easy moldy metamorphism of pellet is unfavorable for preserving, and also can make the content of nutritional labeling relatively reduce; If but product moisture content is too low, enterprise has been caused again to unnecessary loss, and the uneven moisture of height, also cause the unstable of product quality, have influence on the brand reputation of product.In feed process, suitable moisture can reduce costs, and is conducive to granulate, and reduces energy consumption, improves and produce.
The mould inhibitor using mostly at present is solid mould inhibitor, as Chinese patent CN1692725A discloses a kind of solid mould inhibitor, by monomethyl fumarate and/or dimethyl fumarate and 3-methoxy-4-hydroxybenzaldehyde mixed configuration, is formed.It is uniform that but the effect of solid mould inhibitor and solid feed is difficult to reach, and leave mildew-resistant dead angle.
For the problems referred to above, the liquid mould inhibitor occurring on the market at present, can make the effect of mould inhibitor and solid feed more even, its main component is that organic acid and acylate, water are composite, as patent application CN102657281A discloses a kind of liquid mould inhibitor, by propionic acid, propionic acid ammonium with polymeric guanidine is composite forms.
But in use procedure, the free water of solid feed increases, and the mouldy probability of feed increases greatly, its reason be the utilization of fungus growth process be the free water on feed surface.And some liquid mould inhibitor has good anti-mold effect, but can not reduce the polarity of water, can not reduce the surface tension of water, the free water on feed surface is easy to by mould, utilized and cause feed mouldy, some liquid mould inhibitor can well reduce the polarity of water, reduce the water activity in feed, reduce the mouldy potential risk of feed, but both products are furthermore less.Meanwhile, existing liquid mould inhibitor addition is larger, directly increases production of fodder cost.
Summary of the invention
For above-mentioned technical problem, the object of the present invention is to provide a kind of mildew-resistant ability strong, and can significantly reduce surface tension and the extremely low liquid mould inhibitor of consumption of water.
The present invention is achieved by the following technical programs:
One aspect of the present invention is to provide a kind of feed liquid mould inhibitor with mildew-resistant, water conservation effect, by mass fraction, comprising:
Preferably, described feed liquid mould inhibitor, by mass fraction, comprising:
More preferably, described feed liquid mould inhibitor, by mass fraction, comprising:
Wherein, described propionate is selected from any one or several in the ammonium salt of propionic acid or slaine, wherein, metal in described slaine is selected from the 2-5 cycle of periodic table of elements IA, IIA, IB, IIB family, preferably, described propionate is selected from any one or a few in ammonium salt or alkali metal salt, and more preferably, described propionate is propionic acid ammonium or the propionate mixture that at least contains propionic acid ammonium.
Wherein, described surfactant is selected from anion surfactant, cationic surfactant, non-ionic surface active agent, any one or a few of amphoteric surfactant, wherein, described anion surfactant is as potassium oleate, aluminum stearate etc., described cationic surfactant is as DTAC, hexadecyltrimethylammonium chloride etc., described non-ionic surface active agent is as Tween-20, Tween-40, polysorbate60, Emulsifier EL-60, polyethylene glycol stearate, APEO 60 rilanit specials, LABRAFIL M 1944CS etc., described amphoteric surfactant is as lecithin class, amino acid pattern, betaine type etc.
The present invention also provides the preparation method of described feed liquid mould inhibitor on the other hand, and liquid component is mixed, and then solid constituent is joined in liquid component, mixes.
Further aspect of the present invention also provides a kind of using method of described feed liquid mould inhibitor, by described feed liquid mould inhibitor and water with 1:(15-20) quality than mixed diluting, then add in feed.
Further aspect of the present invention also provides a kind of feed, and described feed contains the described feed liquid mould inhibitor that mass fraction is 0.01-0.2%.
Preferably, described feed contains the described feed liquid mould inhibitor that mass fraction is 0.01-0.08%.
Liquid mould inhibitor of the present invention, component formic acid, propionic acid can penetrate fungal cell wall, discharge H+, make mycotic spore finally dead because of energy exhaustion, and mould is had to very strong killing action; Propionic acid and propionate form powerful buffer system, extend the sterilizing time of propionic acid; In addition, free water is the necessary condition of fungus growth, in order to control water activity, added surfactant, the polarity of water is reduced, help water and feed surface strong bonded, formation is with the combination water of electronics weak bond form, tightr in conjunction with the combination of water and feed, is not easy volatilization, can not allow mould utilization, thereby limit the growth of mould.
Liquid mould inhibitor of the present invention can make vapours more easily infiltrate feed inside, and bactericidal effect is better, and in feed, the quantity of mould obviously reduces, thereby has reduced the risk of going mouldy; Simultaneously, the liquid mould inhibitor conventional with existing market compared, the addition of liquid mould inhibitor of the present invention significantly reduces, existing other liquid mould inhibitor is approximately the addition of 1200g/ ton, and liquid mould inhibitor addition of the present invention only needs 500-600g/ ton, and then reduced production of fodder cost.
The specific embodiment
Embodiment 1
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Embodiment 2
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Embodiment 3
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Embodiment 4
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Embodiment 5
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Embodiment 6
Liquid mould inhibitor described in the present embodiment, by weight, comprising:
Aforesaid liquid component is first added in mixer, then add solid constituent, mix.
Test case
This test case is tested by the following method.
1, test material
Feed formula: 63% corn, 25% dregs of beans, 8% wheat bran, 4% premix
Mould inhibitor sample: embodiment 1,2,3, common liq mould inhibitor on market (main component 40% propionate, 20% propionic acid, 10% lactic acid, 5% phosphoric acid, 15% moisture after tested), it is reported, on market, most common liq mould inhibitor water content are after tested between 15-30%.
2, test method:
(1), the liquid mould inhibitor of common liq mould inhibitor on market and embodiment 1-3 is added in feed and mixed by 0.05%, group, test group 1-3 as a comparison respectively, not add in contrast blank group of mould inhibitor.
(2), prepare the beaker of 1 liter and the little plastic cup of 200 milliliters, feed is placed in to large cup, noggin is placed in to feed middle position.
(3), in noggin, inject 60ml distilled water, and water is not scattered in sample, with two-layer preservative film, large cup is sealed to guarantee whole large cup sealing.
(4), the cup that feed is housed is placed under the insulating box or other similar warm conditions of 30 ° of C.Observe sample every day once, observe and whether have mould (silk) to grow, and test is carried out to record.
3, result of the test
The result of the test of liquid mould inhibitor anti-mold effect test sees subordinate list 1.
Subordinate list 1 liquid mould inhibitor anti-mold effect test card
Experiment number of days/sky Blank group Contrast groups Test group 1 Test group 2 Test group 3
1-7 - - - - -
8 + - - - -
9 ++ - - - -
10 +++ + + - -
11 ++++ ++ ++ + -
12 ++++ +++ ++++ ++ +
Wherein, in table 1, "-" is mouldy for not having, and "+", for gathering mould, " ++ " is that moderate is mouldy, and " +++ " is most of mouldy, " ++++" for all mouldy.
From the data of table 1, can obviously see, under hot and humid condition, blank group test the 8th day is mouldy, and common liq mould inhibitor on market, test group 1 the 10th day are mouldy, and test group 2 the 11st day is mouldy, and test group 3 the 12nd day is mouldy, and anti-mold effect is best.
Comprehensive, liquid mould inhibitor of the present invention can arrive and be better than the prevention effect of common liq mould inhibitor on market, and with water retaining function, simultaneously, use amount significantly reduces, liquid mould inhibitor of the present invention only needs the addition of 500-600g/ ton, far below the addition of the common about 1200g/ ton of liquid mould inhibitor, and then has reduced production of fodder cost.
Above specific embodiments of the invention be have been described in detail, but it is just as example, the present invention is not restricted to specific embodiment described above.To those skilled in the art, any equivalent modifications that the present invention is carried out and alternative also all among category of the present invention.Therefore, equalization conversion and the modification done without departing from the spirit and scope of the invention, all should contain within the scope of the invention.

Claims (10)

1. a feed liquid mould inhibitor with mildew-resistant, water conservation effect, is characterized in that, by mass fraction, comprising:
2. feed liquid mould inhibitor according to claim 1, is characterized in that, by mass fraction, comprising:
3. feed liquid mould inhibitor according to claim 2, is characterized in that, by mass fraction, comprising:
4. feed liquid mould inhibitor according to claim 1, it is characterized in that, described propionate is selected from any one or several in the ammonium salt of propionic acid or slaine, and wherein, the metal in described slaine is selected from the 2-5 cycle of periodic table of elements IA, IIA, IB, IIB family.
5. feed liquid mould inhibitor according to claim 4, is characterized in that, described propionate is selected from any one or several in ammonium salt or alkali metal salt.
6. feed liquid mould inhibitor according to claim 5, is characterized in that, described propionate is propionic acid ammonium or the propionate mixture that at least contains propionic acid ammonium.
7. feed liquid mould inhibitor according to claim 1, is characterized in that, described surfactant is selected from any one or a few in anion surfactant, cationic surfactant, non-ionic surface active agent.
8. a preparation method for described feed liquid mould inhibitor, is characterized in that, liquid component is mixed, and then solid constituent is joined in liquid component, mixes.
9. a using method for described feed liquid mould inhibitor, is characterized in that, by described feed liquid mould inhibitor and water with 1:(15-20) quality than mixed diluting, then add in feed.
10. a feed, is characterized in that, described feed comprises the described feed liquid mould inhibitor that mass fraction is 0.01-0.08%.
CN201410155705.0A 2014-04-17 2014-04-17 A kind of feedstuff liquid mildew preventive with mildew-resistant, water conservation effect Active CN103988989B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105341360A (en) * 2015-12-07 2016-02-24 重庆华睿隆生物科技有限公司 Carrier-free propionic acid solid feed mildew preventive and preparation and use thereof
CN106036035A (en) * 2016-06-13 2016-10-26 江苏盐城源耀生物科技有限公司 Water-retaining agent having mold-proof function and preparation method thereof
CN106819764A (en) * 2016-12-27 2017-06-13 新昌县拜瑞珂生物技术有限公司 It is a kind of with mould proof, water conservation effect feed liquid mildew preventive
CN106819395A (en) * 2017-01-24 2017-06-13 上海邦成生物工程有限公司 A kind of composite mildew inhibitor with acidifying feed effect and preparation method thereof
CN108935983A (en) * 2018-06-20 2018-12-07 刘吉生 A kind of milk cow fully mixed diet additive

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997010724A1 (en) * 1995-09-18 1997-03-27 Basf Aktiengesellschaft Aqueous solutions of formic acid, propionic acid and ammonia and their use
CN101156598A (en) * 2007-09-20 2008-04-09 成都枫澜科技有限公司 Mould inhibitor with mildew resistant and mold toxin adsorption dual behavior as well as preparation method
CN102657281A (en) * 2012-04-12 2012-09-12 广汉隆达饲料有限公司 Dispersion type liquid mildew inhibitor and preparation method thereof
CN102919515A (en) * 2012-11-16 2013-02-13 安佑(中国)动物营养研发有限公司 Liquid mildew preventive
CN103168974A (en) * 2013-03-25 2013-06-26 重庆民泰香料化工有限责任公司 Liquid mildewproof agent for feed and method for avoiding mildew of feed

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997010724A1 (en) * 1995-09-18 1997-03-27 Basf Aktiengesellschaft Aqueous solutions of formic acid, propionic acid and ammonia and their use
CN101156598A (en) * 2007-09-20 2008-04-09 成都枫澜科技有限公司 Mould inhibitor with mildew resistant and mold toxin adsorption dual behavior as well as preparation method
CN102657281A (en) * 2012-04-12 2012-09-12 广汉隆达饲料有限公司 Dispersion type liquid mildew inhibitor and preparation method thereof
CN102919515A (en) * 2012-11-16 2013-02-13 安佑(中国)动物营养研发有限公司 Liquid mildew preventive
CN103168974A (en) * 2013-03-25 2013-06-26 重庆民泰香料化工有限责任公司 Liquid mildewproof agent for feed and method for avoiding mildew of feed

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105341360A (en) * 2015-12-07 2016-02-24 重庆华睿隆生物科技有限公司 Carrier-free propionic acid solid feed mildew preventive and preparation and use thereof
CN106036035A (en) * 2016-06-13 2016-10-26 江苏盐城源耀生物科技有限公司 Water-retaining agent having mold-proof function and preparation method thereof
CN106819764A (en) * 2016-12-27 2017-06-13 新昌县拜瑞珂生物技术有限公司 It is a kind of with mould proof, water conservation effect feed liquid mildew preventive
CN106819395A (en) * 2017-01-24 2017-06-13 上海邦成生物工程有限公司 A kind of composite mildew inhibitor with acidifying feed effect and preparation method thereof
CN108935983A (en) * 2018-06-20 2018-12-07 刘吉生 A kind of milk cow fully mixed diet additive

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