CN103915316B - Stacked nanowire fabrication method - Google Patents

Stacked nanowire fabrication method Download PDF

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Publication number
CN103915316B
CN103915316B CN201310007063.5A CN201310007063A CN103915316B CN 103915316 B CN103915316 B CN 103915316B CN 201310007063 A CN201310007063 A CN 201310007063A CN 103915316 B CN103915316 B CN 103915316B
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groove
nano wire
substrate
fin
etching
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CN103915316A (en
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马小龙
殷华湘
秦长亮
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Institute of Microelectronics of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/785Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • H01L29/7853Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET the body having a non-rectangular crossection

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Drying Of Semiconductors (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The invention discloses a stacked nanowire manufacturing method, which comprises the following steps: step a, forming a hard mask on a substrate; step b, anisotropically etching the substrate to form a first groove and a fin; step c, corroding the fins and the lower substrate by a wet method, and forming a second groove on the side surface of the first groove; repeating the steps b to c for multiple times to form a plurality of fins stacked up and down; and d, rounding the fins to form stacked nanowires. According to the manufacturing method of the stacked nanowire, the dry etching and the wet etching are combined, the high-precision stacked nanowire is formed by utilizing double internal cutting corrosion, the miniaturization of a device is facilitated, and the cost is reduced.

Description

Stack nano wire manufacturing method
Technical field
The present invention relates to a kind of method, semi-conductor device manufacturing methods, more particularly to a kind of manufacturing method stacking nano wire.
Background technology
In current sub- 20nm technologies, three-dimensional multi-gate device (FinFET or Tri-gate) is main device architecture, This structure enhances grid control ability, inhibits electric leakage and short-channel effect.
For example, the MOSFET of double gate SOI structure can inhibit short compared with traditional single grid body Si or SOI MOSFET Channelling effect (SCE) and leakage cause induced barrier to reduce (DIBL) effect, have lower junction capacity, can realize that raceway groove is gently mixed Miscellaneous, work function that can be by the way that metal gates are arranged can obtain about 2 times of driving current, reduce come adjusting threshold voltage Requirement for effective gate oxide thickness (EOT).And tri-gate devices are compared with double-gated devices, grid enclose channel region top surface and Two sides, grid control ability are stronger.Further, loopful is more advantageous around nano wire multi-gate device.
In loopful in the manufacturing process of nano wire multi-gate device, it is known that a kind of method it is as follows:It is formed on a si substrate Hard mask, using SF6The isotropic plasma of etching gas, which is dry-etched in hard mask lower substrate, to be formed in slightly Recessed first groove, there are substrate materials to constitute fin structure between opposite first groove;Using high density CxF (carbon fluorine ratios It is higher) plasma etching of etching gas, on substrate and first groove side wall forms passivation layer;SF again6Respectively to different Property etching, remove substrate on passivation layer, leave the passivation layer of first groove madial wall;SF6Isotropic etching continues etching lining Bottom forms second groove below first groove;And so on, form multiple grooves and fin structure;Between oxidation groove Fin structure removes oxide, leaves nano-wire array.This method technology controlling and process is difficult, and nanowire density is smaller, consistency compared with Difference.
Method known to another kind includes:It is formed epitaxially one after the other the overlapping epitaxial layer of Si and Ge/SiGe on soi substrates, Hard mask layer is formed in top layer, etching forms grid lines, and selective etch removes the Ge/SiGe layers between i layers of adjacent S, stays Lower Si nano wires.This method is limited to the bed boundarys Ge/SiGe poor performance, and process costs are high, it is difficult to universal.
In view of the trench fabrication methods in contrast simple process of Σ shape sections, as long as can relatively good control anisotropy quarter Erosion, then be expected to form uniform, highdensity stacking nano wire.
Invention content
From the above mentioned, inexpensive, efficient nano wire manufacturing method can be stacked the purpose of the present invention is to provide a kind of.
For this purpose, the present invention provides a kind of stacking nano wire manufacturing methods, including:Step a is formed cover firmly on substrate Mould;Step b, anisotropic etching substrate form first groove and fin;Step c, wet etching fin and lower substrate, First groove side forms second groove;Wherein, step b to step c is repeated several times, forms multiple fins stacked on top of one another;Step Rapid d, mellow and fullization fin form and stack nano wire.
Wherein, substrate is body Si or SOI.
Wherein, substrate is (100) crystal face.
Wherein, the anisotropic etching of step b is dry etching.Wherein, dry etching RIE.Wherein, etching gas packet Include fluorine base gas.
Wherein, further include after step c, before step d:Step c1, anisotropic etching substrate form another group first Groove and fin;Step c2, isotropic etching fin and lower substrate form third groove in first groove side;Its In, step b, step c, step c1, step c2 is repeated several times, forms multiple fins stacked on top of one another.
Wherein, the first groove of formation has vertical sidewall.
Wherein, first groove side wall is (110) face, and substrate is (100) face.
Wherein, wet etching liquid includes TMAH.
Wherein, step d further comprises:Oxide layer is formed on fin surface;Removing oxide layer is removed, fin is exposed;In hydrogen It anneals under atmosphere so that fin mellow and fullization forms and stack nano wire.
Wherein, first groove side wall is (110) face, and substrate is (100) face.
Wherein, second groove side wall is (111) face.
Wherein, third trenched side-wall is (110) face.
According to the stacking nano wire manufacturing method of the present invention, dry etching and wet etching are combined, dual inscribe is utilized Corrosion forms high-precision and stacks nano wire, is conducive to device miniaturization, reduces cost.
Description of the drawings
Carry out the technical solution that the present invention will be described in detail referring to the drawings, wherein:
Fig. 1 to Fig. 8 is the cut-away view according to each step of manufacturing method of first embodiment of the invention;
Fig. 9 to Figure 15 is the sectional view according to each step of manufacturing method of second embodiment of the invention;
Figure 16 is the schematic flow chart according to first embodiment of the present invention manufacturing method;And
Figure 17 is the schematic flow chart according to second embodiment of the present invention manufacturing method.
Specific implementation mode
Come the feature and its skill of the present invention will be described in detail technical solution referring to the drawings and in conjunction with schematical embodiment Art effect, disclosing can low cost, efficient stacking nano wire manufacturing method.It should be pointed out that similar reference numeral table Show that similar structure, term use herein " first ", " second ", "upper", "lower" etc. can be used for modifying various devices Structure or manufacturing process.These modifications do not imply that the space, secondary of modified device architecture or manufacturing process unless stated otherwise Sequence or hierarchical relationship.
First, below with reference to the flow chart of Figure 16 and referring to figs. 1 to the diagrammatic cross-section of Fig. 8 come be described in detail according to Each step of method, semi-conductor device manufacturing method of first embodiment of the invention.
As shown in Figure 1, providing substrate 1.Substrate 1 is needed according to device application and is reasonably selected, it may include monocrystalline silicon (Si), silicon-on-insulator (SOI), monocrystal germanium (Ge), germanium on insulator (GeOI), strained silicon (Strained Si), germanium silicon , such as gallium nitride (GaN), GaAs (GaAs), indium phosphide (InP), indium antimonide (SiGe) or compound semiconductor materials (InSb) and carbon-based semiconductors such as graphene, SiC, carbon nanotube etc..Preferably, substrate 1 be body Si so as to CMOS works Skill is compatible and is used to make large scale integrated circuit.It is highly preferred that substrate 1 is (100) crystal face.
As shown in Fig. 2, forming hard mask 2 on substrate 1.By LPCVD, PECVD, UHVCVD, HDPCVD, thermal oxide, The conventional methods such as chemical oxidation, MBE, ALD, evaporation, sputtering form hard mask layer on substrate 1, and utilize already known processes light Quarter/etching forms hard mask figure 2.The material of hard mask 2 can be silica, silicon nitride, silicon oxynitride and combinations thereof.
As shown in figure 3, etched substrate 1 forms first groove 1G, 1 remainder of substrate that 2 lower section of hard mask leaves is constituted First fin 1F.Etching is preferably anisotropic etching, so that the side wall of first groove 1G is that (basic) is vertical.Anisotropy Etching preferably fluorine base gas (such as carbon fluorine base gas CxHyFz, it be 0~8, z is 1~8, xyz three's numbers that wherein x, which is 1~4, y, Magnitude relation meets so that above-mentioned chemical formula constitutes fluoro (saturation is either unsaturated) alkene or alkane;In addition can also be SF6、 NF3) plasma dry etch, in order to accurately control etching depth d by controlling etching conditionE, and then control final nanometer Line height/thickness.Etching is so that the side wall of first groove 1G is (110) face, and 1 surface of substrate remains as (100) face.
As shown in figure 4, executing wet etching, fin 1F and substrate 1 are etched, the second ditch is formed in the sides first groove 1G Slot 1G '.The corrosive liquid of wet etching is tetramethylammonium hydroxide (TMAH), etches the first fin 1F between first groove 1G, (sides first groove 1G) forms second groove 1G ' in fin 1F.In wet etching course, (111) face of Si materials is rotten It loses rate and is substantially less than (100) face and (110) face, therefore etching eventually terminates on (111) face.It in addition can be wet by controlling The velocity and time of method corrosion so that the profile morphology of second groove 1G ' is substantially triangle.As shown in figure 4, in the present invention the In one embodiment, second groove 1G ' does not make fin 1F break-through, but is connected there are a small amount of between opposite second groove Part.Certainly, alternatively, second groove 1G ' can also break-through so that fin 1F and lower substrate (or follow-up fin) point From.It is worth noting that, in the process, since side wall is (110) face, and substrate is (100) face, therefore TMAH is for side wall Corrosion rate be slightly less than substrate do not exist so that second groove 1G ' bottom widths are more than top width namely groove endpoint On vertical line.Subsequently to execute further technique makes second groove endpoint be distributed on vertical line.
As shown in figure 5, executing anisotropic etching, etched substrate 1 so that the substrate portions of fin 1F inclined downward side walls It is etched to form another group of fin 1F ' with vertical sidewall, the groove between fin 1F ', which is then another group, has vertical sidewall First groove 1G.Anisotropic etching can be above-mentioned dry etching, such as plasma etching or reactive ion are carved It loses (RIE), the side wall for etching the fin 1F ' of formation is (110) crystal face, and substrate is still (100) crystal face.It is worth noting that, Fig. 4 The V-groove on 1 surface of middle substrate is still conformally formed in Figure 5, and the sloped sidewall of fin 1F section below is then etched It is modified to vertical sidewall, therefore endpoint is finally distributed on a vertical line second groove 1G ' up and down.In this way, by each to same Property the etching and blocked operation of anisotropic etching, Σ type profile grooves can be made to can be used for forming uniformly neat nanometer Line stacks.
As shown in fig. 6, it is similar with technique shown in Fig. 4, wet etching is executed, continues to etch another group of fin 1F ', wherein Form another group of second groove 1G '.Correspondingly, second groove 11G ' at this time up and down endpoint not on a vertical line.
As shown in fig. 7, it is similar with technique shown in Fig. 5, anisotropic etching is executed, is eliminated prominent below second groove 1G ' The part gone out so that another group of fin 1F ' has vertical sidewall.
As shown in figure 8, it is similar with technique shown in Fig. 4 or Fig. 6, TMAH wet etchings are executed, another group of fin 1F " is formed And second groove 1G ".
Hereafter, subsequent technique processing can be carried out so that fin structure is thinned.Common method includes using thermal oxide, chemistry The method of oxidation forms oxide layer (being not shown, such as silica) on fin structure 1F/1F '/surfaces 1F ", and makes remaining Fin structure 1F/1F '/1F " constitutes nano wire 1NW.Preferably, it can further anneal in atmosphere of hydrogen so that remaining ground Fin structure the 1F/1F '/surfaces 1F " mellow and fullization, forms circular nano wire 1NW.Then, the oxide layer for removing surface, leaves and receives Rice noodles 1NW.Minimizing technology is, for example, that entire device wafer immerses HF bases corrosive liquid (dHF or dBOE (sustained release etching agent)), rotten The oxide layer of etching off silicon material only leaves multiple nano wire 1NW and stacks the grid line array constituted.
Fig. 9 to Figure 15 show each step sectional view of process according to second embodiment of the invention, and Figure 17 shows for it Meaning property flow chart.
It is similar or identical with Fig. 1 of embodiment 1 to Fig. 5 as shown in Fig. 9~Figure 13, form hard mask on substrate 1 2, anisotropic etching substrate 1 formed fin 1F and vertical sidewall first groove 1G, TMAH wet etching fin 1F and Substrate 1 forms the second groove 1G ' of indent, and anisotropic etching fin 1F lower substrates make second groove 1G ' endpoints up and down On vertical line, namely so that another group of fin 1F ' has vertical sidewall below fin 1F.Wherein, etching can shown in Figure 13 To be reactive ion etching (RIE), etching gas can be above-mentioned carbon fluorine base gas, (such as be reduced by adjusting gas mixing ratio Fluorine content improves carbohydrate content and can improve isotropism, and anisotropy can be improved by improving fluorine content) so that RIE be it is each to It is anisotropic.Remaining processing step is similar or identical, therefore repeats no more.
As different from Example 1, embodiment 2 is foring first group of fin 1F, first groove 1G and is modifying Two groove 1G ' make its upper and lower side on vertical line after, be not the cycle as shown in FIG. 6 for continuing next TMAH wet etchings Step, but as shown in figure 14, third groove 1G " is formed using isotropic RIE.It can be by adjusting gas mixing ratio (such as reduction fluorine content, raising carbohydrate content can improve isotropism, and anisotropy can be improved by improving fluorine content) makes This RIE is isotropism.It is worth noting that, although third groove 1G " profile morphologies are circular arc as shown in the figure, actually On can not be all various rational shapes according to etching condition, such as semicircle (D types), large semicircle (c-type), ellipse, parabola, Hyperbola etc. and combinations thereof.Third groove 1G " lower widths herein are still likely larger than or are equal to upper width, but can lead to Adjustment RIE technological parameters are crossed so that finally to make that third groove 1G " is wide up and down.
As shown in figure 15, processing step shown in Fig. 9 to Figure 14 is repeated, etches to form multiple second using isotropism RIE Groove 1G ' and multiple third groove 1G ".
Finally, it is referred to embodiment 1, continues subsequent technique, nano wire is completed and stacks.
According to the stacking nano wire manufacturing method of the present invention, dry etching and wet etching are combined, dual inscribe is utilized Corrosion forms high-precision and stacks nano wire, is conducive to device miniaturization, reduces cost.
Although illustrating the present invention with reference to one or more exemplary embodiments, those skilled in the art, which could be aware that, to be not necessarily to It is detached from the scope of the invention and various suitable changes and equivalents is made to device architecture.In addition, can by disclosed introduction The modification of particular condition or material can be can be adapted to without departing from the scope of the invention by making many.Therefore, the purpose of the present invention does not exist In being limited to as the preferred forms for realizing the present invention and disclosed specific embodiment, and disclosed device architecture And its manufacturing method is by all embodiments including falling within the scope of the present invention.

Claims (11)

1. a kind of stacking nano wire manufacturing method, including:
Step a, forms hard mask on substrate;
Step b, anisotropic etching substrate form first groove and fin;
Step c, wet etching fin and lower substrate form the second groove of triangle, the second ditch in first groove side Endpoint is not on the straight line perpendicular to substrate above and below slot;
Wherein, step b to step c is repeated several times, forms multiple fins stacked on top of one another, wherein the step b in recycling every time Endpoint is distributed in a straight line perpendicular to substrate to the second groove of step c up and down in one cycle before anisotropic etching makes On;
Step d, mellow and fullization fin form and stack nano wire.
2. stacking nano wire manufacturing method as claimed in claim 1, wherein substrate is body Si or SOI.
3. stacking nano wire manufacturing method as claimed in claim 1, wherein substrate is (100) crystal face.
4. stacking nano wire manufacturing method as claimed in claim 1, wherein the anisotropic etching of step b is dry etching.
5. stacking nano wire manufacturing method as claimed in claim 4, wherein dry etching RIE.
6. stacking nano wire manufacturing method as claimed in claim 5, wherein etching gas includes fluorine base gas.
7. stacking nano wire manufacturing method as claimed in claim 1, wherein further include after step c, before step d:Step c1, Anisotropic etching substrate forms another group of first groove and fin;Step c2, isotropic etching fin and lower substrate, Third groove is formed in first groove side;Wherein, step b, step c, step c1, step c2 is repeated several times, forms levels Folded multiple fins.
8. stacking nano wire manufacturing method as claimed in claim 1, wherein the first groove of formation has vertical sidewall.
9. stacking nano wire manufacturing method as claimed in claim 6, wherein first groove side wall is (110) face, and substrate is (100) Face.
10. stacking nano wire manufacturing method as claimed in claim 1, wherein wet etching liquid includes tetramethylammonium hydroxide.
11. stacking nano wire manufacturing method as claimed in claim 1, wherein step d further comprises:Oxygen is formed on fin surface Change layer;Removing oxide layer is removed, fin is exposed;It anneals under an atmosphere of hydrogen so that fin mellow and fullization forms and stack nano wire.
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CN105742153B (en) * 2014-12-11 2019-09-24 中国科学院微电子研究所 Method of forming cascaded nanowires
CN105742232B (en) * 2014-12-11 2019-01-18 中国科学院微电子研究所 Method for forming nanowire array
CN105742175B (en) * 2014-12-11 2019-09-24 中国科学院微电子研究所 Method for forming nanowire array
CN105742231B (en) * 2014-12-11 2020-04-24 中国科学院微电子研究所 Method for forming nanowire array
CN105742239B (en) * 2014-12-11 2018-12-11 中国科学院微电子研究所 Method for forming nanowire array
US9564489B2 (en) * 2015-06-29 2017-02-07 Taiwan Semiconductor Manufacturing Company, Ltd. Multiple gate field-effect transistors having oxygen-scavenged gate stack
CN105590845A (en) * 2015-12-25 2016-05-18 中国科学院微电子研究所 Method for manufacturing stacked fence nanowire
CN105719961B (en) * 2016-02-04 2018-08-10 中国科学院微电子研究所 Stacked nanowire fabrication method
CN107437556A (en) * 2016-05-27 2017-12-05 中芯国际集成电路制造(上海)有限公司 GAA structures MOSFET forming method
CN107871666B (en) * 2017-09-25 2020-08-21 中国科学院上海微系统与信息技术研究所 Method for manufacturing vertical stacking integrated semiconductor nano-wire and field effect transistor thereof
CN109888014B (en) * 2017-12-06 2022-03-22 中芯国际集成电路制造(上海)有限公司 Nanowire device and method of forming the same

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US7736954B2 (en) * 2005-08-26 2010-06-15 Sematech, Inc. Methods for nanoscale feature imprint molding
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