CN103880334B - A kind of skin epoxypaint - Google Patents

A kind of skin epoxypaint Download PDF

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Publication number
CN103880334B
CN103880334B CN201410135157.5A CN201410135157A CN103880334B CN 103880334 B CN103880334 B CN 103880334B CN 201410135157 A CN201410135157 A CN 201410135157A CN 103880334 B CN103880334 B CN 103880334B
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parts
component
weight
epoxypaint
skin
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Expired - Fee Related
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CN201410135157.5A
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CN103880334A (en
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龚利芬
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Shanghai Limin environmental protection energy saving science and Technology Co Ltd
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吴俊�
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Abstract

The invention belongs to technical field of coatings, especially relate to a kind of skin epoxypaint, it is characterized in that it is component A, B ratio=(900 ~ 1800) with weight parts: (30 ~ 50) form; Component A counts by weight and contains: epoxy resin: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Component B contains: coating curing agent, daconil M; The present invention has following main beneficial effect: good fluidity, anti-mildew and anti-corrosion performance is excellent, coating dry fast with setting rate, match colors flexible, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy.

Description

A kind of skin epoxypaint
the application is that name is called: a kind of skin epoxypaint, number of patent application are: 201310049134.8, the applying date is: the divisional application of the application for a patent for invention on February 7th, 2013.
Technical field
the invention belongs to technical field of coatings, especially relate to a kind of skin epoxypaint.
Background technology
in prior art, epoxypaint is widely used, but the epoxypaint rate of drying regrettably used in prior art is slow, can not meet the requirement of rapid construction.
Summary of the invention
in order to solve the problem, the present invention discloses a kind of skin epoxypaint, and it dryly quickly also can be bonded in skin surface securely, and it realizes by the following technical solutions.
a kind of skin epoxypaint, is characterized in that it is made up of component A, B component and component C, with weight parts, meets: component A: component B: component C=(900 ~ 1800): (30 ~ 50): 1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein are dark green or phthalein is blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio takes epoxy resin by weight: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B: component C=(900 ~ 1800): (30 ~ 50): the weight ratio of 1 takes component C and inserts in container the component C that gets product; And rationally take component A and component B in proportion;
4th step: the finished product component C claimed in the 3rd step inserted in finished product component B, abundant stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
skin epoxypaint described above, empirical tests, wherein with weight parts, meets: component A: component B: component C=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 4 parts, daconil M: 3 parts; Component C is dark green or the blue or green red or bright red formula of phthalein of ultramarine or phthalocyanine blue or phthalein, the best results that can reach.
skin epoxypaint described above, is characterized in that described coating curing agent is epoxy curing agent D-230 or D-400 of DSM Di Suo company production or the solidifying agent EC-301 of BASF Chemical Co., Ltd. production.
in the present invention, owing to having the existence of the volatile materials such as acetone, ethylene glycol monobutyl ether, ethanol in component A, therefore by paint when building surface, very rapidly dry with solidify, very be convenient to rapid construction, in addition, making method of the present invention is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects; Good fluidity of the present invention, is not only applicable to artificial coating, and also pole is suitable for machine spraying; Due to the existence of daconil M in the present invention, product is made to have excellent anti-mildew, anti-corrosion performance.
certainly, improve as of the present invention another, can not use component C completely, namely the content of component C is zero, and through test, product can use as usual, only the product color that do not have other to require, but presents white.
during this product export, the mode of packing separately by component A, component B, component C is supplied, and before coating, component C is mixed with B, and then adds in component A and mix; Certainly, when component C does not exist, only need that component B is added component A and mix; The existence of component C, can configure the color of coating neatly, be applied in the occasion of various needs; Certainly, the present invention should be finished upon mixing in 8 hours, in order to avoid solidification.
therefore, the present invention has following main beneficial effect: good fluidity, anti-mildew and anti-corrosion performance is excellent, coating dry fast with setting rate, match colors flexible, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects.
Embodiment
below in conjunction with embodiment, the present invention is further described in detail, but is not limited to this.
embodiment 1
a kind of skin epoxypaint, is characterized in that it is made up of component A, B component and component C, with weight parts, meets: component A: component B: component C=900:30:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 12 parts, acetone: 18 parts, ethylene glycol monobutyl ether: 8 parts, commercially available OP-10 type emulsifying agent: 3 parts, sodium hydroxide: 0.3 part, ethanol: 50 parts, deionized water: 100 parts, titanium dioxide: 180 parts, zinc sulfide white: 45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein are dark green or phthalein is blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 12 parts, acetone: 18 parts, ethylene glycol monobutyl ether: 8 parts, commercially available OP-10 type emulsifying agent: 3 parts, sodium hydroxide: 0.3 part, ethanol: 50 parts, deionized water: 100 parts, titanium dioxide: 180 parts, zinc sulfide white: 45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 180 parts, zinc sulfide white: 45 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B: the weight ratio of component C=900:30:1 takes component C and inserts in container the component C that gets product; And rationally take component A and component B in proportion;
4th step: the finished product component C claimed in the 3rd step inserted in finished product component B, abundant stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
embodiment 2
a kind of skin epoxypaint, is characterized in that it is made up of component A, B component and component C, with weight parts, meets: component A: component B: component C=1800:50:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8 parts, acetone: 12 parts, ethylene glycol monobutyl ether: 3 parts, commercially available OP-10 type emulsifying agent: 1 part, sodium hydroxide: 0.1 part, ethanol: 30 parts, deionized water: 70 parts, titanium dioxide: 140 parts, zinc sulfide white: 35 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein are dark green or phthalein is blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 8 parts, acetone: 12 parts, ethylene glycol monobutyl ether: 3 parts, commercially available OP-10 type emulsifying agent: 1 part, sodium hydroxide: 0.1 part, ethanol: 30 parts, deionized water: 70 parts, titanium dioxide: 140 parts, zinc sulfide white: 35 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140 parts, zinc sulfide white: 35 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B: the weight ratio of component C=1800:30:1 takes component C and inserts in container the component C that gets product; And rationally take component A and component B in proportion;
4th step: the finished product component C claimed in the 3rd step inserted in finished product component B, abundant stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
embodiment 3
a kind of skin epoxypaint, is characterized in that it is made up of component A, B component and component C, with weight parts, meets: component A: component B: component C=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein are dark green or phthalein is blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio epoxy resin by weight: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 160 parts, zinc sulfide white: 40 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B: the weight ratio of component C=1125:35:1 takes component C and inserts in container the component C that gets product; And rationally take component A and component B in proportion;
4th step: the finished product component C claimed in the 3rd step inserted in finished product component B, abundant stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
through the repetition test of contriver, in above-mentioned arbitrary embodiment, the coating adopting following ratio and method to realize can reach object of the present invention:
a kind of skin epoxypaint, is characterized in that it is made up of component A, B component and component C, with weight parts, meets: component A: component B: component C=(900 ~ 1800): (30 ~ 50): 1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Component C is that ultramarine or phthalocyanine blue or phthalein are dark green or phthalein is blue or green red or bright red; Skin epoxypaint described above, it prepares by the following method:
the first step: make component A: first ratio takes epoxy resin by weight: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B: component C=(900 ~ 1800): (30 ~ 50): the weight ratio of 1 takes component C and inserts in container the component C that gets product; And rationally take component A and component B in proportion;
4th step: the finished product component C claimed in the 3rd step inserted in finished product component B, abundant stirring and dissolving, obtains lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
skin epoxypaint described above, empirical tests, wherein with weight parts, meets: component A: component B: component C :=1125:35:1; Wherein, component A counts by weight, includes following material and content: epoxy resin: 10 parts, acetone: 15 parts, ethylene glycol monobutyl ether: 5 parts, commercially available OP-10 type emulsifying agent: 2 parts, sodium hydroxide: 0.2 part, ethanol: 40 parts, deionized water: 90 parts, titanium dioxide: 160 parts, zinc sulfide white: 40 parts; Component B, by by weight, includes following material and content: coating curing agent: 4 parts, daconil M: 3 parts; Component C is dark green or the blue or green red or bright red formula of phthalein of ultramarine or phthalocyanine blue or phthalein, the best results that can reach.
skin epoxypaint described above, is characterized in that described coating curing agent is epoxy curing agent D-230 or D-400 of DSM Di Suo company production or the solidifying agent EC-301 of BASF Chemical Co., Ltd. production.
in the present invention, owing to having the existence of the volatile materials such as acetone, ethylene glycol monobutyl ether, ethanol in component A, therefore by paint when building surface, very rapidly dry with solidify, very be convenient to rapid construction, in addition, making method of the present invention is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects; Good fluidity of the present invention, is not only applicable to artificial coating, and also pole is suitable for machine spraying; Due to the existence of daconil M in the present invention, product is made to have excellent anti-mildew, anti-corrosion performance.
certainly, improve as of the present invention another, can not use component C completely, namely the content of component C is zero, and through test, product can use as usual, only the product color that do not have other to require, but presents white.
during this product export, the mode of packing separately by component A, component B, component C is supplied, and before coating, component C is mixed with B, and then adds in component A and mix; Certainly, when component C does not exist, only need that component B is added component A and mix; The existence of component C, can configure the color of coating neatly, be applied in the occasion of various needs; Certainly, the present invention should be finished upon mixing in 8 hours, in order to avoid solidification.
therefore, the present invention has following main beneficial effect: good fluidity, anti-mildew and anti-corrosion performance is excellent, coating dry fast with setting rate, match colors flexible, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects.
the present invention have passed through following Performance Detection:
Sequence number Interventions Requested Technical requirements Assay Conclusion
1 Condition in container Without lump, in uniform state after stirring Meet the requirements Qualified
2 Application property Brush two roads accessible Meet the requirements Qualified
3 Low-temperature stability (-20 DEG C) Never degenerate Meet the requirements Qualified
4 25 DEG C of set times ≤144h 8h Qualified
5 Appearance of film Normally Meet the requirements Qualified
6 Water-fastness 96h is without exception Meet the requirements Qualified
7 Acid resistance 48h is without exception Meet the requirements Qualified
8 Abrasion resistance (secondary) ≥500 3000 Qualified
9 Midew proof During humidity 40%, continuous 60 days without mildew Without mildew Qualified
and the products solidifying time of the prior art is generally at 72 hours, therefore, set time is substantially increased; In addition, midew proof has and also greatly improves.
the present invention is not limited to above-mentioned preferred forms, and should be appreciated that design of the present invention can be implemented to use by other various forms, they drop in protection scope of the present invention equally.

Claims (2)

1. a skin epoxypaint, is characterized in that it is made up of component A, B component, with weight parts, meets: component A: component B=(900 ~ 1800): (30 ~ 50); Wherein, component A counts by weight, includes following material and content: epoxy resin: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Component B, by by weight, includes following material and content: coating curing agent: 3 ~ 5 parts, daconil M: 2 ~ 4 parts; Skin epoxypaint described above, it prepares by the following method:
The first step: make component A: first ratio takes epoxy resin by weight: 8 ~ 12 parts, acetone: 12 ~ 18 parts, ethylene glycol monobutyl ether: 3 ~ 8 parts, commercially available OP-10 type emulsifying agent: 1 ~ 3 part, sodium hydroxide: 0.1 ~ 0.3 part, ethanol: 30 ~ 50 parts, deionized water: 70 ~ 100 parts, titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts; Epoxy resin, acetone, ethylene glycol monobutyl ether, commercially available OP-10 type emulsifying agent, sodium hydroxide, ethanol, deionized water are fully mixed; Mixture is heated to 75 ~ 85 DEG C; Insulation is also stirred 1 hour simultaneously, obtains initial latex; Again by titanium dioxide: 140 ~ 180 parts, zinc sulfide white: 35 ~ 45 parts add initial latex together and stir and namely obtain component A emulsion; Component A emulsion is loaded in packaging vessel the component A that gets product;
Second step: make component B: ratio takes the various raw material of component B and mixing and stirring loads container namely obtains finished product component B by weight;
3rd step: according to component A: component B=(900 ~ 1800): the weight ratio of (30 ~ 50) exampletake component A and component B;
4th step: by the abundant stirring and dissolving of finished product component B claimed in the 3rd step, obtain lysate; Lysate is joined in finished product component A, stir and obtain skin epoxypaint.
2. according to claim 1 one kindskin epoxypaint, is characterized in that described coating curing agent is epoxy curing agent D-230 or D-400 of DSM Di Suo company production or the solidifying agent EC-301 of BASF Chemical Co., Ltd. production.
CN201410135157.5A 2013-02-07 2013-02-07 A kind of skin epoxypaint Expired - Fee Related CN103880334B (en)

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CN103555103A (en) * 2013-10-16 2014-02-05 苏州瑞邦塑胶有限公司 Novel environment-friendly thermal insulation anti-corrosive coating
CN104559484A (en) * 2015-01-05 2015-04-29 王红玉 Coating for external wall of building
CN106082880A (en) * 2016-06-27 2016-11-09 青岛华联装饰工程有限公司 A kind of environmental protection flame retardant architectural decoration coating material and preparation method thereof

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WO2005063880A1 (en) * 2003-12-30 2005-07-14 Sang Yang Kim Epoxy resin mortar composition and a method of coating the same on concrete surface
CN102807805B (en) * 2011-05-31 2015-09-30 比亚迪股份有限公司 A kind of ultraviolet cured paint composition and preparation method thereof
CN102352161A (en) * 2011-08-25 2012-02-15 杭州传化涂料有限公司 Water-based primer-topcoat in one type paint
CN102702920B (en) * 2012-06-12 2015-07-22 中国科学院长春应用化学研究所 Aqueous polyaniline anti-corrosive paint and preparation method thereof
CN102850878A (en) * 2012-08-31 2013-01-02 芜湖县双宝建材有限公司 Weather-resistant exterior wall paint and preparation method thereof

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Inventor after: Liu Haiyong

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