CN103866569B - Hair stiffening agent and preparation method thereof and using method - Google Patents
Hair stiffening agent and preparation method thereof and using method Download PDFInfo
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- CN103866569B CN103866569B CN201410126170.4A CN201410126170A CN103866569B CN 103866569 B CN103866569 B CN 103866569B CN 201410126170 A CN201410126170 A CN 201410126170A CN 103866569 B CN103866569 B CN 103866569B
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Abstract
The invention belongs to hair products technical field, particularly relate to a kind of hair stiffening agent for hair products and preparation method thereof and using method, it is prepared from by the raw material of following percetage by weight, it is prepared from by the raw material of following percetage by weight, carboxymethyl cellulose 3%-5%, etherificate hexamethylol melamine resin 5%-8%, hexadecyltrimethylammonium chloride 3%-5%, dimethicone 5%-7% after emulsification, 16/18 alcohol 1%-2%, surplus is deionized water, the present invention is using methyl-etherified hexamethylol melamine resin as major ingredient, carboxymethyl cellulose is as dispersant, hexadecyltrimethylammonium chloride is as antistatic additive, dimethicone after emulsification is as softener, 16-18 alcohol is prepared from as superfatting agent, singly do not solve the above-mentioned defect problem of hair products, also there is environmental protection simultaneously, antibacterial effect, cheap, and its preparation technology and using method simple.
Description
Technical field
The invention belongs to hair products technical field, particularly relate to a kind of hair stiffening agent for hair products and preparation method thereof and using method.
Background technology
Mainly there are 3 point defects in current hair products: 1. hair root bone is soft, is difficult to clap together, produces cave-head when dismissing; 2. hair curved edge, crosses three-line machine and causes unnecessary loss; 3. final hair products product hardness shortcoming.
Present stage, sold hair stiffening agent was with dimethicone and higher alcohol for main raw material on the market, and to promote slippery for main purpose, additional properties are that hair slightly has stiffening characteristic.But be limited to feedstock property, the positive correlation of soft slip energy, sliding then soft, sliding then slightly hard.Too soft when existing hair stiffening agent makes hair sliding, should not dismiss, meanwhile, existing hair stiffening agent does not also possess antibacterial effect, and powerful and poor flexibility.
Summary of the invention
The object of the invention is to overcome deficiency of the prior art, and a kind of hair stiffening agent and preparation method thereof and using method are provided, using methyl-etherified hexamethylol melamine resin as major ingredient, carboxymethyl cellulose as dispersant, hexadecyltrimethylammonium chloride as the dimethicone after antistatic additive, emulsification as softener, 16-18 alcohol is prepared from as superfatting agent, singly do not solve the above-mentioned defect problem of hair products, also there is environmental protection, antibacterial effect simultaneously, cheap, and its preparation technology and using method simple.
The technical solution adopted in the present invention: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following percetage by weight, dimethicone 5%-7%, 16-18 alcohol 1%-2% after carboxymethyl cellulose 3%-5%, methyl-etherified hexamethylol melamine resin 5%-8%, hexadecyltrimethylammonium chloride 3%-5%, emulsification, surplus are deionized water.
Described deionized water hardness is not more than 0.03 equivalent parts per million.
Dimethicone after described emulsification be by dimethicone and compound emulsifying agent according to dimethicone: the proportions of compound emulsifying agent=2:1 forms.
Described compound emulsifying agent adopts sorbester p18 and Tween 80 according to sorbester p18: the proportions of Tween 80=3:2 forms.
A preparation method for hair stiffening agent as above, is characterized in that: this preparation method comprises the following steps:
Step 1), carboxymethyl cellulose to be added in 70-80 DEG C of water while stirring, obtain mixed solution;
Step 2), methyl-etherified hexamethylol melamine resin joined in mixed solution that step 1) obtains, and stir 8-12 minute, obtain solution A for subsequent use;
Step 3), hexadecyltrimethylammonium chloride, 16-18 alcohol to be dissolved in the water of 70-80 DEG C, to obtain B solution;
Step 4), in deionized water, slowly add step 2) solution A that obtains, stirs the B solution adding step 3) after 10 minutes and obtain, and stirs 10 minutes, then the dimethicone after emulsification is added, to complete reaction, obtain hair stiffening agent, In Shadely to keep in Dark Place.
A using method for hair stiffening agent as above, is characterized in that: this using method comprises the following steps:
Step 1), be positioned over hair products containing hair stiffening agent the aqueous solution, soak 10 minutes under room temperature;
Step 2), by the hair products clear water soaked in step 1) to soak after hair products carry out cleaning 3-5 time;
Step 3), by step 2) in be soaked in the soft water containing hair stiffening agent with the hair products that clear water is cleaned, soak after 10 minutes at 45 DEG C of temperature, hair products pulled out, and dewaters, dry at 80-90 DEG C after comb is straight.
The concentration containing hair stiffening agent in the aqueous solution of hair stiffening agent in described step 1) is 3kg/L.
The concentration containing hair stiffening agent in the soft water of hair stiffening agent in described step 3) is 50kg/L.
Beneficial effect of the present invention: the present invention using methyl-etherified hexamethylol melamine resin as major ingredient, carboxymethyl cellulose as dispersant, hexadecyltrimethylammonium chloride as the dimethicone after antistatic additive, emulsification as softener, 16-18 alcohol is as superfatting agent, be configured to slurries, hair stiffening agent, hair stiffening agent of the present invention is used on hair products, stiffening agent forms film on hair products, add suitable softener, thus make hair products obtain the feels such as level and smooth, stiffening, abundant, plentiful, and improve its powerful and ABRASION RESISTANCE; In addition, hair stiffening agent of the present invention has environmental protection, antibacterial effect, cheap, and preparation method and using method simple.Under equal conditions, the hair after hair stiffening agent of the present invention process, when using three-line machine process, the hair proportion of goods damageds at least reduce 1.5%; Improve hair products quality qualification rate, solve to dismiss and clap uneven and cave-head's problem, improve up-to-standard rate more than 1.5%.
Detailed description of the invention
Embodiment 1: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A preparation method for hair stiffening agent as above, is characterized in that: this preparation method comprises the following steps:
Step 1), carboxymethyl cellulose to be added in 70-80 DEG C of water while stirring, obtain mixed solution;
Step 2), methyl-etherified hexamethylol melamine resin joined in mixed solution that step 1) obtains, and stir 8-12 minute, obtain solution A for subsequent use;
Step 3), hexadecyltrimethylammonium chloride, 16-18 alcohol to be dissolved in the water of 70-80 DEG C, to obtain B solution;
Step 4), in deionized water, slowly add step 2) solution A that obtains, stirs the B solution adding step 3) after 10 minutes and obtain, and stirs 10 minutes, then the dimethicone after emulsification is added, to complete reaction, obtain hair stiffening agent, In Shadely to keep in Dark Place.
A using method for hair stiffening agent as above, is characterized in that: this using method comprises the following steps:
Step 1), be positioned over hair products containing hair stiffening agent the aqueous solution, soak 10 minutes under room temperature; Requirement is 3kg/L containing the concentration of hair stiffening agent in the aqueous solution of hair stiffening agent;
Step 2), by the hair products clear water soaked in step 1) to soak after hair products carry out cleaning 3-5 time;
Step 3), by step 2) in be soaked in the soft water containing hair stiffening agent with the hair products that clear water is cleaned, soak after 10 minutes at 45 DEG C of temperature, hair products pulled out, and dewaters, dry at 80-90 DEG C after comb is straight; Requirement is 50kg/L containing the concentration of hair stiffening agent in the soft water of hair stiffening agent.
Embodiment 2: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 3: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 4: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 5: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 6: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 7: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 8: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 9: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 10: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 11: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 12: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 13: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 14: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 15: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 16: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 17: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 18: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 19: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 20: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 21: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 22: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 23: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 24: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 25: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 26: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 27: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 28: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 29: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 30: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 31: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 32: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 33: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 1kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 34: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 35: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 5kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 36: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 37: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 2kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 38: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 2kg after carboxymethyl cellulose 5kg, methyl-etherified hexamethylol melamine resin 8kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 39: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 5kg, 16-18 alcohol 2kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 40: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 3kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 41: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 7kg, 16-18 alcohol 1kg after carboxymethyl cellulose 3kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 5kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 42: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1.5kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 43: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1.5kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 44: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 45: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 2kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 6kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 46: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 1kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Embodiment 47: a kind of hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following weight grams, and dimethicone 6kg, 16-18 alcohol 2kg after carboxymethyl cellulose 4kg, methyl-etherified hexamethylol melamine resin 7kg, hexadecyltrimethylammonium chloride 4kg, emulsification, surplus are the deionized water that hardness is not more than 0.03 equivalent parts per million.The solution total amount of participating in reaction is 100kg.
A kind of preparation method of hair stiffening agent as above is identical with the preparation method of the hair stiffening agent described in embodiment 1.
A kind of using method of hair stiffening agent as above is identical with the using method of the hair stiffening agent described in embodiment 1.
Dimethicone after the emulsification adopted in above-mentioned all embodiments adopts compound emulsifying agent to carry out emulsification to dimethicone and obtains, the ratio of dimethicone and compound emulsifying agent is 2:1, wherein adopted compound emulsifying agent be by sorbester p18 and Tween 80 according to sorbester p18: the proportions of Tween 80=3:2 forms; The preparation process of the dimethicone after preparation emulsification is as follows:
Step 1), take sorbester p18 and Tween 80 according to aforementioned proportion, pour in there-necked flask, heat in constant temperature electric heating agitating heating cover and stir, temperature rises to 75-80 DEG C, and stirring 2 hours, obtains compound emulsifying agent altogether;
Step 2), by the compound emulsifying agent obtained in step 1) and dimethicone according to dimethicone: the ratio of compound emulsifying agent=2:1 adds there-necked flask, at the stirred in water bath 2-2.5 hour of 80-85 DEG C, until reactant state is even, not stratified can obtain the dimethicone after emulsification.
Claims (8)
1. a hair stiffening agent, it is characterized in that: it is prepared from by the raw material of following percetage by weight, dimethicone 5%-7%, 16-18 alcohol 1%-2% after carboxymethyl cellulose 3%-5%, methyl-etherified hexamethylol melamine resin 5%-8%, hexadecyltrimethylammonium chloride 3%-5%, emulsification, surplus are deionized water;
Described hair stiffening agent adopts following method to prepare, and this preparation method comprises the following steps:
Step 1), carboxymethyl cellulose to be added in 70-80 DEG C of water while stirring, obtain mixed solution;
Step 2), methyl-etherified hexamethylol melamine resin joined in mixed solution that step 1) obtains, and stir 8-12 minute, obtain solution A for subsequent use;
Step 3), hexadecyltrimethylammonium chloride, 16-18 alcohol to be dissolved in the water of 70-80 DEG C, to obtain B solution;
Step 4), in deionized water, slowly add step 2) solution A that obtains, stirs the B solution adding step 3) after 10 minutes and obtain, and stirs 10 minutes, then the dimethicone after emulsification is added, to complete reaction, obtain hair stiffening agent, In Shadely to keep in Dark Place.
2. hair stiffening agent according to claim 1, is characterized in that: described deionized water hardness is not more than 0.03 equivalent parts per million.
3. hair stiffening agent according to claim 1, is characterized in that: the dimethicone after described emulsification be by dimethicone and compound emulsifying agent according to dimethicone: the proportions of compound emulsifying agent=2:1 forms.
4. hair stiffening agent according to claim 3, is characterized in that: described compound emulsifying agent adopts sorbester p18 and Tween 80 according to sorbester p18: the proportions of Tween 80=3:2 forms.
5., as a preparation method for the hair stiffening agent as described in arbitrary in claim 1 ~ 4, it is characterized in that: this preparation method comprises the following steps:
Step 1), carboxymethyl cellulose to be added in 70-80 DEG C of water while stirring, obtain mixed solution;
Step 2), methyl-etherified hexamethylol melamine resin joined in mixed solution that step 1) obtains, and stir 8-12 minute, obtain solution A for subsequent use;
Step 3), hexadecyltrimethylammonium chloride, 16-18 alcohol to be dissolved in the water of 70-80 DEG C, to obtain B solution;
Step 4), in deionized water, slowly add step 2) solution A that obtains, stirs the B solution adding step 3) after 10 minutes and obtain, and stirs 10 minutes, then the dimethicone after emulsification is added, to complete reaction, obtain hair stiffening agent, In Shadely to keep in Dark Place.
6. the using method of arbitrary described hair stiffening agent in claim 1 ~ 4, is characterized in that: this using method comprises the following steps:
Step 1), be positioned over hair products containing hair stiffening agent the aqueous solution, soak 10 minutes under room temperature;
Step 2), by the hair products clear water soaked in step 1) to soak after hair products carry out cleaning 3-5 time;
Step 3), by step 2) in be soaked in the soft water containing hair stiffening agent with the hair products that clear water is cleaned, soak after 10 minutes at 45 DEG C of temperature, hair products pulled out, and dewaters, dry at 80-90 DEG C after comb is straight.
7. the using method of hair stiffening agent according to claim 6, is characterized in that: the concentration containing hair stiffening agent in the aqueous solution of hair stiffening agent in described step 1) is 3kg/L.
8. the using method of hair stiffening agent according to claim 6, is characterized in that: the concentration containing hair stiffening agent in the soft water of hair stiffening agent in described step 3) is 50kg/L.
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| CN103462844A (en) * | 2013-09-11 | 2013-12-25 | 拉芳家化股份有限公司 | Hair-care composition containing efficient anti-hair-loss compound agent |
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| CN103446021A (en) * | 2013-09-02 | 2013-12-18 | 上海应用技术学院 | Hair conditioner containing silybum marianum extract and preparation method thereof |
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