CN103446021A - Hair conditioner containing silybum marianum extract and preparation method thereof - Google Patents
Hair conditioner containing silybum marianum extract and preparation method thereof Download PDFInfo
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- CN103446021A CN103446021A CN2013103921085A CN201310392108A CN103446021A CN 103446021 A CN103446021 A CN 103446021A CN 2013103921085 A CN2013103921085 A CN 2013103921085A CN 201310392108 A CN201310392108 A CN 201310392108A CN 103446021 A CN103446021 A CN 103446021A
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Abstract
The invention discloses a hair conditioner containing a silybum marianum extract. The hair conditioner comprises the silybum marianum extract, hexadecyl trimethyl ammonium chloride, propylene glycol, cetearyl alcohol, isopropyl palmitate, polyoxyethylene-21 steareth, emulsified silicone oil, ethylene diamine tetraacetic acid, hydroxyethyl cellulose, essence, a preservative and de-ionized water. A preparation method for the hair conditioner comprises the following steps: heating the silybum marianum extract and propylene glycol to obtain an A phase; dissolving ethylene diamine tetraacetic acid and hydroxyethyl cellulose in the de-ionized water to obtain a B phase; mixing hexadecyl trimethyl ammonium chloride, cetearyl alcohol, isopropyl palmitate and polyoxyethylene-21 steareth, heating and dissolving to obtain a C phase; adding the A phase into the B phase and uniformly mixing to obtain a D phase; homogenizing the D phase, adding the C phase into the D phase, emulsifying, stirring for cooling to 60 DEG C, adding the emulsified silicone oil, continuously stirring for cooling to 45 DEG C, adding the essence and the preservative, and uniformly stirring to obtain the hair conditioner containing the silybum marianum extract.
Description
Technical field
The present invention relates to a kind of hair conditioner with antioxidation containing natural plant sunscreen component and fill a prescription and preparation method thereof, particularly a kind of hair conditioner containing Herba Silybi mariani extract and preparation method thereof.
Background technology
Due to Ozone depletion, ultraviolet radiation increases, and to biological damage and to the infringement of human body skin, can cause allergy, skin carcinoma.The same with skin, the ultraviolet in sunlight also can cause the hair injury.Experimentation shows that ultraviolet radiation causes disulfide bond oxidation scission, amino acid degradation, pigment to decompose, lipid oxidation, and make that hair occurs that dry, hot strength descends, superficial makings is coarse, color and loss of gloss, toughness descend, hardening becomes fragile equivalent damage.In cosmetics, commonly used chemical sunscreen is as to oxygen base cinnamate derivative, benzophenone and derivant thereof, para-amino benzoic acid and esters thereof, the o-aminobenzoa class, salicylic acid esters etc., all skin is had to certain zest, consider quality and safety problem, the product that contains plant formula becomes new trend.Herba Silybi mariani is feverfew, and the flavanolignan's compounds extracted from the Herba Silybi mariani plant seed, in to the experiment of Cavia porcellus ultra-vioket radiation, has been brought into play good protective effect; And, as natural antioxidant, aspect hair proteins, lipid, aminoacid and color protection, all there is good effect.It can absorb the effect that ultraviolet has again certain removing free radical, is suitable for preparing the hair conditioner of anti-photooxidation safely and efficiently.
Summary of the invention
One of purpose of the present invention is for a kind of hair conditioner containing Herba Silybi mariani extract is provided.
Two of purpose of the present invention is for above-mentioned a kind of preparation method that contains the hair conditioner of Herba Silybi mariani extract is provided.
Technical scheme of the present invention
A kind of hair conditioner containing Herba Silybi mariani extract, count by weight percentage, and its raw material composition and content are as follows:
Herba Silybi mariani extract 0.5-5%
Hexadecyltrimethylammonium chloride 1.0-3.0%
Propylene glycol 1.0-5.0%
Cetostearyl alcohol 3.0%
Isopropyl palmitate 8.0%
Polyoxyethylene-21 stearyl alcohol polyethers 1.0-3.0%
Emulsified silicone oil 1.0-3.0%
Disodiumedetate 0.05%
Hydroxyethyl-cellulose 0.2-0.5%
Essence 0.1-1.0%
Antiseptic 0.1-0.3%
Surplus is deionized water;
Wherein said essence is compound flower essence, jasmin essence, rose essence, apple essence, Fructus Citri Limoniae essence or aloe flavour, only with compound flower essence, jasmin essence and Fructus Citri Limoniae essence, give an example in a preferred embodiment of the invention, but do not limit the application in the present invention of other daily chemical essences.
Described antiseptic is the mixture that 1.3-dihydroxymethyl-5.5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl form.
The preparation method of the above-mentioned hair conditioner containing Herba Silybi mariani extract, specifically comprise the steps:
(1), by after Herba Silybi mariani extract, mixed with propylene glycol, be heated to 80 ℃, as the A phase;
(2), disodiumedetate, hydroxyethyl-cellulose are joined in deionized water, be heated to 85 ℃ and be uniformly dissolved, as the B phase;
(3), hexadecyltrimethylammonium chloride, cetostearyl alcohol, isopropyl palmitate and polyoxyethylene-21 stearyl alcohol polyethers are mixed after, be heated to 85 ℃ of dissolvings, as the C phase;
(4), by A be added to B mutually in, mix homogeneously, as the D phase, treat that temperature is raised to 85 ℃ again, homogenizing D phase, be added to D by C and carry out emulsifying in mutually, stir and be cooled to 60 ℃ after emulsifying, add emulsified silicone oil, continue to stir, continue to be cooled to 45 ℃, add essence, antiseptic, stir, discharging during room temperature, obtain the hair conditioner containing Herba Silybi mariani extract.
Beneficial effect of the present invention
Hair conditioner containing Herba Silybi mariani extract of the present invention, because the Herba Silybi mariani extract contained is a kind of natural flavone Lignanoids compounds, have certain absorption ultraviolet and antioxidation.Therefore, the hair conditioner containing Herba Silybi mariani extract of the present invention is to daily solar irradiation, and the hair infringement that especially ultraviolet causes has certain protective action.
Further; show by experiment; hair conditioner containing Herba Silybi mariani extract of the present invention all has protection in various degree to protein, lipid, aminoacid and the natural pigment factor in the light-struck hair of simulating sun; be a kind of hair conditioner containing Herba Silybi mariani extract of the present invention; the nutritional labelings such as protein, lipid and tryptophan that have in the protection hair are avoided the effect damaged, and have the protection hair color firmly and the effect of tension simultaneously.
The accompanying drawing explanation
Hair after Fig. 1, blank hair conditioner are processed respectively with the hair conditioner containing Herba Silybi mariani extract is through the contrast of 36h solar simulated pre-irradiation back hydrolyzing protein content;
The contrast of the hair hair lipid peroxidation degree after 36h solar simulated pre-irradiation after Fig. 2, blank hair conditioner are processed respectively with the hair conditioner containing Herba Silybi mariani extract;
Hair after Fig. 3, blank hair conditioner are processed respectively with the hair conditioner containing Herba Silybi mariani extract is through the contrast of 36h solar simulated pre-irradiation back color development histidine content;
Hair after Fig. 4, blank hair conditioner are processed respectively with the hair conditioner containing Herba Silybi mariani extract is through the contrast of 36h solar simulated pre-irradiation back color development difference;
The hair contrast that hair is broken merit after 36h solar simulated pre-irradiation after Fig. 5, blank hair conditioner are processed respectively with the hair conditioner containing Herba Silybi mariani extract.
The specific embodiment
Also by reference to the accompanying drawings the present invention is further set forth below by specific embodiment, but do not limit the present invention.
In various embodiments of the present invention, the information of the specification of various raw materials used and manufacturer is as follows:
Hexadecyltrimethylammonium chloride, mass fraction is 99%, Kening Co.,Ltd;
Cetostearyl alcohol, mass fraction is 99%, Kening Co.,Ltd;
Isopropyl palmitate, cosmetics-stage, Kening Co.,Ltd;
Polyoxyethylene-21 stearyl alcohol polyethers, mass fraction >=99.9%, Kening Co.,Ltd;
Emulsified silicone oil, cosmetics-stage, Dow Corning Corporation;
1,2-PD, cosmetics-stage, Chemical Reagent Co., Ltd., Sinopharm Group;
Herba Silybi mariani extract, mass fraction 85%, Baoji Hao Xiang Bioisystech Co., Ltd;
Sodium lauryl sulphate (SDS), technical grade, Kening Co.,Ltd;
Antiseptic 1,3-dihydroxymethyl-5, the mixture of 5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl, cosmetics-stage, Lonza company;
Hydroxyethyl-cellulose, mass fraction is 99%, sigma company.
embodiment 1
A kind of hair conditioner containing Herba Silybi mariani extract, count by weight percentage, and its raw material composition and content are as follows::
Herba Silybi mariani extract 0.5%
Hexadecyltrimethylammonium chloride 1.0%
Propylene glycol 1.0%
Cetostearyl alcohol 3.0%
Isopropyl palmitate 8.0%
Polyoxyethylene-21 stearyl alcohol polyethers 1.0%
Emulsified silicone oil 1.0%
Disodiumedetate 0.05%
Hydroxyethyl-cellulose 0.2%
Essence 0.1%
Antiseptic 0.1%
Surplus is deionized water;
Wherein said essence is the compound flower essence;
Described antiseptic is the mixture that 1.3-dihydroxymethyl-5.5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl form.
The preparation method of the above-mentioned hair conditioner containing Herba Silybi mariani extract, is characterized in that specifically comprising the steps:
(1), by after Herba Silybi mariani extract, mixed with propylene glycol, be heated to 80 ℃, as the A phase;
(2), disodiumedetate, hydroxyethyl-cellulose are joined in deionized water, be heated to 85 ℃ and be uniformly dissolved, as the B phase;
(3), hexadecyltrimethylammonium chloride, cetostearyl alcohol, isopropyl palmitate, polyoxyethylene-21 stearyl alcohol polyethers are mixed after, be heated to 85 ℃ of dissolvings, as the C phase;
(4) A is added to B mutually in, mix homogeneously, as the D phase, treat that temperature is raised to 85 ℃ again, homogenizing D phase, be added to D by C and carry out emulsifying in mutually, stir and be cooled to 60 ℃ after emulsifying, add emulsified silicone oil, continue to stir, continue to be cooled to 45 ℃, add essence, antiseptic, stir, discharging during room temperature, obtain the hair conditioner containing Herba Silybi mariani extract.
comparative examples 1
Be that Herba Silybi mariani extract in embodiment 1 substitutes with deionized water, the other the same as in Example 1, obtain not the hair conditioner containing Herba Silybi mariani extract.
Not not detecting containing the sun-proof and anti-photooxidation effect of the hair conditioner of Herba Silybi mariani extract containing the hair conditioner of Herba Silybi mariani extract and comparative examples 1 gained to above-described embodiment 1 gained
(1), experimental technique:
With in Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106, the be hydrolyzed content measuring of protein, lipid peroxidation degree, tryptophan and aberration, hair fiber of " Photo-damage determination of human hair " civilian described similarity method broken the merit test.
(2), experimentation
Using Chinese's topknot as sample, the lauryl sodium sulfate aqueous solution that is 3% by mass percent washing hair, then the hair conditioner that does not contain Herba Silybi mariani extract of the hair conditioner containing Herba Silybi mariani extract of embodiment 1 gained and comparative examples 1 gained is applied on topknot, washes away after 10min.After drying, under the xenon lamp tester, irradiate 36h under room temperature, detected by 1 described method.Every kind of hair conditioner is done three groups of parallel laboratory tests.
(3), experimental result
Adopt Ultrasound Instrument (JL-120, the section island, 49kHz) and dual-beam ultraviolet spectrophotometer (UV2300, Shanghai Techcomp Instrument Ltd.), by supersound extraction method of protein (list of references: Photo-damage determination of human hair, Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106.) to above-mentioned comparative examples 1 gained not containing the hair conditioner of Herba Silybi mariani extract be blank hair conditioner and embodiment 1 gained contain hair that Herba Silybi mariani extract hair conditioner processes respectively through 36h xenon lamp (300-800 nm, 550W/m
2cI4000, Atlas, America) aminosal content after pre-irradiation measured, its result as shown in Figure 1, the protein be dissolved in water is more, illustrates that the loss of hair proteins is more, as can be seen from Figure 1, through the 36h solar simulated, irradiate, use is compared with blank hair conditioner containing the hair conditioner of Herba Silybi mariani extract, and the hair proteins loss reduces 20.9%, thereby shows that the hair conditioner containing Herba Silybi mariani extract of the present invention has the effect that the protein of protecting in hair is avoided damage.
Adopt Ultrasound Instrument (JL-120, the section island, 49kHz) and dual-beam ultraviolet spectrophotometer (UV2300, Shanghai Techcomp Instrument Ltd.), test lipid peroxide method (list of references: Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106 by TBA, " Photo-damage determination of human hair. C. Alonso, C. Barba, L. Rubio, S. Scott, A. Kilimnik, L. Coderch, J. Notario, J.L.Parra, An Ex Vivo Metholdology to Asses the Lipid Peroxidation in Stratum Corneum, J. the lipid peroxidation degree of hair after 36h xenon lamp pre-irradiation of Photochem. Photobiol. B:Biol. 97 (2009) 71 – 76.) hair conditioner that contains Herba Silybi mariani extract that is not blank hair conditioner and embodiment 1 gained containing the hair conditioner of Herba Silybi mariani extract of above-mentioned comparative examples 1 gained being processed respectively, be that mda content in Fig. 2 is measured, result as shown in Figure 2, the lipid peroxidation degree can illustrate the hair damage degree that daylight causes, as can be seen from Figure 2, through the 36h solar simulated, irradiate, use containing the hair conditioner of Herba Silybi mariani extract and compare with blank hair conditioner, the lipid peroxidation degree reduces 43.6%, thereby show that the hair conditioner containing Herba Silybi mariani extract of the present invention has the effect that the lipid of protecting in hair is avoided damage.
Adopt spectrofluorophotometer (Hitachi, F 4500) by basic hydrolysis tryptophan and fluorimetry (list of references, A.C.S. Nogueira, M. Richena, L.E. Dicelio, I. Joekes, Photo yellowing of human hair, J.Photochem. Photobiol. B:Biol. 88 (2007) 119 – 125. Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106, " Photo-damage determination of human hair.) tryptophane of hair after 36h xenon lamp pre-irradiation that the hair conditioner that contains Herba Silybi mariani extract that is not blank hair conditioner and embodiment 1 gained containing the hair conditioner of Herba Silybi mariani extract of above-mentioned comparative examples 1 gained is processed respectively measured, result as shown in Figure 3, the phenomenons such as the minimizing that research shows the hair tryptophan and hair xanthochromia are relevant, as can be seen from Figure 3, through the 36h solar simulated, irradiate, use containing the hair conditioner of Herba Silybi mariani extract and compare with blank hair conditioner, the tryptophan degree of degradation reduces 17.8%, thereby show that the hair conditioner containing Herba Silybi mariani extract of the present invention has the effect that the tryptophan of protecting in hair is avoided damage.
Adopt colour difference meter (Konica Minolta, CR-10, Japan) according to literature method (list of references: A. Ford, A. Roberts, Colour Space Conversions (1998). Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106, " Photo-damage determination of human hair.) aberration of hair after 36h xenon lamp pre-irradiation that the hair conditioner that contains Herba Silybi mariani extract that is not blank hair conditioner and embodiment 1 gained containing the hair conditioner of Herba Silybi mariani extract of above-mentioned comparative examples 1 gained is processed respectively measured, result as shown in Figure 4, aberration represents the entire change of hair color, as can be seen from Figure 4, through the 36h solar simulated, irradiate, use containing the hair conditioner of Herba Silybi mariani extract and compare with blank hair conditioner, change color reduces 27.3%, thereby show that the hair conditioner containing Herba Silybi mariani extract of the present invention has the firm effect of protection hair color.
Adopt hair fiber tester (Dia-stron, MTT 175, England) by pulling force-strain curve method of testing (list of references: Photo-damage determination of human hair, Journal of Photochemistry and Photobiology B:Biology 106 (2012) 101 – 106.) hair of hair after 36h xenon lamp pre-irradiation of the hair conditioner that contains Herba Silybi mariani extract that is not blank hair conditioner and embodiment 1 gained containing the hair conditioner of Herba Silybi mariani extract of above-mentioned comparative examples 1 gained being processed respectively broken merit and measured, result as shown in Figure 5, break intensity and degree of impairment that function enough reflects hair, as can be seen from Figure 5, through the 36h solar simulated, irradiate, use containing the hair conditioner of Herba Silybi mariani extract and compare with blank hair conditioner, break merit and increase by 18.3%, thereby show that the hair conditioner containing Herba Silybi mariani extract of the present invention has protection hair tension effect.
In sum, a kind of hair conditioner containing Herba Silybi mariani extract of the present invention, the nutritional labelings such as protein, lipid and tryptophan that have in the protection hair are avoided the effect damaged, and have the protection hair color firmly and the effect of tension simultaneously.
embodiment 2
A kind of hair conditioner containing Herba Silybi mariani extract, count by weight percentage, and its raw material composition and content are as follows:
Herba Silybi mariani extract 5.0%
Hexadecyltrimethylammonium chloride 3.0%
Propylene glycol 5.0%
Cetostearyl alcohol 3.0%
Isopropyl palmitate 8.0%
Polyoxyethylene-21 stearyl alcohol polyethers 3.0%
Emulsified silicone oil 3.0%
Disodiumedetate 0.05%
Hydroxyethyl-cellulose 0.5%
Essence 1.0%
Antiseptic 0.3%
Surplus is deionized water;
Described essence is jasmin essence;
Described antiseptic is the mixture that 1.3-dihydroxymethyl-5.5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl form.
The preparation method of the above-mentioned hair conditioner containing Herba Silybi mariani extract, is characterized in that specifically comprising the steps:
(1), by after Herba Silybi mariani extract, mixed with propylene glycol, be heated to 80 ℃, as the A phase;
(2), disodiumedetate, hydroxyethyl-cellulose are joined in deionized water, be heated to 85 ℃ and be uniformly dissolved, as the B phase;
(3), hexadecyltrimethylammonium chloride, cetostearyl alcohol, isopropyl palmitate, polyoxyethylene-21 stearyl alcohol polyethers are mixed after, be heated to 85 ℃ of dissolvings, as the C phase;
(4), by A be added to B mutually in, mix homogeneously, as the D phase, treat that temperature is raised to 85 ℃ again, homogenizing D phase, after then C being added to D and carrying out emulsifying in mutually, stirring is cooled to 60 ℃, add emulsified silicone oil, continue to stir, continue to be cooled to 45 ℃, add essence, antiseptic, stir, discharging during room temperature, obtain the hair conditioner containing Herba Silybi mariani extract.
embodiment 3
A kind of hair conditioner containing Herba Silybi mariani extract, count by weight percentage, and its raw material composition and content are as follows:
Herba Silybi mariani extract 2.0%
Hexadecyltrimethylammonium chloride 2.0%
Propylene glycol 3.0%
Cetostearyl alcohol 3.0%
Isopropyl palmitate 8.0%
Polyoxyethylene-21 stearyl alcohol polyethers 2.0%
Emulsified silicone oil 2.0%
Disodiumedetate 0.05%
Hydroxyethyl-cellulose 0.3%
Essence 0.5%
Antiseptic 0.2%
Surplus is deionized water;
Described essence is Fructus Citri Limoniae essence;
Described antiseptic is the mixture that 1.3-dihydroxymethyl-5.5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl form.
The preparation method of the above-mentioned hair conditioner containing Herba Silybi mariani extract, is characterized in that specifically comprising the steps:
(1), by after Herba Silybi mariani extract, mixed with propylene glycol, be heated to 80 ℃, as the A phase;
(2), disodiumedetate, hydroxyethyl-cellulose are joined in deionized water, be heated to 85 ℃ and be uniformly dissolved, as the B phase;
(3), hexadecyltrimethylammonium chloride, cetostearyl alcohol, isopropyl palmitate, polyoxyethylene-21 stearyl alcohol polyethers are mixed after, be heated to 85 ℃ of dissolvings, as the C phase;
(4), by A be added to B mutually in, mix homogeneously, as the D phase, treat that temperature is raised to 85 ℃ again, homogenizing D phase, after then C being added to D and carrying out emulsifying in mutually, stir and be cooled to 60 ℃ after emulsifying, add emulsified silicone oil, continue to stir, continue to be cooled to 45 ℃, add essence, antiseptic, stir, discharging during room temperature, obtain the hair conditioner containing Herba Silybi mariani extract.
The above is only giving an example of embodiments of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the technology of the present invention principle; can also make some improvement and modification, these improve and modification all should be considered as protection scope of the present invention.
Claims (2)
1. the hair conditioner containing Herba Silybi mariani extract, is characterized in that counting by weight percentage, and its raw material composition and content are as follows:
Herba Silybi mariani extract 0.5-5%
Hexadecyltrimethylammonium chloride 1.0-3.0%
Propylene glycol 1.0-5.0%
Cetostearyl alcohol 3.0%
Isopropyl palmitate 8.0%
Polyoxyethylene-21 stearyl alcohol polyethers 1.0-3.0%
Emulsified silicone oil 1.0-3.0%
Disodiumedetate 0.05%
Hydroxyethyl-cellulose 0.2-0.5%
Essence 0.1-1.0%
Antiseptic 0.1-0.3%
Surplus is deionized water;
Wherein said essence is compound flower essence, jasmin essence, rose essence, apple essence, Fructus Citri Limoniae essence or aloe flavour;
Described antiseptic is the mixture that 1.3-dihydroxymethyl-5.5-dimethyl hydantoin and butyl carbamic acid-3-iodo-2-propynyl form.
2. the preparation method of a kind of hair conditioner containing Herba Silybi mariani extract as claimed in claim 1, is characterized in that specifically comprising the steps:
(1), by after Herba Silybi mariani extract, mixed with propylene glycol, be heated to 80 ℃, as the A phase;
(2), disodiumedetate, hydroxyethyl-cellulose are joined in deionized water, be heated to 85 ℃ and be uniformly dissolved, as the B phase;
(3), hexadecyltrimethylammonium chloride, cetostearyl alcohol, isopropyl palmitate and polyoxyethylene-21 stearyl alcohol polyethers are mixed after, be heated to 85 ℃ of dissolvings, as the C phase;
(4), by A be added to B mutually in, mix homogeneously, as the D phase, treat that temperature is raised to 85 ℃ again, homogenizing D phase, be added to D by C and carry out emulsifying in mutually, stir and be cooled to 60 ℃ after emulsifying, add emulsified silicone oil, continue to stir, continue to be cooled to 45 ℃, add essence, antiseptic, stir, discharging during room temperature, obtain the hair conditioner containing Herba Silybi mariani extract.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103866569A (en) * | 2014-04-01 | 2014-06-18 | 许昌恒源发制品股份有限公司 | Hair stiffening agent as well as preparation method and application method thereof |
CN104288032A (en) * | 2014-09-29 | 2015-01-21 | 澳宝化妆品(惠州)有限公司 | Method for extracting mignonettetree pigment and application of the extract |
CN105943476A (en) * | 2016-07-11 | 2016-09-21 | 江苏欧亚立日化有限公司 | Vanilla planifolia essence hair conditioner |
CN105997560A (en) * | 2016-05-27 | 2016-10-12 | 江西联锴新材料有限公司 | Camellia seed protein hair conditioner and preparation method |
CN114177106A (en) * | 2021-12-22 | 2022-03-15 | 海南三元星生物科技股份有限公司 | Extraction method of marine organism protein peptide, hair care product and application of hair care product |
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CN1686074A (en) * | 2005-03-29 | 2005-10-26 | 上海应用技术学院 | Hair care cream containing natural plant sunscreen component and its preparation method |
CN101141946A (en) * | 2005-02-11 | 2008-03-12 | 格林法马公司 | Use of silymarine and/or the constituents thereof as promoters of the pigmentation of the skin or hair |
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CN101141946A (en) * | 2005-02-11 | 2008-03-12 | 格林法马公司 | Use of silymarine and/or the constituents thereof as promoters of the pigmentation of the skin or hair |
CN1686074A (en) * | 2005-03-29 | 2005-10-26 | 上海应用技术学院 | Hair care cream containing natural plant sunscreen component and its preparation method |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103866569A (en) * | 2014-04-01 | 2014-06-18 | 许昌恒源发制品股份有限公司 | Hair stiffening agent as well as preparation method and application method thereof |
CN103866569B (en) * | 2014-04-01 | 2016-03-02 | 许昌恒源发制品股份有限公司 | Hair stiffening agent and preparation method thereof and using method |
CN104288032A (en) * | 2014-09-29 | 2015-01-21 | 澳宝化妆品(惠州)有限公司 | Method for extracting mignonettetree pigment and application of the extract |
CN105997560A (en) * | 2016-05-27 | 2016-10-12 | 江西联锴新材料有限公司 | Camellia seed protein hair conditioner and preparation method |
CN105943476A (en) * | 2016-07-11 | 2016-09-21 | 江苏欧亚立日化有限公司 | Vanilla planifolia essence hair conditioner |
CN105943476B (en) * | 2016-07-11 | 2018-08-10 | 江苏欧亚立日化有限公司 | A kind of pod orchid essence hair conditioner |
CN114177106A (en) * | 2021-12-22 | 2022-03-15 | 海南三元星生物科技股份有限公司 | Extraction method of marine organism protein peptide, hair care product and application of hair care product |
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