CN103844330A - 食品环保防腐剂 - Google Patents

食品环保防腐剂 Download PDF

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CN103844330A
CN103844330A CN201410117351.0A CN201410117351A CN103844330A CN 103844330 A CN103844330 A CN 103844330A CN 201410117351 A CN201410117351 A CN 201410117351A CN 103844330 A CN103844330 A CN 103844330A
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environment
foods
xanthyletin
rosmarinic acid
preservative
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CN103844330B (zh
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黄毅
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Shanghai Topyum Bio Technology Co ltd
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Shanghai Taohong Chemical Technology Co Ltd
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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3481—Organic compounds containing oxygen
    • A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
    • A23L3/3517—Carboxylic acid esters
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3544—Organic compounds containing hetero rings
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nutrition Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

本发明公开了一种食品环保防腐剂，由30-70wt%迷迭香酸和30-70wt%美洲花椒素组成。本发明的食品环保防腐剂是将天然安全原料迷迭香酸和美洲花椒素混合而成，协同增效，无毒无副作用，稳定性好，可在避光处长期保存。不受温度、pH影响，可显著延长产品保质期，提高食品安全性。

Description

食品环保防腐剂
技术领域
本发明涉及一种食品防腐剂，尤其涉及一种食品环保防腐剂。
背景技术
食品防腐剂是能防止由微生物引起的腐败变质、延长食品保藏期的食品添加剂。因兼有防止微生物繁殖引起食物中毒的作用，又称抗微生物剂（antimicrobial）。
食品防腐剂是即对以腐败物质为代谢底物的微生物的生长具有持续的抑制作用。重要的是它能在不同情况下抑制最易发生的腐败作用，特别是在一般灭菌作用不充分时仍具有持续性的效果。对纤维和木材的防腐用矿油、煤焦油、丹宁，对生物标本用甲醛、升汞、甲苯、对羟基苯甲酸丁酯、硝基糠腙衍生物或香脂类树脂。在食品中使用防腐剂受到限制，因此多靠干燥、腌制等一些物理的方法。特殊的防腐剂有乙酸等有机酸、以油酸脂为成分的植物油、芥子等特殊的精油成分。对于生物体的局部（如人体表面或消化道），可以根据具体条件采用各种防腐剂（如碘仿、水杨酸苯酯、苯胺染料或吖啶类色素等）。
食品防腐剂的作用机理：
①能使微生物的蛋白质凝固或变性，从而干扰其生长和繁殖。
②防腐剂对微生物细胞壁、细胞膜产生作用。由于能破坏或损伤细胞壁，或能干扰细胞壁合成的机理，致使胞内物质外泄，或影响与膜有关的呼吸链电子传递系统，从而具有抗微生物的作用。
③作用于遗传物质或遗传微粒结构，进而影响到遗传物质的复制、转录、蛋白质的翻译等。
④作用于微生物体内的酶系，抑制酶的活性，干扰其正常代谢。
现有的食品防腐剂，大多为化学合成，毒性较强。
发明内容
针对现有技术中存在的上述不足，本发明所要解决的技术问题是提供一种食品环保防腐剂，提取自天然植物，绿色环保无毒害。
本发明所要解决的技术问题，是通过如下技术方案实现的：
一种食品环保防腐剂，由迷迭香酸和美洲花椒素组成。
优选地，所述的食品环保防腐剂，由30-70wt%迷迭香酸和30-70wt%美洲花椒素组成。
迷迭香酸（Rosmarinicacid，简称RosA），化学名称：[R(E)]α-[[3-(3，4-二羟基苯基)-1-氧代-2-丙烯基]氧基]-3，4-二羟基苯丙酸，CAS登录号：20283-92-5，是一种天然多功能酚酸类化合物。迷迭香酸具有抑菌、抗炎、抗病毒、抗肿瘤、抗过敏、抗氧化、抗血栓抗血小板聚集、防辐射和免疫抑制作用。
美洲花椒素，2H,8H-Benzo[1,2-b:5,4-b']dipyran-2-one,8,8-dimethyl-，CAS登录号：553-19-5。存在于花椒树皮中。呋喃香豆素类化合物。植物来源有芸香科植物美洲花椒[Zan-thoxylum(Xanthoxylum)americaumMill.]，樗叶花椒(Z.ailanthoidesSieb.etZucc.)的根皮，芸香(RutagraveolensL.)根等。
本发明的食品环保防腐剂是将天然安全原料迷迭香酸和美洲花椒素混合而成，协同增效，无毒无副作用，稳定性好，可在避光处长期保存。不受温度、pH影响，可显著延长产品保质期，提高食品安全性。
具体实施方式
实施例1-3
按表1对应实施例1-3数据称取各原料，搅拌混合均匀，即可制得该食品环保防腐剂。
表1：食品环保防腐剂配方表  单位：克
原料 实施例1 实施例2 实施例3
迷迭香酸 30 70 50
美洲花椒素 70 30 50
测试例1
试验材料：将防腐剂加入泡萝卜中，制得成品食品；其中，防腐剂的加入量均为0.1wt%。
将成品食品经真空包装置于30℃，相对湿度85%环境下。具体测试结果，见表2。
表2：防腐效果表
防腐剂 现象
实施例3（50wt%迷迭香酸+50%美洲花椒素） 55天后，未出现斑菌，正常
对比例1（100wt%迷迭香酸） 40天后，开始出现斑菌
对比例2（100wt%美洲花椒素） 50天后，开始出现斑菌
测试例2
将防腐剂按质量浓度0.1％添加到酱油中，室温(25℃)、自然通风条件下敞开存放，每3天取样测试一次，在显微镜下测量菌落总数。结果如表3所示：
表3：防腐剂对酱油中菌落总数影响表(×104cfu/ml)
防腐剂 3天 6天 9天
实施例3（50wt%迷迭香酸+50%美洲花椒素） 3.6 7.1 9.7
对比例1（100wt%迷迭香酸） 5.2 8.1 11.9
对比例2（100wt%美洲花椒素） 4.9 7.6 10.4
空白例（不加防腐剂） 8.3 30.4 多不可计

Claims (2)

1.一种食品环保防腐剂，其特征在于，由迷迭香酸和美洲花椒素组成。
2.如权利要求1所述的食品环保防腐剂，其特征在于，由30-70wt%迷迭香酸和30-70wt%美洲花椒素组成。
CN201410117351.0A 2014-03-27 2014-03-27 食品环保防腐剂 Active CN103844330B (zh)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106722726A (zh) * 2017-01-18 2017-05-31 李光 素食调味料
CN106722748A (zh) * 2017-01-18 2017-05-31 李光 香辣粉调味料
CN106722727A (zh) * 2017-01-18 2017-05-31 李光 浓郁香调味料
CN107996944A (zh) * 2017-12-12 2018-05-08 佛山早稻田环保节能科技有限公司 一种食品防腐剂
CN109793039A (zh) * 2019-03-26 2019-05-24 成都健心食品有限公司 一种天然环保防腐剂、制备方法及肉质环保保鲜膜

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102224937A (zh) * 2011-04-17 2011-10-26 遵义市辣得笑风味食品有限公司 一种天然植物源调味防腐剂

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102224937A (zh) * 2011-04-17 2011-10-26 遵义市辣得笑风味食品有限公司 一种天然植物源调味防腐剂

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孙文基: "《天然活性成分简明手册》", 31 July 1998, article "花椒内酯", pages: 603 *
杨寿清: "新型食品防腐剂及其在调味品中的应用", 《第十届中国国际食品添加剂和配料展览会学术论文集》, 1 March 2006 (2006-03-01) *
苏平: "迷迭香酸的生理活性功能及其来源研究进展", 《食品与发酵工业》, vol. 34, no. 12, 31 December 2008 (2008-12-31) *
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106722726A (zh) * 2017-01-18 2017-05-31 李光 素食调味料
CN106722748A (zh) * 2017-01-18 2017-05-31 李光 香辣粉调味料
CN106722727A (zh) * 2017-01-18 2017-05-31 李光 浓郁香调味料
CN107996944A (zh) * 2017-12-12 2018-05-08 佛山早稻田环保节能科技有限公司 一种食品防腐剂
CN109793039A (zh) * 2019-03-26 2019-05-24 成都健心食品有限公司 一种天然环保防腐剂、制备方法及肉质环保保鲜膜

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