CN103817347B - 光致发光的核-壳纳米铜簇的制备方法 - Google Patents
光致发光的核-壳纳米铜簇的制备方法 Download PDFInfo
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- CN103817347B CN103817347B CN201410098421.2A CN201410098421A CN103817347B CN 103817347 B CN103817347 B CN 103817347B CN 201410098421 A CN201410098421 A CN 201410098421A CN 103817347 B CN103817347 B CN 103817347B
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- copper
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- hydrazine hydrate
- tga
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000010949 copper Substances 0.000 title claims abstract description 52
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 51
- 238000004020 luminiscence type Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011258 core-shell material Substances 0.000 title abstract description 8
- 229920001577 copolymer Polymers 0.000 title abstract description 6
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 36
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 20
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229960001124 trientine Drugs 0.000 claims abstract description 11
- 239000011259 mixed solution Substances 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 239000012670 alkaline solution Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 10
- PLMFYJJFUUUCRZ-UHFFFAOYSA-M decyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCC[N+](C)(C)C PLMFYJJFUUUCRZ-UHFFFAOYSA-M 0.000 claims description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 6
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 claims description 6
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 claims description 5
- 238000006722 reduction reaction Methods 0.000 claims description 4
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000003446 ligand Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 4
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract description 2
- 238000001338 self-assembly Methods 0.000 abstract description 2
- 150000004699 copper complex Chemical group 0.000 abstract 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- -1 e.g. Chemical group 0.000 description 2
- 238000002330 electrospray ionisation mass spectrometry Methods 0.000 description 2
- 238000000295 emission spectrum Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000835 electrochemical detection Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160175773A1 (en) * | 2013-07-25 | 2016-06-23 | Toyota Jidosha Kabushiki Kaisha | Nitric oxide reducing catalyst, method for reducing nitric oxide, method for producing nitrogen, method for treating nitric oxide and carbon monoxide |
Families Citing this family (4)
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CN104972135B (zh) * | 2015-05-28 | 2017-03-01 | 天津师范大学 | 近红外荧光探针铜纳米簇的合成方法及其应用 |
CN108127124B (zh) * | 2016-12-01 | 2020-01-14 | 中国科学院大连化学物理研究所 | 一种荧光颜色可调控的铜纳米簇的制备方法 |
CN107175340B (zh) * | 2017-06-09 | 2019-01-29 | 齐鲁工业大学 | 一种核壳结构Cu@Ag纳米粒子的制备方法 |
CN111157505B (zh) * | 2020-01-17 | 2022-10-21 | 天津师范大学 | 一种检测溶液中含硫污染物巯基乙酸的方法 |
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JP3859882B2 (ja) * | 1998-09-14 | 2006-12-20 | 株式会社リコー | 新規なオリゴフェロセニレン誘導体及び電気化学的に活性なクラスター薄膜の製造方法 |
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CN101406961A (zh) * | 2008-11-25 | 2009-04-15 | 哈尔滨工业大学 | 水溶性金纳米团簇的制备方法 |
CN101875132A (zh) * | 2010-05-31 | 2010-11-03 | 武汉大学 | 一种仿生制备水溶性金纳米团簇的方法 |
CN102127428A (zh) * | 2010-12-14 | 2011-07-20 | 中国科学院苏州纳米技术与纳米仿生研究所 | 荧光银团簇、其制备方法及应用 |
CN102554217A (zh) * | 2012-02-24 | 2012-07-11 | 河南大学 | 一种水溶性纳米铜及其制备方法 |
CN103289684A (zh) * | 2012-02-28 | 2013-09-11 | 中国科学院理化技术研究所 | 一种荧光银纳米团簇及其制备方法和应用 |
CN103357886A (zh) * | 2013-06-28 | 2013-10-23 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种用于荧光传感器的贵金属纳米团簇的制备方法 |
Family Cites Families (1)
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WO2012082612A2 (en) * | 2010-12-13 | 2012-06-21 | THE GOV. OF THE U.S OF AMERICA, As Represented by THE SECRETARY OF THE NAVY | Metal nanoparticles with a pre-selected number of atoms |
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Patent Citations (8)
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JP3859882B2 (ja) * | 1998-09-14 | 2006-12-20 | 株式会社リコー | 新規なオリゴフェロセニレン誘導体及び電気化学的に活性なクラスター薄膜の製造方法 |
CN101003088A (zh) * | 2006-12-08 | 2007-07-25 | 中国工程物理研究院激光聚变研究中心 | 一种有机物单层保护金团簇泡沫材料及其制备方法 |
CN101406961A (zh) * | 2008-11-25 | 2009-04-15 | 哈尔滨工业大学 | 水溶性金纳米团簇的制备方法 |
CN101875132A (zh) * | 2010-05-31 | 2010-11-03 | 武汉大学 | 一种仿生制备水溶性金纳米团簇的方法 |
CN102127428A (zh) * | 2010-12-14 | 2011-07-20 | 中国科学院苏州纳米技术与纳米仿生研究所 | 荧光银团簇、其制备方法及应用 |
CN102554217A (zh) * | 2012-02-24 | 2012-07-11 | 河南大学 | 一种水溶性纳米铜及其制备方法 |
CN103289684A (zh) * | 2012-02-28 | 2013-09-11 | 中国科学院理化技术研究所 | 一种荧光银纳米团簇及其制备方法和应用 |
CN103357886A (zh) * | 2013-06-28 | 2013-10-23 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种用于荧光传感器的贵金属纳米团簇的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US20160175773A1 (en) * | 2013-07-25 | 2016-06-23 | Toyota Jidosha Kabushiki Kaisha | Nitric oxide reducing catalyst, method for reducing nitric oxide, method for producing nitrogen, method for treating nitric oxide and carbon monoxide |
US9707514B2 (en) * | 2013-07-25 | 2017-07-18 | Toyota Jidoahs Kabushiki Kaisha | Nitric oxide reducing catalyst, method for reducing nitric oxide, method for producing nitrogen, method for treating nitric oxide and carbon monoxide |
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Inventor after: Wang Chuanyi Inventor after: Yang Sudong Inventor after: Chen Lin Inventor after: Liu Huayun Inventor before: Liu Huayun Inventor before: Wang Chuanyi Inventor before: Chen Lin Inventor before: Yang Sudong |
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Free format text: CORRECT: INVENTOR; FROM: LIU HUAYUN WANG CHUANYI CHEN LIN YANG SUDONG TO: WANG CHUANYI YANG SUDONG CHEN LIN LIU HUAYUN |
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C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Wang Chuanyi Inventor after: Liu Huayun Inventor after: Chen Lin Inventor after: Yang Sudong Inventor before: Wang Chuanyi Inventor before: Yang Sudong Inventor before: Chen Lin Inventor before: Liu Huayun |
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