CN103787773B - Paddy rice zinc-rich nutrient agent and preparation thereof and the method for the production of rice rich in zinc - Google Patents

Paddy rice zinc-rich nutrient agent and preparation thereof and the method for the production of rice rich in zinc Download PDF

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CN103787773B
CN103787773B CN201410037199.5A CN201410037199A CN103787773B CN 103787773 B CN103787773 B CN 103787773B CN 201410037199 A CN201410037199 A CN 201410037199A CN 103787773 B CN103787773 B CN 103787773B
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zinc
rice
rich
paddy rice
rich nutrient
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CN103787773A (en
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刘琦
王张民
潘斐
毛彦军
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WEIGANG BIOTECHNOLOGY JIANGSU Co Ltd
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WEIGANG BIOTECHNOLOGY JIANGSU Co Ltd
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Abstract

The invention discloses the zinc-rich nutrient agent of a kind of paddy rice and preparation thereof and the method for the production of rice rich in zinc.This paddy rice component of zinc-rich nutrient agent by following parts by weight is formed: zinc source, with zinc weighing scale 0.5 ~ 25.5; Biological organic fertilizer 6.5 ~ 9.2; Ferrous sulfate 0.05 ~ 0.15; Acid-base buffer agent 0.33 ~ 4.8; Fertilizer binding agent 0.01 ~ 0.05.In Rice Cropping process, apply above-mentioned zinc-rich nutrient agent.The rice Zn content produced according to method provided by the invention can reach 14.6 ~ 40.2mg/kg; And the rice produced meets the requirement of state food standard, maintains the object that the original nutrition of rice reaches again rich zinc, has good physiologically active, be easy to digest and assimilate.

Description

Paddy rice zinc-rich nutrient agent and preparation thereof and the method for the production of rice rich in zinc
Technical field
The invention belongs to proportion of crop planting field, be specifically related to the zinc-rich nutrient agent of a kind of paddy rice and preparation thereof and the method for the production of rice rich in zinc.
Background technology
There is the resident of about 2/3rds in China using rice as staple food, and as one of most important food crop of China, the cultivated area of paddy rice accounts for the half of China's plant of grain crops area, and distributed areas are vast.Based on population pressure etc., attach great importance to output in China's rice production in the past and ignore the quality of rice, in today that standard of living progressively improves, people are more and more higher to demand balanced in nutrition, make also more and more to pay attention to the nutritional quality of rice in recent years.
Zinc, symbol of element Zn, being the 4th common metal, is also one of micronutrient element of needed by human, and in human body, its content is only second to iron, and it maintains normal physiological function to human body and plays irreplaceable effect.Having now found that zinc take part in synthesis and the activation of more than 200 kind of enzyme, is the trace element uniquely all existed in six large enzyme systems.Also be the important composition composition of various metals albumen, structural protein and nucleic acid simultaneously, in the synthesis of regulation and control body substance and metabolism, maintain the many aspects such as Stability Analysis of Structures and play an important role.
The zinc recommended intake of being grown up every day is 10 ~ 15mg, find through investigation, the situation that China's rice soil lacks zinc is very general, especially the calcareous Paddy Soils of the north and two sides, the middle and lower reach of Yangtze River, this also result in the shortage of zinc in rice, and then human body zinc insufficiency of intake may be caused, human body Zinc Nutrition Status is had an impact.According to WHO Report, zn deficiencie has become the fifth-largest threat of developing country's residents ' health situation.Zn deficiencie may cause growing fall behind, the generation of a series of disease such as Development in Puberty is slow, abnormal labor, tetter, illness in eye, immunocyte decline, therefore, science zinc supplementation is extremely urgent.
Rice is one of staple food grain of China resident, and the edible rice being rich in zinc becomes one of important means of science zinc supplementation.The rich zinc technology of current rice mainly contains following several:
One, " outer addition ", as the patent No. 200910248713.9, joins in cooked rice by zinc element with the form of additive, is about to containing the solution of zinc or pulvis according to certain ratio and rice mixing, then carries out some and process.Though the rice rich in zinc of such making has certain effect, but people can wash before edible rice, are commonly called as rice washing, and the actual effect that this process will cause the loss of a large amount of zinc to play is very limited.
Two, " inside enforce the law ", dry after namely rice zinc-containing solution being soaked.This method can destroy rice internal structure, affects mouthfeel, and it is expensive to take a lot of work, and should not preserve.
Three, " crop foliar spray method ", namely in tillering phase of paddy rice, boot stage, filling stage to foliage-spray zinc fertilizer, make its Foliage Absorption, be converted into rice rich in zinc, as the patent No. 200410084878.4 and 200610086308.8.Although this method is more advanced, a large amount of inorganic states to be made in rice residual for fertilizer for spraying on leaf surface and this fertilization mode can increase labour cost, and if the liquid fertilizer of high density control the bad damage etc. that may cause crop blade face.
Four, have a large amount of report for applying the research of zinc fertilizer to soil, but these researchs supplement zinc needed for crop normal growth to the impact of crop under mainly paying close attention to soil zinc deficiency situation, the zinc added is not intended to improve the Zn content in crop.A small amount of report is also paid close attention to and is executed zinc improves effect impact on crop Zn content, but general all poor effect, Zn content in crop only can slightly improve, Guo Jiuxin etc. find that in " nitrogen zinc does the impact on rice yield and seed nitrogen, Zn content mutually " direct application of zinc fertilizer can significantly improve the zinc accumulation volume in rice grain in soil, the graphic analyses provided from the document, in rice grain, Zn content can improve about 12% at most.Execute zinc and can improve nitrogen content and crude protein content in rice grain simultaneously, contribute to the quality improving rice.But in actual production life, particularly more and more pay attention to today of quality of life people, the raising of about 10% also seems not enough.In order to meet this demand, we need to obtain more high zinc content rice.Executing nitrogen in a large number and can improve Zn content in rice described in document, but Russia victory wise man waits in " azophoska is on the impact of rice iron, zinc, copper, manganese, magnesium, calcium contents and output " the middle increase found along with applied nitrogen, and in rice grain, Zn content presents the trend first increasing and reduce afterwards.Hao Hulin etc. have also discovered same trend in " for nitrogen level on the impact of rice strain iron, manganese, copper, Zn content and rice quality " literary composition.Therefore, by improving nitrogen fertilizer amount, significantly to improve the method feasibility of Zn content in rice not high.
Therefore, the technical problem obtaining the rice of the more high zinc content of high security has to be solved.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides the zinc-rich nutrient agent of a kind of paddy rice and preparation thereof and the method for the production of rice rich in zinc, is 14.6 ~ 40.2mg/kg with the rice Zn content that this method is produced.
Paddy rice provided by the invention zinc-rich nutrient agent, is made up of the component of following parts by weight:
Zinc source, with zinc weighing scale: 0.5 ~ 25.5;
Biological organic fertilizer: 6.5 ~ 9.2;
Ferrous sulfate: 0.05 ~ 0.15;
Acid-base buffer agent: 0.33 ~ 4.8;
Fertilizer binding agent: 0.01 ~ 0.05.
Preferably, described zinc source is one or more mixture in the mineral material containing zinc element or the compound containing zinc.Further preferably, described zinc source is the mixture of one or more in soluble zinc salt or zinc oxide.More preferably, described soluble zinc salt is the mixture of one or more in zinc sulfate, zinc acetate, zinc chloride or zinc oxide.
Preferably, described acid-base buffer agent is the mixture of sulphur powder and silicate, and the parts by weight of sulphur powder are 0.05 ~ 1.6, and the parts by weight of silicate are 0.28 ~ 3.2.
The invention provides the preparation method of above-mentioned paddy rice zinc-rich nutrient agent, comprise the steps:
1) by stand-by to zinc source, biological organic fertilizer, ferrous sulfate and acid-base buffer agent grinds powder;
2) according to described amount, zinc source, biological organic fertilizer, ferrous sulfate and acid-base buffer agent are mixed;
3) by step 2) described in mixture granulation on disk, add the fertilizer binding agent of described amount during granulation, gained fertiliser granulates is zinc-rich nutrient agent.
The invention provides the agent of above-mentioned paddy rice zinc-rich nutrient for the production of the method for rice rich in zinc, comprise the steps:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 20kg/ mu with the weight of zinc simultaneously, is preferably 14 ~ 18kg/ mu, is more preferably 16kg/ mu.
2) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
The invention provides another kind of above-mentioned paddy rice zinc-rich nutrient agent for the production of the method for rice rich in zinc, comprise the steps:
1) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, paddy rice zinc-rich nutrient agent is applied in rice terrace, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc, be preferably 10 ~ 14kg/ mu, be more preferably 12kg/ mu.
2) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
The invention provides another kind of above-mentioned paddy rice zinc-rich nutrient agent for the production of the method for rice rich in zinc, comprise the steps:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc simultaneously, is preferably 10kg/ mu.
2) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, paddy rice zinc-rich nutrient agent is applied in rice terrace, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 10kg/ mu with the weight of zinc, is preferably 8kg/ mu.
3) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
The invention has the advantages that:
1, the rice Zn content produced according to method provided by the invention can reach 14.6 ~ 40.2mg/kg.
2, the rice produced according to the inventive method meets the requirement of state food standard, maintains the object that the original nutrition of rice reaches again rich zinc, has good physiologically active, be easy to digest and assimilate.
3, there is good controllability, can according to the rice of different demand production Different Zinc content.
4, the present invention is compared with technology before, has better controllability, makes it have and more wide utilizes space.Can be used as biological zinc source, extract and wherein make additive in order to make food, medicine etc. after biological zinc; Appropriate present method production rice can be eaten for its symptom for scarce zinc crowd and reach zinc supplementation effect etc.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, can better understand the present invention and can be implemented, but illustrated embodiment is not as a limitation of the invention to make those skilled in the art.
First by zinc sulfate, zinc chloride, zinc acetate, sulphur, silicate, biological organic fertilizer, ferrous sulfate pulverize.
By weight, take 1 part of sulphur powder and 1 part of silicate, mix, take 0.1 part of ferrous sulfate, take 20 parts of (weighing scale with zinc) zinc sulfate and 8 parts of biological organic fertilizers more successively, mix, add 0.03 part of fertilizer binding agent (fertilizer binding agent commercially available arbitrarily, can be carboxymethyl cellulose) granulation on disk, the agent of gained zinc-rich nutrient is labeled as a nutrition agent;
Take 0.05 part of sulphur powder and 0.28 part of silicate, mix, take 0.15 part of ferrous sulfate, take 0.5 part of (weighing scale with zinc) zinc chloride and 9.2 parts of biological organic fertilizers more successively, mix, add 0.01 part of fertilizer binding agent granulation on disk, the agent of gained zinc-rich nutrient is labeled as No. two nutrition agents;
Take 1.6 parts of sulphur powder and 3.2 parts of silicate, mix, take 0.05 part of ferrous sulfate, take 25.5 parts of (weighing scale with zinc) zinc acetates and 6.5 parts of biological organic fertilizers more successively, mix, add 0.05 part of fertilizer binding agent granulation on disk, the agent of gained zinc-rich nutrient is labeled as No. three nutrition agents.
Take 1 part of sulphur powder and 2 parts of silicate, mix, take 0.05 part of ferrous sulfate, take 18 parts of (weighing scale with zinc) zinc oxide and 8 parts of biological organic fertilizers more successively, mix, add 0.03 part of fertilizer binding agent granulation on disk, the agent of gained zinc-rich nutrient is labeled as No. four nutrition agents.
Take 0.8 part of sulphur powder and 1.8 parts of silicate, mix, take 0.08 part of ferrous sulfate, take 10 parts of (weighing scale in zinc) zinc sulfate and 10 parts of (with zinc) zinc chloride, 7 parts of biological organic fertilizers more successively, mix, add 0.05 part of fertilizer binding agent granulation on disk, gained nutrition agent is labeled as No. five nutrition agents.
Embodiment
At Jiangsu paddy base, carry out the cultivation of rice rich in zinc according to the method for the invention:
Embodiment 1: cultivate according to normal raising rice seedlings, rice transplanting, paddy field management;
Embodiment 2-32: at paddy rice different times, use the paddy rice of the present invention zinc-rich nutrient agent of different amount, all the other carry out rice rich in zinc cultivation according to the method identical with control group.
Method one:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 20kg/ mu with the weight of zinc simultaneously;
2) paddy rice planting method conveniently carries out water and fertilizer management, finally gathers in the crops rice rich in zinc.
Method two:
1) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, in rice terrace, apply paddy rice zinc-rich nutrient agent, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc;
2) paddy rice planting method conveniently carries out water and fertilizer management, finally gathers in the crops rice rich in zinc.
Method three:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc simultaneously;
2) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, in rice terrace, apply paddy rice zinc-rich nutrient agent, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 10kg/ mu with the weight of zinc;
3) paddy rice planting method conveniently carries out water and fertilizer management, finally gathers in the crops rice rich in zinc.
Wherein embodiment 2-23 uses a nutrition agent, and embodiment 24,25,27 uses No. two nutrition agents, and embodiment 26,28 uses No. three nutrition agents, and embodiment 29,30 uses No. four nutrition agents, and embodiment 31,32 uses No. five nutrition agents.
All embodiment acquired results are as follows above:
Embodiment The zinc-rich nutrient agent use age Zinc-rich nutrient agent (in zinc) usage quantity (kg/ mu) Rice Zn content (mg/kg)
Embodiment 1 Do not use 0 13.4
Embodiment 2 Base manure 2 14.6
Embodiment 3 Base manure 10 21.9
Embodiment 4 Base manure 15 36.8
Embodiment 5 Base manure 20 39.3
Embodiment 6 Tillering and jointing stage 2 15.1
Embodiment 7 Tillering and jointing stage 6 18.9
Embodiment 8 Tillering and jointing stage 16 34.8
Embodiment 9 Boot stage 4 18.3
Embodiment 10 Boot stage 8 20.5
Embodiment 11 Boot stage 16 36.4
Embodiment 12 Filling stage 6 18.1
Embodiment 13 Filling stage 10 29.4
Embodiment 14 Filling stage 14 36.6
Embodiment 15 Base manure+tillering and jointing stage 2+2 15.3
Embodiment 16 Base manure+tillering and jointing stage 8+10 38.8
Embodiment 17 Base manure+tillering and jointing stage 12+6 38.2
Embodiment 18 Base manure+boot stage 16+4 40.1
Embodiment 19 Base manure+boot stage 6+10 39.6
Embodiment 20 Base manure+boot stage 12+2 35.8
Embodiment 21 Base manure+filling stage 4+4 18.5
Embodiment 22 Base manure+filling stage 10+6 39.9
Embodiment 23 Base manure+filling stage 10+8 40.2
Embodiment 24 Base manure 20 38.6
Embodiment 25 Tillering and jointing stage 16 33.9
Embodiment 26 Filling stage 14 36.4
Embodiment 27 Base manure+tillering and jointing stage 12+6 36.8
Embodiment 28 Base manure+filling stage 10+8 39.9
Embodiment 29 Base manure 20 38.1
Embodiment 30 Base manure+filling stage 10+8 38.9
Embodiment 31 Base manure 20 39.0
Embodiment 32 Base manure+filling stage 10+8 39.6
As can be seen from the above embodiments: the rice Zn content utilizing method provided by the invention to cultivate can reach 14.6 ~ 40.2mg/kg, and has better controllability, the rice of production Different Zinc content can be needed according to difference.
The above embodiment is only that protection scope of the present invention is not limited thereto in order to absolutely prove the preferred embodiment that the present invention lifts.The equivalent alternative or conversion that those skilled in the art do on basis of the present invention, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.

Claims (9)

1. a paddy rice zinc-rich nutrient agent, is characterized in that, is made up of the component of following parts by weight:
Zinc source, with zinc weighing scale: 0.5 ~ 25.5;
Biological organic fertilizer: 6.5 ~ 9.2;
Ferrous sulfate: 0.05 ~ 0.15;
Acid-base buffer agent: 0.33 ~ 4.8;
Fertilizer binding agent: 0.01 ~ 0.05;
Wherein, described acid-base buffer agent is the mixture of sulphur powder and silicate, and the parts by weight of sulphur powder are 0.05 ~ 1.6, and the parts by weight of silicate are 0.28 ~ 3.2.
2. paddy rice according to claim 1 zinc-rich nutrient agent, is characterized in that, described zinc source is one or more mixture in the mineral material containing zinc element or the compound containing zinc.
3. paddy rice according to claim 2 zinc-rich nutrient agent, is characterized in that, described zinc source is the mixture of one or more in soluble zinc salt or zinc oxide.
4. paddy rice according to claim 3 zinc-rich nutrient agent, is characterized in that, described soluble zinc salt is the mixture of one or more in zinc sulfate, zinc acetate or zinc chloride.
5. the preparation method of zinc-rich nutrient agent of the paddy rice described in any one of claim 1-4, is characterized in that, comprise the steps:
1) by stand-by to zinc source, biological organic fertilizer, ferrous sulfate and acid-base buffer agent grinds powder;
2) according to proportioning, zinc source, biological organic fertilizer, ferrous sulfate and acid-base buffer agent are mixed;
3) by step 2) in mixture granulation on disk, add the fertilizer binding agent of proportional quantity during granulation, gained fertiliser granulates is zinc-rich nutrient agent.
6. the method for zinc-rich nutrient agent for the production of rice rich in zinc of the paddy rice described in any one of claim 1 ~ 4, is characterized in that, comprise the steps:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 20kg/ mu with the weight of zinc simultaneously;
2) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
7. the method for zinc-rich nutrient agent for the production of rice rich in zinc of the paddy rice described in any one of claim 1 ~ 4, is characterized in that, comprise the steps:
1) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, in rice terrace, apply paddy rice zinc-rich nutrient agent, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc;
2) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
8. the method for zinc-rich nutrient agent for the production of rice rich in zinc of the paddy rice described in any one of claim 1 ~ 4, is characterized in that, comprise the steps:
1) apply the zinc-rich nutrient agent of described paddy rice when Fertilizer in Rice base manure, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 16kg/ mu with the weight of zinc simultaneously;
2) one of them or its arbitrary combination of the tillering and jointing stage in growth process of riceplant, boot stage or filling stage, in rice terrace, apply paddy rice zinc-rich nutrient agent, the described paddy rice applied amount of zinc-rich nutrient agent counts 2 ~ 10kg/ mu with the weight of zinc;
3) carry out water and fertilizer management, finally gather in the crops rice rich in zinc.
9. method according to claim 8, is characterized in that, the applied amount of zinc-rich nutrient agent of paddy rice described in step 1) counts 10kg/ mu with the weight of zinc, step 2) described in the applied amount of paddy rice zinc-rich nutrient agent count 8kg/ mu with the weight of zinc.
CN201410037199.5A 2014-01-26 2014-01-26 Paddy rice zinc-rich nutrient agent and preparation thereof and the method for the production of rice rich in zinc Expired - Fee Related CN103787773B (en)

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Publication number Priority date Publication date Assignee Title
CN110041124A (en) * 2019-04-23 2019-07-23 浙江工业大学 A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139230A (en) * 2007-06-20 2008-03-12 林炳营 Low-yield paddy field plow layer soil-modifying fertilizer
CN101445411A (en) * 2008-12-24 2009-06-03 苏玉俊 Nuisance free paddy rice-dedicated fertilizer
CN101503326A (en) * 2009-03-03 2009-08-12 宁夏大学 Improver special for alkaline land alkali-resistant salt-restricting rice and method of processing the same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101139230A (en) * 2007-06-20 2008-03-12 林炳营 Low-yield paddy field plow layer soil-modifying fertilizer
CN101445411A (en) * 2008-12-24 2009-06-03 苏玉俊 Nuisance free paddy rice-dedicated fertilizer
CN101503326A (en) * 2009-03-03 2009-08-12 宁夏大学 Improver special for alkaline land alkali-resistant salt-restricting rice and method of processing the same

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