CN103756413A - Special urine wet showing water-based ink for infant diapers and preparation method of ink - Google Patents

Special urine wet showing water-based ink for infant diapers and preparation method of ink Download PDF

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CN103756413A
CN103756413A CN201310753773.2A CN201310753773A CN103756413A CN 103756413 A CN103756413 A CN 103756413A CN 201310753773 A CN201310753773 A CN 201310753773A CN 103756413 A CN103756413 A CN 103756413A
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urine
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ink
agent
water
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CN103756413B (en
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林国良
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Zhangzhou Green Spring Science And Technology Co ltd
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Abstract

The invention relates to special urine wet showing water-based ink for infant diapers, and a preparation method of the ink. According to the formula, the ink comprises the following components in parts by mass: 30-40 parts of water-soluble resin, 20-70 parts of distilled water, 0.5-5 parts of wetting flatting agent, 0.1-1 part of defoaming agent, 5-10 parts of food coloring, 1-5 parts of silane coupling agent, 1-5 parts of dispersing agent and 1-5 parts of thickening agent. The machining process comprises the following steps: taking the raw materials according to the parts by weight, adding the water-soluble resin into a stirring bucket to stir, adding the edible coloring, the dispersing agent and the silane coupling agent into the water-soluble resin, uniformly stirring, grinding the mixture in the stirring bucket by using grinding equipment in a high speed, after the grinding, adding the distilled water, the wetting flatting agent, the defoaming agent and the thickening agent into the stirring bucket, uniformly stirring, and finally filtering by using a sieve of 200-300 meshes so as to obtain the urine wet showing water-based ink. After the urine wet showing water-based ink is printed on a picture and word part on an ordinary infant diaper, an ink layer can be washed out by the urine after the urine is in contact with the ink layer, and the color vanishes gradually, so that a prompting effect is achieved, and moreover the ink is safe, environment-friendly and free of pollution.

Description

Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof
Technical field
The present invention relates to wet aobvious water color ink of the special urine of a kind of baby paper diaper and preparation method thereof.
Background technology
Conventional paper urine pants, easily because changing not in time, cause because urinating the problems such as the wet red wind wind causing or eczema.The urine of paper diaper is aobvious is designed to new hand father and mother provides certain convenient, can be in the situation that leaving baby alone, and by the variation of paper diaper color, pointing out in time father and mother is that baby changes paper diaper, for baby provides cleaner comfortable growth condition.Have in the market the paper diaper of urine display function, comparatively main flow is hot-melting type urine present gum technology and the aobvious technology of ink urine.
Hot-melting type urine present gum is by the generation effect that combines of hot melt adhesive and material pH value to color sensitivity characteristic, urine present gum is coated in the one side of counterdie towards sandwich layer with lines form, when urine is soaked sandwich layer, be transmitted to the surface of urine present gum, its pH value is changed, thereby cause colour-change, reach the aobvious vision monitoring effect of urine.But urine present gum is exposed to the wet easy variable color of wet among air.When there was dampness in the air, paper diaper are not also used the variable color of urine present gum, therefore can not play well the function of meeting urine variable color.And urine present gum need to add the materials such as softening agent, paraffin while making, on the healthy and safe of baby, can produce certain impact.
Ink urine is aobvious: principle is to add and be with coloured small-molecule substance in ink, and after urine is in contact with it, ink and these small molecules are washed away by urine, and color disappears, and reaches the effect of prompting.What the aobvious major part of disappearance type urine adopted is the aobvious technology of ink urine, and technological core is to solve four subject matters: 1, resin is water-soluble; 2, colorant is water-soluble; 3, the sticking power of China ink layer on paper diaper PE making hole film; 4, the aobvious China ink layer of urine did not lose efficacy in advance in wet environment.The aobvious ink of current urine on the market all can not solve these puzzlements well.
Summary of the invention
In order to overcome above-mentioned defect, the invention provides wet aobvious water color ink of the special urine of a kind of baby paper diaper and preparation method thereof.
The present invention solves the scheme that its technical problem adopts: the wet aobvious water color ink of urine that a kind of baby paper diaper is special, and it comprises the raw material of following parts by weight:
Figure BDA0000450161700000011
Figure BDA0000450161700000021
Preferably, described water soluble resin solid content 45~48%, acid number 300~600mgKOH/g, 20~40 ℃ of second-order transition temperatures, pH value approximately 7.5~9.5, viscosity 500~1000mPa.s.
Preferably, described moistening flatting agent is polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity.
Preferably, described defoamer is the mixture of fatty family mineral oil, effective content 100%, the about 100mPa.s of viscosity.
Preferably, described silane coupling agent is γ-aminopropyl triethoxysilane, molecular weight >=200, flash-point >=90 ℃.
Preferably, described thickening material is association type polyurethane thickener, effective content 50~60%, viscosity 2000~3000mPa.s.
Preferably, described dispersion agent is polycarboxylate sodium's dispersion agent, PH=7.0 ± 1, effective content 50%, viscosity 500~1000mPa.s.
The wet preparation method who shows water color ink of urine that a kind of baby paper diaper is special, according to described parts by weight, get raw material, described water soluble resin is added in agitation vat and stirred, described food dye, dispersion agent, silane coupling agent are added in water soluble resin, stir; Mixture in agitation vat is carried out to speed lapping with grinding plant; After grinding finishes, more described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir; Finally, with 200~300 eye mesh screens filtrations, obtain the wet aobvious water color ink of urine.
Beneficial effect of the present invention: (1) adopts water is solvent, without the volatilization of poisonous organic solvent, pollution-free to air; (2) acrylic resin of employing superelevation acid number, water-soluble fabulous, has certain sterilization effect; (3) use food dye to make colorant, be not only easily dissolved in water, and safety and environmental protection; (4) not only solved the adhesion problem on PE making hole film, and can realize under moisture state and not being hydrolyzed, China ink layer is unchanged, can avoid the inefficacy (under the condition of 80% high humidity, can keep a week do not lose efficacy) of China ink layer under wet environment.Until touch after urine (baby's urine is subacidity), just can make China ink layer sticking power variation, dissolving, and picture and text color disappears at once.
Embodiment
The present invention is further detailed explanation to use embodiment below, is not practical range of the present invention is confined to this.
Embodiment 1, the special wet aobvious water color ink of urine of a kind of baby paper diaper described in the present embodiment, it is added in agitation vat and is obtained through mixing, grind, stirring by the raw material of following parts by weight:
Figure BDA0000450161700000031
Described in the present embodiment, water soluble resin is the water soluble resin that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd produces, solid content 47%, acid number 450,30 ℃ of second-order transition temperatures, pH value approximately 8.5, viscosity 800mPa.s; Moistening flatting agent is
Figure BDA0000450161700000032
flow 425, polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity; Defoamer is
Figure BDA0000450161700000033
foamex K8, the mixture of aliphatics mineral oil, effective content 100%, the about 100mPa.s of viscosity; Food dye is the R122 rhodo pigment of Zhengzhou Tian Tong food ingredients company limited; Silane coupling agent is the KH-550 amino silicane coupling agent of Hangzhou boiling point chemical industry, molecular weight>=200, flash-point>=90 ℃; Dispersion agent is the SN-DISPERSANT 5040 of Japanese Nuo Puke, PH=7.0 ± 1, effective content 50%, viscosity 800mPa.s; Thickening material is
Figure BDA0000450161700000034
viscoPlus 3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.Preparation method is, according to described parts by weight, gets raw material, and described water soluble resin is added to agitation vat high-speed stirring (stirring velocity 800rpm), described food dye, dispersion agent, silane coupling agent added in water soluble resin simultaneously, stirs; Then with grinding plant, the mixture in agitation vat is carried out to speed lapping; When the μ m of fineness≤10, grind and finish, more described distilled water, moistening flatting agent, defoamer, thickening material are added to agitation vat stirring at low speed (stirring velocity 400rpm), stir; Finally, with 260 eye mesh screens filtrations, obtain the wet aobvious water color ink of urine.This ink printing is made to paper diaper finished product on common PE making hole film base material, and the then outer test of committee, measures China ink layer performance 1, meets the disposable use sanitary product of GB15979-2002 hygienic standard; 2, under fixed temperature and humidity condition, (25 ℃/80%) was placed after one week, and China ink layer is unchanged; 3, with the aqueous solution of PH=6.5, drip on China ink layer, picture and text disappear at once.
Embodiment 2, the special wet aobvious water color ink of urine of a kind of baby paper diaper described in the present embodiment, it is added in agitation vat and is obtained through mixing, grind, stirring by the raw material of following parts by weight:
Described in the present embodiment, water soluble resin is the water soluble resin that Green spring (Xiamen) environmental protection science and technology Materials Co., Ltd produces, solid content 47%, acid number 500,30 ℃ of second-order transition temperatures, pH value approximately 8.5, viscosity 800mPa.s; Moistening flatting agent is
Figure BDA0000450161700000042
flow 425, polyether siloxane copolymer, effective content 100%, the about 100mPa.s of viscosity; Defoamer is foamex K8, the mixture of aliphatics mineral oil, effective content 100%, the about 100mPa.s of viscosity; Food dye is the Y14 lemon yellow pigment of Zhengzhou Tian Tong food ingredients company limited; Silane coupling agent is the KH-550 amino silicane coupling agent of Hangzhou boiling point chemical industry, molecular weight>=200, flash-point>=90 ℃; Dispersion agent is the SN-DISPERSANT 5040 of Japanese Nuo Puke, PH=7.0 ± 1, effective content 50%, viscosity 800mPa.s; Thickening material is viscoPlus3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.Preparation method is, according to described parts by weight, gets raw material, and described water soluble resin is added to agitation vat high-speed stirring (stirring velocity 800rpm), described food dye, dispersion agent, silane coupling agent added in water soluble resin simultaneously, stirs; Then with grinding plant, the mixture in agitation vat is carried out to speed lapping; When the μ m of fineness≤10, grind and finish, more described distilled water, moistening flatting agent, defoamer, thickening material are added to agitation vat stirring at low speed (stirring velocity 400rpm), stir; Finally, with 260 eye mesh screens filtrations, obtain the wet aobvious water color ink of urine.This ink printing is made to paper diaper finished product on common PE making hole film base material, and the then outer test of committee, measures China ink layer performance 1, meets the disposable use sanitary product of GB15979-2002 hygienic standard; 2, under fixed temperature and humidity condition, (25 ℃/80%) was placed after one week, and China ink layer is unchanged; 3, with the aqueous solution of PH=6.5, drip on China ink layer, picture and text disappear at once.
The above is only a preferred embodiment of the present invention, just for helping to understand method of the present invention and core concept thereof.It should be pointed out that for those skilled in the art, under the premise of not departing from the present invention, can also carry out some improvement and modification to the present invention, these modifications and modification also fall in the protection domain of the claims in the present invention.

Claims (8)

1. the wet aobvious water color ink of the special urine of baby paper diaper, is characterized in that: it comprises the raw material of following parts by weight:
Figure FDA0000450161690000011
2. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described water soluble resin, solid content 45~48%, acid number 300~600mgKOH/g, 20~40 ℃ of second-order transition temperatures, pH value 7.5~9.5, viscosity 500~1000mPa.s.
3. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described moistening flatting agent is polyether siloxane copolymer effective content 100%, viscosity 50~300mPa.s.
4. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described defoamer is the mixture of fatty family mineral oil effective content 100%, viscosity 50~300mPa.s.
5. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described thickening material is association type polyurethane thickener effective content 50~60%, viscosity 2000~3000mPa.s.
6. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described silane coupling agent type is γ-aminopropyl triethoxysilane, molecular weight >=200, flash-point >=90 ℃.
7. the special wet aobvious water color ink of urine of a kind of baby paper diaper according to claim 1, is characterized in that: described dispersion agent is polycarboxylate sodium's dispersion agent pH=7.0 ± 1, effective content 50%, viscosity 500~1000mPa.s.
8. the wet preparation method who shows water color ink of urine that baby paper diaper is special, according to parts by weight described in claim 1, get raw material, described water soluble resin is added in agitation vat and stirred, described food dye, dispersion agent, silane coupling agent are added in water soluble resin, stir; Mixture in agitation vat is carried out to speed lapping with grinding plant; After grinding finishes, more described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir; Finally, with 200~300 eye mesh screens filtrations, obtain the wet aobvious water color ink of urine.
CN201310753773.2A 2013-12-30 2013-12-30 Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof Active CN103756413B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852135A (en) * 2017-11-30 2019-06-07 金永昌 According to PH change and change colour laminated film and include the paper diaper of the laminated film
CN111995906A (en) * 2020-09-01 2020-11-27 福建琦峰科技有限公司 Printing ventilated membrane that urine wet discolours
CN115537064A (en) * 2022-09-27 2022-12-30 广东佳景科技股份有限公司 Gravure printing sterile water-based ink for breathable film of paper diaper and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110144603A1 (en) * 2009-12-14 2011-06-16 Xuedong Song Aqueous-Triggered Color-Appearing Inks
CN103330958A (en) * 2013-03-29 2013-10-02 佛山南宝高盛高新材料有限公司 Wetness indicating adhesive and preparation technology thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110144603A1 (en) * 2009-12-14 2011-06-16 Xuedong Song Aqueous-Triggered Color-Appearing Inks
CN103330958A (en) * 2013-03-29 2013-10-02 佛山南宝高盛高新材料有限公司 Wetness indicating adhesive and preparation technology thereof

Non-Patent Citations (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109852135A (en) * 2017-11-30 2019-06-07 金永昌 According to PH change and change colour laminated film and include the paper diaper of the laminated film
CN111995906A (en) * 2020-09-01 2020-11-27 福建琦峰科技有限公司 Printing ventilated membrane that urine wet discolours
CN115537064A (en) * 2022-09-27 2022-12-30 广东佳景科技股份有限公司 Gravure printing sterile water-based ink for breathable film of paper diaper and preparation method and application thereof

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