CN103756413B - Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof - Google Patents

Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof Download PDF

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CN103756413B
CN103756413B CN201310753773.2A CN201310753773A CN103756413B CN 103756413 B CN103756413 B CN 103756413B CN 201310753773 A CN201310753773 A CN 201310753773A CN 103756413 B CN103756413 B CN 103756413B
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urine
color ink
soluble resin
agent
paper diaper
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CN103756413A (en
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林国良
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Zhangzhou Green Spring Science And Technology Co ltd
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Fujian Green Spring Technology Co Ltd
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Abstract

The present invention relates to wet aobvious water color ink of the special urine of a kind of paper diaper and preparation method thereof.Described formula comprises following component and mass fraction: water soluble resin 30 ~ 40 parts; Distilled water 20 ~ 70 parts; Moistening flatting agent 0.5 ~ 5 part; Defoamer 0.1 ~ 1 part; Food dye 5 ~ 10 parts; Silane coupling agent 1 ~ 5 part; Dispersion agent 1 ~ 5 part; Thickening material 1 ~ 5 part; Described water soluble resin, for get raw material according to described parts by weight, adds in agitation vat and stirs by its complete processing, adds in water soluble resin, stir described food dye, dispersion agent, silane coupling agent; With grinding plant, the mixture in agitation vat is carried out speed lapping; After grinding terminates, more described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir; Finally, filter with 200 ~ 300 eye mesh screens, obtain the wet aobvious water color ink of urine.The present invention can allow after the wet aobvious water color ink of urine in the printing of common baby paper diaper areas, and realize after urine contacts with layer of ink, layer of ink is washed away by urine, and color fades away, and reaches the effect of prompting, and safety and environmental protection, pollution-free.<pb pnum="1" />

Description

Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof
Technical field
The present invention relates to wet aobvious water color ink of the special urine of a kind of baby paper diaper and preparation method thereof.
Background technology
Conventional paper urine pants, easily because changing not in time, cause because urinating the wet and problem such as the red wind wind that causes or eczema.The urine of paper diaper shows and is designed to new hand father and mother and provides certain convenient, can, when leaving baby alone, point out father and mother to be that baby changes paper diaper in time, for baby provides more totally comfortable growth condition by the change of paper diaper color.Have the paper diaper of urine display function in the market, comparatively main flow is hot-melting type urine present gum technology and the aobvious technology of ink urine.
Hot-melting type urine present gum to be combined generation effect by hot melt adhesive and the material having a Color-sensitive characteristic to pH value, urine present gum is coated in the one side of counterdie towards sandwich layer with lines form, when urine soaks sandwich layer, be transmitted to the surface of urine present gum, its pH value is changed, thus cause colour-change, reach the vision monitoring effect that urine is aobvious.The easy variable color but the wet among air that is exposed to urine present gum wets.When there was dampness in the air, paper diaper also do not use the variable color of urine present gum, therefore can not play the function of meeting urine variable color well.And need to add the material such as softening agent, paraffin during the making of urine present gum, certain impact can be produced on the healthy and safe of baby.
Ink urine is aobvious: principle is in ink, add the coloured small-molecule substance of band, and after urine is in contact with it, ink and these small molecules are washed away by urine, and color disappears, and reaches the effect of prompting.What the aobvious major part of disappearance type urine adopted is the aobvious technology of ink urine, and technological core is solution four subject matters: 1, resin is water-soluble; 2, colorant is water-soluble; 3, the sticking power of layer of ink on paper diaper PE making hole film; 4, the aobvious layer of ink of urine not premature failure in wet environment.Current urine on the market shows ink all can not solve these puzzlements well.
Summary of the invention
In order to overcome above-mentioned defect, the invention provides wet aobvious water color ink of the special urine of a kind of baby paper diaper and preparation method thereof.
The present invention solves the scheme that its technical problem adopts: the wet aobvious water color ink of urine that a kind of baby paper diaper is special, and it comprises the raw material of following parts by weight:
Water soluble resin 30 ~ 40 parts
Distilled water 20 ~ 70 parts
Moistening flatting agent 0.5 ~ 5 part
Defoamer 0.1 ~ 1 part
Food dye 5 ~ 10 parts
Silane coupling agent 1 ~ 5 part
Dispersion agent 1 ~ 5 part
Thickening material 1 ~ 5 part
Preferably, described water soluble resin solid content 45 ~ 48%, acid number 300 ~ 600mgKOH/g, second-order transition temperature 20 ~ 40 DEG C, pH value about 7.5 ~ 9.5, viscosity 500 ~ 1000mPa.s.
Preferably, described moistening flatting agent is polyether siloxane copolymer, and effective content 100%, viscosity is about 100mPa.s.
Preferably, described defoamer is the mixture of fatty race mineral oil, and effective content 100%, viscosity is about 100mPa.s.
Preferably, described silane coupling agent is γ-aminopropyl triethoxysilane, molecular weight >=200, flash-point >=90 DEG C.
Preferably, described thickening material is association type polyurethane thickener, effective content 50 ~ 60%, viscosity 2000 ~ 3000mPa.s.
Preferably, described dispersion agent is polycarboxylate sodium's dispersion agent, PH=7.0 ± 1, effective content 50%, viscosity 500 ~ 1000mPa.s.
The special urine of a kind of baby paper diaper wets the preparation method of aobvious water color ink, raw material is got according to described parts by weight, described water soluble resin is added in agitation vat and stirs, described food dye, dispersion agent, silane coupling agent are added in water soluble resin, stirs; With grinding plant, the mixture in agitation vat is carried out speed lapping; After grinding terminates, more described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir; Finally, filter with 200 ~ 300 eye mesh screens, obtain the wet aobvious water color ink of urine.
Beneficial effect of the present invention: (1) adopts water to be solvent, without the volatilization of toxic organic solvents, to free of air pollution; (2) acrylic resin of superelevation acid number is adopted, water-soluble fabulous, there is certain sterilization effect; (3) use food dye to make colorant, be not only easily dissolved in water, and safety and environmental protection; (4) adhesion problem on PE making hole film is not only solved, and be not hydrolyzed under moisture state can be realized, layer of ink is unchanged, can avoid layer of ink inefficacy in wet condition (under the condition of 80% high humidity, a week can be kept not lose efficacy).Until after touching urine (baby's urine is subacidity), layer of ink sticking power just can be made to be deteriorated, dissolve, and picture and text color disappears at once.
Embodiment
The present invention is further detailed explanation to use embodiment below, is not practical range of the present invention is confined to this.
Embodiment 1, the wet aobvious water color ink of the special urine of a kind of baby paper diaper described in the present embodiment, it is added in agitation vat by the raw material of following parts by weight and obtains through mixing, grinding, stir:
Water soluble resin described in the present embodiment is the water soluble resin that Green spring (Xiamen) environmental protection tech materials company limited produces, solid content 47%, acid number 450, second-order transition temperature 30 DEG C, pH value about 8.5, viscosity 800mPa.s; Moistening flatting agent is 425, polyether siloxane copolymer, effective content 100%, viscosity is about 100mPa.s; Defoamer is foamex K8, the mixture of Aliphatic mineral oils, effective content 100%, viscosity is about 100mPa.s; Food dye is the R122 rhodo pigment of Zhengzhou Tian Tong food ingredients company limited; Silane coupling agent is the KH-550 amino silicane coupling agent of Hangzhou boiling point chemical industry, molecular weight>=200, flash-point>=90 DEG C; Dispersion agent is the SN-DISPERSANT 5040, PH=7.0 ± 1 of Japanese Nuo Puke, effective content 50%, viscosity 800mPa.s; Thickening material is viscoPlus 3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.Preparation method is, gets raw material according to described parts by weight, described water soluble resin is added agitation vat high-speed stirring (stirring velocity 800rpm), adds in water soluble resin simultaneously, stir described food dye, dispersion agent, silane coupling agent; Then with grinding plant, the mixture in agitation vat is carried out speed lapping; When fineness≤10 μm, grinding terminates, more described distilled water, moistening flatting agent, defoamer, thickening material are added agitation vat stirring at low speed (stirring velocity 400rpm), stirs; Finally, filter with 260 eye mesh screens, obtain the wet aobvious water color ink of urine.This ink printing is made paper diaper finished product on common PE making hole film base material, and the then outer test of committee, measures layer of ink performance 1, meets GB15979-2002 Disposable Sanitary Accessory hygienic standard; 2, after under fixed temperature and humidity condition, (25 DEG C/80%) places one week, layer of ink is unchanged; 3, drip in layer of ink with the aqueous solution of PH=6.5, picture and text disappear at once.
Embodiment 2, the wet aobvious water color ink of the special urine of a kind of baby paper diaper described in the present embodiment, it is added in agitation vat by the raw material of following parts by weight and obtains through mixing, grinding, stir:
Water soluble resin described in the present embodiment is the water soluble resin that Green spring (Xiamen) environmental protection tech materials company limited produces, solid content 47%, acid number 500, second-order transition temperature 30 DEG C, pH value about 8.5, viscosity 800mPa.s; Moistening flatting agent is 425, polyether siloxane copolymer, effective content 100%, viscosity is about 100mPa.s; Defoamer is foamex K8, the mixture of Aliphatic mineral oils, effective content 100%, viscosity is about 100mPa.s; Food dye is the Y14 lemon yellow pigment of Zhengzhou Tian Tong food ingredients company limited; Silane coupling agent is the KH-550 amino silicane coupling agent of Hangzhou boiling point chemical industry, molecular weight>=200, flash-point>=90 DEG C; Dispersion agent is the SN-DISPERSANT 5040, PH=7.0 ± 1 of Japanese Nuo Puke, effective content 50%, viscosity 800mPa.s; Thickening material is viscoPlus 3030, association type polyurethane thickener, effective content 55%, viscosity 2500mPa.s.Preparation method is, gets raw material according to described parts by weight, described water soluble resin is added agitation vat high-speed stirring (stirring velocity 800rpm), adds in water soluble resin simultaneously, stir described food dye, dispersion agent, silane coupling agent; Then with grinding plant, the mixture in agitation vat is carried out speed lapping; When fineness≤10 μm, grinding terminates, more described distilled water, moistening flatting agent, defoamer, thickening material are added agitation vat stirring at low speed (stirring velocity 400rpm), stirs; Finally, filter with 260 eye mesh screens, obtain the wet aobvious water color ink of urine.This ink printing is made paper diaper finished product on common PE making hole film base material, and the then outer test of committee, measures layer of ink performance 1, meets GB15979-2002 Disposable Sanitary Accessory hygienic standard; 2, after under fixed temperature and humidity condition, (25 DEG C/80%) places one week, layer of ink is unchanged; 3, drip in layer of ink with the aqueous solution of PH=6.5, picture and text disappear at once.
The above is only a preferred embodiment of the present invention, just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise of not departing from the present invention, can also carry out some improvement and modification to the present invention, these modifications and modification also fall in the protection domain of the claims in the present invention.

Claims (2)

1. the wet aobvious water color ink of the urine that baby paper diaper is special, is characterized in that: it comprises the raw material of following parts by weight:
Described water soluble resin, solid content 45 ~ 48%, acid number 300 ~ 600mgKOH/g, second-order transition temperature 20 ~ 40 DEG C, pH value 7.5 ~ 9.5, viscosity 500 ~ 1000mPa.s;
Described moistening flatting agent is polyether siloxane copolymer, effective content 100%, viscosity 50 ~ 300mPa.s;
Described defoamer is the mixture of fatty race mineral oil, effective content 100%, viscosity 50 ~ 300mPa.s;
Described thickening material is association type polyurethane thickener, effective content 50 ~ 60%, viscosity 2000 ~ 3000mPa.s;
Described silane coupling agent type is γ-aminopropyl triethoxysilane;
Described dispersion agent is polycarboxylate sodium's dispersion agent, pH=7.0 ± 1, effective content 50%, viscosity 500 ~ 1000mPa.s.
2. the urine that a baby paper diaper as claimed in claim 1 is special wets the preparation method of aobvious water color ink, comprise the steps: to get raw material according to parts by weight described in claim 1, described water soluble resin is added in agitation vat and stirs, described food dye, dispersion agent, silane coupling agent are added in water soluble resin, stirs; With grinding plant, the mixture in agitation vat is carried out speed lapping; After grinding terminates, more described distilled water, moistening flatting agent, defoamer, thickening material are added in agitation vat, stir; Finally, filter with 200 ~ 300 eye mesh screens, obtain the wet aobvious water color ink of urine.
CN201310753773.2A 2013-12-30 2013-12-30 Wet aobvious water color ink of urine that a kind of baby paper diaper is special and preparation method thereof Active CN103756413B (en)

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KR102076564B1 (en) * 2017-11-30 2020-02-14 김동규 Composite film to be changed color by ph and disposable diaper including the same
CN111995906A (en) * 2020-09-01 2020-11-27 福建琦峰科技有限公司 Printing ventilated membrane that urine wet discolours
CN115537064B (en) * 2022-09-27 2023-06-30 广东佳景科技股份有限公司 Gravure sterile water-based ink for breathable film of paper diaper, and preparation method and application thereof

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US8697003B2 (en) * 2009-12-14 2014-04-15 Kimberly-Clark Worldwide, Inc. Aqueous-triggered color-appearing inks
CN103330958B (en) * 2013-03-29 2016-05-18 佛山南宝高盛高新材料有限公司 A kind of urine present gum and preparation technology thereof

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