CN103637942B - Alcohol-free transparent perfume composition - Google Patents
Alcohol-free transparent perfume composition Download PDFInfo
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- CN103637942B CN103637942B CN201310630600.1A CN201310630600A CN103637942B CN 103637942 B CN103637942 B CN 103637942B CN 201310630600 A CN201310630600 A CN 201310630600A CN 103637942 B CN103637942 B CN 103637942B
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- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000002304 perfume Substances 0.000 title claims abstract description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 60
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000007908 nanoemulsion Substances 0.000 claims abstract description 42
- -1 polyoxyethylene Polymers 0.000 claims abstract description 34
- 239000004094 surface-active agent Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 22
- 239000010452 phosphate Substances 0.000 claims abstract description 21
- 238000013329 compounding Methods 0.000 claims abstract description 15
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 15
- 235000019437 butane-1,3-diol Nutrition 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical class CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 11
- 238000005352 clarification Methods 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 5
- 229940058015 1,3-butylene glycol Drugs 0.000 claims description 4
- 230000002421 anti-septic effect Effects 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- MGYUQZIGNZFZJS-KTKRTIGZSA-N 2-[2-[(z)-octadec-9-enoxy]ethoxy]ethanol Chemical group CCCCCCCC\C=C/CCCCCCCCOCCOCCO MGYUQZIGNZFZJS-KTKRTIGZSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 abstract description 7
- 239000000839 emulsion Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 239000000341 volatile oil Substances 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 229920000223 polyglycerol Polymers 0.000 abstract 2
- 229960004756 ethanol Drugs 0.000 description 23
- 235000021317 phosphate Nutrition 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000004530 micro-emulsion Substances 0.000 description 5
- 239000003643 water by type Substances 0.000 description 5
- GYCKQBWUSACYIF-UHFFFAOYSA-N Ethyl salicylate Chemical class CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- 230000035943 smell Effects 0.000 description 4
- 229940099259 vaseline Drugs 0.000 description 4
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 3
- 229930003268 Vitamin C Natural products 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 229940068939 glyceryl monolaurate Drugs 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- 239000011718 vitamin C Substances 0.000 description 3
- 235000019154 vitamin C Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 description 2
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical compound CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 229960003943 hypromellose Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- RKHQZMOCQHXUBC-UHFFFAOYSA-N phenol;potassium Chemical compound [K].OC1=CC=CC=C1 RKHQZMOCQHXUBC-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- GCXZDAKFJKCPGK-UHFFFAOYSA-N heptane-1,2-diol Chemical compound CCCCCC(O)CO GCXZDAKFJKCPGK-UHFFFAOYSA-N 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 238000000703 high-speed centrifugation Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention provides an alcohol-free transparent perfume composition which comprises nanoemulsion, water and other auxiliaries, wherein the nanoemulsion comprises the following materials in parts by weight: 5-20 parts of essential oil, 8-12 parts of polyoxyethylene surfactants, 5-8 parts of phosphate surfactants, 4-7 parts of polyglycerol ester surfactants, 0.5-1.2 parts of glycerol and 15-20 parts of water; and grain size of the nanoemulsion is 10 nm-100nm. According to the invention, transparent water-based perfume emulsion is formed by dispersing oil-soluble essential oil in water through compounding effect of the polyoxyethylene surfactants, the phosphate surfactants, and the polyglycerol ester surfactants, so that a problem that organic solvents such as alcohol are used as perfume solvents is avoided, thereby avoiding stimulus and harms on the skin; and nanoemulsion grain size in the nanoemulsion is distributed between 10 nm and 100nm, so that stability is good, and the nanoemulsion is prevented from breaking of emulsion.
Description
Technical field
The present invention relates to perfume area, specifically a kind of without the transparent perfume composition of ethanol.
Background technology
Nanoemulsions is proposed in nineteen forty-three by Schulman and Hoar the earliest, and its Theory and applications development is very rapid, has been widely used in the fields such as drug delivery, washing decontamination, chemical reaction medium and catalysis.Nano-emulsion is normally mixed by water, oil, surfactant and medium chain alcohol, spontaneously can form transparent and translucent dispersion, polar nonionic surfactants also can be utilized to obtain under the condition not adding alcohol.Nano-emulsion, compared with ordinary emulsion, has special character: interfacial tension is little, is generally 10
-2-10
-6mN/m; Micelle particle is very little, and diameter is about 10-100nm; Thermodynamics is more stable, can spontaneously be formed, and does not need the external world to provide energy, is separated lamination does not occur through high speed centrifugation; Appearance transparent or intimate transparent.
Traditional perfume is all solvent type product, and essence and flavoring agent is dissolved in ethanol or isopropyl alcohol becomes clear solution.Solvent-borne type perfume appearance looks elegant, preparing process are simple, the fast thus fragrance of the rear evaporation rate of sprinkling easily comes out, and compare and get consumer reception, be the main product in perfume always.But solvent-borne type perfume will use a large amount of ethanol and isopropyl alcohol, also bring many defects thus.Solvent itself, with the abnormal smells from the patient of oneself, although did deodorize process before using, always can not accomplish do not have abnormal smells from the patient completely.The ratio of solvent and spice is very greatly different, and also can impact the abnormal smells from the patient of spice even if leave a small amount of abnormal smells from the patient, odor type can change to some extent, makes troubles to the perfumery of product.Fragrance component is very complicated, and not each composition can both be dissolved completely among ethanol, and result causes the use of some spice when preparing perfume to be restricted, and perfumery can not be perfect.Because in product, ethanol content is high, so higher to the zest of skin.
At present, dehydrated alcohol perfume composition, majority is milky solution, owing to using exhibiting high surface activating agent, makes compositions viscosity larger; The fragrance of being released by the aroma materials existed in compositions is easily gone bad by solubilizing agent; The easy oxidation by air of the aroma materials existed in compositions, has a strong impact on the stability of compositions.
The patent No. be 5389607 United States Patent (USP) Microemulsion containing a perfuming concentrate and corresponding product disclose a kind of without the water miscible essence microemulsion of ethanol, it take Polyethylene Glycol as surfactant, polyglycerin ester and alkyl phosphate are cosurfactant, utilize microemulsion make essence well solubilising in cosmetics.But do not control the particle diameter of microemulsion, the stability of microemulsion can not be guaranteed.
Authorization Notice No. is that the Chinese patent " ethanol-free aqueous perfume composition " of CN1964691B discloses use 1,2-hexanediol or 1,2-heptandiol obtains ethanol-free aqueous perfume compositions as solvent, but said composition is only semi-transparent combination thing, is unfavorable for that making perfume uses.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and provide a kind of without the transparent perfume composition of ethanol.
A kind of without the transparent perfume composition of ethanol, comprise nano-emulsion, water and auxiliary agent; Described nano-emulsion comprises in composition by weight: 5 ~ 20 parts of quintessence oils, 8 ~ 12 parts of polyoxyethylene surfactants, 5 ~ 8 parts of phosphate type surfactant, 4 ~ 7 parts of polyglycereol esters surface active agents, 0.5 ~ 1.2 part of glycerol, 0.8 ~ 1.5 part of 1,3 butylene glycol and 15 ~ 20 parts of water; Described nano-emulsion particle diameter is 10 ~ 100nm.
Above-mentioned auxiliary agent is one or more in antiseptic, diluent, antioxidant, thickening agent, lubricant, coloring agent and humidizer.
The particle diameter of above-mentioned nano-emulsion is 20 ~ 60nm.
Above-mentioned polyoxyethylene surfactant is the one in fatty alcohol-polyoxyethylene ether or alkylphenol polyoxyethylene.
Above-mentioned phosphates surfactant is the one in alkyl phosphate, aliphatic alcohol polyethenoxy phosphate ester or alkylolamides phosphate ester.
Above-mentioned polyglycereol esters surface active agent is polyglyceryl fatty acid ester.
The above-mentioned preparation method without the transparent perfume composition of ethanol, comprises the following steps:
Step 1, prepare nano-emulsion, quintessence oil, polyoxyethylene surfactant and polyglycereol esters surface active agent are mixed to get solution A, by phosphate type surfactant, glycerol, 1,3-butanediol and water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, by auxiliary agent and water mixing, obtains compounding agent solution;
Step 3, mixes the nano-emulsion of step 1 with step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
The present invention compared with prior art its remarkable advantage is: first, utilize the complex role of polyoxyethylene, phosphate, polyglycerin ester three class surfactant that oil-soluble essential oil dispersion is formed transparent aqueous perfume nanoemulsions in water, solve the problem that organic solvents such as using ethanol makes perfume solvent, avoid the stimulation to skin and injury; The second, the nano-emulsion particle size distribution in nanoemulsions is at 10 ~ 100nm, and good stability, avoids nano-emulsion generation breakdown of emulsion.
Detailed description of the invention
Embodiment 1
Comprise in composition by weight without the transparent perfume composition of ethanol: 5 parts of quintessence oils, 8 parts of stearic alfin ethers of polyoxy second, 5 parts of alkylpolyoxyethylene phosphate esters, 4 part of four glyceryl monolaurate, 0.5 part of glycerol, 0.8 part of 1,3 butylene glycol, 2 parts of para hydroxybenzene potassium acid esters, 50 parts of deionized waters.
Step 1, prepare nano-emulsion, quintessence oil, the stearic alfin ether of polyoxy second and four glyceryl monolaurates are mixed to get solution A, by alkylpolyoxyethylene phosphate ester, glycerol, 1,3-butanediol and deionized water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, by para hydroxybenzene potassium acid esters and deionized water mixing, obtains compounding agent solution;
Step 3, is uniformly mixed the nano-emulsion of step 1 and step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
Embodiment 2
Comprise in composition by weight without the transparent perfume composition of ethanol: 20 parts of quintessence oils, 12 parts of stearic alfin ethers of polyoxy second, 8 parts of alkylpolyoxyethylene phosphate esters, 7 part of four glyceryl monolaurate, 1.2 parts of glycerol, 1.5 parts of 1,3 butylene glycols, 2 parts of methyl hydroxybenzoate, 1 part of sodium carboxymethyl cellulose, 100 parts of deionized waters.
Step 1, prepare nano-emulsion, quintessence oil, the stearic alfin ether of polyoxy second and four glyceryl monolaurates are mixed to get solution A, by alkylpolyoxyethylene phosphate ester, glycerol, 1,3-butanediol and deionized water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, mixes methyl hydroxybenzoate, sodium carboxymethyl cellulose and deionized water, obtains compounding agent solution;
Step 3, is uniformly mixed the nano-emulsion of step 1 and step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
Embodiment 3
Comprise in composition by weight without the transparent perfume composition of ethanol: 15 parts of quintessence oils, 10 parts of stearic alfin ethers of polyoxy second, 7 parts of alkylpolyoxyethylene phosphate esters, 6 part of four glyceryl monolaurate, 1 part of glycerol, 1 part of 1,3 butylene glycol, 2 parts of methyl hydroxybenzoate, 1 part of sodium carboxymethyl cellulose, 2 parts of vitamin Cs, 80 parts of deionized waters.
By above-mentioned raw materials at room temperature mix and blend 30 minutes, obtain without the transparent perfume composition of ethanol.
Step 1, prepare nano-emulsion, quintessence oil, the stearic alfin ether of polyoxy second and four glyceryl monolaurates are mixed to get solution A, by alkylpolyoxyethylene phosphate ester, glycerol, 1,3-butanediol and deionized water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, mixes methyl hydroxybenzoate, sodium carboxymethyl cellulose, vitamin C and deionized water, obtains compounding agent solution;
Step 3, is uniformly mixed the nano-emulsion of step 1 and step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
Embodiment 4
Comprise in composition by weight without the transparent perfume composition of ethanol: 12 parts of quintessence oils, 10 parts of Brij92s, 7 parts of lauryl alcohol phosphate esters, 6 part of six glyceryl monostearate, 0.9 part of glycerol, 1.2 parts of 1,3 butylene glycols, 3 parts of ethyl hydroxybenzoates, 1 part of vaseline, 2 parts of sodium carboxymethyl cellulose, 95 parts of deionized waters.
Step 1, prepare nano-emulsion, quintessence oil, the stearic alfin ether of polyoxy second and six glyceryl monostearates are mixed to get solution A, by lauryl alcohol phosphate ester, glycerol, 1,3-butanediol and deionized water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, mixes ethyl hydroxybenzoate, vaseline, sodium carboxymethyl cellulose and deionized water, obtains compounding agent solution;
Step 3, is uniformly mixed the nano-emulsion of step 1 and step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
Embodiment 5
Comprise in composition by weight without the transparent perfume composition of ethanol: 10 parts of quintessence oils, 9 parts of alkylpolyoxyethylenes, 7 parts of single Tryfac 5573s, 4 parts of DECAGLYCERYL MONOLAURATE, 0.8 part of glycerol, 1.2 part 1,3-butanediol, 3 parts of ethyl hydroxybenzoates, 1 part of vitamin C, 0.5 part of vaseline, 1 part of sodium carboxymethyl cellulose, 0.5 part of hypromellose, 0.5 part of hydroquinone, 88 parts of deionized waters
Step 1, prepare nano-emulsion, quintessence oil, alkylpolyoxyethylene and DECAGLYCERYL MONOLAURATE are mixed to get solution A, by single Tryfac 5573, glycerol, 1,3-butanediol and deionized water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, mixes ethyl hydroxybenzoate, vitamin C, vaseline, sodium carboxymethyl cellulose, hypromellose, hydroquinone and deionized water, obtains compounding agent solution;
Step 3, is uniformly mixed the nano-emulsion of step 1 and step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol.
Claims (4)
1. without the transparent perfume composition of ethanol, it is characterized in that: said composition is made up of nano-emulsion, water and auxiliary agent; Described nano-emulsion comprises in composition by weight: 5 ~ 20 parts of quintessence oils, 8 ~ 12 parts of polyoxyethylene surfactants, 5 ~ 8 parts of phosphate type surfactant, 4 ~ 7 parts of polyglycereol esters surface active agents, 0.5 ~ 1.2 part of glycerol, 0.8 ~ 1.5 part of 1,3 butylene glycol and 15 ~ 20 parts of water; Described nano-emulsion particle diameter is 10 ~ 100nm;
Wherein, polyoxyethylene surfactant is Brij92 or alkylpolyoxyethylene; Phosphate type surfactant is the one in alkylpolyoxyethylene phosphate ester, lauryl alcohol phosphate ester or single Tryfac 5573; Polyglycereol esters surface active agent is the one in four glyceryl monolaurates, six glyceryl monostearates or DECAGLYCERYL MONOLAURATE.
2. according to claim 1ly it is characterized in that without the transparent perfume composition of ethanol, described auxiliary agent is one or more in antiseptic, diluent, antioxidant, thickening agent, lubricant, coloring agent and humidizer.
3. according to claim 1ly it is characterized in that without the transparent perfume composition of ethanol, the particle diameter of described nano-emulsion is 20-60nm.
4. the preparation method without the transparent perfume composition of ethanol of any one of claims 1 to 3, comprises the following steps:
Step 1, prepare nano-emulsion, quintessence oil, polyoxyethylene surfactant and polyglycereol esters surface active agent are mixed to get solution A, by phosphate type surfactant, glycerol, 1,3-butanediol and water are mixed to get solution B, solution A are added drop-wise in solution B, and limit edged stirs, stop stirring to clarification, obtain nano-emulsion;
Step 2, formulation aid, by auxiliary agent and water mixing, obtains compounding agent solution;
Step 3, mixes the nano-emulsion of step 1 with step 2 compounding agent solution, obtains without the transparent perfume composition of ethanol;
Wherein, polyoxyethylene surfactant is Brij92 or alkylpolyoxyethylene; Phosphate type surfactant is the one in alkylpolyoxyethylene phosphate ester, lauryl alcohol phosphate ester or single Tryfac 5573; Polyglycereol esters surface active agent is the one in four glyceryl monolaurates, six glyceryl monostearates or DECAGLYCERYL MONOLAURATE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630600.1A CN103637942B (en) | 2013-06-30 | 2013-12-02 | Alcohol-free transparent perfume composition |
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|---|---|---|---|
| CN201310267200 | 2013-06-30 | ||
| CN2013102672009 | 2013-06-30 | ||
| CN201310267200.9 | 2013-06-30 | ||
| CN201310630600.1A CN103637942B (en) | 2013-06-30 | 2013-12-02 | Alcohol-free transparent perfume composition |
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| Publication Number | Publication Date |
|---|---|
| CN103637942A CN103637942A (en) | 2014-03-19 |
| CN103637942B true CN103637942B (en) | 2015-03-04 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023081742A1 (en) * | 2021-11-04 | 2023-05-11 | Coty Inc. | Ethanol-free fragrance chassis |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106727259A (en) * | 2017-03-17 | 2017-05-31 | 上海名仕新材料有限公司 | A kind of, perfume that storage stability high low to skin irritation and preparation method thereof |
| PL238164B1 (en) | 2018-06-27 | 2021-07-12 | Finea Spolka Z Ograniczona Odpowiedzialnoscia | Alcohol-free perfume and method of producing alcohol-free perfume |
| PL236231B1 (en) | 2018-06-27 | 2020-12-28 | Finea Spolka Z Ograniczona Odpowiedzialnoscia | Method of producing alcohol-free perfume |
| EP4355287A2 (en) | 2021-06-15 | 2024-04-24 | LVMH Recherche | Alcohol-free nanoemulsion perfume |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306418A (en) * | 1998-12-08 | 2001-08-01 | 弗门尼舍有限公司 | Transparent perfume compsn. |
| CN101664372A (en) * | 2009-10-12 | 2010-03-10 | 董萍 | Antioxidant network efficacy nanoemulsion externally used for skin and preparation method thereof |
| CN101801216A (en) * | 2007-08-06 | 2010-08-11 | 韩国食品研究院 | Nanoemulsion and nanoparticle containing plant essential oil and method of production thereof |
| CN101869539A (en) * | 2010-06-08 | 2010-10-27 | 董萍 | Desensitizing composite nano emulsion for sensitive skin repair and preparation method thereof |
-
2013
- 2013-12-02 CN CN201310630600.1A patent/CN103637942B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306418A (en) * | 1998-12-08 | 2001-08-01 | 弗门尼舍有限公司 | Transparent perfume compsn. |
| CN101801216A (en) * | 2007-08-06 | 2010-08-11 | 韩国食品研究院 | Nanoemulsion and nanoparticle containing plant essential oil and method of production thereof |
| CN101664372A (en) * | 2009-10-12 | 2010-03-10 | 董萍 | Antioxidant network efficacy nanoemulsion externally used for skin and preparation method thereof |
| CN101869539A (en) * | 2010-06-08 | 2010-10-27 | 董萍 | Desensitizing composite nano emulsion for sensitive skin repair and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023081742A1 (en) * | 2021-11-04 | 2023-05-11 | Coty Inc. | Ethanol-free fragrance chassis |
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| CN103637942A (en) | 2014-03-19 |
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