CN103613849B - 一种复合塑料编织材料 - Google Patents

一种复合塑料编织材料 Download PDF

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CN103613849B
CN103613849B CN201310615950.0A CN201310615950A CN103613849B CN 103613849 B CN103613849 B CN 103613849B CN 201310615950 A CN201310615950 A CN 201310615950A CN 103613849 B CN103613849 B CN 103613849B
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composite plastic
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raw material
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CN103613849A (zh
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戴之青
汤毅
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ANHUI ANYUAN PLASTIC Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
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  • Polymers & Plastics (AREA)
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Abstract

本发明公开了一种复合塑料编织材料，其特征在于，由下列重量份的原料通过配料、熔融、过滤、挤压出膜、水冷、分丝、拉丝、收卷等工序制成：聚丙烯100、线性低密度聚乙烯12-14、聚苯乙烯2-3、聚异丁烯1-1.5、苯胺甲基三乙氧基硅烷1-1.3、六偏磷酸钠0.8-1.0、甲基丙烯酸丁酯1.3-1.8、当归油0.1-0.2、助剂3-3.5；本发明配方简单，成本低，制成的塑料编织袋可有效的阻止紫外线光照所引起的氧化反应，解决了现有技术中包装袋使用寿命短的问题，而且本发明结实耐用，防滑、不破包，特别适宜远距离运输及出口。

Description

一种复合塑料编织材料
技术领域
本发明涉及化工技术领域，特别是一种复合塑料编织材料。
背景技术
塑料编织袋按主要材料构成分为聚丙烯袋、聚乙烯袋；按缝制方法分为缝底袋、缝边底袋。目前广泛应用于肥料、化工产品等物品的一种包装材料。其主要生产工艺是利用塑料原料经挤出薄膜、切割、单向拉伸为扁丝，经过经纬编织得到产品，一般称为编织袋。传统技术生产的聚丙烯扁丝编制的包装袋，耐候性差，在北方冬季容易出现发硬、发脆、脱膜、起皮、断裂等问题，在南方由于夏季气温高、光照强烈、紫外线穿透力强，容易导致编织袋老化、腐蚀、韧性差、强度低使用寿命短等问题，既浪费资源又污染环境。
发明内容
本发明的目的是提供一种复合塑料编织材料。
为了实现本发明的目的，本发明通过以下方案实施：
一种复合塑料编织材料，由下列重量份的原料通过配料、熔融、过滤、挤压出膜、水冷、分丝、拉丝、收卷等工序制成：聚丙烯100、线性低密度聚乙烯12-14、聚苯乙烯2-3、聚异丁烯1-1.5、苯胺甲基三乙氧基硅烷1-1.3、六偏磷酸钠0.8-1.0、甲基丙烯酸丁酯1.3-1.8、当归油0.1-0.2、助剂3-3.5；
所述助剂由下列重量份的原料制成：粘土20-24、明矾5-6、促进剂DM2-3、交联剂TAC2-3、抗氧剂10101-2、阳起石3-4、二茂铁2-3、吗啉1-2、1,6己二醇二丙烯酸酯5-7、邻苯二甲酸酯35-40、没食子酸丙酯3-4、绿茶粉1-2、薏仁油2-3、二硼化钒2-3、表儿茶素1-2；制备方法是将粘土、阳起石送入煅烧炉中在720-740℃下煅烧2-3小时，然后，取出，送入10-15%的盐酸溶液中浸泡2-3小时，过滤，得滤渣，用清水洗净，烘干、研磨成400-600目粉体；所得粉体与其它剩余成分混合，加热至60-70℃，搅拌反应40-50分钟，冷却，研磨成浆料，即得。
本发明的优异效果是：本发明配方简单，成本低，制成的塑料编织袋可有效的阻止紫外线光照所引起的氧化反应，解决了现有技术中包装袋使用寿命短的问题，而且本发明结实耐用，防滑、不破包，特别适宜远距离运输及出口。
具体实施方式
下面通过具体实例对本发明进行详细说明。
一种复合塑料编织材料，由下列重量份（公斤）的原料通过配料、熔融、过滤、挤压出膜、水冷、分丝、拉丝、收卷等工序制成：聚丙烯100、线性低密度聚乙烯12、聚苯乙烯2、聚异丁烯1、苯胺甲基三乙氧基硅烷1、六偏磷酸钠0.8、甲基丙烯酸丁酯1.3、当归油0.1、助剂3；
所述助剂由下列重量份（公斤）的原料制成：粘土20、明矾5、促进剂DM3、交联剂TAC2、抗氧剂10101、阳起石3、二茂铁2、吗啉1、1,6己二醇二丙烯酸酯5、邻苯二甲酸酯35、没食子酸丙酯3、绿茶粉1、薏仁油2、二硼化钒3、表儿茶素1；制备方法是将粘土、阳起石送入煅烧炉中在720-740℃下煅烧2-3小时，然后，取出，送入10-15%的盐酸溶液中浸泡2-3小时，过滤，得滤渣，用清水洗净，烘干、研磨成400-600目粉体；所得粉体与其它剩余成分混合，加热至60-70℃，搅拌反应40-50分钟，冷却，研磨成浆料，即得。
经测试，本发明生产的扁丝径向拉断力和纬向拉断力均大于800N/50mm，大大提高了扁丝的拉伸强度，杜绝了编织过程中的断丝问题。

Claims (1)

1.一种复合塑料编织材料，其特征在于，由下列重量份的原料通过配料、熔融、过滤、挤压出膜、水冷、分丝、拉丝、收卷工序制成：聚丙烯100、线性低密度聚乙烯12-14、聚苯乙烯2-3、聚异丁烯1-1.5、苯胺甲基三乙氧基硅烷1-1.3、六偏磷酸钠0.8-1.0、甲基丙烯酸丁酯1.3-1.8、当归油0.1-0.2、助剂3-3.5；
所述助剂由下列重量份的原料制成：粘土20-24、明矾5-6、促进剂DM2-3、交联剂TAC2-3、抗氧剂10101-2、阳起石3-4、二茂铁2-3、吗啉1-2、1,6己二醇二丙烯酸酯5-7、邻苯二甲酸酯35-40、没食子酸丙酯3-4、绿茶粉1-2、薏仁油2-3、二硼化钒2-3、表儿茶素1-2；制备方法是将粘土、阳起石送入煅烧炉中在720-740℃下煅烧2-3小时，然后，取出，送入10-15%的盐酸溶液中浸泡2-3小时，过滤，得滤渣，用清水洗净，烘干、研磨成400-600目粉体；所得粉体与其它剩余成分混合，加热至60-70℃，搅拌反应40-50分钟，冷却，研磨成浆料，即得。
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CN104609010A (zh) * 2014-12-25 2015-05-13 辽宁腾华塑料有限公司 防静电编织袋及其制备方法
CN105600093A (zh) * 2015-10-31 2016-05-25 贵州同益塑料制品有限公司 一种塑料编织袋及其制备方法
CN105348610A (zh) * 2015-11-10 2016-02-24 安徽安远塑胶股份有限公司 一种防滑、轻质编织袋复合材料及其制备方法
CN105400072A (zh) * 2015-12-01 2016-03-16 潜山县恒源塑业有限责任公司 一种防潮塑料编织袋用材料
CN105885237A (zh) * 2016-06-27 2016-08-24 安庆石油化工总厂联盟化工厂 一种防潮塑料编织袋
CN105924791A (zh) * 2016-06-28 2016-09-07 安庆石油化工总厂联盟化工厂 一种树脂混合制备的防潮编织袋
CN106243504A (zh) * 2016-08-23 2016-12-21 天津市旭辉恒远塑料包装股份有限公司 一种复合塑料编织布
CN107793638A (zh) * 2017-10-31 2018-03-13 遵义宏龙塑料有限责任公司 一种防虫蛀塑料编织袋
CN107793639A (zh) * 2017-10-31 2018-03-13 遵义宏龙塑料有限责任公司 一种防虫蛀塑料编织袋的生产方法
CN108003641A (zh) * 2017-12-10 2018-05-08 安徽安远塑胶股份有限公司 一种防滑落塑料编织袋
CN111978634A (zh) * 2020-08-18 2020-11-24 天津市久大塑料制品有限公司 一种防水防晒塑料编织袋

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CN102731914A (zh) * 2012-07-23 2012-10-17 安徽安远塑胶股份有限公司 一种用于制备抗老化塑料编织制品的新型组合物

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102731914A (zh) * 2012-07-23 2012-10-17 安徽安远塑胶股份有限公司 一种用于制备抗老化塑料编织制品的新型组合物

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