CN103601463A - Magnesium cement inorganic heat insulation material and preparation method thereof - Google Patents

Magnesium cement inorganic heat insulation material and preparation method thereof Download PDF

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Publication number
CN103601463A
CN103601463A CN201310541416.XA CN201310541416A CN103601463A CN 103601463 A CN103601463 A CN 103601463A CN 201310541416 A CN201310541416 A CN 201310541416A CN 103601463 A CN103601463 A CN 103601463A
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heat insulation
insulation material
weight
inorganic heat
magnesium
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CN201310541416.XA
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CN103601463B (en
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马小翠
王雪
丁益民
张劲
张炎
丁晓云
陆文雄
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Shanghai Fupei New Material Technology Co ltd
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SHANGHAI YUPEI SPECIAL BUILDING MATERIAL CO Ltd
University of Shanghai for Science and Technology
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Abstract

The invention relates to a magnesium cement inorganic heat insulation material and a preparation method thereof. The magnesium cement inorganic heat insulation material comprises the following components in parts by weight: 1000 parts by weight of magnesium oxide, 800 parts by weight of magnesium chloride solution, 800-1400 parts by weight of water-repellent vitreous micro-beads, 5-15 parts by weight of latex powder, 5-25 parts by weight of sepiolite fiber, 50-150 parts by weight of fly ash, 2-5 parts by weight of sodium fluorosilicate, 2-5 parts by weight of sodium hexametaphosphate, 4-8 parts by weight of water-retaining agent, 25-50 parts by weight of phosphoric acid and 25-70 parts by weight of sodium silicate. When the magnesium cement inorganic heat insulation material is used, the powder materials are put into a stirring machine together for uniform stirring, then the magnesium chloride solution is added for stirring, after slurry is uniformly stirred, the light aggregate water-repellent vitreous micro-beads are added for continuously stirring for 3-5min, and finally phosphoric acid and sodium silicate are added for uniform stirring. The magnesium cement inorganic heat insulation material has the advantages of relatively good fire prevention and heat insulation performances, relatively high strength and excellent anti-dehalogenation capability.

Description

Magnesium cement inorganic heat insulation material and preparation method thereof
Technical field
The present invention relates to a kind of magnesium cement inorganic heat insulation material and preparation method thereof.
Background technology
Building heat preservation lagging material can be used for reducing the thermosteresis of architecture indoor external environment, effectively reduce building air conditioning load, it is the important component part that builds energy saving building and implement reducing energy consumption, but because building heat insulation material exists water-repellancy or the poor defect of fire line, thereby limited its further development and application.Therefore, urgently develop intensity high, moistureproof, do not fire, environmentally friendly novel building energy-saving and heat-insulating material.
Along with updating of the various performances of magnesia cement, the purposes of magnesia cement is also more and more extensive.Because the production technique of magnesia cement is simply too much compared with other silicate cements, do not need sintering, do not need to be dried, greatly reduce energy consumption, and the application of magnesia cement solved many environmental problems, be genuine green building productions.The magnesia cement goods of producing by various method of modifying, except having the premium properties of magnesium cement itself, also possessed many other excellent performances, this has also determined the popularity of its Application Areas, can manufacture various building materials, decoration, sound insulation, refractory materials.
Summary of the invention
One of object of the present invention is to provide a kind of magnesium cement inorganic heat insulation material.The present invention take the good magnesium oxide of extremely fireproof insulating property and magnesium chloride to have prepared a kind of magnesium cement inorganic heat insulation material as main gelatinous material.
Two of object of the present invention is to provide the preparation method of this lagging material.
The invention solves the shortcomings such as the water-fast resistivity against fire of existing lagging material is poor, strengthened the performance of existing magnesite material surface halide accumulation resistance simultaneously, become one of effective means of building energy conservation, realized energy-conservation and double effects environmental protection.
A magnesium cement inorganic heat insulation material, is characterized in that the composition of this lagging material and parts by weight are:
Magnesium oxide 1000 weight parts; Magnesium chloride solution 800 weight parts;
Hydrophobic glass bead 800-1400 weight part: latex powder 5-15 weight part;
Sepiolite fibre 5-25 weight part; Flyash 50-150 weight part;
Sodium Silicofluoride 2-5 weight part; Sodium hexametaphosphate 99 2-5 weight part;
Water-holding agent 4-8 weight part; Phosphoric acid 25-50 weight part;
Water glass 25-70 weight part.
Above-mentioned magnesium oxide is light calcined magnesia, content of magnesia >=85% wherein, fineness 180-200 order.
Above-mentioned magnesium chloride solution is the magnesium chloride solution of 27 ° of B é (degree Beaume), and wherein sodium-chlor and KCE content are less than 1%.
Above-mentioned hydrophobic glass bead is environmental protection inorganic light heat-insulating material, and its particle diameter is 50-70 order.
Above-mentioned environmental protection inorganic light heat-insulating material is processed through silylation hydrophober.
Above-mentioned latex powder is any in vinylbenzene-vinylformic acid, acrylate, vinyl acetate between to for plastic-ethene, and its fineness is 100 orders.
Above-mentioned flyash is second class powered coal ash.
Above-mentioned Sodium Silicofluoride is technical grade Sodium Silicofluoride.
Above-mentioned Sodium hexametaphosphate 99 is technical grade Sodium hexametaphosphate 99.
Above-mentioned water-holding agent is at least one in Natvosol, hydroxyethylmethyl-cellulose, Vltra tears.
Above-mentioned phosphoric acid is PHOSPHORIC ACID TECH.GRADE, wherein phosphorus acid content >=85%.
Above-mentioned water glass is the ordinary liquid water glass of 50 ° of B é.
A kind of method of preparing above-mentioned magnesium cement inorganic heat insulation material; the concrete steps that it is characterized in that the method are: first magnesium oxide, latex powder, sepiolite fibre, flyash, Sodium Silicofluoride, Sodium hexametaphosphate 99, water-holding agent are together dropped in stirrer and stirred; then add magnesium chloride solution to stir; treat that slurry stirs; add again light-weight aggregate hydrophobic glass bead to continue to stir 3-5min; finally add phosphoric acid and water glass; stir, obtain the method for magnesium cement inorganic heat insulation material.
Compared with prior art, the magnesium cement inorganic heat insulation material that prepared by the present invention has following features:
1. heat insulating: because magnesium cement inorganic heat insulation material has the filling of inorganic light-weight aggregate hydrophobic glass bead, thermal conductivity is little, and thermal and insulating performance is good.
2. fire protection flame retarding: MgO, MgCl 2be all non-flammable, and in goods hydrate, mass crystallization water can stop and lights, what magnesium cement inorganic heat insulation material was used in addition is inorganic materials entirely, has further improved the fire resistance of material.
3. water-fast, surface halide accumulation resistance: be added with water-fast, surface halide accumulation resistance properties-correcting agent in magnesium cement inorganic heat insulation material, significantly improved the water-fast surface halide accumulation resistance ability of this material.
4. environmental protection: it is high, pollution-free, radiationless that magnesium cement inorganic heat insulation material has intensity is real green material.
Embodiment
After now specific embodiments of the invention being described in.
Embodiment 1
Get magnesium oxide 1000g, latex powder 6g, sepiolite fibre 8g; flyash 55g; Sodium Silicofluoride 2g, Sodium hexametaphosphate 99 3g, water-holding agent 6g; together drop in stirrer and stir; then add 800g magnesium chloride solution to stir, treat that slurry stirs, then add 850g light-weight aggregate hydrophobic glass bead to continue to stir 3-5min; finally add phosphoric acid 30g and water glass 70g, stir and can obtain magnesium cement inorganic heat insulation material.The dry apparent density of this magnesium cement inorganic heat insulation material is 390Kg/m 3, ultimate compression strength is 1.2MPa, combustionproperty rank meets the A level requirement of GB8624 regulation.
 
Embodiment 2
Get magnesium oxide 1000g, latex powder 12g, sepiolite fibre 25g; flyash 135g; Sodium Silicofluoride 5g, Sodium hexametaphosphate 99 4g, water-holding agent 7g; together drop in stirrer and stir; then add 800g magnesium chloride solution to stir, treat that slurry stirs, then add 1350g light-weight aggregate hydrophobic glass bead to continue to stir 3-5min; finally add phosphoric acid 35g and water glass 65g, stir and can obtain magnesium cement inorganic heat insulation material.The dry apparent density of this magnesium cement inorganic heat insulation material is 355 Kg/m 3, ultimate compression strength is 0.75 MPa, combustionproperty rank meets the A level requirement of GB8624 regulation.
 
Embodiment 3
Get magnesium oxide 1000g, latex powder 8g, sepiolite fibre 15g; flyash 90g; Sodium Silicofluoride 4g, Sodium hexametaphosphate 99 4g, water-holding agent 5g; together drop in stirrer and stir; then add 800g magnesium chloride solution to stir, treat that slurry stirs, then add 1000g light-weight aggregate hydrophobic glass bead to continue to stir 3-5min; finally add phosphatase 24 5g and water glass 55g, stir and can obtain magnesium cement inorganic heat insulation material.The dry apparent density of this magnesium cement inorganic heat insulation material is 370 Kg/m 3, ultimate compression strength is 0.98MPa, combustionproperty rank meets the A level requirement of GB8624 regulation.

Claims (13)

1. a magnesium cement inorganic heat insulation material, is characterized in that the composition of this lagging material and parts by weight are:
Magnesium oxide 1000 weight parts; Magnesium chloride solution 800 weight parts;
Hydrophobic glass bead 800-1400 weight part: latex powder 5-15 weight part;
Sepiolite fibre 5-25 weight part; Flyash 50-150 weight part;
Sodium Silicofluoride 2-5 weight part; Sodium hexametaphosphate 99 2-5 weight part;
Water-holding agent 4-8 weight part; Phosphoric acid 25-50 weight part;
Water glass 25-70 weight part.
2. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described magnesium oxide is light calcined magnesia, content of magnesia >=85% wherein, fineness 180-200 order.
3. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described magnesium chloride solution is the magnesium chloride solution of 27 ° of B é (degree Beaume), and wherein sodium-chlor and KCE content are less than 1%.
4. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described hydrophobic glass bead is environmental protection inorganic light heat-insulating material, and its particle diameter is 50-70 order.
5. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described environmental protection inorganic light heat-insulating material is through the processing of silylation hydrophober.
6. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described latex powder is any in vinylbenzene-vinylformic acid, acrylate, vinyl acetate between to for plastic-ethene, and its fineness is 100 orders.
7. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described flyash is second class powered coal ash.
8. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described Sodium Silicofluoride is technical grade Sodium Silicofluoride.
9. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that described Sodium hexametaphosphate 99 is technical grade Sodium hexametaphosphate 99.
10. magnesium cement inorganic heat insulation material according to claim 1, is characterized in that, described water-holding agent is at least one in Natvosol, hydroxyethylmethyl-cellulose, Vltra tears.
11. magnesium cement inorganic heat insulation materials according to claim 1, is characterized in that described phosphoric acid is PHOSPHORIC ACID TECH.GRADE, wherein phosphorus acid content >=85%.
12. magnesium cement inorganic heat insulation materials according to claim 1, is characterized in that described water glass is the ordinary liquid water glass of 50 ° of B é.
Prepare according to the method for the magnesium cement inorganic heat insulation material described in any one in claim 1-12 for 13. 1 kinds; the concrete steps that it is characterized in that the method are: first magnesium oxide, latex powder, sepiolite fibre, flyash, Sodium Silicofluoride, Sodium hexametaphosphate 99, water-holding agent are together dropped in stirrer and stirred; then add magnesium chloride solution to stir; treat that slurry stirs; add again light-weight aggregate hydrophobic glass bead to continue to stir 3-5min; finally add phosphoric acid and water glass; stir, obtain the method for magnesium cement inorganic heat insulation material.
CN201310541416.XA 2013-11-06 2013-11-06 Magnesium cement inorganic heat insulation material and preparation method thereof Active CN103601463B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105520639A (en) * 2016-01-25 2016-04-27 中山昊天节能科技有限公司 Automatic on-off type air energy water dispenser
CN105777026A (en) * 2016-03-10 2016-07-20 徐杰 Heat-preservation material for building external wall and preparation method for heat-preservation material
CN107602055A (en) * 2017-10-17 2018-01-19 陈合华 A kind of preparation method of high breaking strength type fireproof heated board
CN108383479A (en) * 2018-04-09 2018-08-10 合肥聪亨新型建材科技有限公司 A kind of heat-insulating material and preparation method thereof for Cryo Heat Insulation pipeline

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101205432A (en) * 2006-12-19 2008-06-25 唐小菊 Heat insulating coatings and preparation thereof
CN102010174A (en) * 2010-11-12 2011-04-13 中国科学院青海盐湖研究院 Thermal insulation mortar
CN102020453A (en) * 2010-10-08 2011-04-20 眭良 High-strength inorganic magnesium cement building template and production method thereof
CN102850034A (en) * 2012-09-29 2013-01-02 江苏尼高科技有限公司 Chlorine magnesium cement compound foaming insulation board and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101205432A (en) * 2006-12-19 2008-06-25 唐小菊 Heat insulating coatings and preparation thereof
CN102020453A (en) * 2010-10-08 2011-04-20 眭良 High-strength inorganic magnesium cement building template and production method thereof
CN102010174A (en) * 2010-11-12 2011-04-13 中国科学院青海盐湖研究院 Thermal insulation mortar
CN102850034A (en) * 2012-09-29 2013-01-02 江苏尼高科技有限公司 Chlorine magnesium cement compound foaming insulation board and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105520639A (en) * 2016-01-25 2016-04-27 中山昊天节能科技有限公司 Automatic on-off type air energy water dispenser
CN105777026A (en) * 2016-03-10 2016-07-20 徐杰 Heat-preservation material for building external wall and preparation method for heat-preservation material
CN107602055A (en) * 2017-10-17 2018-01-19 陈合华 A kind of preparation method of high breaking strength type fireproof heated board
CN108383479A (en) * 2018-04-09 2018-08-10 合肥聪亨新型建材科技有限公司 A kind of heat-insulating material and preparation method thereof for Cryo Heat Insulation pipeline

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Effective date of registration: 20161025

Address after: 201804 Shanghai city Jiading District Xie Road No. 1000

Patentee after: Shanghai Yupei Special Building Material Co.,Ltd.

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Patentee before: Shanghai University

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Effective date of registration: 20180816

Address after: 201804 J227 8, No. 1112, hang Gui Road, Anting Town, Jiading District, Shanghai.

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Address after: Building 3, No. 75 Hengle Road, Waigang Town, Jiading District, Shanghai, June 2018

Patentee after: Shanghai fupei New Material Technology Co.,Ltd.

Address before: 201804 J227 8, No. 1112, hang Gui Road, Anting Town, Jiading District, Shanghai.

Patentee before: SHANGHAI FODEV NEW MATERIAL TECHNOLOGY CO.,LTD.

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