CN103583573A - Crop growth accelerant and preparation method thereof - Google Patents

Crop growth accelerant and preparation method thereof Download PDF

Info

Publication number
CN103583573A
CN103583573A CN201310576846.5A CN201310576846A CN103583573A CN 103583573 A CN103583573 A CN 103583573A CN 201310576846 A CN201310576846 A CN 201310576846A CN 103583573 A CN103583573 A CN 103583573A
Authority
CN
China
Prior art keywords
plant growth
growth promoter
water
preparation
crop growth
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201310576846.5A
Other languages
Chinese (zh)
Other versions
CN103583573B (en
Inventor
王薇
袁亮
李洪杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DEZHOU COUNTY AGRICULTURAL SCIENCE RESEARCH INSTITUTE
Original Assignee
DEZHOU COUNTY AGRICULTURAL SCIENCE RESEARCH INSTITUTE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DEZHOU COUNTY AGRICULTURAL SCIENCE RESEARCH INSTITUTE filed Critical DEZHOU COUNTY AGRICULTURAL SCIENCE RESEARCH INSTITUTE
Priority to CN201310576846.5A priority Critical patent/CN103583573B/en
Publication of CN103583573A publication Critical patent/CN103583573A/en
Application granted granted Critical
Publication of CN103583573B publication Critical patent/CN103583573B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention provides a crop growth accelerant suitable for a water and fertilizer integration system and a preparation method of the crop growth accelerant. The crop growth accelerant is mainly prepared from potassium tripolyphosphate, glycosaminoglycan, maltose oligosaccharide, ammonium tartrate, indole-3-butyric acid potassium, methyl alcohol and water. The crop growth accelerant provided by the invention is water soluble liquid, can be directly applied in a drop irrigation system, a spray irrigation system or a microspray irrigation system, is added into water according to certain proportion, and is applied to the crop along with the system. The crop growth accelerant takes the methyl alcohol as a solvent and substances like potassium tripolyphosphate as an organic solute, and the crop growth accelerant suitable for the water and fertilizer integration system is prepared through the steps of pH regulating, heating and the like. Tests show that the crop growth accelerant has an excellent accelerating effect on the crop growth, the root activity is improved, the utilization ratio of water and fertilizer and the crop yield are remarkably increased, and secondary pollution is avoided.

Description

A kind of plant growth promoter and preparation method thereof
Technical field
The invention belongs to agricultural cience and farming techniques field, be specifically related to a kind of plant growth promoter, Preparation Method And The Use.
Background technology
The chemical fertilizer utilization ratio of China is generally lower, and nitrogenous fertilizer average utilization is in 30% left and right, and phosphate fertilizer this season availability is in 25% left and right, and potassium utilization rate is in 50% left and right, and China is the country of a water resource famine simultaneously.The scientific worker of China has carried out large quantity research to improving the methods of water and fertilizer utilization, has obtained good effect.Particularly in recent years, along with the deep development of land transformation, Labor Transfer, agriculture industrialization, the Ministry of Agriculture widelys popularize the Integration of Water into Fertilizer, has promoted the raising of water and utilization rate of fertilizer, save labour and production cost, and promote the raising of China's crop yield.Yet; only rely on water and fertilizer compounding application still can not reach best effect of increasing production; also need fully to excavate and bring into play the productive potential of crop itself; plant growth promoter be the production capacity that can promote crop itself; realize moisture, nutrient supply is coordinated mutually with plant growth; not only crop yield can be improved, also liquid manure utilization ratio, protection of the environment can be increased substantially.
Abroad, particularly the water soluble fertilizer effect of Israel, Norway is very outstanding, its technological core has been used plant growth promoter exactly, the ,Zhong Hua company of MARUBENI of Japan, the second largest Nong Hua HELENA of service company of the U.S. all have a large amount of plant growth promoter technology, but because applying for a patent, enterprise needs information disclosure, enterprise scarcely applies for a patent, and only in inside, uses these technology.China to the research and development of plant growth promoter still in the starting stage, development with the intensive management on land transformation and farm, water-fertilizer integral is inexorable trend, plant growth promoter will be used widely safely and efficiently, but the plant growth promoter that does not also match with the Integration of Water into Fertilizer in the market, is connected mutually.
Summary of the invention
The object of this invention is to provide a kind of plant growth promoter that is applicable to water-fertilizer integral system and preparation method thereof.
Plant growth promoter of the present invention, is mainly prepared from by weight the ratio of 10:1-5:2-4:5-10:2-4:5-16.5:50-82.5 by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water.
Preferably, plant growth promoter of the present invention, is mainly prepared from by weight the ratio of 10:2-4:2.5-3.5:6-8:2.5-3.5:7-12:60-75 by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water.
Preferred, plant growth promoter of the present invention, is mainly prepared from by weight the ratio of 10:3:3:7:3:8-10:65-70 by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water.
The preparation method of plant growth promoter of the present invention, mainly comprises the steps:
The preparation of A, solvent: the methanol aqueous solution that compound concentration is 10%-20%;
The preparation of B, organic solute: get in proportion PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, after mixing, obtain organic solute;
The preparation of C, plant growth promoter: solvent described in 100 weight portion steps A is joined in reactor, slowly add while stirring organic solute described in the step B of 20-33 weight portion, after continuous stirring 10-15min, it is 6-8 that the inorganic acid that is 0.5%-1% by concentration or inorganic base regulate pH, continue to stir 5-10min, then be slowly heated to while stirring after 50 ℃-60 ℃, continue 1-3 hour, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
Preferably, described inorganic acid is selected from a kind of in hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid.
Preferably, described inorganic base is selected from a kind of in sodium hydroxide, potassium hydroxide, sodium carbonate, potash, saleratus, sodium bicarbonate.
The present invention also provides the application of described plant growth promoter in water-fertilizer integral system.
According to above-mentioned application, in described plant growth promoter and water-fertilizer integral system, the part by weight of water is 0.5-1:1000.
Plant growth promoter of the present invention is water-soluble liquid, can directly apply in drip irrigation and spray irrigation, micro-sprinkler irrigation system, add to by a certain percentage in water, with systemic application in crop, during use, in this plant growth promoter and system, the part by weight of water is 0.5-1:1000, and before use, this plant growth promoter should seal preservation.
The present invention be take methanol solution as solvent, take the materials such as PTPP as organic solute, is applicable to the plant growth promoter of water-fertilizer integral system through step preparations such as pH adjusting and heating.Production process is without special solvent, temperature required gentleness, and energy consumption is low, good stability, safety and environmental protection.Test shows, plant growth promoter of the present invention has good facilitation to plant growth, can improve improving activity of root system, significantly improves water and fertilizer utilization and crop yield, has avoided secondary pollution.
Embodiment
By following embodiment and test example, can understand better the present invention.
embodiment 1
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 10% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:1:2:5:2 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 20 weight portions, after continuous stirring 10min, the sulphur acid for adjusting pH that is 0.5% by concentration is 6, continues to stir 5min, is then slowly heated to while stirring after 50 ℃, continue 1 hour, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
embodiment 2
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 20% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:5:4:10:4 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 33 weight portions, after continuous stirring 15min, it is 8 that the sodium hydroxide that is 1% by concentration regulates pH, continues to stir 10min, is then slowly heated to while stirring after 60 ℃, continue 3 hours, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
embodiment 3
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 12% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:2:2.5:6:2.5 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 25 weight portions, after continuous stirring 12min, the salt acid for adjusting pH that is 0.6% by concentration is 6.5, continues to stir 6min, is then slowly heated to while stirring after 52 ℃, continue 1.5 hours, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
embodiment 4
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 18% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:4:3.5:8:3.5 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 30 weight portions, after continuous stirring 14min, it is 7.5 that the potassium hydroxide that is 0.8% by concentration regulates pH, continues to stir 8min, is then slowly heated to while stirring after 58 ℃, continue 2.5 hours, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
embodiment 5
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 15% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:3:3:7:3 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 28 weight portions, after continuous stirring 13min, the phosphorus acid for adjusting pH that is 0.75% by concentration is 6.8, continues to stir 7.5min, is then slowly heated to while stirring after 55 ℃, continue 2 hours, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
embodiment 6
Implementation step is as follows:
The preparation of A, solvent
Compound concentration is 17.5% methanol aqueous solution.
The preparation of B, organic solute
After the ratio of 10:3.5:2.8:8.5:3.8 mixes by weight by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, obtain organic solute.
The preparation of C, plant growth promoter
Solvent prepared by 100 weight portion steps A joins in reactor, slowly add while stirring the organic solute of 29.5 weight portions, after continuous stirring 13.5min, it is 7.9 that the potash that is 0.85% by concentration regulates pH, continues to stir 9min, is then slowly heated to while stirring after 59 ℃, continue 2.6 hours, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
test example 1:the impact of plant growth promoter of the present invention on Maize Seedling improving activity of root system
Utilize sand culture test to study the impact of described plant growth promoter on Seedling Root Systems In Maize vigor.Conventional contrast (CK) and 4 processing of plant growth promoter of the present invention (C-1, C-2, C-3) are established in test, and C-1, C-2, C-3 are respectively the plant growth promoter of the water-fertilizer integral system that is applicable to of embodiment 1,2,3 preparations, repeat 6 times.First quartz sand is cleaned with clear water, put into stainless steel pallet, keep certain humidity, corn kernel is put into dish, with wet cloth, cover on it, under the condition of 25 ℃ of temperature, grow seedlings.When corn sprouts while growing to 3-5cm, corn is taken out and puts into the cultivation cup that fills with quartz sand, water concentration every day and be 0.2% plant growth promoter 25 mL or CK and water 25 mL water.When corn grows to 20 cm left and right, take out root system, with clear water, clean, employing TTC method (list of references a: hero. by " TTC " method (red tetrazolium), measure vigor and the application [J] thereof of wheat root and pollen, Plant Physiology Communications, the 3rd phase of nineteen eighty-two.) measure the improving activity of root system of corn.
Its result of the test is listed in the table below in 1.
Table 1: Root Activity in Maize (mg/gh, TTC method)
Process Improving activity of root system
CK 0.942
C-1 1.330
C-2 1.374
C-3 1.351
Above-mentioned result of the test shows, contrasts and compares with routine, and plant growth promoter of the present invention can significantly improve the improving activity of root system of Maize Seedling, and C-1, C-2, C-3 exceed 41.2%, 45.8% and 43.4% than contrast respectively.
test example 2: add the impact of described plant growth promoter on corn yield and yield component
Test arranges 4 processing and (processes 1: conventional liquid manure is processed; Process 2: conventional liquid manure+C-1; Process 3: conventional liquid manure+C-2; Process 4: conventional liquid manure+C-3.Plant growth promoter is 1:1500 with the ratio of watering the water yield), community area 50m 2.Each is processed irrigation quantity and is 3.6Dun/ community, and fertilizing amount is 12kgN, 4kgP 2o 5, 8kgK 2o, fertilizer variety is urea, diammonium phosphate and potassium chloride.Each is processed and is microspray irrigation (oblique 5 holes), and water and fertilizer use respectively 50% at Maize at Seedling Stage and typhon mouth phase.
Table 2: corn yield and constituent element
Process Grain yield (kg/ mu) Grain number per spike 100-grain weight (g)
CK 522.4 338 18.60
Process 1 578.6 252 18.84
Process 2 610.1 277 19.05
Process 3 591.7 263 18.82
Above-mentioned result of the test: compare with conventional treatment, use grain number per spike, 100-grain weight and grain yield that plant growth promoter of the present invention can significantly increase corn.Process 1,2,3 corn yield contrast increase by 10.8%, 16.8% and 13.3% respectively.
test example 3: add the impact of described plant growth promoter on Ginger Yield
This test is carried out in Qingzhou City Dong Xia town, and test arranges 4 processing and (processes 1: conventional liquid manure is processed; Process 2: conventional liquid manure+C-1; Process 3: conventional liquid manure+C-2; Process 4: conventional liquid manure+C-3.Plant growth promoter is 1:1000 with the ratio of watering the water yield), each processes 3 row (line width: 0.75m * row is long: 20 meters) ginger, repeats 3 times.The irrigation quantity of every row is 1 ton/time, and liquid manure is together used, and uses altogether 3 times, and each fertilizing amount is 8kgN, 4kgP 2o 5, 4kgK 2o, fertilizer variety is urea, diammonium phosphate and potassium chloride.
The impact of table 3 plant growth promoter on Ginger Yield
Process Output (kg/ mu)
CK 8047
Process 1 10190
Process 2 11508
Process 3 10924
Compare with conventional treatment, use the output that plant growth promoter of the present invention can significantly increase ginger.Process 1,2,3 Ginger Yield contrast increase by 26.6%, 43.0% and 35.8% respectively.
As can be seen here, in the situation that fertilizer amount is identical, applying plant growth promoter of the present invention can significantly increase maize grain yield and Ginger Yield.

Claims (8)

1. a plant growth promoter, it is characterized in that, mainly by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water, by weight the ratio of 10:1-5:2-4:5-10:2-4:5-16.5:50-82.5, be prepared from.
2. plant growth promoter as claimed in claim 1, it is characterized in that, mainly by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water, by weight the ratio of 10:2-4:2.5-3.5:6-8:2.5-3.5:7-12:60-75, be prepared from.
3. plant growth promoter as claimed in claim 2, is characterized in that, mainly by PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate, indolebutyric acid potassium, first alcohol and water, by weight the ratio of 10:3:3:7:3:8-10:65-70, is prepared from.
4. the preparation method of plant growth promoter as described in claim 1-3 any one, is characterized in that, mainly comprises the steps:
The preparation of A, solvent: the methanol aqueous solution that compound concentration is 10%-20%;
The preparation of B, organic solute: get in proportion PTPP, glycosaminoglycan, oligomeric maltose, ammonium tartrate and indolebutyric acid potassium, after mixing, obtain organic solute;
The preparation of C, plant growth promoter: solvent described in 100 weight portion steps A is joined in reactor, slowly add while stirring organic solute described in the step B of 20-33 weight portion, after continuous stirring 10-15min, it is 6-8 that the inorganic acid that is 0.5%-1% by concentration or inorganic base regulate pH, continue to stir 5-10min, then be slowly heated to while stirring after 50 ℃-60 ℃, continue 1-3 hour, then from discharge port, emit the liquid reactor, to be cooled to room temperature, obtain described plant growth promoter.
5. the preparation method of plant growth promoter as claimed in claim 4, is characterized in that, described inorganic acid is selected from a kind of in hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid.
6. the preparation method of plant growth promoter as claimed in claim 4, is characterized in that, described inorganic base is selected from a kind of in sodium hydroxide, potassium hydroxide, sodium carbonate, potash, saleratus, sodium bicarbonate.
7. the application of plant growth promoter in water-fertilizer integral system as described in claim 1-3 any one.
8. application as claimed in claim 7, is characterized in that, in described plant growth promoter and water-fertilizer integral system, the part by weight of water is 0.5-1:1000.
CN201310576846.5A 2013-11-19 2013-11-19 Crop growth accelerant and preparation method thereof Expired - Fee Related CN103583573B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310576846.5A CN103583573B (en) 2013-11-19 2013-11-19 Crop growth accelerant and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310576846.5A CN103583573B (en) 2013-11-19 2013-11-19 Crop growth accelerant and preparation method thereof

Publications (2)

Publication Number Publication Date
CN103583573A true CN103583573A (en) 2014-02-19
CN103583573B CN103583573B (en) 2015-05-13

Family

ID=50074062

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310576846.5A Expired - Fee Related CN103583573B (en) 2013-11-19 2013-11-19 Crop growth accelerant and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103583573B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106171413A (en) * 2016-07-12 2016-12-07 保山市兴邦农业发展有限公司 Hylocereus undatus treelet Cultivate administration method
CN107324878A (en) * 2017-07-07 2017-11-07 安徽誉秀农业科技有限公司 A kind of crop growth accelerant
CN109169588A (en) * 2018-08-28 2019-01-11 倪晓燕 A kind of promotion crop growthing development method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850141A (en) * 2012-10-19 2013-01-02 新疆农业科学院土壤肥料与农业节水研究所 Multifunctional biogas slurry fertilizer for fruit trees
CN102919247A (en) * 2012-10-31 2013-02-13 四川国光农化股份有限公司 Plant growth adjustment composition containing 6-benayl aminopurine
CN102992902A (en) * 2012-11-30 2013-03-27 王正泽 Method for preparing plant growth promotor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102850141A (en) * 2012-10-19 2013-01-02 新疆农业科学院土壤肥料与农业节水研究所 Multifunctional biogas slurry fertilizer for fruit trees
CN102919247A (en) * 2012-10-31 2013-02-13 四川国光农化股份有限公司 Plant growth adjustment composition containing 6-benayl aminopurine
CN102992902A (en) * 2012-11-30 2013-03-27 王正泽 Method for preparing plant growth promotor

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
杜广红等: "不同施肥处理对土壤微生物学特性和作物产量的影响", 《中国土壤与肥料》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106171413A (en) * 2016-07-12 2016-12-07 保山市兴邦农业发展有限公司 Hylocereus undatus treelet Cultivate administration method
CN107324878A (en) * 2017-07-07 2017-11-07 安徽誉秀农业科技有限公司 A kind of crop growth accelerant
CN109169588A (en) * 2018-08-28 2019-01-11 倪晓燕 A kind of promotion crop growthing development method

Also Published As

Publication number Publication date
CN103583573B (en) 2015-05-13

Similar Documents

Publication Publication Date Title
CN102936166B (en) Water-soluble organic/inorganic compound fertilizer prepared by molasses fermentation liquor and preparation method of fertilizer
CN101891549B (en) Fulvic acid chelated nano element synergistic urea and preparation method thereof
CN104904361A (en) Water-saving fertilizing method for wheat
CN102976869A (en) Technique for producing macroelement water-soluble fertilizer and coproducing slow-release fertilizer
CN107935668A (en) It is a kind of to be used to improve blade face preparation of crop anti-adversity and preparation method thereof
CN101560123A (en) Humic acid degradable liquid manure plastic film and production method thereof
CN108358712A (en) A kind of vegetables Water soluble fertilizer and preparation method thereof
CN105367207A (en) Nitrogen fertilizer synergist and application thereof
CN104892164A (en) Water-soluble fertilizer synergist
CN108947631A (en) A kind of promoting root growth mentions seedling functional form solid water-soluble fertilizer and the preparation method and application thereof
CN105036903A (en) Biocarbon sustain-released paddy rice dedicated basic fertilizer and preparation method thereof
CN103539509B (en) Compound controlled-release fertilizer special for spring corns and production method thereof
CN103583573B (en) Crop growth accelerant and preparation method thereof
CN107986885A (en) A kind of coated compound fertilizer
CN105016882A (en) Liquid fertilizer with transpiration resistance and preparation method thereof
CN105272620A (en) High-concentration suspension type liquid compound fertilizer and preparation method thereof
CN105027786A (en) Fertilizing method realizing integration of water and fertilizer for pears
CN110759777A (en) Special liquid compound fertilizer suitable for lateral deep application of rice and preparation method thereof
CN103708889A (en) Compound full water-soluble water flush fertilizer and preparation method thereof
CN111201967A (en) Water-saving and fertilizer-saving method for crop rotation of winter wheat and summer corn
CN104892166A (en) Synergistic ammonium nitrate urea-urea liquid nitrogen fertilizer
CN106242812A (en) Kalanchoe blossfeldiana fertilizer
CN112088737A (en) Fine planting method of high-quality rice
CN111635278A (en) Nutrient fertilizer for improving green tea quality and efficient nutrient management method
CN104987190A (en) High-nitrogen slow-release fertilizer synergist used for corn and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150513

Termination date: 20171119