CN103563958A - Bactericidal composition containing prochloraz and lentinan and application thereof - Google Patents
Bactericidal composition containing prochloraz and lentinan and application thereof Download PDFInfo
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- CN103563958A CN103563958A CN201210280700.1A CN201210280700A CN103563958A CN 103563958 A CN103563958 A CN 103563958A CN 201210280700 A CN201210280700 A CN 201210280700A CN 103563958 A CN103563958 A CN 103563958A
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Abstract
The invention belongs to the field of pesticides, and discloses a bactericidal composition containing prochloraz and lentinan and application thereof. The bactericidal composition uses prochloraz and lentinan as main effective components, wherein the weight ratio of the prochloraz to the lentinan is (1-70):(1-50). The bactericidal composition can be used for preventing and treating diseases on cereals, melons and fruits, or vegetable crops, has higher synergic effect, overcomes and postpones the drug resistance of pathogenic bacteria, has the advantages of high bactericidal speed and long duration time, lowers the use cost, and has obviously better preventing and treating effects than a single agent.
Description
Technical field:
The invention belongs to pesticide field, relate to a kind of bactericidal composition and uses thereof, be specifically related to a kind of bactericidal composition and application thereof containing Prochloraz and lentinan.
Background technology
Prochloraz (prochloraz), chemical name: N-propyl group-N-[2-(2,4,6-Trichlorophenoxy) ethyl]-imidazoles-1-formamide, structural formula is as follows:
Prochloraz is a kind of wide spectrum, low toxicity bactericide, and the disease that various crop is caused by sac fungi and imperfect fungus has obvious preventive effect, also can be mixed with most of bactericide, bactericide, Insecticides (tech) & Herbicides (tech), all there is good control efficiency.Prochloraz has interior suction conduction, prevention protection, the multiple actions such as treatment, to field crop, fruit and vegetable, multiple diseases on turf and ornamental plants has treatment and eradicant action, conventional use can be used for preventing and treating conventional use and prevent and treat bakanae disease of rice, rice blast, false smut, citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, pear scab etc., Prochloraz is also widely used in the fields such as fruit freshness preserving.
The main component of mushroom is polysaccharose and unsaturated fatty acid, also contains ergosterol and the fungisterol of a large amount of changed into vitamin Ds, has both had very strong inhibition and killing action, the effect that have again obvious disease-resistant yield-increasing, improves crop quality.Lentinan (Lentinan), molecular formula: C
42h
72o
36, belong to fungi polysaccharide, have with glucan exciton and similarly press down sick, anti-disease activity, can induce plant or cell to produce and accumulate disease resistance material, as protective plant protecting agent, chitinase etc.Being a kind of glucan of separation and purification from mushroom, is to strengthen the immunopotentiator that T cell nucleus macrophage function is master.Lentinan has hygroscopicity, in 25 ℃ of room temperature environments that are 92.5%, places 15 days in relative moisture, and water absorption can reach 40%.Lentinan is polarity macromolecular compound, and its specific structure and immunocompetence have substantial connection.Therefore in the extraction of lentinan and preparation process, mostly adopt water and the sig water of different temperatures, and avoid too under acid condition, operating as far as possible, because strong acid performance causes the fracture of polysaccharide glycosidic bond.Lentinan is for preventing and treating the virus disease of the various crop such as paddy rice, tomato, capsicum, cucumber, tobacco, potato, flowers, and mixed with the bactericide of antifungal have good preventive and therapeutic effect to fungal disease.
Summary of the invention
The object of the invention is for above-mentioned technical problem provide a kind of applied widely, cost is low, the effective controlling plant diseases composition containing Prochloraz and lentinan.
Another object of the present invention is to provide the application of this bactericidal composition.
The object of the invention is to realize by following measures:
, it contains Prochloraz and lentinan, and wherein Prochloraz and lentinan weight ratio are 1 ~ 70:1 ~ 50, and wherein in bactericidal composition, effective ingredient is present in composition with synergy effective dose.
Described bactericidal composition, wherein said Prochloraz and lentinan weight ratio are preferably 5 ~ 50:10 ~ 50, more preferably 5 ~ 40:10 ~ 30, particularly preferably 1:0.1 ~ 20.
In the present composition, described Prochloraz and the lentinan gross weight percentage composition in described bactericidal composition is 2 ~ 80%, is preferably 5 ~ 50%, most preferably 8 ~ 40%.
Described bactericidal composition, wherein Prochloraz and lentinan and known auxiliary agent and excipient are re-dubbed any one formulation allowing on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoamer, wetting agent, disintegrant etc.Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), the one or more combinations in polyoxyethylene nonylphenol ether, excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Described bactericidal composition, its formulation is missible oil, pulvis, wetting powder, suspending agent, suspension emulsion or water dispersion granule etc.
The application of described bactericidal composition in the medicine of preparation control Cereal, melon and fruit or vegetable crop fungal disease.
Described fungal disease is banded sclerotial blight, rice blast, false smut, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off or gray mold.
" % " of the present invention is mass percent.
Lentinan of the present invention can be made by oneself according to prior art, also can commercially availablely buy.The consumption of lentinan of the present invention refers to the consumption of active ingredient.
Beneficial effect of the present invention:
1, the present invention's Prochloraz used plays bactericidal action by suppressing ergosterol biosynthesis, and lentinan is biological product-derived, and mechanism is unique, is mutually mixed and can not produces low touching, can Synergistic, reduce dosage, and reduce costs.
2, the present composition scope of application increases, be applicable to prevent and treat Cereal, various melons and fruits, the crop pest of vegetables, particularly prevent and treat paddy rice, wheat, tomato, capsicum, cucumber, tobacco, potato, flowers, the crop pests such as fruit tree, as bakanae disease of rice, rice blast, false smut, banded sclerotial blight, citrus anthracnose, blossom-end rot, penicilliosis, green mould, banana anthracnose, leaf spot, mango anthracnose, leaf spot of peanut, capsicum, eggplant, muskmelon, the vegetables anthracnose such as tomato, Strawberry anthracnose, sclerotinia rot of colza, leaf spot, mushroom brown spot, apple anthracnose, pear scab, and cereal greengrocery virus disease etc.
Bactericidal composition of the present invention has good control efficiency to sac fungi, imperfect fungus fungal disease and virus disease; And suppress the drug-fast generation of disease to unitary agent (Prochloraz and lentinan are arbitrary).
Embodiment
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of formulation is conventional method.
Lentinan used in following examples is according to Chen Xiaoguang, Wei rattan children, Peng Menghui etc., and inner ebullition method is extracted the process optimization of lentinan, [J]. Food Science, and 2011,, medicinal extract prepared by the method that 32 (10), 31-34 optimizes.Lentinan described in embodiment refers to the content of lentinan active ingredient in medicinal extract.Certainly, the lentinan of preparing with additive method or commercially available lentinan are also applicable to the present invention.
The lentinan using in following examples is prepared by the following method:
Take 5g mushroom powder, the ethanolic solution that is 20% by 5mL volume fraction is wetting 30min evenly, makes ethanolic solution fully permeate material; The water of 90 ℃ that adds rapidly 25ml, extracts after 30min, filters, and the filtrate taking a morsel, measures thick polyoses content by phenolsulfuric acid method.The volume of the extract obtaining respectively (being filtrate) is concentrated to 1.2 times by extract material, then adds 95% ethanol to make the ethanol content in concentrate be 75%, and standing, alcohol precipitation spends the night, and filters, and 50 ℃ of vacuum dryings, obtain lentinan CE.The CE that takes a morsel is analyzed polyoses content.Adopt phenolsulfuric acid method to measure total sugar content, adopt 3.5-dinitrosalicylic Acid Colorimetry to measure content of reducing sugar, mushroom proteoglycan content %=(total sugar content-reduction total sugar content) * 0.9 * 100.Lentinan recovery rate is 5.05%, and in CE, polyoses content is 53.5%.
Indoor biometrics test:
Taking Prochloraz (A), lentinan (B) adopts conventional formulation method to be mixed with in different quality ratio the Prochloraz lentinan missible oil that main active ingredient weight percentage is 30%; Concrete ratio is in Table 1.
In indoor employing mycelial growth rate method, measure the EC of different medicaments to bacterial strain
50be worth, adopt the coefficient calculations method of spending together of the abundant introduction of Sun Yun, calculate the co-toxicity coefficient (CTC) of mixture, determine the synergy of mixture.
The a certain single dose of take in mixture (is selected EC conventionally as standard medicament
50junior), calculate:
Single dose toxicity index=standard medicament EC
50/ certain single dose EC
50* 100
Toxicity index * B single dose proportion in mixture of toxicity index * A single dose proportion+B single dose in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose
50the EC of value/mixture
50value * 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index * 100
CTC is greater than 120 o'clock mixtures and has synergetic, and it is antagonism that CTC is less than at 80 o'clock, and CTC is summation action between 80-120.
Table 1: the indoor biometrics result of the different proportionings of Prochloraz+lentinan to rice blast pathogen (Pyricularia grisea (Cooke) Sacc.)
| Medicament | Virulence regression equation | EC 50（mg/L） | Co-toxicity coefficient |
| 50% Prochloraz EC(A) | Y=4.4241X+1.8192 | 5.2356 | / |
| 0.8% lentinan AS(B) | Y=1.9392X+2.2662 | 25.6887 | / |
| Embodiment 1 | Y=3.2199X+2.7732 | 4.9154 | 126.8 |
| Embodiment 7 | Y=2.911X+2.9001 | 5.2645 | 129.2 |
| Embodiment 12 | Y=2.3208X+3.0648 | 6.8211 | 128.0 |
Field control effectiveness test:
1, test is processed: this test medicine consumption is established respectively three concentration for the treatment of according to the difference of each composition, and contrast medicament is respectively commercially available agricultural chemicals 50% Prochloraz EC and 0.8% lentinan AS and the test of blank clear water.
2, each community area of test method is 66.7m
2, repeat 3 times; Inspection drug effect method before dispenser after Investigation and Prevention is: random sampling 5 points in test treatment region, check rice blast, false smut occurrence degree.
3, result of the test sees the following form 2:
Table 2: after medicine, 50 days 50% Prochloraz+lentinans are to the control efficiency of rice green smut, rice blast (%)
By indoor biometrics and field efficacy result, show, Prochloraz and lentinan composition have obvious synergistic function, and the control efficiency of composition is good, and control efficiency is all better than single dose kind, in agricultural application, have using value.And after application process, have effect of increasing production, crop has no adverse reaction.By Jiangsu Province's plant protection unit field trial, Prochloraz+lentinan and the phase dispenser of paddy rice cut have good control action to rice green smut, and paddy rice ear stem seasonal febrile diseases are also had to good control efficiency, rice sheath blight disease are also had to the double effect of controlling simultaneously.Its preventive effect, safety, volume increase and contrast medicament and like that 15 milliliters of processing of seedling, without significant difference, can promote paddy growth after dispenser, the early ageing of control rice leaf, all has effect of increasing production, can large scale application.
Two kinds of reactive compounds of Prochloraz and lentinan can be processed into any one formulation of permission, and below with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 1:
By Prochloraz 20g, lentinan 5g, detergent LS(to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 25% wetting powder.
Embodiment 2:
By Prochloraz 10g, lentinan 40g, detergent LS 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 50% wetting powder.
Embodiment 3:
By Prochloraz 4g, lentinan 32g, detergent LS 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 36% wetting powder.
Embodiment 4:
Take 5g Prochloraz, 50g lentinan, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% Prochloraz-lentinan aqueous emulsion.
Embodiment 5:
Take 2g Prochloraz, 30g lentinan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 32% Prochloraz-lentinan microemulsion.
Embodiment 6:
Take 1g Prochloraz, 5g lentinan, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 6% Prochloraz-lentinan aqueous emulsion.
Embodiment 7:
Take 50g Prochloraz, 20g lentinan, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 70% Prochloraz-lentinan missible oil.
Embodiment 8:
Take 2g Prochloraz, 40g lentinan, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 42% Prochloraz-lentinan missible oil.
Embodiment 9:
Take 5g Prochloraz, 20g lentinan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 25% Prochloraz-lentinan microemulsion.
Embodiment 10:
Take 5g Prochloraz, 0.5g lentinan, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 5.5% Prochloraz-lentinan missible oil.
Embodiment 11:
Take 5g Prochloraz, 30g lentinan, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 35% Prochloraz-lentinan missible oil.
Embodiment 12:
Take 10g Prochloraz, 10g lentinan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 20% Prochloraz-lentinan suspending agent.
Embodiment 13:
Take 30g Prochloraz, 12g lentinan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% Prochloraz-lentinan suspending agent.
Embodiment 13:
Take 2g Prochloraz, 5g lentinan, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and it is 7% Prochloraz-lentinan water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 14:
Take 4g Prochloraz, 13g lentinan, the 8g of wooden sodium sulfonate, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite 28g complements to 100g, and it is 17% Prochloraz-lentinan water dispersion granule that above raw material is made to main active ingredient weight percentage by water dispersible granular agent method.
Embodiment 15:
Take 5g Prochloraz, 15g lentinan, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 20% Prochloraz-lentinan suspending agent.
Embodiment 16
By Prochloraz 5g, lentinan 10g, detergent LS(to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 15% wetting powder.
Claims (10)
1. a bactericidal composition, is characterized in that take that Prochloraz and lentinan are as main active ingredient, and wherein the weight ratio of Prochloraz and lentinan is 1 ~ 70:1 ~ 50.
2. bactericidal composition according to claim 1, is characterized in that described Prochloraz and the weight ratio of lentinan are 5 ~ 50:10 ~ 50.
3. bactericidal composition according to claim 2, is characterized in that described Prochloraz and the weight ratio of lentinan are 5 ~ 40:10 ~ 30, preferably 1:0.1 ~ 20.
4. bactericidal composition according to claim 1, is characterized in that the two gross weight percentage composition in described bactericidal composition of Prochloraz and lentinan is 2-80%.
5. bactericidal composition according to claim 4, is characterized in that the two gross weight percentage composition in described bactericidal composition of Prochloraz and lentinan is 5-50%.
6. bactericidal composition according to claim 5, is characterized in that the two gross weight percentage composition in described bactericidal composition of described Prochloraz and lentinan is 8-40%.
7. bactericidal composition according to claim 1, is characterized in that take that Prochloraz and lentinan are mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipient.
8. bactericidal composition according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersion granule.
9. the application of bactericidal composition claimed in claim 1 in the medicine of preparation control Cereal, melon and fruit or vegetable crop fungal disease.
10. application according to claim 9, is characterized in that described fungal disease is banded sclerotial blight, rice blast, false smut, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off or gray mold.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105191997A (en) * | 2015-08-10 | 2015-12-30 | 谢绪叶 | Fungicide containing prochloraz and scutellaria baicalensis |
| CN105284947A (en) * | 2015-12-05 | 2016-02-03 | 济南舜昊生物科技有限公司 | Suspending agent used for preventing and treating powdery mildew of cucumbers |
| CN105994384A (en) * | 2016-05-21 | 2016-10-12 | 张素香 | Sterilizing composition |
| CN107006507A (en) * | 2017-05-31 | 2017-08-04 | 宾阳禾医生农业服务有限公司 | Sterilization synergistic composition containing Prochloraz |
| CN107494710A (en) * | 2017-09-06 | 2017-12-22 | 山东省果树研究所 | Lentinan combines application of the fludioxonil in preventing and treating fruit, vegetable storage disease |
| CN107535529A (en) * | 2017-07-27 | 2018-01-05 | 张银花 | A kind of agriculturally useful compositions for preventing and treating bacterial leaf streak of rice |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0040007A2 (en) * | 1980-04-24 | 1981-11-18 | Fbc Limited | Fungicidal compositions |
| CN101486773A (en) * | 2009-03-10 | 2009-07-22 | 北京燕化永乐农药有限公司 | Mushroom polysaccharide mother liquor for producing pesticide preparation and preparation thereof |
| CN101647438A (en) * | 2009-09-07 | 2010-02-17 | 山东农业大学 | Anti-plant virus composition containing lentinan |
| CN102308791A (en) * | 2011-05-18 | 2012-01-11 | 江西正邦生物化工股份有限公司 | Prochloraz emulsifiable granules and preparation method thereof |
| CN103563957A (en) * | 2012-08-04 | 2014-02-12 | 南京华洲药业有限公司 | Bactericidal composition containing prochloraz and biological source fungicide, and application of composition |
-
2012
- 2012-08-09 CN CN201210280700.1A patent/CN103563958B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0040007A2 (en) * | 1980-04-24 | 1981-11-18 | Fbc Limited | Fungicidal compositions |
| CN101486773A (en) * | 2009-03-10 | 2009-07-22 | 北京燕化永乐农药有限公司 | Mushroom polysaccharide mother liquor for producing pesticide preparation and preparation thereof |
| CN101647438A (en) * | 2009-09-07 | 2010-02-17 | 山东农业大学 | Anti-plant virus composition containing lentinan |
| CN102308791A (en) * | 2011-05-18 | 2012-01-11 | 江西正邦生物化工股份有限公司 | Prochloraz emulsifiable granules and preparation method thereof |
| CN103563957A (en) * | 2012-08-04 | 2014-02-12 | 南京华洲药业有限公司 | Bactericidal composition containing prochloraz and biological source fungicide, and application of composition |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105191997A (en) * | 2015-08-10 | 2015-12-30 | 谢绪叶 | Fungicide containing prochloraz and scutellaria baicalensis |
| CN105284947A (en) * | 2015-12-05 | 2016-02-03 | 济南舜昊生物科技有限公司 | Suspending agent used for preventing and treating powdery mildew of cucumbers |
| CN105994384A (en) * | 2016-05-21 | 2016-10-12 | 张素香 | Sterilizing composition |
| CN107006507A (en) * | 2017-05-31 | 2017-08-04 | 宾阳禾医生农业服务有限公司 | Sterilization synergistic composition containing Prochloraz |
| CN107535529A (en) * | 2017-07-27 | 2018-01-05 | 张银花 | A kind of agriculturally useful compositions for preventing and treating bacterial leaf streak of rice |
| CN107494710A (en) * | 2017-09-06 | 2017-12-22 | 山东省果树研究所 | Lentinan combines application of the fludioxonil in preventing and treating fruit, vegetable storage disease |
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|---|---|
| CN103563958B (en) | 2015-06-03 |
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Effective date of registration: 20180521 Address after: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Co-patentee after: Nanjing Redsun Co., Ltd. Patentee after: Nanjing Huazhou Pharmaceutical Co., Ltd. Address before: 211318 Dongfeng Road 8, Yalong Town, Gaochun, Nanjing, Jiangsu Patentee before: Nanjing Huazhou Pharmaceutical Co., Ltd. |