CN103563940A - Bactericidal composition containing pyraclostrobin and probenazole and application thereof - Google Patents
Bactericidal composition containing pyraclostrobin and probenazole and application thereof Download PDFInfo
- Publication number
- CN103563940A CN103563940A CN201210276567.2A CN201210276567A CN103563940A CN 103563940 A CN103563940 A CN 103563940A CN 201210276567 A CN201210276567 A CN 201210276567A CN 103563940 A CN103563940 A CN 103563940A
- Authority
- CN
- China
- Prior art keywords
- pyraclostrobin
- bactericidal composition
- allyl isothiazole
- composition according
- isothiazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericidal composition containing pyraclostrobin and probenazole and an application thereof. The bactericidal composition takes pyraclostrobin and probenazole as main active ingredients, wherein the weight ratio of pyraclostrobin to probenazole is (1-70):(1-50). The bactericidal composition can be used for preventing the diseases of cereal, melon and fruit or vegetable crops, has relatively high synergistic effect, overcomes and delays the drug resistance of germs, and realizes high bactericidal speed and long duration while the application cost is reduced and the prevention effect is obviously better than that of using a single agent. The bactericidal composition disclosed by the invention can be used for preventing fungal diseases of crops and particularly can be used for preventing the fungal diseases such as rice blast, leaf blight, rust disease, powdery mildew, downy mildew, epidemic disease, anthracnose, cab, brown spot, damping off, gray mold, clubroot and late blight of the cereal, melon and fruit or vegetable crops, and the effect is better than that of using a single agent.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind ofly take bactericidal composition and the application thereof that pyraclostrobin and allyl isothiazole be main active.
Background technology
Pyraclostrobin (Pyraclostrobin), has another name called: pyraclostrobin, chemical name is N-methoxyl group-N-2-[(N-rubigan)-3-pyrazoles oxygen ylmethyl] carbanilate.Structural formula is as follows:
Pyraclostrobin toxicity is low: rat oral >5000, and through skin >2000, to lagophthalmos eyeball nonirritant, without potential mutagenicity, without teratogenesis carcinogenicity, harmless to honeybee, hydrolysising half-life DT in water
50>30d, stable during pH5-7, Photolysis Half DT in water
50<2h, large Tanaka's soil half life period DT
502-37d.This compound not only toxicity is low, to non-target organism safety, and also all friendly safely to user and environment, by U.S. EPA, classified as " the candidate's medicament that reduces risk ".Pyraclostrobin is a kind of mitochondrial respiratory inhibitor, and it,, by suppressing electron transport system in mitochondria, present antibacterial activity, and pyraclostrobin has significant volume increase with protein complex III effect.This medicament can hinder spore-germination, gemma growth, mycelia intrusion, hapteron formation and the sporulation in pathogen living chain and cause effect, especially spore-germination is had to extremely strong inhibitory action, therefore there is distinguished preventive effect.Simultaneously, it has osmotic effect in very strong leaf and has very high rain fastness, can be used for the various crops such as wheat, peanut, paddy rice, vegetables, fruit tree, tobacco, tea tree, ornamental plants, lawn, the multiple diseases such as control sac fungi, basidiomycetes, imperfect fungus and the fungus-caused leaf blight of Oomycete, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off.Pyraclostrobin is mainly applicable to protection and morbidity is used early stage.
Allyl isothiazole (probenazole), chemical name: 3-(2-acrylic oxygen base)-1,2-benzisothiazole 1,1-dioxide, structural formula is as follows:
Allyl isothiazole belongs to salicylic acid immune system promoter, in isolated test, and slightly antimicrobial activity.Process paddy rice, promote the absorption of root system, cover crop is not subject to rice blast pathogen and infecting to leaf spot bacteria.Suitable crop paddy rice, is mainly used to prevent and treat rice blast, bacterial leaf-blight, conventionally before transplanting, with granula, imposes on paddy rice or seedling growing box, and control rice blast effect is up to more than 97%.Under recommended dose to crop safety.
The difficulty of prevention and cure of phytopathogen is increasing at present, and on the one hand, along with the change of pattern of farming, the economic crops cultivated areas such as melon and fruit, vegetables progressively expand, and disease occurrence degree, generation quantity all increase, and in control, difficulty strengthens; On the other hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the control efficiency of single dose is had a greatly reduced quality, and control of plant disease is faced with significant challenge.
Summary of the invention:
The object of the invention is for above-mentioned technical problem provide a kind of applied widely, cost is low, the plant bactericidal composition of effective pyraclostrobin-containing and allyl isothiazole.
A further object of the invention is to provide the application of this bactericidal composition on preparation control resistance plant fungal disease germ killing drugs.
The object of the invention is to realize by following measures:
, it contains pyraclostrobin and allyl isothiazole, and wherein pyraclostrobin and allyl isothiazole weight ratio are 1 ~ 70:1 ~ 50, and wherein in bactericidal composition, effective ingredient is present in composition with synergy effective dose.
Described bactericidal composition, wherein pyraclostrobin and allyl isothiazole weight ratio are preferably 5 ~ 50:10 ~ 50, more preferably 5 ~ 40:10 ~ 30.
In the present composition, the two percentage by weight that accounts for composition of pyraclostrobin and allyl isothiazole is 2% ~ 80%.Be preferably 5% ~ 50%, most preferably 8% ~ 40%.
Described bactericidal composition, wherein take pyraclostrobin and allyl isothiazole to be re-dubbed any one formulation allowing on agricultural chemicals as main active ingredient and known auxiliary agent and excipient.These known auxiliary agents, excipient have dispersant, diffusant, defoamer, wetting agent, disintegrant etc.Auxiliary agent can adopt calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, the rare block compound of polyoxyethylene polyoxy third (as agriculture breast 33
#), the one or more combinations in polyoxyethylene nonylphenol ether etc., excipient comprises cyclohexanone, dimethylbenzene, solvent naphtha, water, antifreezing agent (as propane diols), deionized water etc.Above auxiliary agent, excipient and other auxiliary material can alone or and use.
Described bactericidal composition, its formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
The application of described bactericidal composition on preparation control resistance plant fungal disease germ killing drugs.
Above-mentioned this bactericidal composition that is applied as occurs in the application on the fungal disease germ killing drugs such as rice blast on Cereal, melon and fruit or vegetable crop, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off, gray mold, club root, late blight in preparation control.
Beneficial effect of the present invention:
1, the present invention's pyraclostrobin used is methoxy acrylate bactericide, and allyl isothiazole is pyridines bactericide, and the mechanism of action is different, be mutually mixed and can not produce conflict, but can Synergistic, reduce dosage, reduce costs.
2, the present composition scope of application increases, be applicable to prevent and treat the crop pest of Cereal, various melon and fruit, vegetables, particularly prevent and treat the crop pests such as paddy rice, wheat, capsicum, banana, mango, pineapple, cucumber, tomato, as rice blast, rice sheath blight disease, apple scab, balsam pear scab, lawn spot disease, powdery mildew of cucumber, tomato late blight etc.
Bactericidal composition of the present invention has good control efficiency to sac fungi, basidiomycetes, imperfect fungus and Oomycete fungal disease; And suppress insect or the drug-fast generation of fungi to unitary agent (pyraclostrobin and allyl isothiazole are arbitrary).
Bactericidal composition of the present invention is prevented and treated the application on resistance fungi in preparation, and especially the application in control rice blast, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off, gray mold, club root, late blight all has significant effect.Above-mentioned bactericidal composition can produce higher synergistic function, and the consumption of the independent reactive compound of amount ratio of this mixture reduces greatly, and the activity of mixture is greater than the activity of independent component.
Beneficial effect of the present invention compared with prior art: (1) is compared with single dose, said composition antagonism fungal disease has obvious synergistic function as fungal diseases such as rice blast, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off, gray mold, club root, late blights, overcome and delayed pesticide resistance, expanding prevention spectrum, has obviously improved control efficiency; (2) reduce control recruitment, drug cost; (3) alternative routine and the easily agricultural chemicals of generation resistance; (4) compare with single dose, produce and use cost reduction; (5) the drug-fast generation of Antifungi, its successful is used higher than its single dose.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of formulation is conventional method.
Two kinds of reactive compounds can be processed into any one formulation of permission, and below with two kinds of preparations that active ingredient is processed into of specific embodiment explanation, but the preparation that these two kinds of active components can be processed is not limited only to following listed.
Embodiment 1:
By pyraclostrobin 7.5g, allyl isothiazole 7.5g, detergent LS(to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 15% wetting powder.
Embodiment 2:
By pyraclostrobin 3g, allyl isothiazole 12g, detergent LS 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 15% wetting powder.
Embodiment 3:
By pyraclostrobin 2g, allyl isothiazole 13g, detergent LS 3g, dispersing agent NNO 4g, white carbon 5g, kaolin adds to 100g mixture and carries out air-flow crushing, and making main active ingredient weight percentage is 15% wetting powder.
Embodiment 4:
Take 5g pyraclostrobin, 50g allyl isothiazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 55% pyraclostrobin allyl isothiazole aqueous emulsion.
Embodiment 5:
Take 10g pyraclostrobin, 30g allyl isothiazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 40% pyraclostrobin allyl isothiazole microemulsion.
Embodiment 6:
Take 1g pyraclostrobin, 5g allyl isothiazole, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, solvent naphtha 13g, adds water to 100g.The method of above raw material being prepared routinely to aqueous emulsion drops into the mixing of mixing kettle high speed, and making main active ingredient weight percentage is 6% pyraclostrobin allyl isothiazole aqueous emulsion.
Embodiment 7:
Take 50g pyraclostrobin, 20g allyl isothiazole, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 70% pyraclostrobin allyl isothiazole missible oil.
Embodiment 8:
Take 2g pyraclostrobin, 40g allyl isothiazole, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 42% pyraclostrobin allyl isothiazole missible oil.
Embodiment 9:
Take 5g pyraclostrobin, 20g allyl isothiazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropyl alcohol 10g, adds water to 100g.The method that above raw material is prepared to microemulsion routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 25% pyraclostrobin allyl isothiazole microemulsion.
Embodiment 10:
Take 20g pyraclostrobin, 10g allyl isothiazole, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 30% pyraclostrobin allyl isothiazole missible oil.
Embodiment 11:
Take 5g pyraclostrobin, 30g allyl isothiazole, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent naphtha are to 100g.The method that above raw material is prepared to missible oil routinely drops in mixing kettle mixes, and making main active ingredient weight percentage is 35% pyraclostrobin allyl isothiazole missible oil.
Embodiment 12:
Take 10g pyraclostrobin, 10g allyl isothiazole, lignin 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 20% pyraclostrobin allyl isothiazole suspending agent.
Embodiment 13:
Take 30g pyraclostrobin, 12g allyl isothiazole, lignin 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 42% pyraclostrobin allyl isothiazole suspending agent.
Embodiment 14:
Take 2g pyraclostrobin, 5g allyl isothiazole, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and it is 7% pyraclostrobin allyl isothiazole water dispersible granules that above raw material is made to main active ingredient weight percentage by water-dispersible grain agent method.
Embodiment 15:
Take 4g pyraclostrobin, 13g allyl isothiazole, sodium lignin sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyvinyl alcohol 5g, borax 2g, diatomite complements to 100g, and it is 17% pyraclostrobin allyl isothiazole water dispersible granules that above raw material is made to main active ingredient weight percentage by water-dispersible grain agent method.
Embodiment 16:
Take 70g pyraclostrobin, 2g allyl isothiazole, lignin 2g, alkyl phenol (or fatty alcohol) polyoxyethylene poly-oxygen propylene aether and sulphate 4g thereof, xanthans 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, water complements to 100g, and under the effect of sand mill, making main active ingredient weight percentage is 72% pyraclostrobin allyl isothiazole suspending agent.
Indoor biometrics test:
In indoor employing mycelial growth rate method, measure the EC of different medicaments to bacterial strain
50be worth, adopt the co-toxicity coefficient computational methods of the abundant introduction of Sun Yun, calculate the co-toxicity coefficient (CTC) of mixture, determine the synergy of mixture.
The a certain single dose of take in mixture (is selected EC conventionally as standard medicament
50junior), calculate:
Single dose toxicity index=standard medicament EC
50/ certain single dose EC
50* 100
Toxicity index * B single dose proportion in mixture of toxicity index * A single dose proportion+B single dose in mixture of theoretical toxicity index=A single dose
The EC of actual measurement toxicity index=standard single dose
50the EC of value/mixture
50value * 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index * 100
CTC is greater than 120 o'clock mixtures and has synergetic, and it is antagonism that CTC is less than at 80 o'clock, and CTC is summation action between 80-120.
Table 1: the indoor biometrics result of the different proportionings of pyraclostrobin+allyl isothiazole to rice blast fungus
| Medicament | Virulence regression equation | EC50（mg/L） | Co-toxicity coefficient |
| 24% pyraclostrobin EC | Y= 2.1617X+ 3.8655 | 3.3484 | — |
| 10% allyl isothiazole WP | Y= 1.4698X+ 3.8098 | 6.4534 | — |
| Embodiment 1 | Y= 4.7666X+ 2.7158 | 3.0144 | 146 |
| Embodiment 2 | Y= 7.5399X+ 1.2926 | 3.1025 | 174 |
| Embodiment 3 | Y= 4.0883X+ 2.7036 | 3.6450 | 158 |
Field control effectiveness test:
The pesticidal preparations control rice blast test making with above-described embodiment.
1, test is processed: this test medicine consumption is established respectively three concentration for the treatment of according to the difference of each composition, and contrast medicament is respectively commercially available agricultural chemicals 10% allyl isothiazole WP (wetting powder) and 24% pyraclostrobin EC(missible oil) and the test of blank clear water.
2, each community area of test method is 66.7m
2, repeat 3 times; Inspection drug effect method before dispenser after Investigation and Prevention is: random sampling 5 points in test treatment region, check Occurrence Degree of Rice Blast.
3, result of the test sees the following form:
Note: a is illustrated in the level of α=0.05 remarkable, and b is illustrated in the level of α=0.05 variant, and c is illustrated in the level of α=0.05 not remarkable.
By indoor biometrics and field efficacy result, show, pyraclostrobin and allyl isothiazole composition have obvious synergistic function, and the control efficiency of composition is good, and control efficiency is all better than single dose kind, in agricultural application, have using value.
Claims (10)
1. a bactericidal composition, is characterized in that containing pyraclostrobin and allyl isothiazole, and wherein the weight ratio of pyraclostrobin and allyl isothiazole is 1 ~ 70:1 ~ 50.
2. bactericidal composition according to claim 1, the weight ratio that it is characterized in that pyraclostrobin and allyl isothiazole is 5 ~ 50:10 ~ 50.
3. bactericidal composition according to claim 2, is characterized in that described pyraclostrobin and the weight ratio of allyl isothiazole are 5 ~ 40:10 ~ 30.
4. bactericidal composition according to claim 1, is characterized in that the two weight percentage that accounts for composition of pyraclostrobin and allyl isothiazole is 2% ~ 80%.
5. bactericidal composition according to claim 4, is characterized in that the two weight percentage that accounts for composition of pyraclostrobin and allyl isothiazole is 5% ~ 50%.
6. bactericidal composition according to claim 5, is characterized in that the two weight percentage that accounts for composition of pyraclostrobin and allyl isothiazole is 8% ~ 40%.
7. bactericidal composition according to claim 1, is characterized in that take that pyraclostrobin and allyl isothiazole are mixed with any one formulation allowing on agricultural chemicals as main active ingredient and insecticides adjuvant, excipient.
8. bactericidal composition according to claim 7, is characterized in that described formulation is missible oil, suspending agent, aqueous emulsion, wetting powder, microemulsion or water dispersible granules.
9. the application of bactericidal composition claimed in claim 1 on preparation control resistance plant fungal disease germ killing drugs.
10. this bactericidal composition that is applied as according to claim 9 occurs in the application on the fungal disease germ killing drugs such as rice blast on Cereal, melon and fruit or vegetable crop, leaf blight, rust, powdery mildew, downy mildew, epidemic disease, anthracnose, S.scabies, brown spot, damping off, gray mold, club root, late blight in preparation control.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210276567.2A CN103563940A (en) | 2012-08-05 | 2012-08-05 | Bactericidal composition containing pyraclostrobin and probenazole and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210276567.2A CN103563940A (en) | 2012-08-05 | 2012-08-05 | Bactericidal composition containing pyraclostrobin and probenazole and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103563940A true CN103563940A (en) | 2014-02-12 |
Family
ID=50037336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210276567.2A Pending CN103563940A (en) | 2012-08-05 | 2012-08-05 | Bactericidal composition containing pyraclostrobin and probenazole and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103563940A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578108A (en) * | 2012-02-20 | 2012-07-18 | 广西田园生化股份有限公司 | Bactericidal composition containing probenazole |
| CN103238606A (en) * | 2012-02-08 | 2013-08-14 | 陕西美邦农药有限公司 | Sterilization composition containing probenazole and methoxy acrylates |
-
2012
- 2012-08-05 CN CN201210276567.2A patent/CN103563940A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103238606A (en) * | 2012-02-08 | 2013-08-14 | 陕西美邦农药有限公司 | Sterilization composition containing probenazole and methoxy acrylates |
| CN102578108A (en) * | 2012-02-20 | 2012-07-18 | 广西田园生化股份有限公司 | Bactericidal composition containing probenazole |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103563945A (en) | Bactericidal composition containing pyraclostrobin and prothioconazole and application thereof | |
| CN103563944A (en) | Bactericidal composition containing pyraclostrobin and tebuconazole and application thereof | |
| CN103563942A (en) | Bactericidal composition containing pyraclostrobin and epoxiconazole and application thereof | |
| CN103563939A (en) | Bactericidal composition containing pyraclostrobin and fluazinam and application thereof | |
| CN103563938A (en) | Bactericidal composition containing pyraclostrobin and difenoconazole and application thereof | |
| CN104621168A (en) | Sterilization composition containing prothioconazole and prochloraz-manganese chloride and application thereof | |
| CN105941416A (en) | Sterilizing composition containing bixafen and tebuconazole and application thereof | |
| CN103563976A (en) | Bactericidal composition containing pyraclostrobin and iprobenfos and application thereof | |
| CN104621129A (en) | Sterilization composition containing prothioconazole and metalaxyl-M and application thereof | |
| CN103563940A (en) | Bactericidal composition containing pyraclostrobin and probenazole and application thereof | |
| CN105941440A (en) | Sterilization composition containing Bixafen and zineb and application thereof | |
| CN105941438A (en) | {0><}0{>Sterilization composition containing fluoride ether bacteria amide and thiophal and application of sterilization composition<0} | |
| CN106538535A (en) | The bactericidal composition and its application of a kind of 2-cyano-3-amino-3-phenylancryic acetate-containing and Metalaxyl-M | |
| CN105379753B (en) | A kind of bactericidal composition and its application containing mepanipyrim and different rice blast net | |
| CN106508931A (en) | Fungicidal composition containing benthiavalicarb-isopropyl and thifluzamide and application thereof | |
| CN103563914B (en) | A kind of bactericidal composition and application thereof containing thifluzamide and nitrile bacterium azoles | |
| CN103563921B (en) | A kind of bactericidal composition and application thereof containing thifluzamide and Flutriafol | |
| CN103563941A (en) | Bactericidal composition containing pyraclostrobin and hexaconazole and application thereof | |
| CN103907605A (en) | Composite synergic sterilization composition containing boscalid and bixafen and application thereof | |
| CN103907606A (en) | Composite synergic sterilization composition containing boscalid and isopyrazam and application thereof | |
| CN103891743A (en) | Bactericidal composition containing isopyrazam and pyraclostrobin and application thereof | |
| CN106973919A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and cyazofamid | |
| CN107047583A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and Mancozeb | |
| CN105900998A (en) | Sterilization composition containing spiroxamine and famoxadone and application thereof | |
| CN106973920A (en) | A kind of bactericidal composition and its application containing fluoxastrobin and fenoxanil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140212 |