CN103541243A - Anti-yellowing printing adhesive and preparation method thereof - Google Patents
Anti-yellowing printing adhesive and preparation method thereof Download PDFInfo
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- CN103541243A CN103541243A CN201310502228.6A CN201310502228A CN103541243A CN 103541243 A CN103541243 A CN 103541243A CN 201310502228 A CN201310502228 A CN 201310502228A CN 103541243 A CN103541243 A CN 103541243A
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Abstract
The invention discloses an anti-yellowing printing adhesive and a preparation method thereof. The anti-yellowing printing adhesive is prepared from the following raw materials in parts by weight: 32-35 parts of polyether acrylate, 2-3 parts of N-methyl pyrrolidone, 8-10 parts of isophorone diisocyanate, 1-2 parts of dibutyltin dilaurate, 6-8 parts of polyethylene glycol, 3-4 parts of trimethylolpropane, 5-10 parts of propylene glycol methyl ether acetate, 2-5 parts of polydimethyl siloxane, 1-2 parts of acetylsalicylic acid, 1-2 parts of N-methylolacrylamide, 1-2 parts of iso-tridecanol polyoxyethylene ether, 1-2 parts of 8-hydroxyquinoline, 1-2 parts of ammonium persulfate, 4-5 parts of an auxiliary agent and 60-70 parts of water. The anti-yellowing printing adhesive disclosed by the invention has excellent properties of polyether acrylate and isophorone diisocyanate, light resistance, yellowing resistance and resistance to chemicals, and monomers including propylene glycol methyl ether acetate and the like are used for performing graft modification to form a net-like structure, so that the anti-yellowing printing adhesive has better crockfastness and brushing fastness than single polyether acrylate resin, and is soft in hand feeling. The anti-yellowing printing adhesive disclosed by the invention is wide in application range and simple and convenient in operation.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of printing adhesive of resistance to xanthochromia and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of printing adhesive of resistance to xanthochromia and preparation method thereof, this adhesive has fast light good, resistance to xanthochromia, soft feature.
Technical scheme of the present invention is as follows:
A kind of printing adhesive of resistance to xanthochromia, is characterized in that being made by the raw material of following weight portion: polyether acrylate 32-35,1-METHYLPYRROLIDONE 2-3, isophorone diisocyanate 8-10, dibutyl tin laurate 1-2, polyethylene glycol 6-8, trimethylolpropane 3-4,1-Methoxy-2-propyl acetate 5-10, dimethyl silicone polymer 2-5, acetylsalicylic acid 1-2, N hydroxymethyl acrylamide 1-2, isomerous tridecanol polyoxyethylene ether 1-2, oxine 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 60-70; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of the described printing adhesive of resistance to xanthochromia, it is characterized in that comprising the following steps: polyether acrylate, 1-METHYLPYRROLIDONE, isophorone diisocyanate, polyethylene glycol, trimethylolpropane, 1-Methoxy-2-propyl acetate, dimethyl silicone polymer, acetylsalicylic acid, N hydroxymethyl acrylamide are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add isomerous tridecanol polyoxyethylene ether, oxine, dibutyl tin laurate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has the advantageous property of polyether acrylate and isophorone diisocyanate, fast light, resistance to xanthochromia, chemical proofing, and through using the monomer graft modifications such as 1-Methoxy-2-propyl acetate, form network structure, friction and brushing fastness are better, soft than independent polyether acrylate resin; Adhesive application scope of the present invention is wide, easy and simple to handle.
The specific embodiment
A kind of printing adhesive of resistance to xanthochromia, by following weight portion (kilogram) raw material make: polyether acrylate 33,1-METHYLPYRROLIDONE 2.5, isophorone diisocyanate 9, dibutyl tin laurate 1.5, polyethylene glycol 7, trimethylolpropane 3.5,1-Methoxy-2-propyl acetate 7, dimethyl silicone polymer 2.5, acetylsalicylic acid 1.5, N hydroxymethyl acrylamide 1.5, isomerous tridecanol polyoxyethylene ether 1.5, oxine 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 65; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, styrene 4, maleic anhydride 3, Tween-81 2, acrylonitrile 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 12; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of the described printing adhesive of resistance to xanthochromia, comprise the following steps: polyether acrylate, 1-METHYLPYRROLIDONE, isophorone diisocyanate, polyethylene glycol, trimethylolpropane, 1-Methoxy-2-propyl acetate, dimethyl silicone polymer, acetylsalicylic acid, N hydroxymethyl acrylamide are mixed, under 1000 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add isomerous tridecanol polyoxyethylene ether, oxine, dibutyl tin laurate, with the speed of 6 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This printing adhesive of resistance to xanthochromia, for stamp, is pressed GB standard detection, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and brushing fastness 3-4 level, glues 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. the printing adhesive of resistance to xanthochromia, is characterized in that being made by the raw material of following weight portion: polyether acrylate 32-35,1-METHYLPYRROLIDONE 2-3, isophorone diisocyanate 8-10, dibutyl tin laurate 1-2, polyethylene glycol 6-8, trimethylolpropane 3-4,1-Methoxy-2-propyl acetate 5-10, dimethyl silicone polymer 2-5, acetylsalicylic acid 1-2, N hydroxymethyl acrylamide 1-2, isomerous tridecanol polyoxyethylene ether 1-2, oxine 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 60-70; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, styrene 3-4, maleic anhydride 2-3, Tween-81 2-3, acrylonitrile 2-3, antioxidant 1035 1-2, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, maleic anhydride, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of the printing adhesive of resistance to xanthochromia according to claim 1, it is characterized in that comprising the following steps: polyether acrylate, 1-METHYLPYRROLIDONE, isophorone diisocyanate, polyethylene glycol, trimethylolpropane, 1-Methoxy-2-propyl acetate, dimethyl silicone polymer, acetylsalicylic acid, N hydroxymethyl acrylamide are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add isomerous tridecanol polyoxyethylene ether, oxine, dibutyl tin laurate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502228.6A CN103541243A (en) | 2013-10-23 | 2013-10-23 | Anti-yellowing printing adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310502228.6A CN103541243A (en) | 2013-10-23 | 2013-10-23 | Anti-yellowing printing adhesive and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103541243A true CN103541243A (en) | 2014-01-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310502228.6A Pending CN103541243A (en) | 2013-10-23 | 2013-10-23 | Anti-yellowing printing adhesive and preparation method thereof |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1746251A (en) * | 2005-09-14 | 2006-03-15 | 北京高盟化工有限公司 | Special binder of reflecting material and production thereof |
| US7166649B2 (en) * | 2004-04-27 | 2007-01-23 | Ashland Chemical, Inc. | Polyester-polyether hybrid urethane acrylate oligomer for UV curing pressure sensitive adhesives |
| CN101698788A (en) * | 2009-09-22 | 2010-04-28 | 北京高盟化工有限公司 | Adhesive for light-reflecting particles and preparation method thereof |
| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103820037A (en) * | 2014-03-12 | 2014-05-28 | 深圳市中显微电子有限公司 | Yellowing-resistant liquid optical adhesive and a preparation method thereof |
-
2013
- 2013-10-23 CN CN201310502228.6A patent/CN103541243A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7166649B2 (en) * | 2004-04-27 | 2007-01-23 | Ashland Chemical, Inc. | Polyester-polyether hybrid urethane acrylate oligomer for UV curing pressure sensitive adhesives |
| CN1746251A (en) * | 2005-09-14 | 2006-03-15 | 北京高盟化工有限公司 | Special binder of reflecting material and production thereof |
| CN101698788A (en) * | 2009-09-22 | 2010-04-28 | 北京高盟化工有限公司 | Adhesive for light-reflecting particles and preparation method thereof |
| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103820037A (en) * | 2014-03-12 | 2014-05-28 | 深圳市中显微电子有限公司 | Yellowing-resistant liquid optical adhesive and a preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 黄茂福: "涂料印花的创新与发展动向", 《印染助剂》 * |
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Application publication date: 20140129 |