CN103540223A - High-adhesion-force epoxy resin powdery paint - Google Patents

High-adhesion-force epoxy resin powdery paint Download PDF

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Publication number
CN103540223A
CN103540223A CN201310478451.1A CN201310478451A CN103540223A CN 103540223 A CN103540223 A CN 103540223A CN 201310478451 A CN201310478451 A CN 201310478451A CN 103540223 A CN103540223 A CN 103540223A
Authority
CN
China
Prior art keywords
parts
raw material
mix
epoxy resin
powder coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310478451.1A
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Chinese (zh)
Inventor
万鹏程
马千里
徐磊
徐曙
代宝成
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI MINGDU ELECTRICAL Co Ltd
Original Assignee
ANHUI MINGDU ELECTRICAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI MINGDU ELECTRICAL Co Ltd filed Critical ANHUI MINGDU ELECTRICAL Co Ltd
Priority to CN201310478451.1A priority Critical patent/CN103540223A/en
Publication of CN103540223A publication Critical patent/CN103540223A/en
Pending legal-status Critical Current

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Abstract

The invention discloses high-adhesion-force epoxy resin powdery paint which is composed of the raw materials of, by weight: 50-60 parts of E-51 epoxy resin, 6-10 parts of diethylene triamine, 3-5 parts of shell powder, 4-5 parts of hexagonal boron nitride, 2-3 parts of bisphenol a diglycidyl, 0.1-2 parts of a floating agent, 2-3 parts of cuprous oxide, 1-2 parts of zinc, 10-12 parts of ultra-fine barium sulfate, 1-2 parts of N,N,N',N'-tetra(2-hydroxyethyl)adipamide, 2-4 parts of polyvinyl chloride, and 4-10 parts of a composite filling material. The powdery paint provided by the invention is safe and has no toxic or side effect. The paint has good environment friendliness, good decorative effect, good hardness, and good pollution resistance. The powdery paint has excellent comprehensive performance.

Description

A kind of high adhesive force epoxy powder coating
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of high adhesive force epoxy powder coating.
Background technology
China has determined the status of manufacturing conventional household electrical appliance center in the whole world.And approaching along with external product, along with domestic consumer's consumers demand constantly promotes, market is to the requirement to exterior quality from single emphasis functional type Synchronous lifting of the demand of household appliances, and the traditional processing technology of existing appliance shell (spraying) is difficult to meet this demand.
Summary of the invention
The object of the invention is exactly for a kind of high adhesive force epoxy powder coating is provided.
The present invention is achieved by the following technical solutions:
An epoxy powder coating, it is comprised of the raw material of following weight parts:
E-51 epoxy resin 50-60, diethylenetriamine 6-10, oyster shell whiting 3-5, hexagonal boron nitride 4-5, bis-phenol a diglycidylether 2-3, sludge ice agent 0.1-2, Red copper oxide 2-3, zinc powder 1-2, ultra-fine barium sulfate 10-12, N, N, N', N'-tetra-(2-hydroxyethyl) adipamide 1-2, polyvinyl chloride 2-4, compounded mix 4-10;
Described compounded mix is comprised of the raw material of following weight parts:
Laterite 40-45, tetrafluoroethylene 6-8, aluminium acetylacetonate 2-3, vanadium diboride 1-2, N,N methylene bis acrylamide 0.6-1, TriMethylolPropane(TMP) 1-2;
Above-mentioned laterite is calcined to 3-5 hour at 600-800 ℃, add tetrafluoroethylene, ball milling mixing 1-2 hour, after TriMethylolPropane(TMP) is heated to 55-60 ℃, add, mix, add each raw material of residue, 400-600 rev/min of dispersed with stirring 20-25 minute, dry, fully ball milling, obtains described compounded mix.
A preparation method for high adhesive force epoxy powder coating, comprises the following steps:
Above-mentioned Red copper oxide, zinc powder, ultra-fine barium sulfate, polyvinyl chloride are mixed, heated and stirred reaction 10-15 minute at 70-80 ℃, after discharging is cooling, mix with each raw material of residue, putting into high-speed mixer mixes fully, again gained compound is put into mixing extrusion in high-speed extruder, then after compressing tablet fragmentation, then pulverize, sieve through pulverising mill, described in obtaining, obtain described high adhesive force epoxy powder coating.
Advantage of the present invention is:
Powder coating safe without toxic side effect of the present invention, the feature of environmental protection is good, and good decorating effect has good hardness and resistance to crocking, and over-all properties is superior.
Embodiment
Embodiment 1,
An epoxy powder coating, it by following weight parts (kilogram) raw material form:
E-51 epoxy resin 60, diethylenetriamine 10, oyster shell whiting 5, hexagonal boron nitride 5, bis-phenol a diglycidylether 2, sludge ice agent 2, Red copper oxide 2, zinc powder 2, ultra-fine barium sulfate 12, N, N, N', N'-tetra-(2-hydroxyethyl) adipamide 1-2, polyvinyl chloride 4, compounded mix 10;
Described compounded mix is comprised of the raw material of following weight parts:
Laterite 45, tetrafluoroethylene 8, aluminium acetylacetonate 3, vanadium diboride 2, N,N methylene bis acrylamide 0.6, TriMethylolPropane(TMP) 2;
Above-mentioned laterite is calcined 3 hours at 800 ℃, added tetrafluoroethylene, ball milling mixes 2 hours, adds after TriMethylolPropane(TMP) is heated to 60 ℃, mix, add each raw material of residue, 600 revs/min of dispersed with stirring 25 minutes, dry, fully ball milling, obtains described compounded mix.
A preparation method for high adhesive force epoxy powder coating, comprises the following steps:
Above-mentioned Red copper oxide, zinc powder, ultra-fine barium sulfate, polyvinyl chloride are mixed, at 80 ℃, heated and stirred reaction is 15 minutes, after discharging is cooling, mix with each raw material of residue, putting into high-speed mixer mixes fully, again gained compound is put into mixing extrusion in high-speed extruder, then after compressing tablet fragmentation, then pulverize, sieve through pulverising mill, described in obtaining, obtain described high adhesive force epoxy powder coating.
Performance test:
24H cathodic disbonding 2.9mm;
Hardness >=2H.

Claims (2)

1. a high adhesive force epoxy powder coating, is characterized in that what it was comprised of the raw material of following weight parts:
E-51 epoxy resin 50-60, diethylenetriamine 6-10, oyster shell whiting 3-5, hexagonal boron nitride 4-5, bis-phenol a diglycidylether 2-3, sludge ice agent 0.1-2, Red copper oxide 2-3, zinc powder 1-2, ultra-fine barium sulfate 10-12, N, N, N', N'-tetra-(2-hydroxyethyl) adipamide 1-2, polyvinyl chloride 2-4, compounded mix 4-10;
Described compounded mix is comprised of the raw material of following weight parts:
Laterite 40-45, tetrafluoroethylene 6-8, aluminium acetylacetonate 2-3, vanadium diboride 1-2, N,N methylene bis acrylamide 0.6-1, TriMethylolPropane(TMP) 1-2;
Above-mentioned laterite is calcined to 3-5 hour at 600-800 ℃, add tetrafluoroethylene, ball milling mixing 1-2 hour, after TriMethylolPropane(TMP) is heated to 55-60 ℃, add, mix, add each raw material of residue, 400-600 rev/min of dispersed with stirring 20-25 minute, dry, fully ball milling, obtains described compounded mix.
2. a preparation method for high adhesive force epoxy powder coating as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned Red copper oxide, zinc powder, ultra-fine barium sulfate, polyvinyl chloride are mixed, heated and stirred reaction 10-15 minute at 70-80 ℃, after discharging is cooling, mix with each raw material of residue, putting into high-speed mixer mixes fully, again gained compound is put into mixing extrusion in high-speed extruder, then after compressing tablet fragmentation, then pulverize, sieve through pulverising mill, described in obtaining, obtain described high adhesive force epoxy powder coating.
CN201310478451.1A 2013-10-14 2013-10-14 High-adhesion-force epoxy resin powdery paint Pending CN103540223A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310478451.1A CN103540223A (en) 2013-10-14 2013-10-14 High-adhesion-force epoxy resin powdery paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310478451.1A CN103540223A (en) 2013-10-14 2013-10-14 High-adhesion-force epoxy resin powdery paint

Publications (1)

Publication Number Publication Date
CN103540223A true CN103540223A (en) 2014-01-29

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310478451.1A Pending CN103540223A (en) 2013-10-14 2013-10-14 High-adhesion-force epoxy resin powdery paint

Country Status (1)

Country Link
CN (1) CN103540223A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104177988A (en) * 2014-07-11 2014-12-03 安徽桑瑞斯环保新材料有限公司 Power coating for metal bonding
CN107556829A (en) * 2016-07-01 2018-01-09 夏杰 A kind of fire-fighting powdery paints

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643611A (en) * 2008-08-05 2010-02-10 上海海隆赛能新材料有限公司 Steel pipe epoxy anti-corrosion powder low-temperature curing coating for over-X80 grade oil and gas pipes
CN101643616A (en) * 2008-08-05 2010-02-10 上海海隆赛能新材料有限公司 Steel pipeline epoxy powder anti-corrosion coating capable of resisting cathodic disbanding for over 30 days
CN101698775A (en) * 2009-09-18 2010-04-28 上海海隆赛能新材料有限公司 Fused-bonded epoxy powder paint with high resistance to cathodic disbonding
CN102002303A (en) * 2010-12-24 2011-04-06 江苏华光粉末有限公司 Pure epoxy quickly-cured powder coating and production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101643611A (en) * 2008-08-05 2010-02-10 上海海隆赛能新材料有限公司 Steel pipe epoxy anti-corrosion powder low-temperature curing coating for over-X80 grade oil and gas pipes
CN101643616A (en) * 2008-08-05 2010-02-10 上海海隆赛能新材料有限公司 Steel pipeline epoxy powder anti-corrosion coating capable of resisting cathodic disbanding for over 30 days
CN101698775A (en) * 2009-09-18 2010-04-28 上海海隆赛能新材料有限公司 Fused-bonded epoxy powder paint with high resistance to cathodic disbonding
CN102002303A (en) * 2010-12-24 2011-04-06 江苏华光粉末有限公司 Pure epoxy quickly-cured powder coating and production method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104177988A (en) * 2014-07-11 2014-12-03 安徽桑瑞斯环保新材料有限公司 Power coating for metal bonding
CN107556829A (en) * 2016-07-01 2018-01-09 夏杰 A kind of fire-fighting powdery paints

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Application publication date: 20140129

RJ01 Rejection of invention patent application after publication