CN103539536A - Plant antifreeze containing ribitol substances - Google Patents

Plant antifreeze containing ribitol substances Download PDF

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Publication number
CN103539536A
CN103539536A CN201310468838.9A CN201310468838A CN103539536A CN 103539536 A CN103539536 A CN 103539536A CN 201310468838 A CN201310468838 A CN 201310468838A CN 103539536 A CN103539536 A CN 103539536A
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sulfate
hours
stir
stirring
percent
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CN103539536B (en
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马梅静
石丽丽
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XINJIANG GAOGUAN SOIL RESEARCH INSTITUTE
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XINJIANG GAOGUAN SOIL RESEARCH INSTITUTE
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Abstract

The invention relates to plant antifreeze containing ribitol substances. With the adoption of the plant antifreeze, the problem that freezing injury on growing crops due to late spring cold and cold currents can be effectively solved. According to the technical scheme solving the problem, the plant antifreeze is prepared from the components in percentage by weight: 6-13 percent of nucleotide, 6-13 percent of glucose, 6-13 percent of amino acid, 6-13 percent of glycerol, 4-8 percent of zinc sulfate, 5-10 percent of ferrous sulfate, 3-5 percent of copper sulfate, 3-5 percent of magnesium sulfate, 3-5 percent of borax, 2-3 percent of manganese sulfate, 3-5 percent of citric acid, 5-10 percent of urea, 3-5 percent of potassium dihydrogen phosphate and 18-22 percent of water. The plant antifreeze is simple in method, good in the using effect, comprehensive in nutrition, high in concentration and good in absorption, and is the very good plant antifreeze containing the ribitol substances for crops under the adverse climate conditions of severe cold, the late spring cold and the like.

Description

A kind of plant frostproofer containing ribitol material
Technical field
The present invention relates to chemical industry production, particularly a kind of plant frostproofer containing ribitol material.
Background technology
Along with the fast development of national economy, the improving constantly of national standard of living, when its people enjoy happy that material life brings, the continuous deterioration of environment is also day by day serious.As: sandstorm, rubble flow, cold spell in later spring, May snow disaster, hail etc.; The abuse of a large amount of chemical fertilizer; The excessive of plant hormone used, cause perennial plant itself malnutritive, dry-matter accumulation lacks, to resisting the ability of extraneous natural disaster, greatly decline, finally cause in the situation of mercury dropped, can not normally pass the winter, cause plant Large Scale Death or whole strain, half strain death, just there is the meteorological report in various places annual March--May: the generation of cold spell in later spring, cold current, cause freeze injury to the crop growing, to peasant, cause imponderable financial loss.Therefore, the improvement of fertilizer is the problem of needing at present solution badly.
Summary of the invention
For above-mentioned situation, for solving the defect of prior art, the present invention's object is just to provide a kind of plant frostproofer containing ribitol material, and the generation that can effectively solve cold spell in later spring, cold current causes the problem of freeze injury to the crop growing.
The technical scheme that the present invention solves is, this frostproofer is by following weight percent meter: Nucleotide 6~13%, glucose 6~13%, amino acid 6~13%, glycerol 6~13%, zinc sulfate 4~8%, ferrous sulfate 5~10%, copper sulfate 3~5%, sal epsom 3~5%, borax 3~5%, manganous sulfate 2~3%, citric acid 3~5%, urea 5~10%, potassium primary phosphate 3~5% and water 18~22% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain, described Nucleotide is one or more the mixture in Triphosaden, uridine triphosphate, cytidine, GTP (guanosine triphosphate), described amino acid is one or more the mixture in Threonine, α-amino-isovaleric acid, methionine(Met), Isoleucine, phenylalanine, arginine, glycine, Methionin, Histidine.
The inventive method is simple, and result of use is good, and nutrition is complete, and concentration is high, and good absorption is a kind of plant frostproofers that well contain ribitol material of farm crop under the bad climate conditions such as severe cold, cold spell in later spring.
Accompanying drawing explanation
Fig. 1 is the cotton seedling figure that area, Usu of the present invention is subject to hail in May, 2013.
Fig. 2 is that area, Usu of the present invention is subject to the cotton seedling of hail to spray recovery situation map after the calamity of product of the present invention in May, 2013.
Tu3Wei Hami Prefecture of the present invention in April, 2013 cold spell in later spring causes rudiment freeze injury figure.
Tu4Wei Hami Prefecture of the present invention sprays the grape growth situation map of product of the present invention in April, 2013 after rudiment freeze injury.
Five, embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described in further detail.
Embodiment 1
This frostproofer is by following weight percent meter: Nucleotide 7~9%, glucose 7~9%, amino acid/11 0~12%, glycerol 10~12%, zinc sulfate 4~6%, ferrous sulfate 8~10%, copper sulfate 3~4%, sal epsom 4~5%, borax 3~4%, manganous sulfate 2~3%, citric acid 4~5%, urea 5~7%, potassium primary phosphate 4~5% and water 18~20% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain.
Embodiment 2
This frostproofer is by following weight percent meter: Nucleotide 10~13%, glucose 10~13%, amino acid 6~9%, glycerol 6~9%, zinc sulfate 7~8%, ferrous sulfate 5~7%, copper sulfate 3.6~5%, sal epsom 3~3.5%, borax 3.6~5%, manganous sulfate 2.6~3%, citric acid 3~3.5%, urea 8~10%, potassium primary phosphate 3~3.5% and water 19~22% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain.
Embodiment 3
This frostproofer is by following weight percent meter: Triphosaden 9%, glucose 9%, α-amino-isovaleric acid 6%, methionine(Met) 5%, glycerol 11%, zinc sulfate 8%, ferrous sulfate 10%, copper sulfate 3%, sal epsom 3%, borax 3%, manganous sulfate 2%, citric acid 3%, urea 7%, potassium primary phosphate 3% and water 18% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25 ℃, react after 2 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2 hours, add while stirring glycerol, stir 2 hours, be down to room temperature, obtain.
Embodiment 4
This frostproofer is by following weight percent meter: cytidine 5%, uridine triphosphate 5%, glucose 10%, arginine 4%, glycine 4%, glycerol 9.5%, zinc sulfate 6%, ferrous sulfate 7%, copper sulfate 4%, sal epsom 4%, borax 4%, manganous sulfate 2.5%, citric acid 4%, urea 8%, potassium primary phosphate 4% and water 20% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 38 ℃, react after 2.5 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 3 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2.5 hours, add while stirring glycerol, stir 2.5 hours, be down to room temperature, obtain.
Embodiment 5
This frostproofer is by following weight percent meter: cytidine 3%, GTP (guanosine triphosphate) 3%, glucose 8%, methionine(Met) 4%, Isoleucine 4%, phenylalanine 5%, glycerol 8%, zinc sulfate 5%, ferrous sulfate 5%, copper sulfate 5%, sal epsom 5%, borax 5%, manganous sulfate 3%, citric acid 5%, urea 5%, potassium primary phosphate 5% and water 22% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 50 ℃, react after 3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 3 hours, add while stirring glycerol, stir 3 hours, be down to room temperature, obtain.
Component of the present invention is reasonable, easily produces, and under equal weather condition, the present invention uses for continuous 3 years on wheat, grape, cotton, 10 mu, experimental plot, and wherein comparative group is 5 mu, and 5 mu of test group are on probation, test group the present invention.
Test-results and analysis:
The present invention sprays before wheatland enters the winter, can promote under wheat root to prick, regulate needed moisture and nutrient in plant body, and wheat seeding is survived the winter and cold spell in later spring is antifreeze a positive effect.Test-results shows, every mu sprays 50 grams of the present invention, and the cold spell in later spring freeze injury rate of wheat seeding only has 3.1%, and the comparative group cold spell in later spring freeze injury rate not spraying is up to 45%.
After grape is plucked, in time to foliage spray product of the present invention, impel blade face photosynthesis to strengthen, dry-matter accumulation is many, improves the activity of enzyme, accelerates the conversion of sugar.Test-results shows, grape is before and after leaves, and dry branch sprays the spray spraying of product of the present invention 1:500~800, grape freeze injury rate 5.6%, and the freeze injury rate not spraying is up to 30%.
In area, Usu, Xinjiang after in May, 2013, cotton was suffered hail invasion and attack, with product 1:800 of the present invention, spray blade face, root at once, spray in every 3 days once, sprays 2 times continuously, after spraying 20 days, the recovery life of cotton seedling (seeing Fig. 1-2) being injured by a crashing object by hail.
Hami Prefecture in April, 2013, at grape, sprout the phase, mercury dropped, cold spell in later spring causes rudiment freeze injury photo and sprays the grape growth situation (seeing Fig. 3-4) of product of the present invention.
Product of the present invention is nontoxic, without hormone.Its nontoxicity test situation is as follows:
One, test objective
By test, understand product oral administration toxic action situation of the present invention.
Two, materials and methods
1, tested material: the present invention is colourless liquid, proportion 1.4.
2, laboratory animal: 40 of the SD rats being provided by Henan Province's Experimental Animal Center, body weight 182~196g, male and female half and half, are in a good state of health, and quarantine on this basis one week.
3, animal grouping and dosage: adopt HornShi method, with 2.15 multiple proportions relation design dosage groups.Experimental animal is divided into four groups at random after weighing, every group female, male each 5.
4, test operation step: experimental animal fasting overnight, medicine is made into suspension with distilled water, and gavage amount is pressed 1.0ml/100g body weight, and a per os gavage is observed 2 weeks, records animal performance situation.
5, evaluation of result: according to the animal dead situation of each dosage group of mouse female, great and mighty or powerful, utilize HornShi method to obtain the credibility interval of LD50 and 95%.According to People's Republic of China's agricultural chemicals acute toxicity grading criteria (GB15670-1995), tested material is made to acute toxicity classification.
Three, test-results
Dosage grouping and test-results see the following form, and female, the great and mighty or powerful mouse of each dosage group is all without dead.
Real from upper illness that has not attacked the vital organs of the human body, after mouse oral administration female, great and mighty or powerful, without obvious toxicity symptom, in the observation period, rat is without death.
Four, conclusion
Product of the present invention is greater than 5050mg/kg body weight to male rat and female rats oral administration, without abnormal conditions, therefore according to State Standard of the People's Republic of China < < agriculture chemical registration toxicology test method > > (GB15670-1995) Pesticides acute oral toxicity grade scale, the invention belongs to hypotoxicity or nontoxicity, safe and reliable, it is a kind of good plant frostproofer containing ribitol material, its Application and Development is in agriculture frost resistance plant protection, there is good economic and social benefit.

Claims (6)

1. the plant frostproofer containing ribitol material, it is characterized in that, this frostproofer is by following weight percent meter: Nucleotide 6~13%, glucose 6~13%, amino acid 6~13%, glycerol 6~13%, zinc sulfate 4~8%, ferrous sulfate 5~10%, copper sulfate 3~5%, sal epsom 3~5%, borax 3~5%, manganous sulfate 2~3%, citric acid 3~5%, urea 5~10%, potassium primary phosphate 3~5% and water 18~22% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain, described Nucleotide is one or more the mixture in Triphosaden, uridine triphosphate, cytidine, GTP (guanosine triphosphate), described amino acid is one or more the mixture in Threonine, α-amino-isovaleric acid, methionine(Met), Isoleucine, phenylalanine, arginine, glycine, Methionin, Histidine.
2. the plant frostproofer containing ribitol material according to claim 1, it is characterized in that, this frostproofer is by following weight percent meter: Nucleotide 7~9%, glucose 7~9%, amino acid/11 0~12%, glycerol 10~12%, zinc sulfate 4~6%, ferrous sulfate 8~10%, copper sulfate 3~4%, sal epsom 4~5%, borax 3~4%, manganous sulfate 2~3%, citric acid 4~5%, urea 5~7%, potassium primary phosphate 4~5% and water 18~20% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain.
3. the plant frostproofer containing ribitol material according to claim 1, it is characterized in that, this frostproofer is by following weight percent meter: Nucleotide 10~13%, glucose 10~13%, amino acid 6~9%, glycerol 6~9%, zinc sulfate 7~8%, ferrous sulfate 5~7%, copper sulfate 3.6~5%, sal epsom 3~3.5%, borax 3.6~5%, manganous sulfate 2.6~3%, citric acid 3~3.5%, urea 8~10%, potassium primary phosphate 3~3.5% and water 19~22% are made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25~50 ℃, react after 2~3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2~4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2~3 hours, add while stirring glycerol, stir 2~3 hours, be down to room temperature, obtain.
4. the plant frostproofer containing ribitol material according to claim 1, it is characterized in that, this frostproofer is by following weight percent meter: Triphosaden 9%, glucose 9%, α-amino-isovaleric acid 6%, methionine(Met) 5%, glycerol 11%, zinc sulfate 8%, ferrous sulfate 10%, copper sulfate 3%, sal epsom 3%, borax 3%, manganous sulfate 2%, citric acid 3%, urea 7%, potassium primary phosphate 3% and water 18% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 25 ℃, react after 2 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 2 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2 hours, add while stirring glycerol, stir 2 hours, be down to room temperature, obtain.
5. the plant frostproofer containing ribitol material according to claim 1, it is characterized in that, this frostproofer is by following weight percent meter: cytidine 5%, uridine triphosphate 5%, glucose 10%, arginine 4%, glycine 4%, glycerol 9.5%, zinc sulfate 6%, ferrous sulfate 7%, copper sulfate 4%, sal epsom 4%, borax 4%, manganous sulfate 2.5%, citric acid 4%, urea 8%, potassium primary phosphate 4% and water 20% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 38 ℃, react after 2.5 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 3 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 2.5 hours, add while stirring glycerol, stir 2.5 hours, be down to room temperature, obtain.
6. the plant frostproofer containing ribitol material according to claim 1, it is characterized in that, this frostproofer is by following weight percent meter: cytidine 3%, GTP (guanosine triphosphate) 3%, glucose 8%, methionine(Met) 4%, Isoleucine 4%, phenylalanine 5%, glycerol 8%, zinc sulfate 5%, ferrous sulfate 5%, copper sulfate 5%, sal epsom 5%, borax 5%, manganous sulfate 3%, citric acid 5%, urea 5%, potassium primary phosphate 5% and water 22% is made, wherein, first by amino acid, glucose, Nucleotide is poured the water being placed in reactor into, at 50 ℃, react after 3 hours, add successively while stirring citric acid, zinc sulfate, ferrous sulfate, sal epsom, manganous sulfate, copper sulfate, borax, stir after 4 hours, add successively while stirring again urea, potassium primary phosphate, stir and mix for 3 hours, add while stirring glycerol, stir 3 hours, be down to room temperature, obtain.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922840A (en) * 2014-04-04 2014-07-16 李美凤 Compound plant anti-freezing agent and preparation method thereof
CN104472285A (en) * 2015-01-13 2015-04-01 薛金国 Preparation and method for preventing freezing damage to plants
CN105272612A (en) * 2015-10-27 2016-01-27 丹阳市香逸林果专业合作社 Anti-freezing nutrient solution for crape myrtle
WO2016167284A1 (en) * 2015-04-16 2016-10-20 学校法人関西大学 Anti-ice nucleation activator
CN106747905A (en) * 2016-11-18 2017-05-31 安徽新视野园林绿化工程有限公司 A kind of Plant antifreezer with disinsection efficiency and preparation method thereof
CN107646598A (en) * 2017-11-18 2018-02-02 五河县金满塘生态种养殖家庭农场 A kind of field management method for promoting mung bean full seed
CN108892587A (en) * 2018-08-15 2018-11-27 河南七喜龙生物科技有限公司 A kind of selenium-enriched fertilizer of glycosidase containing nucleotide
CN114456007A (en) * 2022-02-25 2022-05-10 郑州盛润生物质能源化工研究院 Compound phosphorus-potassium coloring sugar-increasing fertilizer and preparation method thereof

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CN1672496A (en) * 2005-04-01 2005-09-28 郑博恩 Plant-antifreezing liquid and its prepn
CN101485340A (en) * 2009-02-18 2009-07-22 宫玲玲 Nutrient solution for preventing frost damage of plant and production method
CN101774852A (en) * 2010-01-12 2010-07-14 湖南农大海特农化有限公司 Multifunctional composite seed coating agent
CN102040417A (en) * 2009-10-22 2011-05-04 李绍龙 Plant anti-freezing fluid
CN103332998A (en) * 2010-10-21 2013-10-02 高旌 Method for producing high-quality high-yield bark type traditional Chinese medicinal material
CN103332980A (en) * 2010-10-21 2013-10-02 高旌 Method for preparing nutrient for promoting growth of bark type traditional Chinese medicinal materials

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CN1672496A (en) * 2005-04-01 2005-09-28 郑博恩 Plant-antifreezing liquid and its prepn
CN101485340A (en) * 2009-02-18 2009-07-22 宫玲玲 Nutrient solution for preventing frost damage of plant and production method
CN102040417A (en) * 2009-10-22 2011-05-04 李绍龙 Plant anti-freezing fluid
CN101774852A (en) * 2010-01-12 2010-07-14 湖南农大海特农化有限公司 Multifunctional composite seed coating agent
CN103332998A (en) * 2010-10-21 2013-10-02 高旌 Method for producing high-quality high-yield bark type traditional Chinese medicinal material
CN103332980A (en) * 2010-10-21 2013-10-02 高旌 Method for preparing nutrient for promoting growth of bark type traditional Chinese medicinal materials

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103922840A (en) * 2014-04-04 2014-07-16 李美凤 Compound plant anti-freezing agent and preparation method thereof
CN103922840B (en) * 2014-04-04 2016-08-17 青岛大学 A kind of compound plant antifreezing agent and preparation method thereof
CN104472285A (en) * 2015-01-13 2015-04-01 薛金国 Preparation and method for preventing freezing damage to plants
WO2016167284A1 (en) * 2015-04-16 2016-10-20 学校法人関西大学 Anti-ice nucleation activator
JPWO2016167284A1 (en) * 2015-04-16 2018-03-01 学校法人 関西大学 Anti-ice nuclear activator
US10633570B2 (en) 2015-04-16 2020-04-28 The School Corporation Kansai University Anti-ice nucleation activator
CN105272612A (en) * 2015-10-27 2016-01-27 丹阳市香逸林果专业合作社 Anti-freezing nutrient solution for crape myrtle
CN106747905A (en) * 2016-11-18 2017-05-31 安徽新视野园林绿化工程有限公司 A kind of Plant antifreezer with disinsection efficiency and preparation method thereof
CN107646598A (en) * 2017-11-18 2018-02-02 五河县金满塘生态种养殖家庭农场 A kind of field management method for promoting mung bean full seed
CN107646598B (en) * 2017-11-18 2020-10-20 阜阳市艺凯农业科技有限公司 Method for promoting field management of full mung bean seeds
CN108892587A (en) * 2018-08-15 2018-11-27 河南七喜龙生物科技有限公司 A kind of selenium-enriched fertilizer of glycosidase containing nucleotide
CN114456007A (en) * 2022-02-25 2022-05-10 郑州盛润生物质能源化工研究院 Compound phosphorus-potassium coloring sugar-increasing fertilizer and preparation method thereof

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