CN101333132A - Plant acid water-solubility foliage fertilizer - Google Patents

Plant acid water-solubility foliage fertilizer Download PDF

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CN101333132A
CN101333132A CNA2008101408370A CN200810140837A CN101333132A CN 101333132 A CN101333132 A CN 101333132A CN A2008101408370 A CNA2008101408370 A CN A2008101408370A CN 200810140837 A CN200810140837 A CN 200810140837A CN 101333132 A CN101333132 A CN 101333132A
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sulfate
acid
under
hours
borax
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李海涛
马梅静
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Abstract

The invention relates to a plant acid water-soluble foliar fertilizer, which effectively solves the problems that the existing fertilizer contains hormones and is harmful to the health of people. The technical proposal is that based on weight percentage, the fertilizer comprises 25-66% of plant acid, 7-32% of zinc sulfate, 2-16% of copper sulfate, 3-16% of ferrous sulfate, 2-17% of manganese sulfate, 3-14% of magnesium sulfate, 5-25% of borax and 0.2-5% of ammonium molybdate, with a total amount of 100%; the preparation method comprises the following steps: pouring the plant acid into a reactor; at 18-25 DEG C, sequentially adding the zinc sulfate and the copper sulfate during stirring, and enabling the materials in the reactor to be completely dissolved within 2-4 hours; at 18-25 DEG C, sequentially adding the ferrous sulfate and the manganese sulfate during stirring, and evenly mixing the materials to make the materials completely dissolved within 2 to 3 hours; at 18-25 DEG C, sequentially adding the magnesium sulfate, the borax and the ammonium molybdate during stirring, and mixing the materials for 2 to 3 hours to make the materials completely dissolved, namely, the pH value reaches 3-6 and the finished product with a proportion of 1.1-1.3 can be obtained. The method of the invention is simple and effective, which is a major creation in the crop fertilizer field.

Description

A kind of plant acid water-solubility foliage fertilizer
One, technical field
The present invention relates to agricultural fertilizer, particularly a kind of plant acid water-solubility foliage fertilizer.
Two, background technology
Agricultural be unable to do without applies fertilizer to farm crop, at present because long-term application chemical fertilizer and hormones foliage fertilizer, cause soil compaction, the quality of agricultural product mouthfeel descends, and is human because the food of long-term edible hormones fertiliser production, thereby caused a series of untoward reaction, increase as present childhood obesity, the liver sickness rate improves, and not only influences the Agro-ecology balance, but also serious harm people healthy, be expert at so it improves gesture.
Three, summary of the invention
At above-mentioned situation, for overcoming the prior art defective, the present invention's purpose just provides the water-soluble foliage fertilizer of vegetable acid, can effectively solve in the existing chemical fertilizer and contain hormone, the farm crop that cause growing eat the untoward reaction that cause the back, the healthy problem of harm people, the technical scheme of its solution is, by by weight percentage: vegetable acid 25-66%, zinc sulfate 7-32%, copper sulfate 2-16%, ferrous sulfate 3-16%, manganous sulfate 2-17%, sal epsom 3-14%, borax 5-25% and molybdenum acid ammonia 0.2-5%, total amount is 100% to make, said vegetable acid is by by weight percentage: acetic acid 48%, propionic acid 43%, acetone 1.7%, 2-Furan Aldehydes 2.1%, 2-cyclopentenone 0.2%, o-hydroxyanisole 0.3%, p-cresol 1.0%, to cresols 1.4%, ortho-cresol 1.2%, ethyl guaiacol 0.3%, furfural 0.5% and flavones 0.7% mixes composition; During preparation,, earlier vegetable acid is poured in the reactor by above-mentioned component requirement, under 18-25 ℃, add zinc sulfate, copper sulfate while stirring successively, dissolving fully in 2-4 hour, under 18-25 ℃, add ferrous sulfate, manganous sulfate, stirring and evenly mixing while stirring successively again, dissolving fully in 2-3 hour under 18-25 ℃, adds sal epsom, borax, molybdenum acid ammonia while stirring successively, stirred 2-3 hour, dissolving is pH value 3-6, the finished product of proportion 1.1-1.3 fully.The inventive method is simple, and result of use is good, and infertile field, strong sprout, volume increase, disease-resistant do not contain hormone, and purposes is wide, is that create greatly in one on the farm crop chemical fertilizer field.
Four, embodiment
Below in conjunction with practical situation, the specific embodiment of the present invention is elaborated.
In force, the present invention can be by by weight: vegetable acid 500-1000 part, zinc sulfate 150-400 part, copper sulfate 50-180 part, ferrous sulfate 80-180 part, manganous sulfate 50-200 part, sal epsom 60-160, borax 120-300 part and molybdenum acid ammonia 5-50 part are made, during preparation, by above-mentioned component requirement, earlier vegetable acid is poured in the reactor, under 18-25 ℃ of temperature, add zinc sulfate while stirring successively, copper sulfate, dissolving fully in 2-4 hour adds ferrous sulfate more while stirring successively under 18-25 ℃ of temperature, manganous sulfate, stirred 2-3 hour, dissolving adds sal epsom while stirring successively under 18-25 ℃ of temperature fully, borax, molybdenum acid ammonia stirred 2-3 hour, dissolving fully, be finished product, the finished product pH value is 3-6, proportion 1.1-1.3.
Embodiment 1: the present invention is by by weight percentage: vegetable acid 45%, zinc sulfate 20%, copper sulfate 5.6%, ferrous sulfate 6.7%, manganous sulfate 4.5%, sal epsom 6.7%, borax 11% and molybdenum acid ammonia 0.5% made, during preparation, earlier vegetable acid is poured in the reactor, under 19 ℃ of temperature, added zinc sulfate more while stirring successively by above-mentioned component requirement, copper sulfate, 3.5 hour dissolving fully, under 19 ℃ of temperature, add ferrous sulfate while stirring successively again, manganous sulfate stirred 3 hours, dissolving fully, under 19 ℃ of temperature, add sal epsom while stirring successively, borax, molybdenum acid ammonia stirred 3 hours, dissolving fully, be finished product, the finished product pH value is 3.8, proportion 1.17.
Embodiment 2: the present invention is by by weight: 800 parts of vegetable acids, 350 parts in zinc sulfate, 100 parts in copper sulfate, 120 parts in ferrous sulfate, 80 parts of manganous sulfates, 120 parts in sal epsom, 200 parts of boraxs and molybdenum acid ammonia are made for 10 parts, during preparation, earlier vegetable acid is poured in the reactor, under 21 ℃ of temperature, added zinc sulfate more while stirring successively by above-mentioned component requirement, copper sulfate, 2.5 hour dissolving fully, under 21 ℃ of temperature, add ferrous sulfate while stirring successively again, manganous sulfate stirred 2.5 hours, dissolving fully, under 21 ℃ of temperature, add sal epsom while stirring successively, borax, molybdenum acid ammonia stirred 2.5 hours, dissolving fully, be finished product, the finished product pH value is 4, proportion 1.2.
Embodiment 3: the present invention is by vegetable acid 800kg, zinc sulfate 350kg, copper sulfate 100kg, ferrous sulfate 120kg, manganous sulfate 80kg, sal epsom 120kg, borax 200kg and molybdenum acid ammonia 10kg make, and during preparation, earlier vegetable acid are poured in the reactor by above-mentioned component requirement, under 24 ℃ of temperature, add zinc sulfate more while stirring successively, copper sulfate, dissolving fully in 2 hours under 24 ℃ of temperature, adds ferrous sulfate more while stirring successively, manganous sulfate, stirred 2 hours, dissolving fully under 24 ℃ of temperature, adds while stirring successively, sal epsom, borax, molybdenum acid ammonia, stirred 2 hours, dissolving is finished product fully, the finished product pH value is 5.7, proportion 1.27.
Component of the present invention is reasonable, easily produces, and result of use is good, and through on probation, its product has following outstanding function:
1, increases output, improve quality; 10 mu in experimental plot, wherein comparative group is 5 mu, 5 mu of test group are on probation, and comparative group is with conventional nitrogen, phosphorus, potassic fertilizer, test group the present invention, after common wheat is used, under equal weather condition, continuous 3 years, the comparable comparative group of thousand seed weight increased the 4-6 gram, improve output more than 20%, the wet gluten value can reach 35; Corn, paddy rice, beans were tried out through continuous 3 years, and volume increase is all at 15-30%, and fruit increases sugar degree 3-5%, and flowers prolong 5-10 days flowering period.
2, can take precautions against drought, antifreeze, anti-hot dry wind, natural repair ability is strong behind the hail, and very strong anti-adversity ability is arranged.Through adjacent with weather condition under, the 5 mu of tests in continuous 3 years in experimental plot, with the wheat is example, comparative group is with conventional fertilizer or other sprays commonly used (blade face treasured), test group the present invention, test group seldom has the situation of lodging, yellow strain, death, and comparative group has tangible lodging, yellow strain, the phenomena of mortality.
3, use the weedicide choline dichloride farm crop, when agricultural chemicals specially use excessive after, in time spray liquid of the present invention, can remove murder by poisoning, restore normal growth.
4, can prevent and cure diseases by sterilization and disinfestation, be the root rot of the yellow blight of cotton, dish class, it is all fine to use the back effect, and red spider, aphid, bean worm etc. all can kill.
5, use extensively, each kind of plant all can be used, and can spray, irritates root, seed soaking, dress seed, smears, dips in root etc., and effect is all fine.
6, seepage force is strong, spray four hours after, meet rain and need not respray.
7, Different Crop, the product of suitable different concns can carry out thin up as required, and is very convenient.
8, the present invention contains various trace elements, contains boron 3100mg, copper 980mg, iron 1630mg, molybdenum 400mg, zinc 4770mg in wherein every kilograms of product, can fully satisfy the needs of crop to trace element.
9, through authoritative department test, nontoxic, the no hormone of product of the present invention, and can eliminate and reduce that the interior medicine of soil and crop is residual, worm is residual, clearance rate reaches more than 98%, and its nontoxicity test situation is as follows:
One, test objective
Understand product oral administration toxic action situation of the present invention by test.
Two, material and method
1, tried thing: the present invention is brown liquid, proportion 1.2887.
2, laboratory animal: 40 of the SD rats that provides by Henan Province's Experimental Animal Center, body weight 182-196g, male and female half and half are in a good state of health, and quarantine on this basis a week.
3, animal grouping and dosage: adopt the HornShi method, with 2.15 multiple proportions relation design dosage group.After weighing, experimental animal is divided into four groups at random, every group female, male each 5.
4, test operation step: experimental animal fasting overnight, medicine is made into suspension with distilled water, irritates the stomach amount and presses the 1.0ml/100g body weight, and one time per os is irritated stomach, observes for 2 weeks, record animal performance situation.
5, evaluation of result:, utilize the HornShi method to obtain LD according to the animal dead situation of female, great and mighty or powerful each dosage group of mouse 50And 95% credibility interval.According to People's Republic of China's agricultural chemicals acute toxicity grading criteria (GB15670-1995), made the acute toxicity classification to trying thing.
Three, test-results
Dosage grouping and test-results see the following form, because of female, the great and mighty or powerful mouse of dosage 5000mg/kg body weight group does not all have death, so all the other each group tests are not carried out again.
Figure A20081014083700071
Real from last illness that has not attacked the vital organs of the human body, no obvious toxicity symptom after female, the great and mighty or powerful mouse oral administration, rat does not have death in the observation period.
Four, conclusion
Product of the present invention to male rat and female rats oral administration greater than the 5050mg/kg body weight, no abnormal situation, so according to State Standard of the People's Republic of China's " agriculture chemical registration toxicology test method " (GB15670-1995) in agricultural chemicals acute oral toxicity grade scale, the invention belongs to hypotoxicity or nontoxicity, safe and reliable, be that a kind of good agricultural chemicals and farming are fertile, its Application and Development has huge economic and social benefit.

Claims (4)

1, a kind of plant acid water-solubility foliage fertilizer is characterized in that, by by weight percentage: vegetable acid 25-66%, zinc sulfate 7-32%, copper sulfate 2-16%, ferrous sulfate 3-16%, manganous sulfate 2-17%, sal epsom 3-14%, borax 5-25% and molybdenum acid ammonia 0.2-5%, total amount is 100% to make, said vegetable acid is by by weight percentage: acetic acid 48%, propionic acid 43%, acetone 1.7%, 2-Furan Aldehydes 2.1%, 2-cyclopentenone 0.2%, o-hydroxyanisole 0.3%, p-cresol 1.0%, to cresols 1.4%, ortho-cresol 1.2%, ethyl guaiacol 0.3%, furfural 0.5% and flavones 0.7% mixes composition; Wherein, earlier vegetable acid is poured in the reactor, under 18-25 ℃, add zinc sulfate, copper sulfate while stirring successively, 2-4 hour, fully after the dissolving, under 18-25 ℃, add ferrous sulfate, manganous sulfate, stirring and evenly mixing while stirring successively again, 2-3 hour, fully after the dissolving, under 18-25 ℃, add sal epsom, borax, molybdenum acid ammonia while stirring successively, stirred pH value 3-6, proportion 1.1-1.3 2-3 hour.
2, a kind of plant acid water-solubility foliage fertilizer according to claim 1, it is characterized in that, by said by weight percentage: vegetable acid 45%, zinc sulfate 20%, copper sulfate 5.6%, ferrous sulfate 6.7%, manganous sulfate 4.5%, sal epsom 6.7%, borax 11% and molybdenum acid ammonia 0.5% made, wherein, earlier vegetable acid is poured in the reactor, under 19 ℃ of temperature, added zinc sulfate more while stirring successively, copper sulfate, 3.5 hours, fully after the dissolving, under 19 ℃ of temperature, add ferrous sulfate while stirring successively again, manganous sulfate stirred 3 hours, fully after the dissolving, under 19 ℃ of temperature, add sal epsom while stirring successively, borax, molybdenum acid ammonia stirred 3 hours, pH value is 3.8, proportion 1.17.
3, a kind of plant acid water-solubility foliage fertilizer according to claim 1, it is characterized in that, by said by weight: 800 parts of vegetable acids, 350 parts in zinc sulfate, 100 parts in copper sulfate, 120 parts in ferrous sulfate, 80 parts of manganous sulfates, 120 parts in sal epsom, 200 parts of boraxs and molybdenum acid ammonia are made for 10 parts, wherein, earlier vegetable acid is poured in the reactor, under 21 ℃ of temperature, added zinc sulfate more while stirring successively, copper sulfate, 2.5 hours, fully after the dissolving, under 21 ℃ of temperature, add ferrous sulfate while stirring successively again, manganous sulfate stirred 2.5 hours, fully after the dissolving, under 21 ℃ of temperature, add sal epsom while stirring successively, borax, molybdenum acid ammonia stirred 2.5 hours, pH value is 4, proportion 1.2.
4, a kind of plant acid water-solubility foliage fertilizer according to claim 1, it is characterized in that, by said vegetable acid 800kg, zinc sulfate 350kg, copper sulfate 100kg, ferrous sulfate 120kg, manganous sulfate 80kg, sal epsom 120kg, borax 200kg and molybdenum acid ammonia 10kg make, wherein, earlier vegetable acid is poured in the reactor, under 24 ℃ of temperature, added zinc sulfate more while stirring successively, copper sulfate, 2 hours, after the dissolving, under 24 ℃ of temperature, add ferrous sulfate while stirring successively more fully, manganous sulfate, stirred 2 hours, after the dissolving, under 24 ℃ of temperature, add successively while stirring fully, sal epsom, borax, molybdenum acid ammonia, stirred 2 hours, pH value is 5.7, proportion 1.27.
CNA2008101408370A 2008-07-28 2008-07-28 Plant acid water-solubility foliage fertilizer Pending CN101333132A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249795A (en) * 2011-04-19 2011-11-23 李海涛 Vegetable acid complex inorganic salt composite agent water-soluble leaf fertilizer
CN102557804A (en) * 2012-02-29 2012-07-11 北京农业职业学院 Foliar spray fertilizer for preventing yellow leaf disease of pear nursery stock
CN103964916A (en) * 2013-01-24 2014-08-06 周军 Multi-element nutrition growth promoter for plants
CN108834711A (en) * 2018-06-13 2018-11-20 凌云县九燕山特色生态种植农民专业合作社 A kind of implantation methods of der Bockdorn

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102249795A (en) * 2011-04-19 2011-11-23 李海涛 Vegetable acid complex inorganic salt composite agent water-soluble leaf fertilizer
CN102557804A (en) * 2012-02-29 2012-07-11 北京农业职业学院 Foliar spray fertilizer for preventing yellow leaf disease of pear nursery stock
CN102557804B (en) * 2012-02-29 2014-05-07 北京农业职业学院 Foliar spray fertilizer for preventing yellow leaf disease of pear nursery stock
CN103964916A (en) * 2013-01-24 2014-08-06 周军 Multi-element nutrition growth promoter for plants
CN108834711A (en) * 2018-06-13 2018-11-20 凌云县九燕山特色生态种植农民专业合作社 A kind of implantation methods of der Bockdorn

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Open date: 20081231