CN103535350A - Plant source fumigation insecticide containing methyl salicylate and trans-cinnamaldehyde - Google Patents
Plant source fumigation insecticide containing methyl salicylate and trans-cinnamaldehyde Download PDFInfo
- Publication number
- CN103535350A CN103535350A CN201310496646.9A CN201310496646A CN103535350A CN 103535350 A CN103535350 A CN 103535350A CN 201310496646 A CN201310496646 A CN 201310496646A CN 103535350 A CN103535350 A CN 103535350A
- Authority
- CN
- China
- Prior art keywords
- trans
- agent
- gaultherolin
- mosquito
- cinnamaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a plant source fumigation insecticide containing methyl salicylate and trans-cinnamaldehyde. The prepared fumigation insecticide is prepared from a knockdown agent and a lethal agent in a volume ratio of 1:1, wherein the knockdown agent is wintergreen oil or methyl salicylate; the lethal agent is cinnamon oil or trans-cinnamaldehyde. The preparation form is aerosol, spray, smoke agent, disc type mosquito-repellent incense, electric warming mosquito incense liquor or electric warming mosquito incense plate, so that pests are controlled in the form of aerosol, fine spray, smoke or vapor. The plant source fumigation insecticide containing methyl salicylate and trans-cinnamaldehyde disclosed by the invention is safe and nonirritant to human body, easy to decompose without residues, free from pollution to environment, and can be used as a substitute product of the conventional chemical fumigation agent.
Description
Technical field
The present invention relates to a kind of fumigating insecticide, particularly a kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde, is mainly used in the sanitary insect pests such as control mosquito, fly.
Background technology
Mosquito is important sanitary insect pest, they by harassing, bite, the various ways harm humans such as parasitic lives, and the epidemic disease such as can spread disease pathogene and the plague, typhoid fever, malaria, serious threat people's life security.Hygienic insecticide, owing to being directly applied in human residential environment, contacts when long with human body, therefore higher to its security requirement.For a long time, what the control of sanitary insect pest was mainly used is the agricultural chemicals of chemosynthesis, and long-term use meeting has potential impact to living environment and health.
Wintergreen and cinnamon oil are two kinds and from the branches and leaves of leaf of Chinese ilex and Chinese cassia tree, extract respectively the plants essential oil obtaining, and at occurring in nature aboundresources, and have realized suitability for industrialized production, are widely used at present the industries such as food, daily use chemicals, spices, medicine.Wintergreen and Chinese cassia tree main body of oil are respectively gaultherolin and trans-cinnamic aldehyde, and these two kinds of compounds all can manually synthesize.Wintergreen and cinnamon oil be easily volatilization in environment, thus residual lower, do not pollute living environment, safer to people and animals, and there is salubrious pleasant fragrance, there are the potentiality that exploitation becomes the plant resource fumigating insecticide of safety, green, efficient, environmental protection.
Summary of the invention
The object of the invention is to, a kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde is provided, this fumigating insecticide is non-stimulated to human-body safety, easily decomposes noresidue, environmentally safe.
In order to realize above-mentioned task, the present invention takes following technical solution:
A kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde, it is characterized in that, this fumigating insecticide making is formulated for 1:1 by volume by knock down agent and lethal agent, and wherein knock down agent is wintergreen or gaultherolin, and lethal agent is cinnamon oil or trans-cinnamic aldehyde.
Preparation form is aerosol, spray, aerosol, coiled mosquito-repellent incense, mosquito liquid or electric mosquito repellent tablet, can pass through the form control insect of aerosol, mist, cigarette or steam.
Plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde of the present invention, take botanical components as active ingredient, has following characteristics:
1, active ingredient is wintergreen and cinnamon oil, or gaultherolin and trans-cinnamic aldehyde, and these four kinds of materials are natural plant active substance, green noresidue, to human-body safety, and do not pollute indoor environment, be applicable to the sanitary insect pest control in places such as living, handle official business, have a dinner.
2, active ingredient is two classes: wintergreen or gaultherolin can be used as stifling knock down agent, and cinnamon oil or trans-cinnamic aldehyde can be used as stifling lethal agent, and two class materials, through composite, have and knock down fast and efficient lethal effect insect.
Accompanying drawing explanation
Fig. 1 is wintergreen and gaultherolin stifling knocking down-time effect figure to Culex pipiens pallens under 0.6 μ L/L concentration;
Fig. 2 is cinnamon oil and trans-cinnamic aldehyde stifling knocking down-time effect figure to Culex pipiens pallens under 0.6 μ L/L concentration;
Fig. 3 is two kinds of compositions (wintergreen and cinnamon oils; Gaultherolin and trans-cinnamic aldehyde) knock down-time effect figure to Culex pipiens pallens;
Below in conjunction with drawings and Examples, the present invention is described in further detail.
Embodiment
Applicant, through wintergreen and cinnamon oil and active ingredient gaultherolin thereof and trans-cinnamic aldehyde are studied, determines that four after reasonable compatibility, as a kind of fumigating insecticide, to killing the sanitary insect pests such as mosquito, fly, has good effect.Preparation form can be aerosol, spray, aerosol, coiled mosquito-repellent incense, mosquito liquid or electric mosquito repellent tablet, by the form control insect of aerosol, mist, cigarette or steam.Can be according to the known solvent of corresponding dosage form selection and auxiliary agent preparation, as the substitute products of traditional chemical fumigant.
Below the specific experiment that inventor provides:
1) adopt the airtight fumigating system of triangular flask, measure wintergreen and the stifling lethal activity of cinnamon oil to Culex pipiens pallens, concrete grammar is:
20 female worms of healthy Culex pipiens pallens of access in triangular flask (V=330mL).One end of the filter paper bar of a wide 1cm of long 3cm is fixed on rubber stopper with pin simultaneously, with microsyringe, on filter paper, adds the four kinds of test samples (wintergreen, gaultherolin, cinnamon oil and trans-cinnamic aldehyde) that become different gradient concentrations by acetone diluted.Sample adds rear rapid jam-pack rubber stopper, 26 ℃ ± 1 ℃ of temperature, under relative moisture 65% ± 5% condition, processes, and checks the dead result of mosquito after 5h.To stimulate mosquito belly with tweezers tip, mosquito not reaction is death standard.Every processing repeats 3 times, establishes blank.Result is as shown in table 1:
Table 1: wintergreen and cinnamon oil and main component thereof are to the fumigation effect of Culex pipiens pallens (5h)
| Sequence number | Sample | LC 50(μL/L) | LC 95(μL/L) | 95% confidence interval (μ L/L) |
| 1 | Wintergreen | 1.693 | 2.916 | 1.527～1.930 |
| 2 | Gaultherolin | 1.277 | 2.160 | 1.193～1.363 |
| 3 | Cinnamon oil | 0.313 | 0.837 | 0.267～0.380 |
| 4 | Trans-cinnamic aldehyde | 0.293 | 0.597 | 0.243～0.330 |
2) adopt the airtight fumigating system of triangular flask, measure wintergreen and cinnamon oil and main component gaultherolin and trans-cinnamic aldehyde stifling activity of knocking down to Culex pipiens pallens under low dosage, concrete grammar is:
20 healthy Culex pipiens pallens examination worms of access in triangular flask (V=330mL).One end of the filter paper bar of a wide 1cm of long 3cm is fixed on rubber stopper with pin simultaneously, the confession examination essential oil (wintergreen or cinnamon oil) that adds doses with microsyringe on filter paper, rapid jam-pack rubber stopper, be placed in 26 ℃ ± 1 ℃ of temperature, under relative moisture 65% ± 5% condition, every 5min～10min, check and knock down borer population.The standard of knocking down is that mosquito back lands, six foots upward or lie on one's side, can not normally climb and fly.Every processing repeats 3 times, sets up blank.
On the basis of afore-mentioned test result, select and be equivalent to trans-cinnamic aldehyde LC
95concentration 0.6 μ L/L carry out wintergreen, gaultherolin, cinnamon oil and cinnamic acid to the knock down-time effect test in the stifling 5h of Culex pipiens pallens.Test result is shown in Fig. 1, Fig. 2.
From above result, gaultherolin is consistent with wintergreen and cinnamon oil result respectively to the stifling knocking down-time effect of Culex pipiens pallens with trans-cinnamic aldehyde, and the LC to the stifling 5h of Culex pipiens pallens
50all be less than respectively wintergreen and trans-cinnamic aldehyde.In addition they are respectively again the chief component monomers of wintergreen and cinnamon oil, therefore can be tentatively definite, and gaultherolin and trans-cinnamic aldehyde are respectively the effective active composition of wintergreen and cinnamon oil.Also can find out that the two shows different biologically active effects, wintergreen and gaultherolin have preferably and fumigate and knock down activity Culex pipiens pallens simultaneously, and cinnamon oil and trans-cinnamic aldehyde have preferably stifling lethal activity to Culex pipiens pallens.The poisoning force data of associative list 1 is known, and 0.6 μ L/L is wintergreen and the sublethal concentration of gaultherolin to Culex pipiens pallens, and under this concentration, wintergreen and gaultherolin are knock down agents, can be by Culex pipiens pallens fast, all knock down, but mosquito still can recover after going down; Cinnamon oil and trans-cinnamic aldehyde are lethal agents under 0.6 μ L/L concentration, but slower to the speed of knocking down of Culex pipiens pallens.
In actual mosquito control work, to the requirement of medicament, be efficient, quick, therefore the application is to wintergreen and cinnamon oil, and gaultherolin and the trans-cinnamic aldehyde synergy research of having carried out being mixed, to inquire between the two whether there is synergistic function, for the plants essential oil hygienic insecticide of exploitation for mosquito control lays the first stone.
According to gaultherolin, under 0.6 μ L/L concentration, can knock down whole mosquitoes (after again recovery), and trans-cinnamic aldehyde can make mosquito lethality reach 95% under 0.6 μ L/L concentration, therefore the two is mixed under this concentration, (concentration that is gaultherolin and trans-cinnamic aldehyde is 0.6 μ L/L, the two volume ratio is 1:1), wintergreen and cinnamon oil are carried out to same processing as a comparison, test result is shown in Fig. 3 simultaneously.
Result from Fig. 3, wintergreen and cinnamon oil are at 1:1(v/v) ratio under be mixed, gaultherolin and trans-cinnamic aldehyde are at 1:1(v/v) ratio under be mixed, all there is good synergistic activity, at 1.2 μ L/L, supply under examination concentration, Mixed Pharmacy has and well knocks down fast activity Culex pipiens pallens, and 30min rate of knockdown can reach 90%, and mosquito can not recover after going down.Can find out, wintergreen and gaultherolin are knock down agents under sublethal dose, and cinnamon oil and trans-cinnamic aldehyde are lethal agents, and the two has concurrently and knock down fast and efficient lethal effect Culex pipiens pallens after being mixed, and demonstrates certain synergistic function.
Claims (2)
1. the plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde, it is characterized in that, this fumigating insecticide making is formulated for 1:1 by volume by knock down agent and lethal agent, and wherein knock down agent is wintergreen or gaultherolin, and lethal agent is cinnamon oil or trans-cinnamic aldehyde.
2. the plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde as claimed in claim 1, is characterized in that, described preparation form is aerosol, spray, aerosol, coiled mosquito-repellent incense, mosquito liquid or electric mosquito repellent tablet.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310496646.9A CN103535350B (en) | 2013-10-21 | 2013-10-21 | A kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310496646.9A CN103535350B (en) | 2013-10-21 | 2013-10-21 | A kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103535350A true CN103535350A (en) | 2014-01-29 |
| CN103535350B CN103535350B (en) | 2015-08-19 |
Family
ID=49959519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310496646.9A Active CN103535350B (en) | 2013-10-21 | 2013-10-21 | A kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103535350B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4449987A (en) * | 1981-10-29 | 1984-05-22 | Avon Products, Inc. | Fragrant insect repellent composition and combustible candle composition containing same |
| CN1953659A (en) * | 2004-05-10 | 2007-04-25 | 地球制药株式会社 | Insect pest control agent, insecticidal powdery formulation and isopod behavior disruptive agent |
| CN101489377A (en) * | 2006-07-17 | 2009-07-22 | 蒂拉德克公司 | Compositions and methods for controlling insects |
| CN101703075A (en) * | 2009-11-19 | 2010-05-12 | 中国热带农业科学院南亚热带作物研究所 | Botanical plant-protecting agent and preparation method thereof |
-
2013
- 2013-10-21 CN CN201310496646.9A patent/CN103535350B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4449987A (en) * | 1981-10-29 | 1984-05-22 | Avon Products, Inc. | Fragrant insect repellent composition and combustible candle composition containing same |
| CN1953659A (en) * | 2004-05-10 | 2007-04-25 | 地球制药株式会社 | Insect pest control agent, insecticidal powdery formulation and isopod behavior disruptive agent |
| CN101489377A (en) * | 2006-07-17 | 2009-07-22 | 蒂拉德克公司 | Compositions and methods for controlling insects |
| CN101703075A (en) * | 2009-11-19 | 2010-05-12 | 中国热带农业科学院南亚热带作物研究所 | Botanical plant-protecting agent and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| R.S. YOUSSIF, E.A.SHAALAN: "Mosquitocidal activity of some volatile oils against Aedes caspius mosquitoes", 《J VECTOR BORNE》 * |
| 付臣臣 等: "41种植物精油对淡色库蚊的熏蒸活性", 《昆虫学报》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103535350B (en) | 2015-08-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102326590A (en) | Mugwort leaf mosquito incense | |
| CN104054758A (en) | Harmless plant insecticide | |
| US20130196006A1 (en) | pH MODIFIED INSECT REPELLENT/INSECTICIDE COMPOSED OF PLANT ESSENTIAL OILS | |
| CN102919282B (en) | Rat repelling agent | |
| CN107873701A (en) | A kind of aerosol for expelling parasite, sterilizing and mite killing and preparation method thereof | |
| CN106265168A (en) | A kind of preparation method of natural composite plant mosquito-driving liquid antibacterial, antipruritic | |
| CN105597126A (en) | Botanical disinfection deodorant | |
| CN102907420B (en) | Insect aerosol synergist | |
| CN106726871A (en) | Sweet wormwood mosquito-expelling and antipruritic floral water and preparation method thereof | |
| CN110384113A (en) | A kind of prevention and treatment mosquitos and flies insecticide and its preparation method and application | |
| KR101301144B1 (en) | Insect repellent having wood vineger as an active ingredient | |
| CN106236614A (en) | A kind of preparation method of composite natral plant mosquito-driving liquid | |
| KR100947580B1 (en) | Record and cultural antiseptic composition for cital, pyrethrin, linalyl acetate | |
| CN103535350B (en) | A kind of plant resource fumigating insecticide containing gaultherolin and trans-cinnamic aldehyde | |
| CN105028536B (en) | It is a kind of for the compound plant insecticide of mosquito larvae control and its preparation and application | |
| CN101341877B (en) | Pesticide preparation mixed with tubatoxin, pyrethroid and phoxim | |
| CN103109819A (en) | Fragrant pesticide | |
| Baker et al. | Cedarwood oil profile | |
| CN106135261A (en) | A kind of vaporizer mosquito liquid | |
| Uppala et al. | Formulation and Evaluation of Mosquito Repellent Activity of Polyherbal Formulations of Extraction of Annona squamosa, Azadirachta indica, Eucalyptus alba, Citrus aurantium and Rosa indica and their phytochemical analysis | |
| CN110651797A (en) | Plant extract, compound botanical insecticide, preparation method and application | |
| CN107751252A (en) | Application of the Du Xiang branches and leaves total volatile oil in grain storage pest is prevented and treated | |
| JPH0469308A (en) | Centipede repellent | |
| CN106172389A (en) | A kind of natural plants mosquito incense and preparation method thereof | |
| Hiremath | Review on Study of Insecticidal Activity of Cymbopogon citratus, and Aloe vera against Musca domestica |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210121 Address after: 712100 Shaanxi Province, Xi'an city Yangling District Tai Road No. 3 demonstration Patentee after: NORTHWEST A & F University Address before: 712100 Shaanxi Province, Xi'an city Yangling District Tai Road No. 3 demonstration Patentee before: RESEARCH & DEVELOPMENT CENTER OF BIORATIONAL PESTICIDE YANGLING NONGKEDA |