CN103534228A - 制备2，3，3，3-四氟-2-丙烯的方法 - Google Patents

制备2，3，3，3-四氟-2-丙烯的方法 Download PDF

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Publication number
CN103534228A
CN103534228A CN201280005395.3A CN201280005395A CN103534228A CN 103534228 A CN103534228 A CN 103534228A CN 201280005395 A CN201280005395 A CN 201280005395A CN 103534228 A CN103534228 A CN 103534228A
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reactor
tcp
hydrofluorination
phase
liquid phase
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English (en)
Chinese (zh)
Inventor
H·科卡利
S·A·科特雷尔
Y·邱
童雪松
K·D·乌里奇
P·施奈德
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Honeywell International Inc
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Honeywell International Inc
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Priority to CN201810257855.0A priority Critical patent/CN108358745A/zh
Publication of CN103534228A publication Critical patent/CN103534228A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201280005395.3A 2011-01-19 2012-01-13 制备2，3，3，3-四氟-2-丙烯的方法 Pending CN103534228A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810257855.0A CN108358745A (zh) 2011-01-19 2012-01-13 制备2，3，3，3-四氟-2-丙烯的方法

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201161434005P 2011-01-19 2011-01-19
US61/434,005 2011-01-19
US13/313,649 US9890096B2 (en) 2011-01-19 2011-12-07 Methods of making 2,3,3,3-tetrafluoro-2-propene
US13/313,649 2011-12-07
PCT/US2012/021158 WO2012099776A1 (en) 2011-01-19 2012-01-13 Methods of making 2,3,3,3-tetrafluoro-2-propene

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CN103534228A true CN103534228A (zh) 2014-01-22

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CN201280005395.3A Pending CN103534228A (zh) 2011-01-19 2012-01-13 制备2，3，3，3-四氟-2-丙烯的方法
CN201810257855.0A Pending CN108358745A (zh) 2011-01-19 2012-01-13 制备2，3，3，3-四氟-2-丙烯的方法

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Country Link
US (1) US9890096B2 (enExample)
EP (1) EP2665696B1 (enExample)
JP (1) JP5953317B2 (enExample)
KR (1) KR101925339B1 (enExample)
CN (2) CN103534228A (enExample)
ES (1) ES2666489T3 (enExample)
MX (1) MX2013008287A (enExample)
WO (1) WO2012099776A1 (enExample)

Cited By (5)

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CN105960277A (zh) * 2014-02-10 2016-09-21 霍尼韦尔国际公司 用于液相氟化的反应器设计
CN107848916A (zh) * 2015-07-17 2018-03-27 墨西哥氟石股份公司 用于制备2,3,3,3‑四氟丙烯(1234yf)的制程
CN107848919A (zh) * 2015-07-17 2018-03-27 墨西哥氟石股份公司 用于干燥氢(氯)氟烯烃的方法
CN108137448A (zh) * 2015-08-19 2018-06-08 霍尼韦尔国际公司 从卤代丙烯中除去酸性杂质的方法
CN111344270A (zh) * 2017-10-13 2020-06-26 霍尼韦尔国际公司 用于从2，3，3，3-四氟丙烯(HFO-1234yf)中移除不饱和卤化杂质的方法

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US8927791B2 (en) * 2010-04-29 2015-01-06 Honeywell International Inc. Method for producing tetrafluoropropenes
EP2755937B1 (en) 2011-09-15 2019-10-30 Daikin Industries, Ltd. Method for purifying chlorinated hydrocarbon
ES2709201T3 (es) 2013-03-12 2019-04-15 Honeywell Int Inc Un método de mitigar la formación de HCF-245cb durante la hidrofluoración de HCFO-1233xf en HCFC-244bb
WO2014165094A1 (en) * 2013-03-13 2014-10-09 Honeywell International Inc. Staged fluorination process and reactor system
US9272968B2 (en) 2013-03-14 2016-03-01 Honeywell International Inc. Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture
US9353029B2 (en) 2013-03-14 2016-05-31 Honeywell International, Inc. Fluorination process and reactor
US20140275651A1 (en) * 2013-03-15 2014-09-18 Honeywell International Inc. Process for producing 2,3,3,3-tetrafluoropropene
EP2986583B1 (en) * 2013-04-18 2019-07-17 Honeywell International Inc. Reaction system and process to produce fluorinated organics
KR20160122786A (ko) * 2014-02-10 2016-10-24 허니웰 인터내셔날 인코포레이티드 액상 플루오르화 반응을 위한 반응기
US9975824B2 (en) 2014-09-30 2018-05-22 Daikin Industries, Ltd. Method for producing 2,3,3,3-tetrafluoropropene
JP6210073B2 (ja) * 2015-01-21 2017-10-11 ダイキン工業株式会社 フルオロプロペンの製造方法
EP3286160A4 (en) * 2015-04-24 2019-01-16 Honeywell International Inc. METHOD FOR REDUCING 1233XF CONCENTRATION IN 244BB
CN107635955A (zh) * 2015-05-21 2018-01-26 科慕埃弗西有限公司 通过SbF5进行的1233xf至244bb的氢氟化
GB201701099D0 (en) * 2017-01-23 2017-03-08 Mexichem Fluor Sa De Cv Process
KR101992230B1 (ko) 2017-08-08 2019-06-25 (주)후성 기상 촉매를 이용한 1,1,1-트리플루오로-2-클로로프로펜과 1,1,1,2-테트라플루오로프로펜의 동시 제조 방법
US10351494B1 (en) 2018-01-08 2019-07-16 Honeywell International Inc. Systems and methods for reducing the formation of impurities during 244bb dehydrochlorination to 1234yf
US10246389B1 (en) 2018-01-08 2019-04-02 Honeywell International Inc. Compositions containing 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb)
CN119118781A (zh) 2018-06-06 2024-12-13 霍尼韦尔国际公司 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法
US10941091B2 (en) 2018-12-03 2021-03-09 Honeywell International Inc. Processes for producing high-purity trifluoroiodomethane
US20220080243A1 (en) * 2020-09-11 2022-03-17 Honeywell International Inc. Azeotrope or azeotrope-like compositions of trifluoroiodomethane (cf3i) and water

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WO2009125201A2 (en) * 2008-04-09 2009-10-15 Ineos Fluor Holdings Liimited Process
CN101597209A (zh) * 2008-03-20 2009-12-09 霍尼韦尔国际公司 用于制备2,3,3,3-四氟丙烯的一体式方法
US20100036179A1 (en) * 2008-08-08 2010-02-11 Merkel Daniel C PROCESS TO MANUFACTURE 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE (HCFC-244bb)
WO2011056441A2 (en) * 2009-11-03 2011-05-12 Honeywell International Inc. Integrated process for fluoro-olefin production

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ES2155201T3 (es) * 1995-10-10 2001-05-01 Ici Plc Procedimiento para la recuperacion de fluoruro de hidrogeno.
US7880040B2 (en) * 2004-04-29 2011-02-01 Honeywell International Inc. Method for producing fluorinated organic compounds
US8058486B2 (en) * 2004-04-29 2011-11-15 Honeywell International Inc. Integrated process to produce 2,3,3,3-tetrafluoropropene
US8084653B2 (en) * 2004-04-29 2011-12-27 Honeywell International, Inc. Method for producing fluorinated organic compounds
US8067649B2 (en) * 2004-04-29 2011-11-29 Honeywell International Inc. Method for producing fluorinated organic compounds
US9102579B2 (en) * 2004-04-29 2015-08-11 Honeywell International Inc. Method for producing fluorinated organic compounds
EP3336074B1 (en) * 2006-01-03 2025-07-09 Honeywell International Inc. Method for producing fluorinated organic compounds
US8071825B2 (en) * 2006-01-03 2011-12-06 Honeywell International Inc. Method for producing fluorinated organic compounds
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GB0625214D0 (en) * 2006-12-19 2007-01-24 Ineos Fluor Holdings Ltd Process
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US8916733B2 (en) * 2008-06-17 2014-12-23 Honeywell International Inc. Processes for hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane
JP2011525925A (ja) 2008-06-26 2011-09-29 アーケマ・インコーポレイテッド １２３０ｘａから１２３４ｙｆへの触媒的気相フッ素化
FR2933402B1 (fr) 2008-07-03 2010-07-30 Arkema France Procede de purification de 2,3,3,3-tetrafluoro-1-propene (hfo1234yf)
ES2365303T3 (es) * 2008-08-08 2011-09-28 Honeywell International Inc. Proceso mejorado para fabricar 2-cloro-1,1,1,2-tetrafluoropropano (hcfc-244bb).
CA2743842C (en) * 2008-11-19 2016-02-09 Arkema Inc. Process for the manufacture of hydrofluoroolefins
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CN101597209A (zh) * 2008-03-20 2009-12-09 霍尼韦尔国际公司 用于制备2,3,3,3-四氟丙烯的一体式方法
WO2009125201A2 (en) * 2008-04-09 2009-10-15 Ineos Fluor Holdings Liimited Process
US20100036179A1 (en) * 2008-08-08 2010-02-11 Merkel Daniel C PROCESS TO MANUFACTURE 2-CHLORO-1,1,1,2-TETRAFLUOROPROPANE (HCFC-244bb)
WO2011056441A2 (en) * 2009-11-03 2011-05-12 Honeywell International Inc. Integrated process for fluoro-olefin production

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105960277A (zh) * 2014-02-10 2016-09-21 霍尼韦尔国际公司 用于液相氟化的反应器设计
CN107848916A (zh) * 2015-07-17 2018-03-27 墨西哥氟石股份公司 用于制备2,3,3,3‑四氟丙烯(1234yf)的制程
CN107848919A (zh) * 2015-07-17 2018-03-27 墨西哥氟石股份公司 用于干燥氢(氯)氟烯烃的方法
US10899686B2 (en) 2015-07-17 2021-01-26 Mexichem Fluor S.A. De C.V. Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
CN107848916B (zh) * 2015-07-17 2021-09-14 墨西哥氟石股份公司 用于制备2,3,3,3-四氟丙烯(1234yf)的制程
CN116640042A (zh) * 2015-07-17 2023-08-25 墨西哥氟石股份公司 用于干燥氢(氯)氟烯烃的方法
CN108137448A (zh) * 2015-08-19 2018-06-08 霍尼韦尔国际公司 从卤代丙烯中除去酸性杂质的方法
CN113683479A (zh) * 2015-08-19 2021-11-23 霍尼韦尔国际公司 从卤代丙烯中除去酸性杂质的方法
CN108137448B (zh) * 2015-08-19 2022-02-22 霍尼韦尔国际公司 从卤代丙烯中除去酸性杂质的方法
CN113683479B (zh) * 2015-08-19 2025-05-27 霍尼韦尔国际公司 从卤代丙烯中除去酸性杂质的方法
CN111344270A (zh) * 2017-10-13 2020-06-26 霍尼韦尔国际公司 用于从2，3，3，3-四氟丙烯(HFO-1234yf)中移除不饱和卤化杂质的方法
CN111344270B (zh) * 2017-10-13 2023-01-03 霍尼韦尔国际公司 用于从2，3，3，3-四氟丙烯(HFO-1234yf)中移除不饱和卤化杂质的方法

Also Published As

Publication number Publication date
MX2013008287A (es) 2013-09-13
ES2666489T3 (es) 2018-05-04
JP2014510716A (ja) 2014-05-01
KR101925339B1 (ko) 2019-02-27
CN108358745A (zh) 2018-08-03
EP2665696A1 (en) 2013-11-27
US9890096B2 (en) 2018-02-13
WO2012099776A1 (en) 2012-07-26
US20120184785A1 (en) 2012-07-19
EP2665696A4 (en) 2015-12-23
KR20140004725A (ko) 2014-01-13
EP2665696B1 (en) 2018-03-14
JP5953317B2 (ja) 2016-07-20

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