CN103518723A - Fenaminstrobin and isoprothiolane-containing pesticide composition - Google Patents
Fenaminstrobin and isoprothiolane-containing pesticide composition Download PDFInfo
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Abstract
The invention belongs to the field of pesticides, and particularly relates to an agricultural sterilization composition with fenaminstrobin and isoprothiolane as active ingredients. The composition is mainly used for preventing and treating fungal diseases such as rice blast, and meanwhile has the characteristics that the crop quality is improved and the crop yield is increased. The composition has more acting mechanisms and sites, can effectively delay the occurrence and the development of drug resistance of pathogens, is simple in preparation process, is low in cost and has an obvious economic benefit.
Description
Technical field
The invention belongs to pesticide field, specifically take the composition pesticide that alkene oxime amine and Isoprothiolane be active ingredient; For preventing and treating the fungal disease of crops, especially prevent and treat rice blast.
Background technology
Alkene oxime amine (Fenaminstrobin) is the methoxy acrylic bactericide of Shenyang Chemical Engineering Inst's development in 1999, within 2003, obtains Chinese invention patent; Its chemical name is (E, E, E)-N-methyl-2-[2-((((1-methyl-3-(2,6-dichlorophenyl)-2-acrylic) imino group) oxygen base) methyl) phenyl]-2-methoxyimino acetic amide, CAS registration number is 366815 – 39 – 6.There is following structural formula:
Alkene oxime amine all has good preventive and therapeutic effect to the plurality of plant diseases on the crops such as cereal, fruit tree, vegetables, especially remarkable to powdery mildew, rust, leaf spot preventive effect.Its fungicidal spectrum is wide, active high, has prevention and therapeutic action, to having good preventive effect by fungus-caused plurality of plant diseases such as mastigomycetes, zygomycete, sac fungi, basidiomycetes and imperfect funguss.Can prevent and treat wheat rust, wheat powdery mildew, rice sheath blight disease, false smut, rice blast, powdery mildew of cucumber, alternaria leaf spot of apple, apple mildew, pear scab, powdery mildew of strawberry, rust of sunflower etc.Meanwhile, plant growth proterties and quality are significantly improved.
Isoprothiolane, English common name Isoprothiolane, is a kind of efficient, systemic fungicide.Rice blast is had to special efficacy.Rice plant can suppress germ intrusion after absorbing, and especially suppresses phosphatide N-methyltransferase, thereby suppresses pathogen growth, plays preventive and therapeutic action.China is the main medicament of national rice district using it as control rice blast after 1981, but due to long-term use, germ field drug-fastness is day by day serious.
Rice blast is that one of plant disease ， China Nan,Bei Dao district the most widely that distributes has generation, is listed in first of the large Major Diseases of paddy rice three.Rice blast has generation in whole breeding time, different with position according to the period of being injured, and can be divided into seedling pest, leaf pest, pulvinus pest, joint pest, fringe pest, panicle blast, branch stalk pest and grain pest.Wherein common with leaf pest, panicle blast and branch stalk pest, harm is maximum.When leaf pest are serious, Quan Tiancheng burns shape.Fringe portion falls ill when serious, causes a large amount of dead ears or flat grain.
Summary of the invention
The object of the invention is by alkene oxime amine and Isoprothiolane rational mixture, obtains bactericidal composition, for preventing and treating rice blast, delays pathogen development of drug resistance, reduces peasant's drug cost.
The present invention is a kind of by alkene oxime amine and the composite composition pesticide forming of Isoprothiolane, by the test of pesticide effectiveness of formula indoor Screening test test, mixture, defines the rational formula of the two.
The method that the present composition can be known by oneself is prepared into a kind of formulation that is applicable to agricultural use.
The auxiliary agent using in the present composition comprises that emulsifier, dispersant, wetting agent, stabilizing agent, antifreezing agent, thickener etc. and other are of value to the material of active ingredient stable and drug effect performance in preparation.These auxiliary agents are various compositions conventional in pesticidal preparations or that allow to use, are not particularly limited, and concrete composition and consumption can require to determine by test according to formula.
Composition pesticide of the present invention is mainly used in preventing and treating rice blast.
The invention provides a kind of composition pesticide, it is characterized in that, the active ingredient of this composition pesticide comprises alkene oxime amine and Isoprothiolane.
The invention provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is for being 100:1～1:100.
The invention provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is for being 40:1～1:40.
The invention provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is for being 1:1～1:40.
The invention provides a kind of composition pesticide that contains alkene oxime amine, Isoprothiolane, it is characterized in that, described alkene oxime amine and Isoprothiolane weight summation account for 5～80% of composition gross weight.
The invention provides a kind of composition pesticide that contains alkene oxime amine, Isoprothiolane, it is characterized in that, described alkene oxime amine and Isoprothiolane weight summation account for 10～60% of composition gross weight.
The present invention also provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, also contains pesticidal preparations auxiliary agent in described composition pesticide, so that composition pesticide is made the formulation of using on applicable crops.
The present invention also provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that described composition, can be mixed with aqueous suspension agent, dispersible oil-suspending agent, missible oil, aqueous emulsion, microemulsion, wetting powder, seed coat agent or water dispersible granules.
The present invention also provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, described composition is for preventing and treating the fungal disease of crops.
The present invention also provides a kind of composition pesticide that contains alkene oxime amine and Isoprothiolane, it is characterized in that, described composition is used for preventing and treating rice blast etc.
Invention effect
The present invention has following remarkable result and advantage:
1. alkene oxime amine is methoxy acrylic bactericide, and Isoprothiolane is heterocyclic nitrogen-group fungicide.The two has different mechanism of action, there is no cross resistance, can Synergistic, reduce using dosage.
2. alkene oxime amine and Isoprothiolane composition have health care yield increasing effect, can prevent paddy rice early ageing, promote increasing production of rice.
Inventor is mixed alkene oxime amine and Isoprothiolane rice blast is carried out to co-toxicity test, and concrete test situation and result are as follows:
Test medicine adopts the former medicine of alkene oxime amine and isoprothiolane, and the matched proportion density according to setting, is mixed with desired concn liquid.
Table 1. alkene oxime amine and the indoor joint toxicity measuring result of Isoprothiolane control rice blast
Adopt containing toxic medium method and measure.The PDA medium (PDA refers to potato dextrose agar) having melted is cooled to 60～70 ℃, by set concentration, add reagent agent, make the toxic medium that contains variable concentrations liquid, after it is cooling, the confession examination pathogen bacterium sheet of inoculation diameter 5mm, be placed in incubator and cultivate (26 ± 1 ℃), after 7 days, investigate.The confession examination pathogen colony diameter of measuring respectively each processing during investigation, calculates inhibiting rate according to following formula.
Inhibiting rate (%)=(contrast colony diameter-processing colony diameter)/contrast colony diameter * 100
According to inhibiting rate, obtain virulence regression equation and EC
50value; According to the abundant co-toxicity coefficient method of Sun Yun, (CTC evaluates the synergy type of the different mixed ratios of two kinds of active constituents of medicine: if co-toxicity coefficient is greater than 120, showing has synergistic effect; If lower than 80, be indicated as antagonism; Between 80～120, be indicated as summation action.
As can be seen from Table 1, alkene oxime amine and Isoprothiolane are mixed rice blast are had to good control efficiency, six EC for examination proportioning mixture
50value is between 0.40mg/L-3.10mg/L; The co-toxicity coefficient of alkene oxime amine and Isoprothiolane 1:1,1:3,1:5,1:10, five proportioning mixtures of 1:40 is greater than 120, shows obvious synergistic effect; And 1:20 proportioning co-toxicity coefficient is less than 120, it is summation action.Illustrate that alkene oxime amine and Isoprothiolane are mixed and have reasonability and feasibility.
Embodiment
Composition of the present invention, can be according to method known in those skilled in the art (for example, in " formulations of pesticide process technology ", Liu Bulin edits, and the preparation processing method relating in second edition, is hereby incorporated by) when preparation.
While being mixed with suspending agent, auxiliary agent comprises: dispersant, wetting agent, thickener, preservative, defoamer, antifreezing agent and water.
Wherein, dispersant is selected from one or more in polycarboxylate salt dispersant, rosin based dispersant, phosphoric acid ester dispersant, macromolecule emulsion dispersant, alkyl naphthalene sulfonic acid condensation polymer sodium salt, alkylnaphthalene sulfonate condensation polymer, ethyoxyl triphenylethylene phenol phosphate, organophosphorus compounds, comb type high-molecular copolymer, polyoxyethylene aryl ether, polyoxyethylene aryl phenyl ether phosphoric acid amine salt and styrene phenol polyoxyethylene anionic dispersing agents.Consumption is the 1-8% of total formulation weight amount, preferably 3-6%.
Wetting agent is selected from one or more in the poly-base ether formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, aryl sulfonate formaldehyde condensates, alkylnaphthalene sulfonate and anion wetting agent mixture, isopropyl naphthalene sodium sulfonate, normal-butyl naphthalene sulfonate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, sulfosuccinate, ethoxy alcohol, block copolymer, polyxyethylated alcohol and fatty alcohol-polyoxyethylene ether.Consumption is the 1-6% of total formulation weight amount, preferably 2-4%.
Thickener is selected from one or more in xanthans, aluminium-magnesium silicate and bentonite.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
Preservative is selected from one or more in benzoic acid, Sodium Benzoate and BIT (BIT is BIT).Consumption is the 0.1-10% of total formulation weight amount, preferably 0.2-2%.
Defoamer is silicone based defoamer.Consumption is the 0.1-10% of total formulation weight amount, preferably 0.4-1.0%.
Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea and inorganic salts as one or more in sodium chloride.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
Surplus is water.
When being mixed with wetting powder, auxiliary agent comprises: dispersant, wetting agent and filler.
Wherein, dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate and alkylnaphthalene sulfonate formaldehyde condensation products.Consumption is the 1-10% of total formulation weight amount, preferably 3-7%;
Wetting agent is selected from one or more in alkyl sulfate, alkylsulfonate and naphthalene sulfonate.Consumption is the 1-10% of total formulation weight amount, preferably 3-7%;
All the other are filler, are selected from one or more in diatomite, kaolin, white carbon, fine particle calcium carbonate, talcum powder, attapulgite and potter's clay etc.
When being mixed with water dispersible granules, auxiliary agent comprises dispersant, wetting agent, disintegrant, binding agent and filler.
Wherein, dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate and alkylnaphthalene sulfonate formaldehyde condensation products.Consumption is the 1-10% of total formulation weight amount, preferably 3-7%.
Wetting agent is selected from one or more in polyoxyethylene alcohol, alkyl sulfate, alkylsulfonate and naphthalene sulfonate etc.Consumption is the 1-10% of total formulation weight amount, preferably 2-7%.
Disintegrant is selected from one or more in ammonium sulfate, urea, sucrose, glucose, citric acid, succinic acid and sodium bicarbonate.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
Binding agent is selected from diatomite, corn starch, PVA(polyvinyl alcohol), one or more in carboxymethyl (ethyl) cellulose family and microcrystalline cellulose class.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
All the other are filler, are selected from one or more in diatomite, kaolin, white carbon, fine particle calcium carbonate, sepiolite, talcum powder, attapulgite and potter's clay etc.
When being mixed with when dispersibling oil and suspending, auxiliary agent comprises dispersant, wetting agent, thickener, preservative, defoamer, antifreezing agent and grease auxiliary agent.
Wherein, dispersant is selected from one or more in polycarboxylate salt dispersant, rosin based dispersant, phosphoric acid ester dispersant, macromolecule emulsion dispersant, alkyl naphthalene sulfonic acid condensation polymer sodium salt, alkylnaphthalene sulfonate condensation polymer, ethyoxyl triphenylethylene phenol phosphate, organophosphorus compounds, comb type high-molecular copolymer, polyoxyethylene aryl ether, polyoxyethylene aryl phenyl ether phosphoric acid amine salt and styrene phenol polyoxyethylene anionic dispersing agents.Consumption is the 1-8% of total formulation weight amount, preferably 3-6%.
Wetting agent is selected from one or more in the poly-base ether formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, aryl sulfonate formaldehyde condensates, alkylnaphthalene sulfonate and anion wetting agent mixture, isopropyl naphthalene sodium sulfonate, normal-butyl naphthalene sulfonate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyethenoxy base ether phosphate, alkyl sulfate, sulfosuccinate, ethoxy alcohol, block copolymer, polyxyethylated alcohol and fatty alcohol-polyoxyethylene ether.Consumption is the 1-6% of total formulation weight amount, preferably 2-4%.
Thickener is selected from one or more in xanthans, aluminium-magnesium silicate and organobentonite.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
Preservative is selected from one or more in benzoic acid, Sodium Benzoate and BIT (BIT).Consumption is the 0.1-10% of total formulation weight amount, preferably 0.2-2%.
Defoamer is silicone based defoamer.Consumption is the 0.1-10% of total formulation weight amount, preferably 0.4-1.0%.
Antifreezing agent is selected from ethylene glycol, propane diols, glycerine, urea and inorganic salts as one or more in sodium chloride.Consumption is the 0.1-10% of total formulation weight amount, preferably 1-5%.
All the other are grease analog assistant, are selected from one or more in methyl oleate, vegetable oil, animal wet goods.
Embodiment
Following examples are only further to illustrate the present invention, and do not limit the invention to the intention of these specific embodiments.One skilled in the art would recognize that the present invention contained all alternatives, improvement project and the equivalents that within the scope of claims, may comprise.
1, example of formulations
In all preparation proportionings, percentage composition is mass percent.
Embodiment 1:44% alkene oxime amine Isoprothiolane suspending agent
Take the former medicine of 4g alkene oxime amine, 40g isoprothiolane, 5g FS3000 (Phosphate Anionic Surfactants), 1g TXC (sulfonate anionic surfactant), 0.3g xanthans, 1g aluminium-magnesium silicate, 4g ethylene glycol, 0.2g BIT (1,2-benzisothiazole-3-ketone), the organically-modified silica alkane of 0.3g defoamer, deionized water adds to 100g.Above-mentioned raw materials is joined and in high-shear emulsion machine, shears 10min, then use after sand mill sand milling, obtain suspending agent.
Embodiment 2:42% alkene oxime amine Isoprothiolane missible oil
Take the former medicine of 2g alkene oxime amine, 40g isoprothiolane, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 1g, polyoxyethylene nonylphenol ether 2g, dimethylbenzene adds to 100g.Be mixed to homogeneous phase liquid, make composition missible oil.
Embodiment 3:41% alkene oxime amine 'Daowenling ' water dispersible granule
Take the former medicine of 1g alkene oxime amine, 40g isoprothiolane, 5g Ufoxane3A (lignosulfonates), 3g EFW (alkylnaphthalene sulfonate and anion wetting agent mixture), 4g white carbon, 10g ammonium sulfate, 10g corn starch, kaolin add to 100g.Mix, after air-flow crushing, in comminutor, carry out granulation, be then dried, sieve and obtain granular product.
Embodiment 4:44% alkene oxime amine Isoprothiolane dispersibles oil-suspending agent
Take the former medicine of 4g alkene oxime amine, 40g isoprothiolane, 17g TERMUL3015 (non-ionic surface active agent), 5g TERSPERSE2501 (non-ionic dispersing agent), 1.0g organobentonite, 25g Solvesso200 (solvent naphtha), methyl oleate adds to 100g.Above-mentioned raw materials is joined and in high-shear emulsion machine, shears 10min, then use after sand mill sand milling, obtain oil-suspending agent.
Embodiment 5:40% alkene oxime amine Isoprothiolane missible oil
Take the former medicine of 10g alkene oxime amine, 30g isoprothiolane, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 1g, polyoxyethylene nonylphenol ether 2g, dimethylbenzene adds to 100g.Be mixed to homogeneous phase liquid, make composition missible oil.
2, field control effectiveness test is measured embodiment
The field control effectiveness test of control Rice blast disease
Trial crops: paddy rice;
Controlling object: panicle blast;
Test method: 8 processing are established in test, every processing repeats 3 times.Adopt random district group to arrange ，Mei community area 50m
2.Totally 2 dispensers in 14 days after first 7 days of cut and a medicine.30 kilograms of mu water consumptions, adopt manual sprayer even spraying.
Investigation method: the incidence ，Mei community of rice blast 14 days investigation Rice blasts after 2 dispensers adopts parallel great-jump-forward sampling ，Mei community 5 points, and every some investigation 50 strains, record morbidity strain and severity (calculating disease index and protection effect).Protection effect is evaluated with reference to " field control effectiveness test criterion (one) ".
Panicle blast (Yi Suiwei unit) investigation, disease refers to that grade scale is as follows:
0 grade: anosis;
1 grade: every fringe loss is (morbidity of indivedual branch stalk) below 5%;
3 grades: every fringe loss 6%-20% (1/3 left and right branch stalk morbidity);
5 grades: every fringe loss 21%-50% (fringe neck or main shaft morbidity, grain half is flat);
7 grades: every fringe loss 51%-70% (morbidity of fringe neck, large portion shrivelled kernel);
9 grades: every fringe loss 71%-100% (morbidity of fringe neck, causes dead ears).
Each processes 20 samplings first 1 day of paddy rice harvesting, and every 3 clumps of spike of rice totally 60 Cong Sui rice carry out species test, investigation ripening rate and thousand kernel weight, and add scale sample weight in wet base and dry weight, and with dry weight, carry out theory and survey product.
Result of the test in table 2 is: the different dosage form sample in five embodiment is to the preventive effect of rice blast 82.74～87.83%, and the preventive effect that alkene oxime amine and Isoprothiolane single dose are processed is respectively 74.56% and 75.88%.Be mixed and show obvious synergistic effect.
The sick field test results of different sample control Rice blast in table 2. embodiment
| Chemicals treatment | Dosage (g/ mu) | Disease refers to | Preventive effect (%) |
| 44% alkene oxime amine Isoprothiolane suspending agent | 100 | 1.156 | 82.74 |
| 42% alkene oxime amine Isoprothiolane missible oil | 100 | 0.919 | 86.28 |
| 41% alkene oxime amine 'Daowenling ' water dispersible granule | 100 | 1.111 | 83.41 |
| 44% alkene oxime amine Isoprothiolane dispersibles oil-suspending agent | 100 | 0.889 | 86.73 |
| 40% alkene oxime amine Isoprothiolane missible oil | 100 | 0.815 | 87.83 |
| 5% alkene oxime amine missible oil | 100 | 1.704 | 74.56 |
| 40% Isoprothiolane missible oil | 100 | 1.615 | 75.88 |
| Space management | - | 6.696 | ? |
Experimental data in table 3 shows: two single doses of alkene oxime amine and Isoprothiolane can make increasing production of rice 13% and 2.6% respectively; And its theoretical volume increase ratio that is mixed is at 5.9-14%.Be mixed and show obvious inhibition early ageing and yield increasing effect.
The rice yield of different sample treatment in table 3. embodiment
The beneficial effect of Bactericidal composite deposits yields of the present invention is:
(1) compare with single dose, this bactericidal composition has synergistic effect to disease, has improved bactericidal effect;
(2) reduce drug cost, reduce environmental pollution and residue of pesticide;
(3) composition is comprised of the active ingredient of different mechanism of action, and action site increases, and is conducive to overcome and delays the drug-fast generation of germ.
(4) alkene oxime amine and Isoprothiolane composition have health care yield increasing effect, can prevent paddy rice early ageing, promote increasing production of rice.
The present composition is to trial crops all without obviously harmful effect, and safety is good, meets the security requirement of pesticidal preparations.
Claims (10)
1. a composition pesticide, is characterized in that, the active component of this composition pesticide comprises alkene oxime amine and Isoprothiolane.
2. composition pesticide according to claim 1, is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is 100:1～1:100.
3. composition pesticide according to claim 2, is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is 40:1～1:40.
4. composition pesticide according to claim 2, is characterized in that, the ratio of weight and number of alkene oxime amine and Isoprothiolane is 1:1～1:40.
5. composition pesticide according to claim 1, is characterized in that, described alkene oxime amine and Isoprothiolane weight summation account for 5～80% of composition gross weight.
6. composition pesticide according to claim 5, is characterized in that, described alkene oxime amine and Isoprothiolane weight summation account for 10～60% of composition gross weight.
7. composition pesticide according to claim 1, is characterized in that, also contains pesticidal preparations auxiliary agent in described composition, so that said composition is made the formulation of using on applicable crops.
8. composition pesticide according to claim 1, is characterized in that, described composition can be configured to aqueous suspension agent, dispersibles oil-suspending agent, missible oil, aqueous emulsion, microemulsion, wetting powder, seed coat agent or water dispersible granules.
9. composition pesticide according to claim 1, is characterized in that, described composition is for preventing and treating the fungal disease of crops.
10. composition pesticide according to claim 1, is characterized in that, described composition is used for preventing and treating rice blast.
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| CN105309434A (en) * | 2014-07-18 | 2016-02-10 | 中化农化有限公司 | Method for improving crop growth |
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| CN102204562A (en) * | 2011-04-08 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Enestroburin containing antibacterial composition |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
| WO2012084670A1 (en) * | 2010-12-20 | 2012-06-28 | Basf Se | Pesticidal active mixtures comprising pyrazole compounds |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2012084670A1 (en) * | 2010-12-20 | 2012-06-28 | Basf Se | Pesticidal active mixtures comprising pyrazole compounds |
| CN102204562A (en) * | 2011-04-08 | 2011-10-05 | 陕西汤普森生物科技有限公司 | Enestroburin containing antibacterial composition |
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| CN105309434A (en) * | 2014-07-18 | 2016-02-10 | 中化农化有限公司 | Method for improving crop growth |
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