CN103509292A - High temperature resistant polyvinyl chloride cable material - Google Patents
High temperature resistant polyvinyl chloride cable material Download PDFInfo
- Publication number
- CN103509292A CN103509292A CN201310473860.2A CN201310473860A CN103509292A CN 103509292 A CN103509292 A CN 103509292A CN 201310473860 A CN201310473860 A CN 201310473860A CN 103509292 A CN103509292 A CN 103509292A
- Authority
- CN
- China
- Prior art keywords
- parts
- polyvinyl chloride
- sepiolite
- cable material
- diatomite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention provides a high temperature resistant polyvinyl chloride cable material which is prepared from the following ingredients by weight: 50-60 parts of a polyvinyl chloride resin, 10-15 parts of trioctyl trimellitate, 10-12 parts of trioctyl phosphate, 1-2 parts of acetic acid, 0.2-0.3 part of tribasic lead sulfate, 0.2-0.3 part of dibasic lead stearate, 1-2 parts of bisphenol A, 1-2 parts of didodecyl carbon alcohol ester, 8-10 parts of sepiolite, 5-6 parts of magnesium carbonate, 8-10 parts of mica powder, 5-7 parts of perlite, 4-6 parts of vermiculite, 8-10 parts of magnesium hydrate, 1-2 parts of barium sulfate, 1-2 parts of zinc oxide, 1-2 parts of dicumyl peroxide DCP, 1-2 parts of phosphoguanidine, 1-2 parts of calcium stearate, 1-2 parts of pentaerythritol, 1-2 parts of melamine chlorinated Isocyanurates, 0.2-0.4 part of high melting point paraffin, and 5-8 parts of a modified filler. A cable wire made of the cable material provided by the invention is high in high temperature resistance, low in smoke, ageing resistant and good in flame retardant property.
Description
Technical field
The present invention relates to CABLE MATERIALS field, be specifically related to a kind of resistant to elevated temperatures polyvinyl chloride cable material.
Background technology
Electric wire is important materials indispensable in industrial and agricultural production and the modern life, China is that the electric wire of whole world maximum is produced country, wires and cables industry occupies very important status in the national economy of China, but, at present, CABLE MATERIALS on market exists non-refractory, not ageing-resistant, and after weathering test, the phenomenon that becomes fragile of turning to be yellow appears in material.Electric wire fire aging and that cause is also more and more, how to reduce the incidence of fire and presence of fire time mortality ratio, low cigarette, Halogen, the developing direction that fire-retardant, environmental protection also becomes wires and cables industry.Wherein the demand of the resistant to elevated temperatures polyvinyl chloride cable material of halide-free smokeless is increasing, the production of the resistant to elevated temperatures polyvinyl chloride cable material of halide-free smokeless is in polyolefin substrate, to add a large amount of Shawinigan blacks or Shawinigan black to reach flame retardant effect mostly at present, yet, adding of a large amount of inorganic materials, physical and mechanical properties and the processing of CABLE MATERIALS have been affected.Fire-retardant, low cigarette, environmental protection, good weatherability, the CABLE MATERIALS that cost is low become the direction of CABLE MATERIALS development.
Summary of the invention
The invention provides a kind of resistant to elevated temperatures polyvinyl chloride cable material and preparation method thereof.The cable being processed into by CABLE MATERIALS of the present invention has high temperature resistant, low cigarette, ageing-resistant, and flame retardant properties is good.
The technical solution used in the present invention is:
A kind of resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 50-60, trioctyl trimellitate 10-15, trioctyl phosphate 10-12, acetic acid 1-2, tribasic lead sulfate 0.2-0.3, dibasic lead stearate 0.2-0.3, dihydroxyphenyl propane 1-2, two Lauryl Alcohol ester 1-2, sepiolite 8-10, magnesiumcarbonate 5-6, mica powder 8-10, perlite 5-7, vermiculite power 4-6, magnesium hydroxide 8-10, barium sulfate 1-2, zinc oxide 1-2, dicumyl peroxide DCP1-2, phosphoguanidine 1-2, calcium stearate 1-2, tetramethylolmethane 1-2, melamine cyanurate 1-2, inspissated wax 0.2-0.4, modified filler 5-8,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
Described resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol esters 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
The preparation method of CABLE MATERIALS of the present invention:
By formula rate, take each constitutive material, constitutive material is dropped into homogenizer mixing 3-5miu, blowing, the material mixing is put in twin screw extruder, extruding pelletization, then after entering and being dried in hot air dryer, obtain resistant to elevated temperatures polyvinyl chloride cable material, while extruding, twin screw extruder temperature setting is set to: 105 ℃ of feeding sections, 170 ℃ of melt zones, melt conveying zone 170-180 ℃, 185 ℃ of mixing sections, 185 ℃ of homogenizing zones, 180 ℃ of head metering zones.
Beneficial effect
The cable that CABLE MATERIALS of the present invention is processed into has high temperature resistant, low cigarette, ageing-resistant, and flame retardant properties is good.
Embodiment
A polyvinyl chloride cable material, is obtained by the component raw material preparation of following weight (kg):
Polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol ester 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7
Wherein, modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.。
The preparation method of resistant to elevated temperatures polyvinyl chloride cable material:
By formula rate, take each constitutive material, constitutive material is dropped into homogenizer mixing 3-5miu, blowing, the material mixing is put in twin screw extruder, extruding pelletization, then after entering and being dried in hot air dryer, obtain resistant to elevated temperatures polyvinyl chloride cable material, while extruding, twin screw extruder temperature setting is set to: 105 ℃ of feeding sections, 170 ℃ of melt zones, melt conveying zone 170-180 ℃, 185 ℃ of mixing sections, 185 ℃ of homogenizing zones, 180 ℃ of head metering zones.
The performance test results of the CABLE MATERIALS that the present embodiment makes is as following table:
Claims (2)
1. a resistant to elevated temperatures polyvinyl chloride cable material, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 50-60, trioctyl trimellitate 10-15, trioctyl phosphate 10-12, acetic acid 1-2, tribasic lead sulfate 0.2-0.3, dibasic lead stearate 0.2-0.3, dihydroxyphenyl propane 1-2, two Lauryl Alcohol ester 1-2, sepiolite 8-10, magnesiumcarbonate 5-6, mica powder 8-10, perlite 5-7, vermiculite power 4-6, magnesium hydroxide 8-10, barium sulfate 1-2, zinc oxide 1-2, dicumyl peroxide DCP1-2, phosphoguanidine 1-2, calcium stearate 1-2, tetramethylolmethane 1-2, melamine cyanurate 1-2, inspissated wax 0.2-0.4, modified filler 5-8,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 200-210, diatomite 120-130, sepiolite 10-12, nano-sized carbon 1-2, Zirconium tetrafluoride 1-2, alum 2-3, Fruit of Caraway essential oil 2-3, xitix 1-2, sodium alginate 2-3, precipitated silica 30-34, tea-polyphenol 3-4,2-hydroxypropyl acrylate 1-2, lapis amiridis 1-2, irgasfos 168 1-2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
2. resistant to elevated temperatures polyvinyl chloride cable material according to claim 1, it is characterized in that, by the component raw material preparation of following weight part, obtained: polyvinyl chloride (PVC) RESINS 55, trioctyl trimellitate 13, trioctyl phosphate 11, acetic acid 1, tribasic lead sulfate 0.3, dibasic lead stearate 0.2, dihydroxyphenyl propane 1, two Lauryl Alcohol esters 2, sepiolite 10, magnesiumcarbonate 5, mica powder 9, perlite 6, vermiculite power 5, magnesium hydroxide 9, barium sulfate 1, zinc oxide 2, dicumyl peroxide DCP 1, phosphoguanidine 2, calcium stearate 1, tetramethylolmethane 1, melamine cyanurate 2, inspissated wax 0.3, modified filler 7,
Described modified filler is to be prepared and obtained by following method: a. takes off the raw material of row weight part: kaolin 205, diatomite 125, sepiolite 11, nano-sized carbon 2, Zirconium tetrafluoride 1, alum 2.5, Fruit of Caraway essential oil 2, xitix 1.5, sodium alginate 2.5, precipitated silica 32, tea-polyphenol 3,2-hydroxypropyl acrylate 2, lapis amiridis 1, irgasfos 168 2;
B, by kaolin, diatomite, sepiolite, at 480-550 ℃, calcine 4-5h, be cooled to room temperature, after taking-up, add in the sodium hydroxide solution of 3-4% and grind 1-2 hour, then, add the hydrochloric acid soln of 12-15%, adjusting pH value is 4-5, ageing 10-15 hour, it is neutral that repeated hydrogenation sodium hydroxide solution regulates lapping liquid pH, filters, and dries and obtains filler powder;
C, above-mentioned gained powder is mixed with other remaining component, and even with the high speed dispersion of 9000-12000 rev/min, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473860.2A CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473860.2A CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103509292A true CN103509292A (en) | 2014-01-15 |
| CN103509292B CN103509292B (en) | 2016-03-02 |
Family
ID=49892750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310473860.2A Active CN103509292B (en) | 2013-10-12 | 2013-10-12 | A kind of resistant to elevated temperatures polyvinyl chloride cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103509292B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558966A (en) * | 2015-01-15 | 2015-04-29 | 无为县华祥电缆材料有限公司 | Chlorinated-esterified polybutadiene rubber modified polyvinyl chloride cable material |
| CN105623154A (en) * | 2016-03-30 | 2016-06-01 | 苗庆龄 | Heat-resistant and anti-tensile special cable material for automobile wire harness and preparation method for cable material |
| CN108659265A (en) * | 2017-03-31 | 2018-10-16 | 中国石油化工股份有限公司 | A kind of flame-proof smoke-restraining polyvinyl chloride cable material and preparation method thereof |
| CN114429842A (en) * | 2022-03-02 | 2022-05-03 | 广东新亚光电缆股份有限公司 | Preparation method of compact cable with steel core |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
| CN101412834A (en) * | 2008-11-12 | 2009-04-22 | 江苏三角洲塑化有限公司 | High temperature resistant environment-protective polychloroethylene material for electric wire and cable |
| CN101463169A (en) * | 2008-12-30 | 2009-06-24 | 深圳市领亚电子有限公司 | Dual wave soldering high temperature resistant polychloroethylene composition for electric wire and cable and preparation thereof |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
| CN102408619A (en) * | 2011-09-22 | 2012-04-11 | 安徽塞帕斯电缆材料有限公司 | Modified high-temperature-resistance polyvinyl chloride (PVC) cable material and preparation method thereof |
-
2013
- 2013-10-12 CN CN201310473860.2A patent/CN103509292B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977280B2 (en) * | 2003-06-11 | 2005-12-20 | Teknor Apex Company | Polyvinyl chloride or polyolefin melt processable compositions containing polytetrafluoroethylene micropowder |
| CN101412834A (en) * | 2008-11-12 | 2009-04-22 | 江苏三角洲塑化有限公司 | High temperature resistant environment-protective polychloroethylene material for electric wire and cable |
| CN101463169A (en) * | 2008-12-30 | 2009-06-24 | 深圳市领亚电子有限公司 | Dual wave soldering high temperature resistant polychloroethylene composition for electric wire and cable and preparation thereof |
| CN101497727A (en) * | 2009-03-04 | 2009-08-05 | 南亚塑胶工业股份有限公司 | PVC resin composition and product thereof |
| CN102408619A (en) * | 2011-09-22 | 2012-04-11 | 安徽塞帕斯电缆材料有限公司 | Modified high-temperature-resistance polyvinyl chloride (PVC) cable material and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104558966A (en) * | 2015-01-15 | 2015-04-29 | 无为县华祥电缆材料有限公司 | Chlorinated-esterified polybutadiene rubber modified polyvinyl chloride cable material |
| CN105623154A (en) * | 2016-03-30 | 2016-06-01 | 苗庆龄 | Heat-resistant and anti-tensile special cable material for automobile wire harness and preparation method for cable material |
| CN108659265A (en) * | 2017-03-31 | 2018-10-16 | 中国石油化工股份有限公司 | A kind of flame-proof smoke-restraining polyvinyl chloride cable material and preparation method thereof |
| CN108659265B (en) * | 2017-03-31 | 2020-09-08 | 中国石油化工股份有限公司 | Flame-retardant smoke-inhibiting polyvinyl chloride cable material and preparation method thereof |
| CN114429842A (en) * | 2022-03-02 | 2022-05-03 | 广东新亚光电缆股份有限公司 | Preparation method of compact cable with steel core |
| CN114429842B (en) * | 2022-03-02 | 2023-12-26 | 广东新亚光电缆股份有限公司 | Preparation method of strip steel core tight compression type cable |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103509292B (en) | 2016-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103509295B (en) | A kind of environment-friendly heatproof composite elastic cable material for wires and cables | |
| CN103509296B (en) | A kind of silicone hydride crosslinked non-halogen flame-proof polyvinyl chloride granula for cable | |
| CN103509228B (en) | A kind of fire-retardant polyethylene cable material with mould-proof function | |
| CN103571031B (en) | A kind of low cigarette environment-friendly cable material | |
| CN103509229B (en) | A kind of photovoltaic cable irradiation crosslinking type low-smoke halogen-free flame-retardant polyolefin CABLE MATERIALS | |
| CN103554715B (en) | A kind of halogen-free flame-proof environmental protection cross-linked polrvinyl chloride CABLE MATERIALS | |
| CN103524937B (en) | A kind of high-flame-retardant polyvinyl | |
| CN103524904B (en) | A kind of Special cable material and preparation method thereof | |
| CN103509236B (en) | A kind of high-flame-retardance low-smoke halogen-free cable material and preparation method thereof | |
| CN103509293B (en) | A kind of Environment-friendlycold-resistant cold-resistant polyvinyl chloride cable | |
| CN103509292B (en) | A kind of resistant to elevated temperatures polyvinyl chloride cable material | |
| CN103524933A (en) | Flame-retardant cable material and preparation method | |
| CN103524895B (en) | A kind of Halogen-free flame-retardant polypropylene cable material with high temperature resistance and preparation method thereof | |
| CN103524935B (en) | A kind of modified PVC CABLE MATERIALS and preparation method thereof | |
| CN103467820A (en) | Low-smoke, halogen-free and flame-retardant polyolefin cable material and preparation method thereof | |
| CN103524868A (en) | Low-temperature-resistant oil-resistant low-smoke halogen-free flame-retardant polyolefin cable material | |
| CN103554807B (en) | A kind of wear-resistant cable material of nano modification | |
| CN103509235B (en) | A kind of Environment-friendlypolyethylene polyethylene cable material and preparation method thereof | |
| CN103524865B (en) | A kind of nano modification lower shrinkage low smoke halogen-free fire retardant polyolefin cable material | |
| CN103509294B (en) | A kind of cold-resistant fire-retardant PVC CABLE MATERIALS | |
| CN103571087A (en) | Environment-friendly filled cable material | |
| CN103509237B (en) | A kind of fast ceramic flame-resistant cable | |
| CN103509234B (en) | A kind of halogen-free environment-friendly flame-proof cable material of polyolefin containing polysiloxane | |
| CN103524940B (en) | A kind of cold-resistant PVC cable material and preparation method thereof | |
| CN103554630A (en) | Polyvinyl chloride cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Zhen Inventor before: Xie Hua |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171110 Address after: 266000 Hechuan road 3, Licang District, Shandong, Qingdao Patentee after: Qingdao aoter mesnac kaimei Technology Co. Ltd. Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: Lvbao Cable (Group) Co., Ltd. |