CN102408619A - Modified high-temperature-resistance polyvinyl chloride (PVC) cable material and preparation method thereof - Google Patents

Modified high-temperature-resistance polyvinyl chloride (PVC) cable material and preparation method thereof Download PDF

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Publication number
CN102408619A
CN102408619A CN2011102821023A CN201110282102A CN102408619A CN 102408619 A CN102408619 A CN 102408619A CN 2011102821023 A CN2011102821023 A CN 2011102821023A CN 201110282102 A CN201110282102 A CN 201110282102A CN 102408619 A CN102408619 A CN 102408619A
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polyvinyl chloride
cable material
preparation
compound
temperature
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CN102408619B (en
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陶善如
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ANHUI SEPASI CABLE MATERIAL CO LTD
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ANHUI SEPASI CABLE MATERIAL CO LTD
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Abstract

The invention discloses a modified high-temperature-resistance polyvinyl chloride (PVC) cable material and a preparation method thereof. The modified high-temperature-resistance polyvinyl chloride cable material is prepared by the step of mixing raw materials in certain parts by weight, wherein the raw materials comprise a ethylene-vinyl acetate copolymer EVA, PVC resins, kaolin, ammonium polyphosphate, calcined zeolite powder, carbon black, straw ashes, attapulgite, a silane coupling agent, titanate, 6-tert-butyl-3-methyl phenol, paraffin and acrylic rubber. The preparation method is simple and convenient to operate, the formula of raw materials is reasonable, and the prepared cable material has the advantages of high mechanical property, high temperature resistance and high flame retardant property and is low-smoke and non-toxic when being burnt.

Description

A kind of modified, high temperature resistant polyvinyl chloride cable material and preparation method thereof
Technical field
The present invention relates to a kind of modified, high temperature resistant polyvinyl chloride cable material and preparation method thereof, belong to field of cables.
Background technology
Along with rapid economic development, electric wire all is widely used in industry-by-industry, field.Along with the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually.Discharge a large amount of smog during cable fire and deleterious, corrosive gas is Hazard Factor in the fire, in fire, hindered people's safe escape and fire-fighting work, make lives and properties suffer heavy losses.While is along with the development of communication career, automotive industry and computer industry; Particularly many occasions such as aviation lead, line for cars, high temperature instrument cable, oil drilling platform cable more and more need be used low smoke no-halogen wire cable high temperature resistant, weather.
Summary of the invention
The purpose of this invention is to provide a kind of modified, high temperature resistant polyvinyl chloride cable material and preparation method thereof, CABLE MATERIALS of the present invention have the mechanical property height, high temperature resistant, flame retardant properties is high, LSZH during burning.
For realizing the following technical scheme of above-mentioned purpose employing of the present invention:
The modified, high temperature resistant polyvinyl chloride cable material is characterized in that the weight part of its constitutive material is:
Figure BDA0000093212350000011
Figure BDA0000093212350000021
The preparation method of described modified, high temperature resistant polyvinyl chloride cable material is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, and ethylene-vinyl acetate copolymer EVA, PVC RESINS, attapulgite, kaolin, roasting zeolite powder and carbon black are mixed, and obtains compound A;
(2) add ammonium polyphosphate, stalk ashes, silane coupling agent, titanic acid ester, the 6-tertiary butyl-3-methylphenol, paraffin and acrylic rubber among the compound A in above-mentioned steps (1) by weight; Under the normal temperature stirring at low speed 1-2 minute; Make to mix, obtain compound B;
(3) the compound B that above-mentioned steps (2) is obtained adds mill and Banbury mixer or twin screw extruder is mixing, granulation, controlled temperature 140-170 ℃, obtains finished product.
Beneficial effect of the present invention:
Preparing method of the present invention is simple, and is easy to operate, and the constitutive material prescription is reasonable, the CABLE MATERIALS that makes have the mechanical property height, high temperature resistant, flame retardant properties is high, LSZH during burning.
Embodiment
Embodiment 1: the modified, high temperature resistant polyvinyl chloride cable material, and the weight part of its constitutive material is:
Figure BDA0000093212350000022
The preparation method of described modified, high temperature resistant polyvinyl chloride cable material may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, and ethylene-vinyl acetate copolymer EVA, PVC RESINS, attapulgite, kaolin, roasting zeolite powder and carbon black are mixed, and obtains compound A;
(2) add ammonium polyphosphate, stalk ashes, silane coupling agent, titanic acid ester, the 6-tertiary butyl-3-methylphenol, paraffin and acrylic rubber among the compound A in above-mentioned steps (1) by weight; Under the normal temperature stirring at low speed 1-2 minute; Make to mix, obtain compound B;
(3) the compound B that above-mentioned steps (2) is obtained adds mill and Banbury mixer or twin screw extruder is mixing, granulation, controlled temperature 140-170 ℃, obtains finished product.
Embodiment 2: CABLE MATERIALS of the present invention and existing CABLE MATERIALS general property compare:
Figure BDA0000093212350000031
Embodiment 3: test correlated results relatively like following table after above-mentioned materials is vulcanized film-making:
Figure BDA0000093212350000032
Figure BDA0000093212350000041

Claims (2)

1. modified, high temperature resistant polyvinyl chloride cable material is characterized in that the weight part of its constitutive material is:
Ethylene-vinyl acetate copolymer EVA 65-75 part
PVC RESINS 20-30 part
Kaolin 15-25 part
Ammonium polyphosphate 10-20 part
Roasting zeolite powder 10-15 part
Carbon black 20-25 part
Stalk ashes 3-8 part
Attapulgite 15-25 part
Silane coupling agent 1-2 part
Titanic acid ester 1-2 part
The 6-tertiary butyl-3-methylphenol 1-1.5 part
Paraffin 0.5-1 part
Acrylic rubber 4-5 part.
2. the preparation method of a modified, high temperature resistant polyvinyl chloride cable material as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part by constitutive material takes by weighing each raw material, and ethylene-vinyl acetate copolymer EVA, PVC RESINS, attapulgite, kaolin, roasting zeolite powder and carbon black are mixed, and obtains compound A;
(2) add ammonium polyphosphate, stalk ashes, silane coupling agent, titanic acid ester, the 6-tertiary butyl-3-methylphenol, paraffin and acrylic rubber among the compound A in above-mentioned steps (1) by weight; Under the normal temperature stirring at low speed 1-2 minute; Make to mix, obtain compound B;
(3) the compound B that above-mentioned steps (2) is obtained adds mill and Banbury mixer or twin screw extruder is mixing, granulation, controlled temperature 140-170 ℃, obtains finished product.
CN 201110282102 2011-09-22 2011-09-22 Modified high-temperature-resistance polyvinyl chloride (PVC) cable material and preparation method thereof Expired - Fee Related CN102408619B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509286A (en) * 2013-09-06 2014-01-15 安徽华鸿电气股份有限公司 Anti-aging complex cable material
CN103509280A (en) * 2013-09-06 2014-01-15 安徽华通电缆集团有限公司 High-temperature-resistant cable material
CN103509287A (en) * 2013-09-06 2014-01-15 安徽华鸿电气股份有限公司 High-elasticity polyvinyl chloride flexible cable material
CN103509292A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 High temperature resistant polyvinyl chloride cable material
CN103724872A (en) * 2013-12-10 2014-04-16 芜湖佳诚电子科技有限公司 Environmentally-friendly PVC cable material and preparation method thereof
CN104610682A (en) * 2015-01-08 2015-05-13 江苏黄金龙风筒科技有限公司 Composite PVC water hose and preparation method thereof
CN105237866A (en) * 2014-04-21 2016-01-13 赵月 Electric cable
CN105924832A (en) * 2016-05-18 2016-09-07 安徽华星电缆集团有限公司 Computer cable sheathing material
CN106800720A (en) * 2016-12-20 2017-06-06 安徽华天电缆有限公司 A kind of fire-resistant waterproof rigid polyvinyl chloride cable material
CN108623896A (en) * 2018-05-31 2018-10-09 安徽电信器材贸易工业有限责任公司 It is a kind of to be used to shield insulating materials of optical cable and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106397954A (en) * 2016-08-31 2017-02-15 裴秀琴 Cable sheath material for electric engineering and preparation method thereof

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CN101735546A (en) * 2009-12-30 2010-06-16 浙江北化阻燃材料有限公司 High flame-retardant and high heat-resisting halogen-free expansion type fire-resistant cable material and preparation method thereof
CN101875747A (en) * 2009-04-28 2010-11-03 杭州德裕饰品有限公司 Ultralow temperature polyvinyl chloride (PVC) modified insulating sheath cable material and preparation method thereof
CN101880417A (en) * 2010-06-29 2010-11-10 武汉新天地特种电缆有限公司 Silane crosslinked halogen-free flame-retardant polyethylene cable material and preparation method thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN101875747A (en) * 2009-04-28 2010-11-03 杭州德裕饰品有限公司 Ultralow temperature polyvinyl chloride (PVC) modified insulating sheath cable material and preparation method thereof
CN101735546A (en) * 2009-12-30 2010-06-16 浙江北化阻燃材料有限公司 High flame-retardant and high heat-resisting halogen-free expansion type fire-resistant cable material and preparation method thereof
CN101880417A (en) * 2010-06-29 2010-11-10 武汉新天地特种电缆有限公司 Silane crosslinked halogen-free flame-retardant polyethylene cable material and preparation method thereof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509287B (en) * 2013-09-06 2016-01-27 安徽华鸿电气股份有限公司 A kind of High-elasticity polyvinyl chloride flexible cable material
CN103509280A (en) * 2013-09-06 2014-01-15 安徽华通电缆集团有限公司 High-temperature-resistant cable material
CN103509287A (en) * 2013-09-06 2014-01-15 安徽华鸿电气股份有限公司 High-elasticity polyvinyl chloride flexible cable material
CN103509286A (en) * 2013-09-06 2014-01-15 安徽华鸿电气股份有限公司 Anti-aging complex cable material
CN103509280B (en) * 2013-09-06 2015-12-02 安徽华通电缆集团有限公司 A kind of High-temperature-rescablet cablet material
CN103509286B (en) * 2013-09-06 2016-01-27 安徽华鸿电气股份有限公司 A kind of anti-aging compound cable material
CN103509292A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 High temperature resistant polyvinyl chloride cable material
CN103509292B (en) * 2013-10-12 2016-03-02 绿宝电缆(集团)有限公司 A kind of resistant to elevated temperatures polyvinyl chloride cable material
CN103724872A (en) * 2013-12-10 2014-04-16 芜湖佳诚电子科技有限公司 Environmentally-friendly PVC cable material and preparation method thereof
CN105237866A (en) * 2014-04-21 2016-01-13 赵月 Electric cable
CN105237866B (en) * 2014-04-21 2017-07-14 正规电线电缆(东莞)有限公司 Cable
CN104610682A (en) * 2015-01-08 2015-05-13 江苏黄金龙风筒科技有限公司 Composite PVC water hose and preparation method thereof
CN104610682B (en) * 2015-01-08 2016-10-26 江苏黄金龙风筒科技有限公司 A kind of composite PVC water band and preparation method thereof
CN105924832A (en) * 2016-05-18 2016-09-07 安徽华星电缆集团有限公司 Computer cable sheathing material
CN106800720A (en) * 2016-12-20 2017-06-06 安徽华天电缆有限公司 A kind of fire-resistant waterproof rigid polyvinyl chloride cable material
CN108623896A (en) * 2018-05-31 2018-10-09 安徽电信器材贸易工业有限责任公司 It is a kind of to be used to shield insulating materials of optical cable and preparation method thereof

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