CN103501601A - Fumigant, fogging space treatment device, and space treatment method - Google Patents
Fumigant, fogging space treatment device, and space treatment method Download PDFInfo
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- CN103501601A CN103501601A CN201280020520.8A CN201280020520A CN103501601A CN 103501601 A CN103501601 A CN 103501601A CN 201280020520 A CN201280020520 A CN 201280020520A CN 103501601 A CN103501601 A CN 103501601A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/02—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
- A61L9/03—Apparatus therefor
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2061—Poisoning or narcotising insects by vaporising an insecticide using a heat source
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M13/00—Fumigators; Apparatus for distributing gases
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
Abstract
The invention relates to a fumigant containing (A) a polyol and (B) an active ingredient, a fogging space treatment device wherein the fumigant and a heating part that generates heat of 150-450 DEG C are disposed with a heat-transferring part therebetween, and a space treatment method wherein the fumigant is heated at 150-450 DEG C. The invention provides a fumigant that is easily handled, has low polluting properties, has high efficacy due to the active ingredient and with which the user can get a sense of the effectiveness, and a fogging space treatment device and a space treatment method that use the fumigant.
Description
Technical field
The present invention relates to a kind of sootiness type waves powder, uses described sootiness type to wave sootiness type spatial manipulation device and the spatial manipulation method of powder.
The application advocate based on April 28th, 2011 application number in Japanese publication be 2011-102352 and August 19, the application number in Japanese publication was 2011-179604 in 2011 priority, quote its content herein.
Background technology
Technology as discharge, spread (hereinafter referred to as " waving loose ") active ingredient in broad space, proposed the whole bag of tricks.For example, carry out the method that sprays after the active ingredient aerosolization.
As an example wherein, disclose in agricultural use, use motor or the petrol engine device as drive source, the agricultural chemicals distributing method (reference example is as Japanese documentation 1) that liquid medicine is sprayed under the state of pressurization from spray nozzle by compressor.In this way, can in greenhouse, scatter equably agricultural chemicals.
In addition, in general family, for pest, such as the sanitary insect pest of fly, mosquito, cockroach etc. or the control of mould, bacterium etc. etc., processed with fumigant (fumigant) in space in house, in car etc.
Fumigant be by the heat generation matrix that is mixed with various incendiary agents, blowing agent etc. and by active ingredient the solid pharmaceutical preparation as principal component.As heat generation matrix, generally use nitrocellulose, Celogen Az, p, p '-oxo two (benzene sulfonyl hydrazide), N, N '-dinitrosopentamethylene tetramine etc.
Heat in use fumigant, by the burning of heat generation matrix or decomposition, produce cigarette (gas and particulate), according to cigarette and hot effect, active ingredient is waved and fall apart in air.Therefore, can at short notice active ingredient be full of to ，Dui Gai space, whole space is processed.
During the heating fumigant, can use a part of lighting fumigant to make the direct mode of heating of fumigant burning, or fumigant is heated to the indirect mode of 150～450 ℃ of left and right temperature by the hydration reaction heat of the heating agents such as calcium oxide.For example, proposed to utilize the hydration reaction heat of calcium oxide to heat in the indirect mode containing the heat generation matrix such as Celogen Az with containing the fumigant composition of effective composition, the cigarette (gas produced by thermolysis and particulate) that spontaneous combustion by heat generation matrix produces makes active ingredient wave loose fumigating device, and this has been put into actual use (reference example is as Japanese documentation 2～3).
On the other hand, proposed heating active ingredient and be dissolved in the fluid composition in solvent, made active ingredient wave loose heating evaporation agent.Such heating evaporation agent is housed in the device that possesses liquid-sucking core, is absorbed by liquid-sucking core, by heating described liquid-sucking core, active ingredient is slowly volatilized.Its heating-up temperature, lower than the situation of using fumigant, is generally (reference example is as Japanese documentation 4～5) below 135 ℃.
The prior art document
Patent documentation
Patent documentation 1: the clear 61-224928 communique of Japanese Patent Laid-Open
Patent documentation 2: Japan Patent examined patent publication 58-28842 communique
Patent documentation 3: Japan Patent examined patent publication 59-49201 communique
Patent documentation 4: Japanese patent laid-open 7-69805 communique
Patent documentation 5: Japanese Patent Laid-Open 2009-232915 communique
Summary of the invention
Yet the method for patent documentation 1 is large-scale plant, can not be called easy method, be not suitable for especially domestic use.
As the fumigant containing the heat generation matrix such as Celogen Az of record in patent documentation 2～3, active ingredient wave loose effect excellence, but the white precipitum caused due to the cigarette produced etc. have the problem that produces space-pollution.
In addition, the heating evaporation agent of the type of putting down in writing in patent documentation 4～5, due to not containing heat generation matrix, is difficult for producing the problem of space-pollution, but, because waving of active ingredient is slowly loose, active ingredient can not be full of fully in each corner in space.Therefore, the weak problem of effect obtained is arranged.Because the loose state of waving of active ingredient can not be visible as the fumigant heating produces cigarette, there is the user to be difficult to obtain the problem of actual effect sense in addition.
Problem of the present invention is In view of the foregoing, provides to process the sootiness type that the high and user of effect that convenient, low contaminative, active ingredient cause can obtain the actual effect sense and wave powder, use this sootiness type to wave sootiness type spatial manipulation device and the spatial manipulation method of powder.
The inventor addresses the above problem the result of being furtherd investigate, and selects polyalcohol to replace the heat generation matrix (such as Celogen Az etc.) of the fumigant that uses in prior art.Composition using polyalcohol as matrix heats under 150～450 ℃, the same with fumigant of the prior art, the cigarette shape thing of visible white, and thinking that active ingredient can be waved falls apart to whole space, thereby has completed the present invention.
The present invention has following mode.
[1] a kind of sootiness type is waved powder, wherein, and containing (A) polyalcohol and (B) active ingredient.
[2] the sootiness type described in [1] is waved powder, and wherein, described (B) active ingredient contains the composition more than a kind in the cohort that is selected from microorganism deactivated composition, repellent composition, beauty treatment composition, antistatic composition and fragrance component formation.
[3] the sootiness type described in [1] or [2] is waved powder, wherein, and not containing the heat generation matrix with autoreaction.
[4] the sootiness type described in [1] is waved powder, and wherein, described (A) composition is following general formula (A1) or the compound that (A2) means.
HO-R
1-OH...(A1)
HO-(R
2O)
n-H...(A2)
[in formula, R
1and R
2independent separately is the divalent aliphatic alkyl of carbon number 2～18, the integer that n is 2～14.]
[5] the sootiness type described in [1] is waved powder, wherein, described microorganism deactivated composition is for being selected from triclosan, isopropyl methyl phenol, thymol, phenoxetol, the iodo-2-propynyl butyl carbamate of 3-, methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, Trichlorocarbanilide, Hinokitiol, butyl p-hydroxybenzoate, propylparaben, chlorhexidine hydrochloride, chlorhexidine gluconate, benzethonium chloride, benzalkonium chloride, Cetylpyridinium Chloride, DDAC, hypochlorous acid or its salt, chlorous acid or its salt, chlorine dioxide, chlorinated isocyanuric acid or its salt, povidon iodine, to chlorobenzene-3-iodine propinyl dimethoxym ethane, the iodo-2-propynyl butyl carbamate of 3-, CMIT, MIT, Kathon and 1, the composition of at least one in the cohort that 2-[4-morpholinodithio ketone forms.
[6] the sootiness type described in [1] is waved powder, and wherein, described repellent composition is at least one the composition be selected from the cohort that DEET, rosemary oil, lavender oil, peppermint oil, basil and citronellal form.
[7] the sootiness type described in [1] is waved powder, and wherein, described beauty treatment composition is at least one the composition be selected from the cohort that pyrrolidone carboxylic acid salt, sodium lactate, hyaluronic acid, squalene, silicone oil, loquat-leaf extract and glutinous rehmannia extract form.
[8] the sootiness type described in [1] is waved powder, and wherein, described antistatic composition is at least one the composition be selected from the cohort that quaternary ammonium salt, amine, amine salt, acid amides and phosphate form.
[9] wave powder as the sootiness type of record in [1], wherein, described fragrance component is for being selected from lemon oil, orange oil, bergamot oil, Java Cananga Oil, patchouli oil, citronella oil, lemongrass oil, rosewood oil, caryophyllus oil, eucalyptus oil, cedar oil, lavender oil, sandalwood oil, vetiver oil, pelargonium oil, ladanum oil, peppermint oil, attar of rose, jasmine oil, litsea cubeba oil, the geraniol of separating from these natural plant essential oils, citronellol, eugenol, Moschus, civetta, ambergris, castoreum, benzyl carbinol, dihydromyrcenol, benzyl acetate, vanillin, cinnamic acid, heliotropin, anise alcohol, anisaldehyde, irisone, cis-3-hexenol, benzylalcohol, the amyl group cinnamyl alcohol, dimethyl benzyl carbinyl acetate, cinnamyl acetate, isoamyl salicylate, MDJ, α-preparing piperonyl propionaldehyde, geranonitrile, citronellyl nitrile, jasminolene, lilial, cyclamen aldehyde, γ-11 carbon lactone, iris ester, the composition of at least one in the cohort that ambrox and Jiale muskiness form.
[10] the sootiness type described in [1] is waved powder, wherein, the content of described (A) composition, the gross mass of waving powder with respect to the sootiness type, be 20～98 quality %.
[11] the sootiness type described in [1] is waved powder, wherein, the content of described (B) composition, the gross mass of waving powder with respect to the sootiness type, be 0.001～10 quality %.
[12] a kind of sootiness type spatial manipulation device, wherein, [1]～[11] the described sootiness type of any one is waved powder and is produced the heating part of 150～450 ℃ of heat, by heat transfer part, configures.
[13] a kind of spatial manipulation method is the sootiness type described in any one of [1]～[11] to be waved to powder under 150～450 ℃, heat.
The effect of invention
According to the present invention, the sootiness type that provides the high and user of a kind of effect of using simple, low contaminative, active ingredient to cause can obtain the actual effect sense is waved powder, uses described sootiness type to wave sootiness type spatial manipulation device and the spatial manipulation method of powder.
The accompanying drawing explanation
[Fig. 1] is the overview cutaway view of an illustrated embodiment of the formation of sootiness type spatial manipulation device.
Symbol description
1, sootiness type spatial manipulation device 10, outer container 12, main body 14, cap 16, bottom 20, inner pressurd vessel 30, heating part 40, sootiness type are waved powder
Embodiment
" the sootiness type is waved powder "
Sootiness type of the present invention is waved powder and is contained (A) polyalcohol (hereinafter referred to as (A) composition.) and (B) active ingredient (hereinafter referred to as (B) composition.)。
The sootiness type is waved powder and is produced steam by heating, thereby by steam, active ingredient is waved to fall apart, in space, carries out spatial manipulation.
In the present invention, " carrying out spatial manipulation " refers to that the effect of active ingredient arrives the meaning of the article of existence in the Huo Gai space, space of the processing object waited in house etc.
As the space of the processing object that becomes spatial manipulation, suitable the is sealable space in (bathroom, parlor, bedroom, wardrobe etc.), vehicle etc. in house for example.
Sootiness type of the present invention is waved powder, during use, under the high temperature of 150～450 ℃ of left and right, heats, and can make (B) composition wave at short notice and fall apart in the space of processing object.Identical with fumigant in the past during above-mentioned heating, the user can be visual to white cigarette shape thing, obtains the actual effect sense.That is to say, when sootiness type of the present invention is waved powder and carried out described heating, (A) the composition gasification is ejected in the space such as indoor.It is identical that steam that should (A) composition and the cigarette of fumigant in the past play a part, and therefore enough (B) compositions can be waved the whole space of faling apart to processing object at short notice, brings into play the effect of the excellence that active ingredient causes.In addition, different from the cigarette of existing fumigant, the cigarette shape thing of described white derives from the steam of (A) composition, therefore can suppress the pollution in space.
In addition, sootiness type of the present invention is waved in powder, does not preferably comprise the heat generation matrix of autoreaction.Therefore, because the sootiness type is waved the particulate that powder does not contain burning or the decomposition generation of heat generation matrix, can prevent the pollution of white precipitum to space.
Here, " heat generation matrix " refers to by heating flame or decomposes the combustion heat or the decomposition heat that produce and make active ingredient wave loose composition, can use the various materials such as organic foaming agent, heating agent, incendiary agent, particularly, can enumerate nitrocellulose, Celogen Az, p, p '-oxo two (benzene sulfonyl hydrazide), N, N '-dinitrosopentamethylene tetramine etc.
Here " the heat generation matrix of autoreaction " refers to and can be burnt on one's own initiative when the temperature reached more than certain or the material of decomposition reaction.Particularly, the Celogen Az of can giving an example.
[(A) composition]
" polyalcohol " refers in molecule the compound with 2 above hydroxyls, and what have 2 hydroxyls is called dihydroxylic alcohols (as ethylene glycol), has the trihydroxylic alcohol that is called of 3 hydroxyls, contains the polyalcohol that is referred to as more than 2.When polyalcohol is heated under 150～450 ℃, find that there is the feature of the white cigarette shape deposits yields identical with existing fumigant, use as the matrix of being fuming in the present invention.
(A) there is no particular limitation for composition, can be from the material for medicine, medicine part outer article, cosmetics, groceries, industrial products etc., and the heating-up temperature when fluidization property of consideration (B) composition, dissolution dispersity, use etc. is suitably selected.
(A) boiling point of composition, consider from the point of the fluidization property of (B) composition, preferably 150～300 ℃, and further preferably 170～300 ℃.
As (A) composition, can enumerate the above polyalcohol of dihydroxylic alcohols (as ethylene glycol), ternary, sugar, sugar alcohol etc.
As the suitable material of dihydroxylic alcohols, carbon number is more than 2, even can enumerate, is inserting also each compound in conjunction with the structure of a hydroxyl on passable 2 carbon atoms with aliphatic hydrocarbon of etheric oxygen atom (O-) between carbon atom.
In above-claimed cpd, aliphatic hydrocarbon can be saturated can be also undersaturated.In addition above-mentioned aliphatic hydrocarbon can be chain can be also ring-type, also can be its combination, be preferably chain.In the situation of chain, above-mentioned aliphatic hydrocarbon can be the straight chain shape can be also chain.In the situation of ring-type, above-mentioned aliphatic hydrocarbon can be monocyclic can be also polycycle.
As such compound, particularly, the compound that can enumerate following general formula (A1) or (A2) mean.
HO-R
1-OH...(A1)
HO-(R
2O)
n-H...(A2)
[in formula, R
1with R
2independent separately is the divalent aliphatic hydrocarbon base of carbon number 2～18, the integer that n is 2～14]
In formula (A1), R
1the carbon number of middle divalent aliphatic hydrocarbon base preferably 2～18, more preferably 2～4, further preferably 3 or 4.As R
1, acrylic particularly preferably.
The compound that formula (A2) means is so-called polyethers.
In formula (A2), as R
2can enumerate and R
1identical material, preferred vinyl or acrylic, particularly preferably vinyl.
The integer that preferably n is 2～14, further preferred 2～4 integer.
The compound meaned as above-mentioned general formula (A1), can enumerate ethylene glycol, propane diols, 1,3-BDO, trans-2-butene-Isosorbide-5-Nitrae-glycol, 2-butine-Isosorbide-5-Nitrae-glycol, 2,5-hexylene glycol, the 2-methyl isophthalic acid, the 3-pentanediol, 2-methyl-2, the 4-pentanediol, Pinacol, 2,4-heptandiol, 2,2-diethyl-1,3-PD, 2-ethyl-1, the 3-hexylene glycol, 2-ethyl-2-butyl-1,3-PD, the isoamyl glycol, propane diols, BDO, 1,5-PD, 1,6-hexylene glycol, 1,7-heptandiol, 1,8-ethohexadiol, 1,9-nonanediol, 1,10-decanediol, 1,11-hendecane glycol, 1,12-dodecanediol, 1,13-tridecane glycol, 1,14-tetradecane glycol, 1,15-pentadecane glycol, 1,16-hexadecane glycol, 1,17-heptadecane glycol, 1,18-octacosanol, 1,19-nonadecane glycol, 1,20-eicosane glycol, 1,2-ethohexadiol, 1,2-decanediol, 1,2-dodecanediol, 1,2-tetradecane glycol, 1,2-hexadecane glycol, 1,2-octacosanol etc., wherein, preferred propane diols.
The compound meaned as above-mentioned general formula (A2), can enumerate diethylene glycol (DEG), triethylene glycol, the polyethylene glycol that mean molecule quantity is 200～20000, dipropylene glycol, tripropylene glycol, the polypropylene glycol that mean molecule quantity is 300～2000 etc.Wherein, preferred dipropylene glycol.
The polyethylene glycol that mean molecule quantity is 200～20000, also referred to as Macrogol (polyethylene glycol), can enumerate Macrogol 200 (mean molecule quantity 190～210), Liquid Macrogol (mean molecule quantity 280～320), PEG400 (mean molecule quantity 380～420), Macrogol 600 (mean molecule quantity 570～630), cetomacrogol 1000 (mean molecule quantity 950～1050), polyethylene glycol 1500 (equal amount of mixture of Liquid Macrogol and Macrogol 1540), Macrogol 1540 (mean molecule quantity 1290～1650), Macrogol 2000 (mean molecule quantity 1850～2150), Macrogol 4000 (mean molecule quantity 2600～3800), Macrogol 6000 (mean molecule quantity 7300～9300), PEG20000 (mean molecule quantity 9300～12500), PEG 20000 (mean molecule quantity 15500～20000) etc.Wherein, the polyethylene glycol that preferably mean molecule quantity is 200～600.
These polyethylene glycol for example can be used the commercially available product obtained from Sanyo Chemical Industries, Ltd. or Japan Oil Co.The commercially available product of polyethylene glycol with the numerical value of mean molecule quantity, according to commodity, for example, as polyethylene glycol #1000, has the situation that adds # between polyethylene glycol and numerical value usually.
In addition, the mean molecule quantity of above-mentioned polyethylene glycol means the mean molecule quantity of medicine part outer article raw material specification 2006 record, is the value that the assay method by 2006 records of medicine part outer article raw material specification obtains.
The polypropylene glycol that is 300～2000 as mean molecule quantity, can enumerate the polypropylene glycol that the degree of polymerization is 4～34, as such polypropylene glycol, can use the commercially available products such as Newpol PP-400, PP-1000, PP-2000 (Sanyo Chemical Industries, Ltd.'s system).
In addition, the mean molecule quantity of polypropylene glycol is number-average molecular weight, is the value of obtaining by hydroxyl value.
As material suitable in sugar, can enumerate the monose such as glucose, fructose; The disaccharides such as sucrose, lactose, maltose, trehalose; The polysaccharide that trisaccharide is above etc.
As material suitable in sugar alcohol, can enumerate glycerine, two glycerine, polyglycereol, antierythrite, xylitol, D-sorbitol, mannitol, maltitol etc.Glycerine, two glycerine, polyglycereol can be used the commercially available product such as this pharmaceutical industries of slope Co., Ltd. etc.
In above-mentioned, as (A) composition, from especially easily gasification of heating, active ingredient is easily waved the consideration of loose aspect, preferred dihydroxylic alcohols, wherein, the polyethylene glycol that particularly preferably propane diols, dipropylene glycol, tripropylene glycol, 1,3-BDO, mean molecule quantity are 200～600.
Sootiness type of the present invention wave (A) composition of containing in powder can for a kind of also can be for two or more.
Kind according to (A) composition, perhaps according to different (A) compositions and use, can control the concentration, the generation of cigarette shape thing, the generation duration (being fuming the duration) of cigarette shape thing of color of the cigarette shape thing of generation, further, also can control the amount of volatilization of (B) composition to space.
Sootiness type of the present invention is waved in powder, and (A) content of composition is waved the gross mass of powder with respect to the sootiness type, preferably more than 20 quality %, more preferably more than 25 quality %, further preferably more than 30 quality %.During less than 20 quality %, there is (B) composition can not fully wave loose possibility.
(A) upper limit of the content of composition, if just there is no particular limitation in the scope of 100 quality % for the total amount of all formulated components, can suitably set according to the proportional quantity of other compositions.(A) content of composition is waved the gross mass of powder with respect to the sootiness type, is below 98 quality %, preferably below 90 quality %, more preferably below 85 quality %.(A) when the content of composition surpasses 98 quality %, the content of relative (B) composition tails off, and (B) composition can not be waved loosely fully thus, and the effect that active ingredient causes may be insufficient.
That is, (A) content of composition, the gross mass that relatively the sootiness type is waved powder, be 20～98 quality %, preferred 20～90 quality %, further preferred 25～85 quality %.
[(B) composition]
Active ingredient, for being waved the composition fallen apart to applying effect in the ，Gai space, whole space of processing object, can suitably be selected according to purposes.
As (B) composition, can be used for purposes for example shown below.
The sterilization in Nei Deng space, house, antibiotic, reduce virus activity, reduce allergen activity, kill mould or kill the purposes of mildew-resistant etc.: microorganism deactivated composition.
The biological repellent purposes of acarid etc.: repellent composition.
The beautifying use of health (skin, hair etc.): beauty treatment composition.
Antistatic purposes: antistatic composition.
The purposes of fragrance, deodorizing etc.: fragrance component.
(microorganism deactivated composition)
Microorganism deactivated composition refers to have sterilization, kills mouldly, makes the composition of inactivation of virus texts, comprises make to exist in space microorganism deactivated, or suppresses the composition (also comprising the inactivation composition that a kind of composition has above-mentioned a plurality of effects simultaneously) that microorganism increases.
As microorganism deactivated composition, can enumerate the nonionic compound of triclosan, isopropyl methyl phenol, thymol, phenoxetol, the iodo-2-propynyl butyl carbamate of 3-, methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, Trichlorocarbanilide, Hinokitiol, butyl p-hydroxybenzoate, propylparaben, chlorhexidine hydrochloride etc.; The cationic compound of chlorhexidine hydrochloride, chlorhexidine gluconate, benzethonium chloride, benzalkonium chloride, Cetylpyridinium Chloride, DDAC etc.; Hypochlorous acid or its salt, chlorous acid or its salt, chlorine dioxide, chlorinated isocyanuric acid or its salt, povidon iodine, to the halide of chlorobenzene-3-iodine propinyl dimethoxym ethane, the iodo-2-propynyl butyl carbamate of 3-etc.; CMIT, MIT, Kathon, 1, the isothiazolinone based compound of 2-[4-morpholinodithio ketone etc.
In above-mentioned, preferred nonionic compound, particularly preferably isopropyl methyl phenol (boiling point: 246 ℃), Hinokitiol (140 ℃ of boiling points).In addition, in this specification, " boiling point " refers to the boiling point under normal pressure.
When (B) composition is isopropyl methyl phenol (246 ℃ of boiling points), preferably (A) composition is used dipropylene glycol (230 ℃ of boiling points).According to this combination, can bring into play excellent bacteria-eliminating efficacy.
In addition, when (B) composition is Hinokitiol (140 ℃ of boiling points), preferably (A) composition is used propane diols (190 ℃ of boiling points).According to this combination, can bring into play excellent bacteria-eliminating efficacy.
Sootiness type of the present invention is waved the microorganism deactivated composition comprised in powder, can for a kind of also can be for two or more.
(repellent composition)
The repellent composition refers to the composition that the animal (mouse etc.) that suppresses in space, insect (mosquito, cockroach, fly etc.), acarid etc. are invaded.
As the repellent composition, can enumerate DEET (also referred to as DEET), rosemary oil, lavender oil, peppermint oil, basil, citronellal etc.
In above-mentioned, preferred DEET (285 ℃ of boiling points), citronellal (206 ℃ of boiling points).
When preferably (B) composition is DEET (285 ℃ of boiling points), (A) composition is used tripropylene glycol (273 ℃ of boiling points).According to this combination, can bring into play excellent repellent effect.
In addition, when preferably (B) composition is citronellal (206 ℃ of boiling points), (A) composition is used propane diols (189 ℃ of boiling points).According to this combination, can bring into play excellent repellent effect.
Sootiness type of the present invention wave the repellent composition that contains in powder can for a kind of also can be for two or more.
(beauty treatment composition)
The beauty treatment composition refers to the composition that acts on health (skin, hair etc.), comprises the middle active ingredients of using such as cosmetics.
As the beauty treatment composition, can enumerate pyrrolidone carboxylic acid salt, sodium lactate, hyaluronic acid, squalene, the moisturizing composition of silicone oil etc.; Loquat-leaf extract, the blood circulation of glutinous rehmannia extract etc. promotes into and grades.
In above-mentioned moisturizing composition, squalene (285 ℃ of boiling points) particularly preferably.
When preferably (B) composition is squalene (285 ℃ of boiling points), (A) composition is used tripropylene glycol (273 ℃ of boiling points).According to this combination, can bring into play good moistening effect.
Sootiness type of the present invention is waved the beauty treatment composition contained in powder, can for a kind of also can be for two or more.
(antistatic composition)
The composition that the antistatic composition refers to the composition that suppresses to produce in space static, thereby floating dust and pollen etc. are removed airborne these materials in can absorbed air.
As the antistatic composition, can enumerate quaternary ammonium salt, amine, amine salt, acid amides, phosphate etc.
In above-mentioned, preferred quaternary ammonium salt.
As quaternary ammonium salt, single long-chain or two long chain quaternary of the alkyl or alkenyl that can to enumerate carbon atom quantity be 12～22, alkyl imidazoline salt, two (alkylamide ethyl) dimethyl hydroxyethyl ammonium salt, two (alkyl acyloxy ethyl) dimethyl hydroxyethyl ammonium salt etc., particularly, can enumerate two (hydrogenated tallow alkyl) Methylethyl ethyl-sulfate ammonium, distearyl Dimethyl Ammonium Methylsulfate, two (hydrogenated tallow alkyl) dimethyl acetic acid ammonium, the stearyl trimethyl ammonium chloride, two oil base alkyl dimethyl ammonium chlorides, two (palm oil alkyl) dimethyl ammonium phosphate, Dodecyl trimethyl ammonium chloride etc.Wherein, stearyl trimethyl ammonium chloride particularly preferably.
When preferably (B) composition is stearyl trimethyl ammonium chloride (100 ℃ of boiling points), (A) composition is used propane diols (189 ℃ of boiling points).According to this combination, can bring into play excellent anti-static effect.
As amine, can enumerate N, N-bis--(2-hydroxyethyl amine) etc.
As amine salt, can enumerate stearyl amine acetate etc.
As acid amides, can enumerate Stearic acid diethanolamine salt etc.
As phosphate, can enumerate dodecylphosphoric acid sodium etc.
Sootiness type of the present invention is waved the antistatic composition contained in powder, can for a kind of also can be for two or more.
(fragrance component)
Fragrance component can be by natural perfume material, and essential oil and synthetic perfume at random mix use.
As fragrance component, can enumerate the natural plant essential oil of lemon oil, orange oil, bergamot oil, Java Cananga Oil, patchouli oil, citronella oil, lemongrass oil, rosewood oil, caryophyllus oil, eucalyptus oil, cedar oil, lavender oil, sandalwood oil, vetiver oil, pelargonium oil, ladanum oil, peppermint oil, attar of rose, jasmine oil, fruit of a cubeb litsea tree wet goods, the mono-isolate class of the geraniol of separating from these natural plant essential oils, citronellol, eugenol etc., the natural animal perfumery of Moschus, civetta, castoreum, ambergris etc., benzyl carbinol, dihydromyrcenol, benzyl acetate, vanillin, cinnamic acid, heliotropin, anise alcohol, anisaldehyde, irisone, cis-3-hexenol, benzylalcohol, the amyl group cinnamyl alcohol, dimethyl benzyl carbinyl acetate, cinnamyl acetate, isoamyl salicylate, MDJ, α-preparing piperonyl propionaldehyde, geranonitrile, citronellyl nitrile, jasminolene, lilial, cyclamen aldehyde, γ-11 carbon lactone, iris ester, ambrox, the synthetic perfume of Jiale muskiness etc. etc.
As other fragrance component, can enumerate chemical overview, 1, 2, the wide river of 3[Tian Zhizhu difficult to understand bookstore publishing], Perfume and flavor Chemicals, 1, 2[SteffenArctander work], " synthetic perfume chemistry and knowledge of goods " [printing one work chemical industry daily paper publishing house of rattan unit publishes], the 3rd used for cosmetic spices of known conventional techniques collection (spices), [waste well combines one to the encyclopedia of spices, the holt husband that cites, vow island spring, Kawasaki is logical clear towards storehouse bookstore], the natural perfume material of record in " practical intelligence of spices " [printing rattan unit one work Japan economy publishes] etc., flavor compounds.
In above-mentioned, from the point of sleep derivation effect, consider, particularly preferably heliotropin (264 ℃ of boiling points).
When preferably (B) composition is heliotropin (264 ℃ of boiling points), (A) composition is used dipropylene glycol (230 ℃ of boiling points).According to such combination, can bring into play excellent sleep derivation effect.
(B) composition comprised in Hypatmism type volatilizer of the present invention, can for a kind of also can be for two or more.
As (B) composition, preferably contain at least one the above composition in the cohort that is selected from mentioned microorganism inactivation composition, repellent composition, beauty treatment composition, antistatic composition and fragrance component formation.
In addition, (B) composition is considered from more holding volatile angle, preferably the material close with (A) composition boiling point.As (B) composition, preferably boiling point is 100～450 ℃, more preferably 150～300 ℃.(B) boiling point of composition, when above-mentioned scope, is more easily waved loose.Particularly with natural evaporation in the past or add the method for soaking the liquid-sucking core contained in the fluid composition that is dissolved with active ingredient in the hot flashing solvent, be difficult to wave loose active ingredient also become easily wave loose.
Sootiness type of the present invention is waved in powder, (B) the sootiness type used when the content of composition can be processed according to its kind, titer, primary space is waved the amount (such as the loading of sootiness type spatial manipulation device etc.), heater means of powder etc. and is carried out suitable setting, the gross mass that the sootiness type is waved powder relatively, preferably 0.001～10 quality %, more preferably 0.01～5 quality %.
(B) composition when the quantity not sufficient 0.001 quality %, the effect that active ingredient causes may be insufficient.While surpassing 10 quality %, the content of relative (A) composition reduces, and (B) composition waves loose rate and may reduce.In addition, can damage its dissolubility and dispersiveness in (A) composition, the situation of preparation difficulty is arranged.In addition, even proportioning surpasses 10 quality %, the effect that active ingredient causes also can change hardly, also not preferred from economic angle.
Sootiness type of the present invention is waved in powder, further, take that to reduce contaminative etc. be purpose, also can contain water.By (A) composition and water are also used, can control the concentration, the generation of cigarette shape thing, the generation duration (being fuming the duration) of cigarette shape thing of color of the cigarette shape thing of generation, further, can also control the space amount of volatilization of (B) composition.
As water, can use pure water, ion exchange water, distilled water etc.
The content of water, the gross mass of waving powder with respect to the sootiness type, preferably below 50 quality %, more preferably below 20 quality %, particularly preferably below 10 quality %.The content of water is 50 quality % when following, and the specific heat of the steam produced during due to heating is enough little, easily produces dense cigarette shape thing, visual better.
Yet the content of water can suitably be set according to the kind of purposes, (B) composition.For example, while as (B) composition, using microorganism deactivated composition, the content of water, the gross mass that relatively the sootiness type is waved powder, be preferably 1～50 quality %, more preferably 2～20 quality %, further preferred 3～10 quality %, can be not moisture yet.While as (B) composition, using fragrance component, the content of water, the gross mass that the sootiness type is waved powder relatively, preferred 10～90 quality %, more preferably 30～80 quality %, further preferred 50～70 quality %.
(A) ratio of composition and water, from the viewpoint of the space amount of volatilization of the reduction of the generation of the concentration of the color of the cigarette shape thing that produces, cigarette shape thing and the control of the duration of being fuming, contaminative, (B) composition, consider, the mass ratio that (A) composition/water meter of preferably take shows is 20/80～100/0, more preferably 20/80～90/10, can suitably select according to expected effect.
Wherein, the concentration of the color of the cigarette shape thing produced from easy realization, generation and the control of the duration of being fuming of cigarette shape thing, (B) angle of existing side by side of the reduction of the space volatile quantity of composition, contaminative is considered, the mass ratio that (A) composition/water meter of more preferably take shows is 30/70～98/2, further preferably 50/50～98/2, particularly preferably 80/20～95/5.
Sootiness type of the present invention is waved in powder, as required, in the scope of not damaging effect of the present invention, can also contain above-mentioned (A) composition, (B) composition and water other composition in addition, as above-mentioned other composition, can enumerate surfactant, preservative, gelling agent, excipient etc.
As surfactant if the material usually used in medicine, medicine part outer article, cosmetics, groceries etc. just has no particular limits, for the dissolubility in (A) composition, dispersed viewpoint, preferably nonionic surface active agent.Particularly, can enumerate Crodaret, polyoxyethylene alkyl ether, polyoxyethylene polyoxy-propylene, sorbitan fatty acid ester, fatty acid glyceride, methyl glycol fatty acid ester, cithrol, polyglyceryl fatty acid ester, polyoxyethylene fatty acid glyceride, polyoxyethylene sorbitan fatty acid ester, sucrose fatty ester etc.
Sootiness type of the present invention is waved powder, can be prepared by mixing above-mentioned each composition.
" spatial manipulation method "
Sootiness type of the present invention is waved powder, and as mentioned above, by heating under 150～450 ℃, when producing white cigarette shape thing, (B) composition is waved loose.Heat sootiness type of the present invention in space in house, in vehicle etc. and wave powder, due to above-mentioned cigarette shape thing (B) composition, wave at short notice and fall apart in above-mentioned space, carry out spatial manipulation (by active ingredient, bringing into play various effects).
The heating-up temperature that the sootiness type is waved powder is 150～450 ℃, preferably 170～400 ℃, and more preferably 190～400 ℃.When heating more than 150 ℃, the steam of (A) composition of generation is the ejection of cigarette shape, can make (B) composition wave at short notice and fall apart to the whole space of processing object.In above-mentioned scope, heating-up temperature is higher, and it is shorter that (B) composition is waved the loose time to whole space, waves loose scope wider.When heating-up temperature surpasses 450 ℃, (B) become branch that thermolysis occurs, the amount of volatilization under effective status (undecomposed state) likely reduces (waving loose Efficiency Decreasing).
The sootiness type is waved the heating of powder, from the angle of anti-fouling effect excellence, considers, preferably by the indirect mode, is heated.The indirect mode, as a kind of method in the mode of heating of fumigant by cognition, do not make fumigant burning, the simple method by the necessary temperature of the thermolysis of heat generation matrix (heat energy) by heat transfer part (such as the space of the wall of a container of accommodating above-mentioned fumigant (sidewall or diapire), said vesse etc.) supply.That is to say in the present invention and preferably do not make the sootiness type wave the powder burning, (A) the needed temperature of the gasification of composition (heat energy) is supplied with by heat transfer part.
As heating means, there is no particular limitation, can use the heating means of using in indirect mode in the past.For example, after contacting with water, the material of heating contacts with water, utilize the method for this reaction heat, by metal with than above-mentioned metal ion tendency, little metal oxide or oxidant mixes (mixing such as iron powder and oxidant (ammonium chlorate etc.)), the method of the heat of utilizing this oxidation reaction to produce, utilize electric power as the heating wire class (such as hot plate etc.) to produce hot method etc.Wherein, the viewpoint of practicality is considered, preferably will contact with water the rear material generated heat and contact with water, utilizes the method for this reaction heat, more preferably utilizes the method for the reaction heat of calcium oxide and water.
As the material with the water contact heating, can enumerate calcium oxide, magnesium chloride, aluminium chloride, calcium chloride, iron chloride etc.For example, while making calcium oxide and water reaction, can produce the heat of 200～400 ℃ of left and right.
By the heating of indirect mode, for example, in the container that can use by the fumigating device of the indirect mode in the past, add sootiness type of the present invention to wave powder and implement.
In addition, preferably add the temperature that thermogenetic sootiness type is waved powder, within the short as far as possible time, arrive design temperature.Particularly, the heating that preferred sootiness type is waved powder can make the heat transfer part surface reach design temperature arbitrarily within the short as far as possible time.Further specifically, after starting heating by above-mentioned each reaction or heating wire, preferably, in 120 seconds, more preferably in 60 seconds, reach design temperature and heated.By such control firing rate, the thermolysis that can further suppress (B) composition improves the effect that active ingredient causes.
In addition, preferably keep as far as possible for a long time the temperature of setting arbitrarily.Particularly, preferably, more than 90 seconds, more preferably, more than 150 seconds, for keeping design temperature, heated.By keeping design temperature, the duration of being fuming is elongated like this, and (B) composition can further be waved the whole space of faling apart to processing object, or, can make (B) composition further increase to the amount of volatilization in space.
Above-mentioned design temperature, firing rate and retention time can suitably be set according to the kind of (B) composition.While as the material with the water contact heating, using calcium oxide, the selection of the product hierarchy of ratio that can be by calcium oxide and water, the usage amount of calcium oxide, calcium oxide regulates and controls.In addition, also can wave the capacity of container of powder or material etc. and regulate and control by accommodating the sootiness type.
The sootiness type is waved the usage amount of powder and can suitably be selected according to the area occupied of object.For example, while as (B) composition, using microorganism deactivated composition, every 1m
2, preferably 0.1～2.0g, more preferably 0.2～1.5g.
Processing time (heating starts the time rear, airtight object space), there is no particular limitation, preferably more than 10 minutes, more preferably more than 1 hour.
" sootiness type spatial manipulation device "
In sootiness type spatial manipulation device of the present invention, the sootiness type of the invention described above is waved powder and is produced the heating part of the heat of 150～450 ℃, by heat transfer part, configures and forms.
The structure of sootiness type treating apparatus of the present invention, can be for example except replacing fumigant use sootiness type of the present invention to wave powder, with the same structure of the fumigating device of known indirect mode etc.
An embodiment of sootiness type spatial manipulation device of the present invention, describe by the accompanying drawing added.
Fig. 1 is the general profile chart of the structure of the sootiness type spatial manipulation device 1 of expression present embodiment.
The sootiness type that sootiness type spatial manipulation device 1 is roughly accommodated in the heating part 30 arranged between outer container 10, inboard inner pressurd vessel 20, outer container 10 and the inner pressurd vessel 20 arranged of outer container 10 and inner pressurd vessel 20 is waved powder 40 and is formed.
Wave powder 40 as the sootiness type, can use the sootiness type of the invention described above to wave powder.
The ratio of calcium oxide and water, can consider that the volatile quantity etc. of the concentration of the color of the cigarette shape thing that produces, the generation of cigarette shape thing, the duration of being fuming, (B) composition suitably determines.
In addition, filled for example the example with the material of water contact heating here, but the present invention is not limited to this.For example can be at the interior configuration barrier material of heating part 30 to form a plurality of independently subregions, can fill various metals in each subregion and little metal oxide or the oxidant than above-mentioned metal ion tendency.
In addition, the structure of bottom 16, decide according to the structure of heating part 30, for example, filled metal in heating part 30 and than above-mentioned metal ion tendency when little metal oxide or oxidant, the structure of bottom 16 can not see through water.
The spatial manipulation method of using sootiness type spatial manipulation device 1 is described.
At first, sootiness type spatial manipulation device 1 is placed in object space.Then, make heating part 30 heatings according to the mechanism of heating part 30.For example, setting be while being filled with the heating part 30 of calcium oxide, the bottom of outer container 10 16 is dipped in water.Like this, the water infiltrated from bottom reacts with calcium oxide heating part 30, produces the heat of 200～350 ℃ of left and right.
Now, the temperature of inside bottom surface central portion 22 that preferably can Control the content device 20, the time be immersed in water from the bottom 16 of outer container 10 starts at short notice, preferably, within 120 seconds, more preferably within 60 seconds, reaches design temperature arbitrarily.In addition, preferably the temperature of inside bottom central portion 22 remains at design temperature arbitrarily more than 90 seconds (more preferably more than 150 seconds).In addition, the temperature of inside bottom central portion 22 can be controlled by the amount of adjusting the water reacted with calcium oxide.
Then, from bottom, 16 water that infiltrate reacts sidewall by inner pressurd vessel 20 of the heat that produces and diapire and pass to the sootiness type and wave powder 40 heating part 30 with calcium oxide, the rise steam of generation (A) composition of the temperature that makes the sootiness type wave powder 40.Together with the steam produced, (B) composition is by the hole diffusion of cap 14.Then, by (B) composition, be diffused in object space, can obtain the effect that active ingredient causes.In addition, (A) steam of composition is as visual as white cigarette, and the user can obtain the actual effect sense.Like this, by using sootiness type spatial manipulation device 1 can carry out simply spatial manipulation.
Above-mentioned embodiment, be the sootiness type spatial manipulation device of so-called indirect mode, also can possess such as the impregnating of waving powder (such as liquid-sucking core etc.) or formed body, and the heat transfer part that has spacing ground to arrange between this.
Embodiment
Below, by embodiment, the present invention is specifically described, but the present invention is not limited to this.
Below the raw material that uses in each example as follows.
Propane diols: Kanto Kagaku K. K.'s system.
Isopropyl methyl phenol: Osaka Kasei Co., Ltd.'s system.
Hinokitiol: Takasago spices Industry Co's system.
Heliotropin: Takasago spices Industry Co's system.
DEET: Nippon Seika K.K.
Citronellal: Kanto Kagaku K. K.
Tripropylene glycol: Nacalaitesque Co., Ltd.
Mix, dissolve by each composition by shown in table 1, table 2, prepare each routine smoke-type and wave powder.
In table 1,2, the unit of each composition proportion amount is quality %, and each routine sootiness type is waved powder and be take total amount and prepare respectively as 100 quality %.
And, use the sootiness type spatial manipulation device same with the sootiness type spatial manipulation device 1 of Fig. 1 illustrated embodiment.Particularly, tin can (the L size of using in " fumigation formula insecticide (the water In は じ め Ru バ Le サ Application) 25g that water causes " of Lion Corporation's system; Diameter 66mm * height 75mm) in heating part, fill the calcium oxide as heating agent, special-purpose bottom is installed, using each, routine sootiness type is waved powder and is contained in inner pressurd vessel as sootiness type spatial manipulation device.
In embodiment 1～2, comparative example 1～3, fill calcium oxide 75g in heating part, accommodate the sootiness type and wave powder 8g.In embodiment 3, comparative example 4～5, fill calcium oxide 70g in heating part, accommodate the sootiness type and wave powder 10g.
Each sootiness type spatial manipulation device is carried out to following evaluation.Its result is documented in table 1,2 in the lump.
<embodiment 1～2, comparative example 1～3, the sootiness type spatial manipulation device that degerming is used >
[evaluation of bacteria-eliminating efficacy]
Sterility test sheet (stainless steel rounding plate; Diameter 20mm, surface grade 2B) (the preparation viable count is 1.25 * 10 to go up the dispersion liquid of inoculating staphylococcus aureus (Staphylococcus aureus IFO12732)
8～6.25 * 10
8cfu/m1) 0.01ml, drying at room temperature prepares test film.
Then, at internal volume, be 4.75m
3laboratory in central floor on the test film that is stained with above-mentioned test organisms that has absorbed test organisms is set.Afterwards, in the plastic cup of diameter 8cm, height 7cm, add 26g water, above-mentioned plastic cup is arranged on the central floor in above-mentioned laboratory.Then, preparation sootiness type spatial manipulation device in above-mentioned plastic cup.Recovery test sheet after sootiness starts 10 minutes, as described belowly estimated bacteria-eliminating efficacy.
Wash out test organisms with 10ml SCDLP liquid nutrient medium (day water Pharmaceutical Co., Ltd system) from the test film reclaimed, it is upper that wherein 0.1ml spreads upon standard agar medium (day water Pharmaceutical Co., Ltd system), under 37 ℃, cultivates 24～48 hours.In addition, the test film that is stained with test organisms that with above-mentioned sootiness type spatial manipulation device, does not carry out spatial manipulation is carried out to same cultivation.After cultivation, calculate the clump count embodied, by following formula, try to achieve Δ log, the bacterial population after cultivating is transformed to common logarithm.Then, according to following metewand, estimate bacteria-eliminating efficacy.
Δ log=log (do not carry out the cultivation of the test film that is stained with test organisms of spatial manipulation after bacterial population)-log (carry out the cultivation of the test film that is stained with test organisms of spatial manipulation after bacterial population)
(metewand)
A: Δ log is more than 2.
B: Δ log, more than 1, is less than 2.
C: Δ log is less than 1.
[evaluation of contaminative]
Use the plate of material (floor) of length 12cm * width 12cm, left-half (length 12cm * width 6cm) paper using of making the above-mentioned material plate covers, the sample plane that remaining right half part is naked state.
The above-mentioned sample plane of preparation on the floor of the indoor laboratory that is equivalent to 8 tatamis (width 3.42m * length 3.82m * height 2.4m), the sootiness type spatial manipulation device that on central floor, the sootiness degerming is used in above-mentioned laboratory, airtight 2 hours.
After airtight 2 hours, take out sample plane in above-mentioned laboratory, peel off the paper of covering, the contaminative by 10 syndics for sample plane, follow following benchmark and mark.Then, calculate 10 people's average mark, according to following determinating reference, estimate contaminative.
(scoring)
4 minutes: on the sample plane face, the line of demarcation of left and right can easily distinguish, the right-half plane of sample plane (exposed portions serve)
Change color.
3 minutes: on the sample plane face, the line of demarcation of left and right can distinguish, the color of the right-half plane of sample plane (exposed portions serve) can
See slight variations.
2 minutes: on the sample plane face, although can distinguish when the line of demarcation of left and right is watched attentively, the variation of the color of the right-half plane of sample plane (exposed portions serve) can not identification.
1 minute: on the sample plane face, the line of demarcation of left and right can be distinguished a little, but distinguish difficulty.
0 minute: on the sample plane face, even the line of demarcation of left and right is watched attentively, can not distinguish (there is no contaminative).
(judgment standard)
◎: 10 people's average mark is less than 0.5.
Zero: 10 people's average mark more than 0.5, be less than 1.5.
△: 10 people's average mark more than 1.5, be less than 2.5.
*: 10 people's average mark is more than 2.5.
[table 1]
| ? | Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Propane diols | 98 | 98 | 80 | - | - |
| Water | - | - | 20 | 98 | 98 |
| Isopropyl methyl phenol | 2 | - | - | 2 | - |
| Hinokitiol | - | 2 | - | - | 2 |
| Δlog | 4.4 | 4.5 | 0.5 | 0 | 0 |
| Bacteria-eliminating efficacy | A | A | C | C | C |
| Contaminative (floor) | ◎ | ◎ | ◎ | ◎ | ◎ |
When the sootiness type that embodiment 1, embodiment 2 and comparative example 1 have been accommodated in sootiness is waved the sootiness type spatial manipulation device of powder, in arbitrary examples, cigarette shape thing of visible white all after 1 minute.
Can confirm from result shown in table 1, be suitable for embodiments of the invention 1～2, compare with comparative example 1～3, bacteria-eliminating efficacy is high.In addition, also can confirm that embodiment 1～2 has low contaminative.In addition, do not need large-scale plant, process simple.
<embodiment 3, comparative example 4～5; The sootiness type spatial manipulation device of fragrance use >
[evaluation of flavor strength]
Add 24g water in the plastic cup of diameter 8cm, height 7cm, it is 9.7m that above-mentioned plastic cup is arranged on to internal volume
3laboratory on the central floor of (25 ± 2 ℃ of temperature, relative moisture 45 ± 5%RH).Then, configuration sootiness type spatial manipulation device in above-mentioned plastic cup.
Enter laboratory configuration (beginning sootiness) 10 minutes reliefs 5 experts, in the position from sootiness type spatial manipulation device 1m, hear smell in above-mentioned laboratory to be tested.Then, according to following metewand, the intensity of fragrance is estimated.
(metewand)
◎: whole 5 experts estimate and can perceive fragrance.
In zero: 5, there are 4 people to estimate and can perceive fragrance.
△: have 3 people to estimate in 5 and can perceive fragrance.
*: in 5, there is the following evaluation of 2 people can perceive fragrance.
[evaluation of contaminative]
Contamination evaluating, the sootiness type spatial manipulation device except replacing degerming to use, used outside the sootiness type spatial manipulation device of fragrant use, uses the method identical with above-mentioned [evaluation of contaminative] to carry out.
[table 2]
| ? | Embodiment 3 | Comparative example 4 | Comparative example 5 |
| Propane diols | 35 | 35 | - |
| Water | 64.8 | 65 | 99.8 |
| Heliotropin | 0.2 | - | 0.2 |
| The intensity of fragrance | ◎ | × | △ |
| Contaminative (floor) | ◎ | ◎ | ◎ |
When the sootiness type that embodiment 3 and comparative example 4 have been accommodated in sootiness is waved the sootiness type spatial manipulation device of powder, in arbitrary examples, cigarette shape thing of visible white all after a minute.
Can confirm from result shown in table 2, be suitable for embodiments of the invention 3, compare with comparative example 4～5, can feel stronger fragrance.In addition, also can confirm that embodiment 3 has low contaminative.In addition, do not need large-scale plant, process simple.
<test example (1) >
Use propane diols, tripropylene glycol, glycerine as polyalcohol, prepare respectively the proportioning solution (not containing effective composition) that these each polynary alcohol and water mixes with the ratio (mass ratio) shown in table 3～5.
Then, except replacing the sootiness type to wave powder 40, above-mentioned mixed solution is contained in beyond inner pressurd vessel 20, uses the sootiness type spatial manipulation device of the embodiment same with the sootiness type spatial manipulation device 1 of Fig. 1 illustrated embodiment.Particularly, tin can (the L size of using in Lion Corporation's system " fumigation formula insecticide (the water In は じ め Ru バ Le サ Application) 25g that water causes "; Diameter 66mm * height 75mm) in heating part, fill calcium oxide 75g, Special bottom cap is installed, above-mentioned mixed solution 3g, 9g are accommodated in inner pressurd vessel and use respectively.Then carry out following evaluation.Its result is recorded in table 3～5 in the lump.
(evaluation method)
To add the plastic cup (diameter 8cm, high 7cm) of 26g water to be placed on internal volume 23.8m
3(floor area 9.9m
2the central ground of laboratory (25 ± 2 ℃ of temperature, relative moisture 45 ± 5%RH) * height 2.4m).Then accommodate the sootiness type spatial manipulation device of the mixed solution of above-mentioned polynary alcohol and water in the placed content device in above-mentioned plastic cup, started sootiness.
Sootiness is started to finish to be made a video recording to sootiness, for the time that starts to produce cigarette shape thing (being fuming the time started), the cigarette shape deposits yields duration (being fuming the duration), the concentration of the cigarette of cigarette shape thing, the generation of cigarette shape thing carries out following evaluation.Two direct pipe fluorescent lamp 40 shapes (being equivalent to 37W) are set in addition on the ceiling of laboratory and carry out respectively each evaluation.
[evaluation of be fuming time started, the duration of being fuming]
Measure respectively when the sootiness type spatial manipulation device by above-mentioned is placed on the above-mentioned plastic cup that has added water, to start to produce cigarette shape thing be fuming the time started (second) and from starting to produce cigarette shape thing to being fuming the duration (second) of being fuming and finishing.Carry out 3 meterings, mean value is as evaluation result.
[evaluation of the concentration of the cigarette of cigarette shape thing]
Use image analysis software WinROOF (picture systems (Visual System) of three paddy business Co., Ltd. systems) to resolve the video image of being fuming while finishing.Image choice box (ROI) is set in to the whitest part of the cigarette shape thing of the concluding time point of being fuming, carries out the color extraction process.
Now, measure RGB (RGB color mode) value, use the concentration of B value (blue valve) as the cigarette of cigarette shape thing.Carry out 3 meterings, mean value is as evaluation result.
In addition, the relation of the outward appearance of cigarette shape thing and B value is as described below.
The B value is less than 110: cigarette shape thing is visible, but the white of cigarette is very light.
The B value is, more than 110, to be less than 150: cigarette shape thing is fully visible.
The B value is, more than 150, to be less than 170: the white of the cigarette of cigarette shape thing is dense.
The B value is more than 170: the white of the cigarette of cigarette shape thing is dense.
[evaluation of the generation of cigarette shape thing]
According to the video image of the concluding time point of being fuming, follow following metewand, for the generation of cigarette shape thing, estimated.Carry out 3 meterings, mean value is through the round number, as the result of such evaluation.
(metewand)
5 minutes: cigarette shape thing was full of in laboratory, and the shape of the fluorescent lamp of ceiling almost be cannot see.
4 minutes: cigarette shape thing was full of in laboratory, and the shape of the fluorescent lamp of ceiling is dim visible.
3 minutes: cigarette shape thing was full of in laboratory, and the shape of the fluorescent lamp of ceiling is high-visible.
2 minutes: cigarette shape thing residued in laboratory, but was trapped in a part of space of laboratory.
1 minute: cigarette shape thing did not almost remain in residue in laboratory.
[table 3]
[table 4]
[table 5]
By the result shown in table, can be confirmed separately, the mixed solution of polynary alcohol and water is compared with the situation of only having water, and the duration of being fuming is long, and the white of the cigarette of cigarette shape thing is dense, and the generation of cigarette shape thing is many.
In addition, can see that the ratio of polyalcohol in above-mentioned mixed solution is higher, the duration of being fuming as seen is longer, and the white of the cigarette of cigarette shape thing is denseer, the more tendencies of generation of cigarette shape thing.
In the middle of propane diols, tripropylene glycol, glycerine etc., the duration of being fuming of known tripropylene glycol is the longest, and the white of the cigarette of cigarette shape thing is the denseest, and the generation of cigarette shape thing is maximum.
<test example (2) >
Do not accommodate the sootiness type spatial manipulation device that the sootiness type is waved the embodiment of powder 40 in the inner pressurd vessel 20 of the sootiness type spatial manipulation device 1 of use Fig. 1 illustrated embodiment, measure the variations in temperature of the inside bottom surface central portion 22 of inner pressurd vessel 20.Particularly, tin can (the S size of using in Lion Corporation's system " fumigation formula insecticide (the water In は じ め Ru バ Le サ Application) 12.5g that water causes "; Diameter 52mm * height 67mm), in heating part, fill respectively calcium oxide (37g, 50g), and tin can (the L size of using in " fumigation formula insecticide (the water In は じ め Ru バ Le サ Application) 25g that water causes "; Diameter 66mm * height 75mm) in heating part, fill calcium oxide 75g, on each tin can, Special bottom cap is installed, dispose the sootiness type insect-killing device of mode that the inside bottom surface central portion is fixed with the inner pressurd vessel of temperature inductor.
Then, each being added quantitatively the plastic cup (be all diameter 8cm, height 7cm) of (23g, 16g, 26g) water to be arranged at internal volume is 23.8m
3(floor area 9.9m
2* height 2.4m) in laboratory on the central ground of (25 ± 2 ℃ of temperature, relative moisture 45 ± 5%RH).
After this in above-mentioned plastic cup, be configured in the sootiness type insect-killing device that possesses temperature inductor in above-mentioned inner pressurd vessel.When sootiness starts, start the temperature measuring of the inside bottom surface central portion of inner pressurd vessel.Within every 1 second, measure the once temperature of above-mentioned inside bottom surface central portion, measure respectively maximum temperature, arrive 300 ℃ of desired times, arrive 350 ℃ of desired times, remain on the duration more than 300 ℃.These are measured for each device and measure 3 times, and its average result is recorded in table 6 in the lump.
In addition, as temperature inductor, use banded, goods name ST-13E-015-GW1-ANP, the vertical gauge of peace Co., Ltd. system.As the thermometer be connected with the said temperature inductor, use goods name COMPACT THERMO LOGGER AM-8000E, the vertical gauge of peace Co., Ltd. system.
[table 6]
Can confirm from result shown in table, according to the ratio of calcium oxide and water or the capacity of inner pressurd vessel 20, can control the maximum temperature, firing rate, the duration that arrive.
<embodiment 4～5, comparative example 6; The sootiness type is waved the repellent effect of the mosquito that powder causes >
Mix, dissolve by each composition by shown in table 7, prepare each routine sootiness type and wave powder.
In table 7, the unit of the proportional quantity of each composition is quality %, and each routine sootiness type is waved powder and be take gross mass and prepare respectively as 100 quality %.
Tin can (the L size of using in Lion Corporation's system " fumigation formula insecticide (the water In は じ め Ru バ Le サ Application) 25g that water causes "; Diameter 66mm * height 75mm) in heating part, fill calcium oxide 50g, Special bottom cap is installed, the sootiness type volatilizer 3g shown in table 7 is contained in inner pressurd vessel and uses.Then, carry out following evaluation, its result is recorded in table 7 in the lump.
(evaluation method)
At internal volume, be 0.5m
3the acrylic chamber in, put into the plastic cup (diameter 8cm, height 7cm) that is added with 30g water, airtight sootiness 30 minutes by containing the fumigating device that above-mentioned sootiness type waves powder.After carrying out the ventilation of 5 minutes, in the drug treating box, add 1% white sugar water that has soaked absorbent cotton, be connected with the chamber of the acrylic without chemicals treatment that is placed with 50 mosquitoes, make mosquito in state that can be freely movable.The DO handle box covers with black cloth, makes the interior dimmed placement of box 3 hours.Take off black cloth after 3 hours, calculate residual mosquito number in the drug treating box, according to following standard evaluation repellent effect.
(metewand)
◎: 0～10 is merely able to fully approve the repellent effect of mosquito.
Zero: 11～20 are merely able to approve a little the repellent effect of mosquito.
△: substantially can not approve the mosquito repellent effect for 21～30.
*: 31～50 repellent effects that can not approve mosquito.
[table 7]
| ? | Embodiment 4 | Embodiment 5 | This is example 6 |
| DEET | 5 | ? | ? |
| Citronellal | ? | 10 | ? |
| Tripropylene glycol | 95 | ? | ? |
| Propane diols | ? | 80 | 90 |
| Water | ? | 10 | 10 |
| Amount to | 100 | 100 | 100 |
| Repellent effect | ○ | ◎ | × |
Result is known as shown in Table, and embodiment 4 and 5 sootiness type are waved the repellent effect of the mosquito of powder and fully approved.
Utilize possibility on industry
According to the present invention, provide a kind of and process the sootiness type that the high and user of the effect simple, that contaminative is low, active ingredient causes can obtain the actual effect sense and wave powder, use above-mentioned sootiness type to wave sootiness type spatial manipulation device and the spatial manipulation method of powder.
Claims (13)
1. a sootiness type is waved powder, wherein, and containing (A) polyalcohol and (B) active ingredient.
2. sootiness type as claimed in claim 1 is waved powder, and wherein, described (B) active ingredient contains at least one the above composition in the cohort that is selected from microorganism deactivated composition, repellent composition, beauty treatment composition, antistatic composition and fragrance component formation.
3. sootiness type as claimed in claim 1 or 2 is waved powder, wherein, does not contain the heat generation matrix of autoreaction.
4. sootiness type as claimed in claim 1 is waved powder, and wherein, described (A) composition is following general formula (A1) or the compound that (A2) means,
HO-R
1-OH...(A1)
HO-(R
2O)
n-H...(A2)
In formula, R
1and R
2be independently the divalent aliphatic alkyl of carbon number 2～18 separately, n is 2～14 integer.
5. sootiness type as claimed in claim 1 is waved powder, wherein, described microorganism deactivated composition is for being selected from triclosan, isopropyl methyl phenol, thymol, phenoxetol, the iodo-2-propynyl butyl carbamate of 3-, methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, Trichlorocarbanilide, Hinokitiol, butyl p-hydroxybenzoate, propylparaben, chlorhexidine hydrochloride, chlorhexidine gluconate, benzethonium chloride, benzalkonium chloride, Cetylpyridinium Chloride, DDAC, hypochlorous acid or its salt, chlorous acid or its salt, chlorine dioxide, chlorinated isocyanuric acid or its salt, povidon iodine, to chlorobenzene-3-iodine propinyl dimethoxym ethane, the iodo-2-propynyl butyl carbamate of 3-, CMIT, MIT, Kathon and 1, the composition of at least one in the cohort that 2-[4-morpholinodithio ketone forms.
6. sootiness type as claimed in claim 1 is waved powder, and wherein, described repellent composition is at least one the composition be selected from the cohort that DEET, rosemary oil, lavender oil, peppermint oil, basil and citronellal form.
7. sootiness type as claimed in claim 1 is waved powder, and wherein, described beauty treatment composition is at least one being selected from pyrrolidone carboxylic acid salt, sodium lactate, hyaluronic acid, squalene, silicone oil, loquat-leaf extract and glutinous rehmannia extract.
8. sootiness type as claimed in claim 1 is waved powder, and wherein, described antistatic composition is at least one the composition be selected from the cohort that quaternary ammonium salt, amine, amine salt, acid amides and phosphate form.
9. sootiness type as claimed in claim 1 is waved powder, and wherein, described fragrance component is for being selected from lemon oil, orange oil, bergamot oil, Java Cananga Oil, patchouli oil, citronella oil, lemongrass oil, rosewood oil, caryophyllus oil, eucalyptus oil, cedar oil, lavender oil, sandalwood oil, vetiver oil, pelargonium oil, ladanum oil, peppermint oil, attar of rose, jasmine oil, litsea cubeba oil, the geraniol of separating from these natural plant essential oils, citronellol, eugenol, Moschus, civetta, ambergris, castoreum, benzyl carbinol, dihydromyrcenol, benzyl acetate, vanillin, cinnamic acid, heliotropin, anise alcohol, anisaldehyde, irisone, cis-3-hexenol, benzylalcohol, the amyl group cinnamyl alcohol, dimethyl benzyl carbinyl acetate, cinnamyl acetate, isoamyl salicylate, MDJ, α-preparing piperonyl propionaldehyde, geranonitrile, citronellyl nitrile, jasminolene, lilial, cyclamen aldehyde, γ-11 carbon lactone, iris ester, the composition of at least one in the cohort that ambrox and Jiale muskiness form.
10. sootiness type as claimed in claim 1 is waved powder, wherein, the content of described (A) composition, the gross mass that the sootiness type is waved powder relatively, be 20～98 quality %.
11. sootiness type as claimed in claim 1 is waved powder, it is characterized in that, the content of described (B) composition, and the gross mass that the sootiness type is waved powder relatively, be 0.001～10 quality %.
12. a sootiness type spatial manipulation device, wherein, the sootiness type described in claim 1～11 any one is waved powder and is produced the heating part of 150～450 ℃ of heat, by heat transfer part, configures.
13. a spatial manipulation method is that the sootiness type described in claim 1～11 any one is waved to the method that powder heats under 150～450 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| JP2011102352 | 2011-04-28 | ||
| JP2011-102352 | 2011-04-28 | ||
| JP2011179604 | 2011-08-19 | ||
| JP2011-179604 | 2011-08-19 | ||
| PCT/JP2012/056241 WO2012147421A1 (en) | 2011-04-28 | 2012-03-12 | Fumigant, fogging space treatment device, and space treatment method |
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| Publication Number | Publication Date |
|---|---|
| CN103501601A true CN103501601A (en) | 2014-01-08 |
| CN103501601B CN103501601B (en) | 2016-01-20 |
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|---|---|
| JP (1) | JP5659297B2 (en) |
| KR (1) | KR20140004201A (en) |
| CN (1) | CN103501601B (en) |
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| CN104429737A (en) * | 2014-11-14 | 2015-03-25 | 武汉科磁聚园科技有限公司 | Method for repelling vegetable pests in vegetable greenhouse |
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| JP5947503B2 (en) * | 2011-04-28 | 2016-07-06 | ライオン株式会社 | Smoke type insecticidal device, insecticidal method |
| JP5700815B2 (en) * | 2011-04-28 | 2015-04-15 | ライオン株式会社 | Smoke-type insecticide, smoke-type insecticide, insecticide method |
| KR101569010B1 (en) | 2013-12-24 | 2015-11-16 | 건국대학교 산학협력단 | A method for preventing onion storage disease |
| JP6249831B2 (en) * | 2014-03-13 | 2017-12-20 | 大日本除蟲菊株式会社 | How to avoid bees |
| JP6225354B2 (en) * | 2014-06-25 | 2017-11-08 | ライオン株式会社 | Smoke agent |
| JP2016069368A (en) * | 2014-09-30 | 2016-05-09 | アース製薬株式会社 | Indoor sterilization method |
| JP6355604B2 (en) * | 2014-09-30 | 2018-07-11 | アース製薬株式会社 | How to disinfect the bathroom |
| JP5700480B2 (en) * | 2014-10-31 | 2015-04-15 | ライオン株式会社 | Smoke composition for indirect heating and smoke device of indirect heating type |
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| JP2015096524A (en) * | 2014-12-08 | 2015-05-21 | ライオン株式会社 | Antifungal smoking agent composition for bath room and antifungal smoking device for bath room |
| JP6585966B2 (en) * | 2015-04-17 | 2019-10-02 | 大日本除蟲菊株式会社 | Smoke prevention mold method |
| JP6635589B2 (en) * | 2015-12-28 | 2020-01-29 | ライオン株式会社 | Antifungal composition |
| JP6681773B2 (en) * | 2016-04-08 | 2020-04-15 | レック株式会社 | Smoke agent composition |
| JP6850668B2 (en) * | 2017-04-25 | 2021-03-31 | ライオン株式会社 | Smoke agent composition |
| JP6945337B2 (en) * | 2017-04-26 | 2021-10-06 | ライオン株式会社 | Heated fumigant composition |
| JP7349907B2 (en) | 2019-12-26 | 2023-09-25 | ライオン株式会社 | Microbial suppression method and microbial suppression system |
| JPWO2022019337A1 (en) * | 2020-07-22 | 2022-01-27 | ||
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Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2012147421A1 (en) | 2014-07-28 |
| JP5659297B2 (en) | 2015-01-28 |
| KR20140004201A (en) | 2014-01-10 |
| CN103501601B (en) | 2016-01-20 |
| WO2012147421A1 (en) | 2012-11-01 |
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