CN103485503B - A kind of stable type indoor wall ornament materials and production method thereof - Google Patents
A kind of stable type indoor wall ornament materials and production method thereof Download PDFInfo
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Abstract
The invention discloses a kind of stable type indoor wall ornament materials, have cloth glass layer, cloth the both sides up and down of glass layer, upper layer of PVC and lower layer of PVC, upper layer of PVC is surface wear-resistant layer and micropore alveolar layer, micropore alveolar layer surface wear-resistant layer and cloth between glass layer; Lower layer of PVC is foaming layer, and described upper layer of PVC also has top finishing layer, and surface wear-resistant layer is between described top finishing layer and micropore alveolar layer.The invention also discloses the production technology of this stable type indoor wall ornament materials.The present invention by high-performance fiber cloth glass layer and PVC material carry out compound, improve product stability and intensity, possess the characteristics such as excellent fire-retardant, insulation, moistureproof, sound insulation and mildew-resistant, long service life, product surface pattern is rich and varied.
Description
Technical field
The invention belongs to building materials field, relate to a kind of novel stable type indoor wall ornament materials specifically, the invention still further relates to a kind of production technology of this material.
Background technology
At present, more common on the market indoor wall ornament materials is mainly divided into several large class: wallpaper class, coating class, stone materials and cloth art class etc.Coating is used to account for 70% of inner wall decoration, occupy the leading position in market, but often easily there is the problems such as mouldy, delamination in coating in long-term use procedure, and the color of its decorative effect is single, the decorative effect of decorative pattern cannot be realized, and also have the disadvantages such as washing property of erasable is low, thus gradually abandon by the finishing of some personalizations.Wallpaper class material construction is relatively more expensive than emulsion paint, construction level and quality are not easy to control, product structure is combined into one by the layers of material that the coefficient of expansion is different, still there is the phenomenons such as mouldy, alice, flame retardant effect are poor, life cycle is short in its use procedure, some wallpaper color fastness are poor, are unable to bear scouring, especially the place often irradiated of daylight, time has been grown and has had discolouration phenomena, and range of application is subject to larger restriction.Cloth art class material is a kind of decorative material for internal wall starting at home in recent years to prevail.But its flame-retarding characteristic, the easily shortcoming such as dirty, the generally accreditation of distance customer is had got long long way to go.Stone-like material is due to its radiativity, and construction is complicated, expensive, application that generally can not be a large amount of in wall decoration.So, customer in the urgent need to a kind of indoor wall ornament materials, not only safety and environmental protection but also durable in use.
Summary of the invention
The object of the invention is to for above-mentioned Problems existing, a kind of stable type indoor wall ornament materials is provided, by high-performance fiber cloth glass layer and PVC material carry out compound, construction stability is better, heat stability and intensity high, possess the characteristics such as excellent fire-retardant, insulation, protection against the tide, mildew-resistant, long service life, the pattern of product surface is rich and varied.
In order to realize foregoing invention object, the technical solution used in the present invention is as follows:
A kind of stable type indoor wall ornament materials, have cloth glass layer, cloth the both sides up and down of glass layer, be upper layer of PVC and lower layer of PVC.
Described upper layer of PVC is surface wear-resistant layer and micropore alveolar layer, micropore alveolar layer surface wear-resistant layer and cloth between glass layer;
Described lower layer of PVC is foaming layer.
Described cloth glass layer be terylene, nylon, cotton and numb material cloth glass fiber.
Adopt tatting technique, glass fiber or terylene, nylon, cotton and fiber crops are manufactured embryo cloth.
The material composition of described surface wear-resistant layer is 25%-55%PVC, 20%-60% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 5%-40%.
Surface wear-resistant layer is that the PVC compounded materials of high abrasion loss is obtained.Wherein PVC material selects the high polymerization degree resin that polymerization K value is greater than 70.Wear-resisting PVC layer possesses excellent protection against the tide, mildew-resistant characteristic, abrasion resistance, anti-flammability.
The material composition of described micropore alveolar layer is 20%-60%PVC, 20%-50% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 5%-40%.
Wherein PVC material select suitable as expanded material use EPVC.
The material composition of described foaming layer is 20%-70%PVC rubber plastic foam material, 15%-60% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 2%-40%.
Micropore alveolar layer and foaming layer are that material provides excellent sound-absorption and heat-insulation characteristic.
The foam structure of material uniqueness, coefficient of thermal conductivity is little, and heat preservation and energy conservation effects is good.Material self can digest the phenomenon such as warpage, opposite joint cracking, foaming, delamination that minimal stress is brought.Foam structure design make product have sufficient elasticity, feel more comfortable after can also effectively reduce because of the injury caused of accidentally colliding with, especially effectively can protect the external corner of metope.
Described PVC rubber plastic foam material composition is:
PVC powder 60 ~ 100 parts;
AC blowing agent 2 ~ 8 parts;
Antimony oxide flame retardant 1 ~ 7 part;
Stabilizer 1 ~ 6 part;
Filler 0 ~ 120 part;
Environment-friendly plasticizer 40 ~ 100;
Described PVC powder is the Corvic that suspension method or emulsion method are produced; Described filler is inorganic mineral material.
Adopt PVC to have excellent water repellency, vacuum dehydration performance is less than 10%, farthest can reduce the heat-insulating property caused because of material water suction and decline; In modified formula, add wide spectrum anti-fungus material, reach the effect of fungus-resistant; After being foamed by high temperature, form closed loose structure, the effect of air in the heat conductivility of material itself and closed pore, make product formation independently air structure unit, due to gas molecule spacing farthest, heat conductivility is minimum, and this structure ensure that the insulation capacity of material; Afterwards, composite and flexible cloth or glass fiber material again on perforated foams.
Described filler is preferably calcium carbonate, kaolin, French chalk, magnesium aluminum compounds, wooden molding powder.
Other auxiliary agent described is environment-friendly foaming agent, surfactant, fire retardant or filler; Described environment-friendly plasticizer is non-neighboring benzene class plasticizing agent:
TOTM (TEHTM), as: the different monooctyl ester of trimellitic acid three;
HexamollDINCH, as: cyclohexane 1,2-bis-base diisononyl esters;
ATBC series products, as: ATBC-tributyl 2-acetylcitrate, BHTC-butyryl citric acid tri-n-hexyl ester;
DEHA (DOA), as: dioctyl adipate;
DOTP, as: DOTP; ESO, as: epoxidized soybean oil.
Described upper layer of PVC also has top finishing layer, and surface wear-resistant layer is between described top finishing layer and micropore alveolar layer, and top finishing layer is through the process of Bio-pruf coating.
Described top finishing layer is polyurethane, acrylate material obtains.
Wherein acrylate material selects the high performance resin of yellowing resistance, adhesive power excellence.
, through the process of Bio-pruf coating, there is good inhibitory action on surface to Escherichia coli, staphylococcus aureus, Candida albicans, is detected by the method for " the resistance to mould determination method of GB1741-79 paint film ".Bacteriostasis property can reach more than 98% to common bacteria bacteriostasis rate in 72 hours, ensures that this ornament materials has fungicidal properties effect.
Material environment friendly aspect of performance of the present invention, this product indices is much better than GB-18585-2001 standard.Obtain country's " nonhazardous (green) indoor hardware fitting " certificate, meet the environmental protection standard requirement of indoor hardware fitting completely.
Check through National Fire building materials quality inspection center: this product indices all meets the regulation requirement of nonflammable material, reaches GB8624B-s2, d0, t1 level.
Product is the special pigment possessing good rating for light fastness, and rating for light fastness reaches ISO105B02 standard 7 grades, and anti-look becomes, anti-aging, longer service life compared with traditional decoration material.
Cleaning performance aspect: macromolecule raw material, through special process process, effectively intercept infiltration, acid and alkali-resistance, antistatic, possess water resistance, not easily dust suction.Impervious and the pH resistance test by national experiment of building material center.Not mouldy, not alice, and repeatedly can clean as floor tile.Need not sweep, antistatic performance makes it away from dust.
Insulation, heat-proof quality, through national building materials test Spot detection according to (GB/T17794-2008) detection to its coefficient of thermal conductivity, meet the requirement of country about energy-conserving product.
Due to adding of fiber stabilized zone, the telescopic resilience of material is reduced further, reaches within 0.2%, in work progress, not easily produce construction joint, Material shrinkage will be caused to form gap because of the change of ambient temperature in follow-up use procedure, reach the Expected Results of house ornamentation, finishing work.
The content's index of content of beary metal, pernicious gas and volatile matter is controlled well when purchasing and producing raw material; Considered to add environment-friendlyflame-retardant flame-retardant material in factory formula, thus produce product could environmental protection and fire-retardant.
Control the internal stress parameter of product when producing well, thus produce product and just can prevent the phenomenons such as material generation warpage, foaming, delamination.
A production method for described stable type indoor wall ornament materials, comprises the following steps:
1) by a kind of automatic recipe maker, respectively according to surface wear-resistant layer, micropore alveolar layer, foaming layer and cloth the formula of glass layer carry out the preparation of thickener; The PVC paste material of surface wear-resistant layer, micropore alveolar layer is required proportionally to carry out adding of color according to the color of client;
2) adopt blade coating production technology, scrape coating line, by the thickener blade coating of surface wear-resistant layer in release liners; Release liners carries out the oven dry of surface wear-resistant layer by delivering into baking oven;
3) painting carrying out micropore alveolar layer at the next board of coating line is scraped, by cloth glass layer naturally put down be covered in micropore alveolar layer thickener on; Stick cloth material after glass layer again dry along with release liners enters baking oven;
4) on the next board of coating line, the thickener of foaming layer is coated on cloth on glass layer, then carry out drying and the foaming of material along with release liners sends into baking oven;
5) product is peeled off from release liners, send into print surface coatings operation;
6) printing process carries out the printing of decorative pattern coatings to product wearing layer surface, is made into pattern needed for client, finally sends into packaging and the inspection process of product, select qualified products.
Compared with prior art, the invention has the beneficial effects as follows:
1. the present invention by cloth glass layer compound join in PVC house decorative material, make the stability of material better, not easily produce contraction, solve the problem that pure PVC decorative material easily gaps because of exterior temperature change, after construction, metope is integral, the linking seam not having wall paper-like materials there will be; Construction stability is better, heat stability and intensity high;
2., by the rational formula design to PVC wearing layer and foaming layer, product thickness specification is thicker than the wallpaper of common tape base cloth far away, and product thickness can reach 1.5 ~ 2.0mm, effectively can realize that product is fire-retardant, moistureproof, mildew-resistant, every thermal property;
3. by screening the feature of environmental protection of formula materials, the requirement of country for house decorative material limits of harmful substances can be adapted to completely, long service life, the pattern of product surface is rich and varied, indoor wall ornament materials for middle and high end is one and effectively supplements, and its excellence functional is also the building material classification of encourage growth in country 12 planning.
Accompanying drawing explanation
Fig. 1 is stable type indoor wall ornament materials cross-sectional view of the present invention;
Fig. 2 is the production procedure sketch of material of the present invention;
Wherein, mark in figure: 1 is top finishing layer, and 2 is surface wear-resistant layer, and 3 is micropore alveolar layer, and 4 is Xian Weibu glass layer, 5 is foaming layer.
Detailed description of the invention
Below in conjunction with detailed description of the invention, foregoing invention content of the present invention is described in further detail.
But this should be interpreted as that the scope of the above-mentioned theme of the present invention is only limitted to following embodiment.Without departing from the idea case in the present invention described above, according to ordinary skill knowledge and customary means, make various replacement and change, all should comprise within the scope of the invention.
embodiment 1
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 42%PVC, 20% environment-friendly plasticizer, 4% stabilizer, 34% other auxiliary agent.
The material composition of micropore alveolar layer is 50%PVC, 30% environment-friendly plasticizer, 3% stabilizer, 17% other auxiliary agent.
Cloth the material composition of glass layer be nylon fiber.
The material composition of foaming layer is 40%PVC rubber plastic foam material, 50% environment-friendly plasticizer, 3% stabilizer, 7% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 65 parts;
AC blowing agent 5 parts;
Antimony oxide flame retardant 7 parts;
Stabilizer 4 parts;
Filler 20 parts;
Environment-friendly plasticizer 60 parts;
Described PVC powder, be suspension method produce Corvic; Described plasticizing agent is cyclohexane 1,2-bis-base diisononyl esters; Described filler is calcium carbonate.
embodiment 2
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 25%PVC, 50% environment-friendly plasticizer, 3% stabilizer, 22% other auxiliary agent.
The material composition of micropore alveolar layer is 30%PVC, 40% environment-friendly plasticizer, 0.5% stabilizer, 29.5% other auxiliary agent.
Cloth the material composition of glass layer be glass fiber.
The material composition of foaming layer is 70%PVC rubber plastic foam material, 20% environment-friendly plasticizer, 1% stabilizer, 9% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 90 parts;
AC blowing agent 6 parts;
Antimony oxide flame retardant 5 parts;
Stabilizer 3 parts;
Environment-friendly plasticizer 100 parts;
Described PVC powder, be emulsion method produce Corvic; Described plasticizing agent is citrate plasticizer.
embodiment 3
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 40%PVC, 29% environment-friendly plasticizer, 2% stabilizer, 29% other auxiliary agent.
The material composition of micropore alveolar layer is 60%PVC, 20% environment-friendly plasticizer, 2% stabilizer, 18% other auxiliary agent.
Cloth the material composition of glass layer be numb material fibers.
The material composition of foaming layer is 22%PVC rubber plastic foam material, 60% environment-friendly plasticizer, 0.5% stabilizer, 17.5% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 60 parts;
AC blowing agent 7 parts;
Antimony oxide flame retardant 2 parts;
Stabilizer 6 parts;
Filler 70 parts;
Environment-friendly plasticizer 70 parts;
Described PVC powder, be suspension method produce Corvic; Described plasticizing agent is TOTM plasticizing agent; Described filler is magnesium aluminum compounds.
embodiment 4
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 55%PVC, 35.5% environment-friendly plasticizer, 0.5% stabilizer, 9% other auxiliary agent.
The material composition of micropore alveolar layer is 35%PVC, 24% environment-friendly plasticizer, 1% stabilizer, 40% other auxiliary agent.
Cloth the material composition of glass layer be polyster fibre.
The material composition of foaming layer is 28%PVC rubber plastic foam material, 35% environment-friendly plasticizer, 2% stabilizer, 35% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 80 parts;
AC blowing agent 8 parts;
Antimony oxide flame retardant 6 parts;
Stabilizer 2 parts;
Filler 100 parts;
Environment-friendly plasticizer 40 parts;
Described PVC powder, be emulsion method produce Corvic; Described plasticizing agent is dioctyl adipate; Described filler is kaolin.
embodiment 5
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 35%PVC, 20% environment-friendly plasticizer, 5% stabilizer, 40% other auxiliary agent.
The material composition of micropore alveolar layer is 40%PVC, 50% environment-friendly plasticizer, 5% stabilizer, 5% other auxiliary agent.
Cloth the material composition of glass layer be cotton fiber.
The material composition of foaming layer is 60%PVC rubber plastic foam material, 15% environment-friendly plasticizer, 5% stabilizer, 20% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 100 parts;
AC blowing agent 3 parts;
Antimony oxide flame retardant 4 parts;
Stabilizer 2 parts;
Filler 40 parts;
Environment-friendly plasticizer 100 parts;
Described PVC powder, be emulsion method produce Corvic; Described plasticizing agent is DOTP; Described filler is French chalk.
embodiment 6
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 50%PVC, 41% environment-friendly plasticizer, 4% stabilizer, 5% other auxiliary agent.
The material composition of micropore alveolar layer is 20%PVC, 45% environment-friendly plasticizer, 1% stabilizer, 34% other auxiliary agent.
Cloth the material composition of glass layer be nylon fiber.
The material composition of foaming layer is 20%PVC rubber plastic foam material, 38% environment-friendly plasticizer, 2% stabilizer, 40% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 70 parts;
AC blowing agent 6 parts;
Antimony oxide flame retardant 1 part;
Stabilizer 5 parts;
Filler 120 parts;
Environment-friendly plasticizer 80 parts;
Described PVC powder, be suspension method produce Corvic; Described plasticizing agent is epoxidized soybean oil; Described filler is calcium carbonate.
embodiment 7
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 32%PVC, 60% environment-friendly plasticizer, 1% stabilizer, 7% other auxiliary agent.
The material composition of micropore alveolar layer is 55%PVC, 35% environment-friendly plasticizer, 2% stabilizer, 8% other auxiliary agent.
Cloth the material composition of glass layer be polyster fibre.
The material composition of foaming layer is 50%PVC rubber plastic foam material, 44% environment-friendly plasticizer, 4% stabilizer, 2% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 80 parts;
AC blowing agent 2 parts;
Antimony oxide flame retardant 2 parts;
Stabilizer 1 part;
Filler 80 parts;
Environment-friendly plasticizer 50 parts;
Described PVC powder, be emulsion method produce Corvic; Described plasticizing agent is the different monooctyl ester of trimellitic acid three; Described filler is wooden molding powder.
embodiment 8
Described in the present embodiment, stable type indoor wall ornament materials tool is of five storeys, and layers of material is:
Outermost layer is the top finishing layer through the process of Bio-pruf coating.
The material composition of surface wear-resistant layer is 55%PVC, 21% environment-friendly plasticizer, 0.5% stabilizer, 23.5% other auxiliary agent.
The material composition of micropore alveolar layer is 47%PVC, 29% environment-friendly plasticizer, 4% stabilizer, 20% other auxiliary agent.
Cloth the material composition of glass layer be flaxen fiber.
The material composition of foaming layer is 65%PVC rubber plastic foam material, 25% environment-friendly plasticizer, 5% stabilizer, 5% other auxiliary agent.
Described PVC rubber plastic foam material composition is:
PVC powder 75 parts;
AC blowing agent 7 parts;
Antimony oxide flame retardant 3 parts;
Stabilizer 5 parts;
Filler 60 parts;
Environment-friendly plasticizer 90 parts;
Described PVC powder, be emulsion method produce Corvic; Described plasticizing agent is ATBC-tributyl 2-acetylcitrate; Described filler is kaolin.
embodiment 9
The formula of each embodiment above, produce according to following steps:
1) by a kind of automatic recipe maker, respectively according to surface wear-resistant layer, micropore alveolar layer, foaming layer and cloth the formula of glass layer carry out the preparation of thickener; The PVC paste material of surface wear-resistant layer, micropore alveolar layer is required proportionally to carry out adding of color according to the color of client;
2) adopt blade coating production technology, scrape coating line, by the thickener blade coating of surface wear-resistant layer in release liners; Release liners carries out the oven dry of surface wear-resistant layer by delivering into baking oven;
3) painting carrying out micropore alveolar layer at the next board of coating line is scraped, by cloth glass layer naturally put down be covered in micropore alveolar layer thickener on; Stick cloth material after glass layer again dry along with release liners enters baking oven;
4) on the next board of coating line, the thickener of foaming layer is coated on cloth on glass layer, then carry out drying and the foaming of material along with release liners sends into baking oven;
5) product is peeled off from release liners, send into print surface coatings operation;
6) printing process carries out the printing of decorative pattern coatings to product wearing layer surface, is made into pattern needed for client, finally sends into packaging and the inspection process of product, select qualified products.
In sum, stability of material of the present invention is good, not easily produces contraction, and temperature influence is little, and after construction, metope is integral, and construction stability is better, heat stability and intensity high; This material is thicker than the wallpaper of common tape base cloth, effectively can realize that product is fire-retardant, moistureproof, mildew-resistant, every thermal property; Formula is all environment-friendly materials, and can adapt to the requirement of country for house decorative material limits of harmful substances completely, long service life, the pattern of product surface is rich and varied.
Claims (8)
1. the production method of a stable type indoor wall ornament materials, it is characterized in that: described stable type indoor wall ornament materials have cloth glass layer, cloth the both sides up and down of glass layer, upper layer of PVC and lower layer of PVC, wherein, described upper layer of PVC is surface wear-resistant layer and micropore alveolar layer, micropore alveolar layer surface wear-resistant layer and cloth between glass layer; Described lower layer of PVC is foaming layer, and described production method comprises the following steps:
1) by a kind of automatic recipe maker, the preparation of thickener is carried out respectively according to the formula of surface wear-resistant layer, micropore alveolar layer, foaming layer; The PVC paste material of surface wear-resistant layer, micropore alveolar layer is required proportionally to carry out adding of color according to the color of client;
2) adopt blade coating production technology, scrape coating line, by the thickener blade coating of surface wear-resistant layer in release liners; Release liners carries out the oven dry of surface wear-resistant layer by delivering into baking oven;
3) painting carrying out micropore alveolar layer at the next board of coating line is scraped, by cloth glass layer naturally put down be covered in micropore alveolar layer thickener on; Stick cloth material after glass layer again dry along with release liners enters baking oven;
4) on the next board of coating line, the thickener of foaming layer is coated on cloth on glass layer, then carry out drying and the foaming of material along with release liners sends into baking oven;
5) product is peeled off from release liners, send into print surface coatings operation;
6) printing process carries out the printing of decorative pattern coatings to product wearing layer surface, is made into pattern needed for client, finally sends into packaging and the inspection process of product, select qualified products.
2. the production method of stable type indoor wall ornament materials according to claim 1, is characterized in that: described cloth glass layer be terylene, nylon, cotton and numb material cloth glass fiber.
3. the production method of stable type indoor wall ornament materials according to claim 1, is characterized in that: the material composition of described surface wear-resistant layer is 25%-55%PVC, 20%-60% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 5%-40%.
4. the production method of stable type indoor wall ornament materials according to claim 1, is characterized in that: the material composition of described micropore alveolar layer is 20%-60%PVC, 20%-50% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 5%-40%.
5. the production method of stable type indoor wall ornament materials according to claim 1, is characterized in that: the material composition of described foaming layer is 20%-70%PVC rubber plastic foam material, 15%-60% environment-friendly plasticizer, 0.5%-5% stabilizer, other auxiliary agent of 2%-40%.
6. the production method of stable type indoor wall ornament materials according to claim 5, is characterized in that: described PVC rubber plastic foam material composition is:
PVC powder 60 ~ 100 parts;
AC blowing agent 2 ~ 8 parts;
Antimony oxide flame retardant 1 ~ 7 part;
Stabilizer 1 ~ 6 part;
Filler 0 ~ 120 part;
Environment-friendly plasticizer 40 ~ 100;
Described PVC powder is the Corvic that suspension method or emulsion method are produced; Described filler is inorganic mineral material.
7. the production method of the stable type indoor wall ornament materials according to any one of claim 3-6, is characterized in that: other auxiliary agent described is environment-friendly foaming agent, surfactant, fire retardant or filler; Described environment-friendly plasticizer is non-neighboring benzene class plasticizing agent.
8. the production method of stable type indoor wall ornament materials according to claim 1, it is characterized in that: described upper layer of PVC also has top finishing layer, surface wear-resistant layer is between described top finishing layer and micropore alveolar layer, and described top finishing layer is through the process of Bio-pruf coating.
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| US10202520B2 (en) | 2013-07-17 | 2019-02-12 | Ningbo Callde Biomimetics Materials Co., Ltd. | Multi-function soft wall and manufacturing method thereof |
| CN103951912B (en) * | 2014-04-28 | 2017-01-25 | 广东冠盛塑胶有限公司 | Low-phenol environment-friendly floor tile and manufacturing method thereof |
| CN113119488A (en) * | 2020-01-15 | 2021-07-16 | 吴伟银 | Novel reflective road cone cover cloth base processing technology |
| CN115787955A (en) * | 2020-12-31 | 2023-03-14 | 泰州市华丽新材料有限公司 | High-strength fireproof plate, wear-resistant fireproof veneer taking high-strength fireproof plate as base material and manufacturing method |
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| KR20100043522A (en) * | 2008-10-20 | 2010-04-29 | 왕증권 | Panel for constructional finishing and method of preparing these |
| CN101672089A (en) * | 2009-09-28 | 2010-03-17 | 德阳金路高新材料有限公司 | Flavourless interior wall fancy leather |
| CN101701487A (en) * | 2009-09-28 | 2010-05-05 | 德阳金路高新材料有限公司 | Non-toxic inner wall decorative material |
| CN202164768U (en) * | 2011-05-04 | 2012-03-14 | 德阳金路高新材料有限公司 | Lining-free decoration wall material |
| CN202106633U (en) * | 2011-06-03 | 2012-01-11 | 德阳金路高新材料有限公司 | Engineered floor leather for automobile |
| CN102261003A (en) * | 2011-06-20 | 2011-11-30 | 昆山维信纺织工业有限公司 | Floor or wall surface covering object |
| CN102505820A (en) * | 2011-09-30 | 2012-06-20 | 德阳金路高新材料有限公司 | Flexible thermal-insulating decorative material for internal wall and method for producing flexible thermal-insulating decorative material |
| CN203499173U (en) * | 2013-09-16 | 2014-03-26 | 四川金路高新材料有限公司 | Stable interior wall decorative material |
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