CN101701487A - Non-toxic inner wall decorative material - Google Patents
Non-toxic inner wall decorative material Download PDFInfo
- Publication number
- CN101701487A CN101701487A CN200910167802A CN200910167802A CN101701487A CN 101701487 A CN101701487 A CN 101701487A CN 200910167802 A CN200910167802 A CN 200910167802A CN 200910167802 A CN200910167802 A CN 200910167802A CN 101701487 A CN101701487 A CN 101701487A
- Authority
- CN
- China
- Prior art keywords
- agent
- decorative material
- plasticizer
- toxic
- wall decorative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention discloses a non-toxic inner wall decorative material, which comprises a base layer and a decorative layer coated on the base layer. The decorative layer comprises the following components in parts by weight: 0-100 parts of emulsion polyvinyl chloride (K=52-67), 100-0 part of emulsion polyvinyl chloride (K=70-80), 30-120 parts of plasticizer, 1-10 parts of stabilizer, 50-300 parts of smoke suppressor and 0.1-5 parts of antifungal and antibacterial agents. The invention is characterized in that the plasticizer comprises a main plasticizer and an auxiliary plasticizer, the main plasticizer is non-phthalate plasticizer, and concretely is any one of phosphate, phosphite ester, esters of fatty acids, polyester, epoxy-ester and chlorinated compounds; and the auxiliary plasticizer is chlorinated paraffin. As the formulation has no toxic component, no toxic reaction is generated when the wall material is contacted with people; flue gas is non-toxic when a fire happens, thus avoiding poisoning of the fire-afflicted people; the wall material is neither combustible nor combustion-supporting, the generated flue gas is less, thus greatly reducing the probability of coma and asphyxia of the fire-afflicted people.
Description
Technical field
The present invention relates to decorative material for internal wall, be specifically related to a kind of non-toxic inner wall decorative material.
Background technology
The modern architecture house decorative material mostly is organic material, and many materials contain Toxic matter, and when contacting with human body, the toxigenicity reaction is detrimental to health.Existing inner wall decoration leather, plasticizing agent in its prescription is adjacent benzene class plasticizing agent, be a kind of noxious material, along with the enhancing of people's environment protection health consciousness, some countries begun strictness forbid house decorative material especially with material that human body contact in the adjacent benzene class plasticizing agent of use.
In addition, statistics shows that when building burst fire incident, the poison gas that ornament materials produces is causing death's main cause often.China has proposed new requirement to the decorative material for internal wall that is used for the public place, and the flue gas toxity that burning produces to ornament materials has strict restriction.Existing polyvinyl chloride decorative material for internal wall owing to contain poisonous component in the prescription, although added fire retardant, can make decorative material for internal wall do not burn, not combustion-supporting, but do not solve the flue gas toxity problem.
Summary of the invention
Purpose of the present invention provides a kind of non-toxic inner wall decorative material.When this was decorated leather and contact with human body, toxigenicity reacted, do not fire, not combustion-supporting, the flue gas that produces during the chance fire seldom, and flue gas is nontoxic.
Technical solution of the present invention is:
A kind of non-toxic inner wall decorative material has basic unit and the decorations layer that is coated in the basic unit, and described decorations layer contains the component of following weight portion:
Emulsion pvc (K=52-67) 0～100;
Emulsion pvc (K=70-80) 100～0;
Plasticizing agent 30～120;
Stabilizing agent 1～10;
Antismoke agent 50～300;
Antimildew and antibacterial agent 0.1～5.
Described plasticizing agent comprises primary plasticizer and extender plasticizer.Wherein: the adjacent benzene class of primary plasticizer right and wrong plasticizing agent is specially in phosphoric acid ester, phosphorous acid esters, fatty acid ester, polyesters, epoxy ester series, the chlorine-containing compound any one; Extender plasticizer is a chlorinated paraffin wax.
Described stabilizing agent is Ca-Zn compound stabilizer or Ba-Zn compound stabilizer.
Described antismoke agent is to contain the aluminium of the crystallization water or the oxide of magnesium.
Described antimildew and antibacterial agent is the ZnOw chelate.
Described basic unit be in plant fiber cloth, paper, the PVC foam films any one.
Described PVC foam films contains the component of following weight portion:
Emulsion pvc (K=52-67) 200;
Non-adjacent benzene class primary plasticizer 1～150;
Chlorinated paraffin wax extender plasticizer 1～30;
Ca-Zn compound stabilizer 0.1～5;
Physical blowing agent 0.1～10;
Antimonial fire retardant 0.1～8;
ZnOw chelate antimildew and antibacterial agent 0.1～10.
A kind of improvement project of the present invention is:
Described decorations layer also contains the component of following weight portion
Blowing agent 0～20;
Filler 0～200;
Fire retardant 0～20.
Described blowing agent is a physical blowing agent; This physical blowing agent is the material that will be in a liquid state under the normal temperature, with PP or PE material parcel, is made into the microballoon that contains drop, when being heated, and the liquid gasification, microballoon expands, thereby becomes the physical blowing agent of closed pore.
Described filler is the mineral dust that does not contain heavy metal, is specially in kaolin, the calcium carbonate any one.
Described fire retardant is a sb oxide.
Technique effect of the present invention:
Because the used plasticizing agent of this wall leather adopts non-adjacent benzene class plasticizing agent, no poisonous component, wall leather do not contact with the people and can react by toxigenicity, and when meeting fire, flue gas is nontoxic, can avoid disaster-stricken crowd to poison.
Because this wall leather contains fire retardant and antismoke agent, the wall leather self does not fire, and is not combustion-supporting yet, and the flue gas of generation seldom can reduce the probability that disaster-stricken crowd goes into a coma, suffocates greatly.
Because this wall leather contains antimildew and antibacterial agent, the wall leather can moldy metamorphism, long service life.
In general, the wall leather that adopts prescription of the present invention and technology to make, every technical indicator all meets the latest national standards requirement, sees following table for details.
Description of drawings
Fig. 1 is a process chart of producing this non-toxic inner wall decorative material
The specific embodiment
This non-toxic inner wall decorative material has basic unit and the decorations layer that is coated in the basic unit.
Described decorations layer contains component (by weight): emulsion pvc (K=52-67) 0～100; Emulsion pvc (K=70-80) 100～0; Plasticizing agent 30～120; Stabilizing agent 1～10; Antismoke agent 50～300; Antimildew and antibacterial agent 0.1～5.
Described plasticizing agent comprises primary plasticizer and extender plasticizer, and wherein: the adjacent benzene class of primary plasticizer right and wrong plasticizing agent is specially in phosphoric acid ester, phosphorous acid esters, fatty acid ester, polyesters, epoxy ester series, the chlorine-containing compound any one; Extender plasticizer is a chlorinated paraffin wax.Described stabilizing agent is Ca-Zn compound stabilizer or Ba-Zn compound stabilizer.Described antismoke agent is to contain the aluminium of the crystallization water or the oxide of magnesium.Described antimildew and antibacterial agent is the ZnOw chelate.
Described basic unit be in plant fiber cloth, paper, the PVC foam films any one.
Described PVC foam films contains component (by weight): emulsion pvc (K=52-67) 200; Non-adjacent benzene class primary plasticizer 1～150; Chlorinated paraffin wax extender plasticizer 1～30; Ca-Zn compound stabilizer 0.1～5; Physical blowing agent 0.1～10; Antimonial fire retardant 0.1～8; ZnOw chelate antimildew and antibacterial agent 0.1～10.Described non-adjacent benzene class primary plasticizer is specially in phosphoric acid ester, phosphorous acid esters, fatty acid ester, polyesters, epoxy ester series, the chlorine-containing compound any one.
Decorations layer of the present invention also contains component (by weight): blowing agent 0～20; Filler 0～200; Fire retardant 0～20.
Described blowing agent is a physical blowing agent; This physical blowing agent is the material that will be in a liquid state under the normal temperature, with PP or PE material parcel, is made into the microballoon that contains drop, when being heated, and the liquid gasification, microballoon expands, thereby becomes the physical blowing agent of closed pore.Described filler be in kaolin, the calcium carbonate any one.Described fire retardant is a sb oxide.
Describe the processing step of this non-toxic inner wall decorative material below in detail with a specific embodiment, referring to Fig. 1.
In this example, basic unit selects the PVC foam films for use, therefore, need prepare basic unit's material and decorations layered material simultaneously.Division is as follows:
The PVC of basic unit foam films batching is got by proportioning (weight portion)
Emulsion pvc (K=52-67) 200;
Phosphate primary plasticizer 150;
Chlorinated paraffin wax extender plasticizer 20;
Ca-Zn compound stabilizer 3;
Physical blowing agent 5;
Antimonial fire retardant 4;
ZnOw chelate antimildew and antibacterial agent 5;
Colorant is an amount of.
Liquid charging stock is mixed, add solid material again, continued stirring until few 30 minutes, make the temperature of compound be not less than 50 ℃, add the colorant toning; Again compound is filtered, cross 100 mesh sieves, standby.
Decorations layer batching got by proportioning (weight portion)
Emulsion pvc (K=52-67) 60;
Emulsion pvc (K=70-80) 40;
Phosphate primary plasticizer 90;
Chlorinated paraffin wax extender plasticizer 30;
Ca-Zn compound stabilizer 8;
The magnesia antismoke agent 200 that contains the crystallization water;
ZnOw chelate antimildew and antibacterial agent 3;
Physical blowing agent 10;
Paris white filler 150;
Antimonial fire retardant 5.
Liquid charging stock is mixed, add solid material again, continued stirring until few 30 minutes, make the temperature of compound be not less than 50 ℃, compound is filtered, cross 100 mesh sieves, standby.
To adorn layer compound and evenly be coated on the release liners carrier coating layer thickness 0.18～0.23mm with glue spreader; Oven dry and foaming under 160～180 ℃ of temperature, cooling;
Base mixture is uniformly coated on the decorations layer glue face that has cooled off coating layer thickness 0.38～0.42mm with glue spreader; Dry under 220～230 ℃ of temperature and foaming, after the cooling, basic unit is compound with the decorations layer, and it is stripped down from the release liners carrier, gets wall leather semiproduct.
Processing graphic pattern on the half-finished decorations layer of wall leather promptly gets wall leather finished product.
The design of wall leather has two kinds, and a kind of is that the colorful one shows floral pattern, and another kind is the latent floral pattern of achromatization, shows floral pattern printing machine stamp, 100～140 ℃ of stamp temperature; Latent floral pattern embossing machine embossing, 80～150 ℃ of embossing temperature; Pressure 5～25N/cm
2
If basic unit adopts paper or cloth, then directly will adorn a layer compound and be coated on the surface of paper or cloth, promptly get wall after drying, foaming, the cooling and remove from office semiproduct, stamp, embossed technology are same as described above.
Claims (10)
1. a non-toxic inner wall decorative material has basic unit and the decorations layer that is coated in the basic unit, and described decorations layer contains the component of following weight portion:
Emulsion pvc (K=52-67) 0～100;
Emulsion pvc (K=70-80) 100～0;
Plasticizing agent 30～120;
Stabilizing agent 1～10;
Antismoke agent 50～300;
Antimildew and antibacterial agent 0.1～5;
It is characterized in that: described plasticizing agent comprises primary plasticizer and extender plasticizer, and wherein, the adjacent benzene class of primary plasticizer right and wrong plasticizing agent is specially in phosphoric acid ester, phosphorous acid esters, fatty acid ester, polyesters, epoxy ester series, the chlorine-containing compound any one; Extender plasticizer is a chlorinated paraffin wax.
2. non-toxic inner wall decorative material according to claim 1 is characterized in that: described stabilizing agent is Ca-Zn compound stabilizer or Ba-Zn compound stabilizer.
3. non-toxic inner wall decorative material according to claim 1 is characterized in that: described antismoke agent is to contain the aluminium of the crystallization water or the oxide of magnesium.
4. non-toxic inner wall decorative material according to claim 1 is characterized in that: described antimildew and antibacterial agent is the ZnOw chelate.
5. non-toxic inner wall decorative material according to claim 1 is characterized in that: described decorations layer also contains the component of following weight portion
Blowing agent 0～20;
Filler 0～200;
Fire retardant 0～20.
6. non-toxic inner wall decorative material according to claim 5 is characterized in that: described blowing agent is a physical blowing agent; This physical blowing agent is the material that will be in a liquid state under the normal temperature, with PP or PE material parcel, is made into the microballoon that contains drop, when being heated, and the liquid gasification, microballoon expands, and becomes the physical blowing agent of closed pore.
7. non-toxic inner wall decorative material according to claim 5 is characterized in that: described filler is the mineral dust that does not contain heavy metal, is specially in kaolin, the calcium carbonate any one.
8. non-toxic inner wall decorative material according to claim 5 is characterized in that: described fire retardant is a sb oxide.
9. non-toxic inner wall decorative material according to claim 1 is characterized in that: described basic unit be in plant fiber cloth, paper, the PVC foam films any one.
10. non-toxic inner wall decorative material according to claim 9 is characterized in that:
Described PVC foam films contains the component of following weight portion
Emulsion pvc (K=52-67) 200;
Non-adjacent benzene class primary plasticizer 1～150;
Chlorinated paraffin wax extender plasticizer 1～30;
Ca-Zn compound stabilizer 0.1～5;
Physical blowing agent 0.1～10;
Antimonial fire retardant 0.1～8;
ZnOw chelate antimildew and antibacterial agent 0.1～10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910167802A CN101701487A (en) | 2009-09-28 | 2009-09-28 | Non-toxic inner wall decorative material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910167802A CN101701487A (en) | 2009-09-28 | 2009-09-28 | Non-toxic inner wall decorative material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101701487A true CN101701487A (en) | 2010-05-05 |
Family
ID=42156411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910167802A Pending CN101701487A (en) | 2009-09-28 | 2009-09-28 | Non-toxic inner wall decorative material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101701487A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN103485503A (en) * | 2013-09-16 | 2014-01-01 | 四川金路高新材料有限公司 | Stable interior wall decorative material and method for manufacturing same |
| CN106398032A (en) * | 2016-08-30 | 2017-02-15 | 安徽宏飞户外用品科技有限公司 | Fireproof PVC leather for outdoor tent and preparing method thereof |
| CN106543584A (en) * | 2016-10-31 | 2017-03-29 | 江苏昊晟塑业科技有限公司 | Automotive trim panel is heat-resisting to use expanded material |
-
2009
- 2009-09-28 CN CN200910167802A patent/CN101701487A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102850691A (en) * | 2012-08-08 | 2013-01-02 | 佛山市天安塑料有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN102850691B (en) * | 2012-08-08 | 2014-05-07 | 广东天安新材料股份有限公司 | Low-haze high-simulation automobile interior decoration material and manufacturing method thereof |
| CN103485503A (en) * | 2013-09-16 | 2014-01-01 | 四川金路高新材料有限公司 | Stable interior wall decorative material and method for manufacturing same |
| CN103485503B (en) * | 2013-09-16 | 2015-11-18 | 四川金路高新材料有限公司 | A kind of stable type indoor wall ornament materials and production method thereof |
| CN106398032A (en) * | 2016-08-30 | 2017-02-15 | 安徽宏飞户外用品科技有限公司 | Fireproof PVC leather for outdoor tent and preparing method thereof |
| CN106543584A (en) * | 2016-10-31 | 2017-03-29 | 江苏昊晟塑业科技有限公司 | Automotive trim panel is heat-resisting to use expanded material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101701487A (en) | Non-toxic inner wall decorative material | |
| KR101468382B1 (en) | A non-flammable coating composition and non-flammable building interior and exterior materials containing the same | |
| TWI338020B (en) | ||
| KR101265500B1 (en) | Flame retardant laminate sheet of producing methods therefor and processing device | |
| KR101039637B1 (en) | Water soluble coating materials for paper coating and manufacturing method thereof | |
| US20180195234A1 (en) | Environmentally friendly wallpaper with weathering resistance and contaminating resistance and preparing method | |
| CN104060498B (en) | A kind of environmental-protection flame-retardant wallpaper | |
| CN107151500A (en) | Anti-flaming dope and its application | |
| CN103012991A (en) | Preparation method of PVC (Poly Vinyl Chloride) buckling plate | |
| CN104450990B (en) | The preparation method of flame-retardant leather | |
| CN204914775U (en) | Wall paper with fire behaviour | |
| US20160032191A1 (en) | Flame retardants | |
| CN102359239B (en) | Environment-friendly and flame-retardant decorative plate and production method thereof | |
| CN103694922B (en) | Halogen-free flame-retardant hot melt adhesive membrane applied to electronics industry and preparation method of membrane | |
| CN101089061A (en) | Green inner wall paint and its prepn | |
| KR100886068B1 (en) | Composition for rotary screen printing, interior wallpaper comprising the same and preparation method thereof | |
| CN106568350B (en) | The fireworks cylinder of flame-proof damp-proof | |
| KR100836590B1 (en) | Latex coating having natural rubber and watersoluble wall paper using the same and manufacturing method thereof | |
| CN105755905A (en) | Wallpaper and processing method thereof | |
| WO2007095344A2 (en) | Fire retardant silicone textile coating | |
| CN106700496B (en) | A kind of flame-retardant sponge and preparation method thereof of fire prevention shoes | |
| CN107922038A (en) | The fire-retardant ceramic tile for ship comprising biodegradable polymer | |
| CN109082143A (en) | A kind of finished product shape ordor removing environmental-protection fireproof type diatom ooze and preparation method thereof | |
| CN1702115A (en) | Non-backing flameproof materials and fireproof composite lining and method for making same | |
| CN205189328U (en) | Environment -friendly night light wall paper with indoor air purification function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20100505 |