CN103469219B - A kind of wiredrawing wire rod pickling additive - Google Patents
A kind of wiredrawing wire rod pickling additive Download PDFInfo
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- CN103469219B CN103469219B CN201310372390.0A CN201310372390A CN103469219B CN 103469219 B CN103469219 B CN 103469219B CN 201310372390 A CN201310372390 A CN 201310372390A CN 103469219 B CN103469219 B CN 103469219B
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- dodecylbenzene sulfonate
- sodium dodecylbenzene
- nitride powder
- aluminium nitride
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Abstract
A kind of wiredrawing wire rod pickling additive, be made up of the raw material of following weight part: urotropine 2-3, OP-10? 1-2, dodecenylsuccinic acid 2-3,1.3-dibutyl thiourea 1-2, primary zinc phosphate 1-2,2,6-BIT 0.6-0.8, Sodium dodecylbenzene sulfonate 1-2, tertbutyl peroxide 1-2, modification aluminium nitride powder 1.5-2.3, water 1000.
Description
Technical field
The present invention relates to wire-drawing technology field, is a kind of wiredrawing wire rod pickling additive and preparation method thereof.
Background technology
In existing drawing process, the lubricating oil that adopts as wire drawing medium more, and the conductive line surfaces that drawing goes out is mellow and full, fine and smooth, smooth, bright, no-sundries is detained, and wire broken rate reduces, and quality product improves greatly.But lubricating oil heat radiation is slow, damage mould, affect quality product, while high temperature easily to ignite oil product or oil evaporation is smoldered cause site environment to worsen.
Summary of the invention
The object of this invention is to provide a kind of wiredrawing wire rod pickling additive.
Technical scheme of the present invention is as follows:
A kind of wiredrawing wire rod pickling additive, it is characterized in that being made up of the raw material of following weight part: urotropine 2-3, OP-101-2, dodecenylsuccinic acid 2-3,1.3-dibutyl thiourea 1-2, primary zinc phosphate 1-2,2,6-BIT 0.6-0.8, Sodium dodecylbenzene sulfonate 1-2, tertbutyl peroxide 1-2, modification aluminium nitride powder 1.5-2.3, water 1000;
Modification aluminium nitride powder is made up of the raw material of following weight part:
Tea-polyphenol 0.4-0.6, ammonium persulphate 1.4-1.6, ammonium molybdate 2.3-2.5, morpholine 1.5-1.8, polyvinyl alcohol 2.3-2.5, Sodium dodecylbenzene sulfonate 0.5-0.8, Flos Rosae Rugosae quintessence oil 0.8-0.9, nano aluminum nitride 4.5-5.0, nano silicon 1.2-1.4, methylolurea 1.0-1.2, boric acid 1-1.3, silane coupling agent KH6021.5-2, water 65-70;
The preparation method of described modification aluminium nitride powder is as follows: polyvinyl alcohol, ammonium molybdate, methylolurea are dissolved in the water, are heated to 40-55 DEG C, then add ammonium persulphate, stirring reaction 15-20 minute, then, then add Sodium dodecylbenzene sulfonate, at 60-70 DEG C, 200-500 rev/min is stirred 10-15 minute, then, add other surplus stock, be warming up to 90-95 DEG C, 1200-1500 rev/min of stirring reaction 10-20 minute, dry, abrasive dust and get final product.
Described wiredrawing wire rod pickling additive, is characterized in that, preparation method comprises the following steps:
A. take urotropine, dodecenylsuccinic acid, Sodium dodecylbenzene sulfonate by weight, add suitable quantity of water mixing;
B., under normal temperature, add modification aluminium nitride powder and be stirred into solution;
C. in the solution of step B, add primary zinc phosphate, and stir, then add all the other raw materials, after mixing, to obtain final product.
Beneficial effect of the present invention is:
The present invention promotes peeling off and dissolving of different wire surface iron rust and oxide skin, improves pickling speed, reduces unnecessary acid consumption, saves production cost; The feature of environmental protection is good, nontoxic simultaneously.
Embodiment
A kind of wiredrawing wire rod pickling additive, be made up of the raw material of following weight part (kg): urotropine 3, OP-102, dodecenylsuccinic acid 2,1.3-dibutyl thiourea 2, primary zinc phosphate 2,2,6-BIT 0.8, Sodium dodecylbenzene sulfonate 2, tertbutyl peroxide 2, modification aluminium nitride powder 2.3, water 1000;
Modification aluminium nitride powder is made up of the raw material of following weight part:
Tea-polyphenol 0.4, ammonium persulphate 1.6, ammonium molybdate 2.5, morpholine 1.5, polyvinyl alcohol 2.5, Sodium dodecylbenzene sulfonate 0.5, Flos Rosae Rugosae quintessence oil 0.8, nano aluminum nitride 4.8, nano silicon 1.4, methylolurea 1.1, boric acid 1.3, silane coupling agent KH6021.8, water 65;
The preparation method of described modification aluminium nitride powder is as follows: polyvinyl alcohol, ammonium molybdate, methylolurea are dissolved in the water, and is heated to 40 DEG C, then adds ammonium persulphate, stirring reaction 20 minutes, then, then add Sodium dodecylbenzene sulfonate, at 70 DEG C, 200 revs/min are stirred 15 minutes, then, add other surplus stock, be warming up to 93 DEG C, 1200 revs/min of stirring reactions 20 minutes, dry, abrasive dust and get final product.
Described wiredrawing wire rod pickling additive, preparation method comprises the following steps:
A. take urotropine, dodecenylsuccinic acid, Sodium dodecylbenzene sulfonate by weight, add suitable quantity of water mixing;
B., under normal temperature, add modification aluminium nitride powder and be stirred into solution;
C. in the solution of step B, add primary zinc phosphate, and stir, then add all the other raw materials, after mixing, to obtain final product.
Use the present embodiment, the copper wire rust prevention during manufacture time of producing is more than 5 days; Concentrate the oil sump drain period to be 3 years, the unit oil sump drain period is 9 months, decreases liquid waste disposal and discharge, protects environment.
Claims (1)
1. a wiredrawing wire rod pickling additive, it is characterized in that being made up of the raw material of following weight part: urotropine 2-3, OP-101-2, dodecenylsuccinic acid 2-3,1,3-dibutyl thiourea 1-2, primary zinc phosphate 1-2,2,6-BIT 0.6-0.8, Sodium dodecylbenzene sulfonate 1-2, tertbutyl peroxide 1-2, modification aluminium nitride powder 1.5-2.3, water 1000;
Described modification aluminium nitride powder is made up of the raw material of following weight part: tea-polyphenol 0.4-0.6, ammonium persulphate 1.4-1.6, ammonium molybdate 2.3-2.5, morpholine 1.5-1.8, polyvinyl alcohol 2.3-2.5, Sodium dodecylbenzene sulfonate 0.5-0.8, Flos Rosae Rugosae quintessence oil 0.8-0.9, nano aluminum nitride 4.5-5.0, nano silicon 1.2-1.4, methylolurea 1.0-1.2, boric acid 1-1.3, silane coupling agent KH6021.5-2, water 65-70;
The preparation method of described modification aluminium nitride powder is as follows: polyvinyl alcohol, ammonium molybdate, methylolurea are dissolved in the water, are heated to 40-55 DEG C, then add ammonium persulphate, stirring reaction 15-20 minute, then, then add Sodium dodecylbenzene sulfonate, at 60-70 DEG C, 200-500 rev/min is stirred 10-15 minute, then, add other surplus stock, be warming up to 90-95 DEG C, 1200-1500 rev/min of stirring reaction 10-20 minute, dry, abrasive dust and get final product;
Described wiredrawing wire rod pickling additive, preparation method comprises the following steps:
A. take urotropine, dodecenylsuccinic acid, Sodium dodecylbenzene sulfonate by weight, add suitable quantity of water mixing;
B., under normal temperature, add modification aluminium nitride powder and be stirred into solution;
C. in the solution of step B, add primary zinc phosphate, and stir, then add all the other raw materials, after mixing, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372390.0A CN103469219B (en) | 2013-08-24 | 2013-08-24 | A kind of wiredrawing wire rod pickling additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310372390.0A CN103469219B (en) | 2013-08-24 | 2013-08-24 | A kind of wiredrawing wire rod pickling additive |
Publications (2)
| Publication Number | Publication Date |
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| CN103469219A CN103469219A (en) | 2013-12-25 |
| CN103469219B true CN103469219B (en) | 2016-02-24 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310372390.0A Active CN103469219B (en) | 2013-08-24 | 2013-08-24 | A kind of wiredrawing wire rod pickling additive |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974361A (en) * | 2010-08-20 | 2011-02-16 | 泰安天健应用技术推广中心 | Multifunctional nanocomposite antiwear agent |
| CN102993817A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing peregal O |
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2013
- 2013-08-24 CN CN201310372390.0A patent/CN103469219B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974361A (en) * | 2010-08-20 | 2011-02-16 | 泰安天健应用技术推广中心 | Multifunctional nanocomposite antiwear agent |
| CN102993817A (en) * | 2012-11-01 | 2013-03-27 | 安徽荣达阀门有限公司 | Metal rust inhibitor containing peregal O |
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| Publication number | Publication date |
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| CN103469219A (en) | 2013-12-25 |
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