CN102993817A - Metal rust inhibitor containing peregal O - Google Patents

Metal rust inhibitor containing peregal O Download PDF

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Publication number
CN102993817A
CN102993817A CN201210431180XA CN201210431180A CN102993817A CN 102993817 A CN102993817 A CN 102993817A CN 201210431180X A CN201210431180X A CN 201210431180XA CN 201210431180 A CN201210431180 A CN 201210431180A CN 102993817 A CN102993817 A CN 102993817A
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parts
paregal
weight
peregal
metal
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CN201210431180XA
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CN102993817B (en
Inventor
胡光荣
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Anhui Rongda Valve Co Ltd
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Anhui Rongda Valve Co Ltd
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Abstract

The invention discloses a metal rust inhibitor containing peregal O. The metal rust inhibitor is prepared from the following raw materials in parts by weight: 2-5 parts of urea, 5-8 parts of liquefied paraffin, 3-5 parts of acetyl tri(2-ethylhexyl)ester citrate, 4-6 parts of acrylic acid, 0.2-0.3 part of zinc powder, 3-5 parts of epoxidized rice bran oil, 2-3 parts of dimethylbenzene, 3-5 parts of polyethylene wax, 0.2-0.3 part of potassium persulfate, 0.3-0.5 part of borax, 1-2 parts of zinc naphthenate, 0.5-0.9 part of 2-methylimidazole, 1.3-1.5 parts of benzotriazole, 0.5-1.5 parts of methenamine, 1.1-1.7 parts of 2-n-octyl-4-isothiazolinone, 1.2-1.9 parts of peregal O and 95-105 parts of water. The metal rust inhibitor has rust inhibiting time as long as 4-6 months, has better adaptability to copper and aluminium and can form films on the metal surfaces while carrying out slow release and rust inhibition, thus lengthening the rust inhibiting time.

Description

A kind of metal antirusting agent that contains paregal O
Technical field
The present invention relates to the rust-preventive agent field, exactly is a kind of metal antirusting agent that contains paregal O.
Background technology
Water-based antirust agent is a kind of aqueous rustproof solution, can effectively protect the materials such as steel, iron, prevents from getting rusty.The difference that requires according to rust-proof life, and water the antirust time limit can reach several days to several months than mixing use by certain, if certain outer packaging condition is arranged, the antirust time can reach more than 1 year.The existing many rustless properties of rust-preventive agent are not good, are badly in need of a kind of metal antirusting agent of good antirust property.
Summary of the invention
The object of the present invention is to provide a kind of metal antirusting agent of good antirust property.
Above-mentioned purpose realizes by following scheme:
A kind of metal antirusting agent that contains paregal O is characterized in that: it is that raw material by following weight parts makes: urea 2-5, liquefied petrolatum 5-8, tri(2-ethylhexyl)acetocitrate 3-5, vinylformic acid 4-6, zinc powder 0.2-0.3, nontoxic plasticizer 3-5, dimethylbenzene 2-3, polyethylene wax 3-5, Potassium Persulphate 0.2-0.3, borax 0.3-0.5, zinc naphthenate 1-2,2-Methylimidazole quinoline 0.5-0.9, benzotriazole 1.3-1.5, urotropine 0.5-1.5, di-n-octyl-4-isothiazolinone 1.1-1.7, paregal O 1.2-1.9, water 95-105.
Described a kind of metal antirusting agent that contains paregal O, it is characterized in that: the preparation method may further comprise the steps:
(1) by weight liquefied petrolatum, tri(2-ethylhexyl)acetocitrate, vinylformic acid, nontoxic plasticizer, dimethylbenzene, polyethylene wax are added stainless steel cauldron, be warming up to 110 ± 5 ℃, begin to stir and add by weight urea, Potassium Persulphate, borax, zinc powder;
(2) then be warmed up to 180-195 ℃ with 50-60 ℃ of/hour speed;
(3) 1-2 hour stopped heating of reaction;
(4) will add by weight surplus stock and add stainless steel cauldron, after the mixing dissolving and get final product.
Beneficial effect of the present invention is: the consistency of the present invention and each material is good, and the antirust time is long, can reach 4-6 month, and copper, aluminum are had preferably adaptability, when the present invention is can slowly-releasing antirust in the metallic surface film forming, thereby prolong the antirust time.The adding of paregal O can be played the effect of removing metal surface greasy dirt, also plays simultaneously the effect that improves stability of the present invention.
Embodiment
A kind of metal antirusting agent that contains paregal O, it is that raw material by following weight parts (kg) makes: urea 3, liquefied petrolatum 6, tri(2-ethylhexyl)acetocitrate 4, vinylformic acid 5, zinc powder 0.2, nontoxic plasticizer 4, dimethylbenzene 2, polyethylene wax 4, Potassium Persulphate 0.2, borax 0.3, zinc naphthenate 1,2-Methylimidazole quinoline 0.7, benzotriazole 1.4, urotropine 1.1, di-n-octyl-4-isothiazolinone 1.4, paregal O 1.4, water 95.
Described a kind of metal antirusting agent that contains paregal O, the preparation method may further comprise the steps:
(1) by weight liquefied petrolatum, tri(2-ethylhexyl)acetocitrate, vinylformic acid, nontoxic plasticizer, dimethylbenzene, polyethylene wax are added stainless steel cauldron, be warming up to 110 ℃, begin to stir and add by weight urea, Potassium Persulphate, borax, zinc powder;
(2) then be warmed up to 185 ℃ with 60 ℃ of/hour speed;
(3) 2 hours stopped heatings of reaction;
(4) will add by weight surplus stock and add stainless steel cauldron, after the mixing dissolving and get final product.
Present embodiment and commercially available domestic rust-preventive agent are compared experiment, and wherein property indices is measured respectively as follows:
High low temperature stability test: carry out according to JB/T4323.2-1999.
Damp and hot rust prevention test: the test piece of one-level grey cast iron is soaked 1min in 50~70 ℃ rust protection liquid, take out oven dry (110 ℃), test piece is put on the dividing plate of moisture eliminator (500~1000ml distilled water is injected in the bottom), add a cover and be placed on constant temperature placement under 35 ℃ ± 2 ℃ conditions, observe the antirust time.
Corrosion test: carry out according to JB/T4323.2-1999.
Indoor hanging test: the test piece of one-level grey cast iron hangs up indoor after antirust processing, observes test piece surface corrosion situation.
Seal rust prevention test up for safekeeping: after the antirust processing of one-level grey cast iron test piece, transparent sealed plastic bag is put in test piece, the surface appearance of good seal routine observation test piece.
Measurement result sees Table one:
Table one
Figure BDA0000234669671
As shown in Table 1, the anti-embroidery time of the present invention is long, can reach 4~6 months, and copper, aluminium are had preferably adaptability.Pass through simultaneously compatibility test, the consistency of present embodiment and each material is good, can't affect the normal operation of parts.

Claims (2)

1. metal antirusting agent that contains paregal O is characterized in that: it is that raw material by following weight parts makes: urea 2-5, liquefied petrolatum 5-8, tri(2-ethylhexyl)acetocitrate 3-5, vinylformic acid 4-6, zinc powder 0.2-0.3, nontoxic plasticizer 3-5, dimethylbenzene 2-3, polyethylene wax 3-5, Potassium Persulphate 0.2-0.3, borax 0.3-0.5, zinc naphthenate 1-2,2-Methylimidazole quinoline 0.5-0.9, benzotriazole 1.3-1.5, urotropine 0.5-1.5, di-n-octyl-4-isothiazolinone 1.1-1.7, paregal O 1.2-1.9, water 95-105.
2. a kind of metal antirusting agent that contains paregal O according to claim 1, it is characterized in that: the preparation method may further comprise the steps:
(1) by weight liquefied petrolatum, tri(2-ethylhexyl)acetocitrate, vinylformic acid, nontoxic plasticizer, dimethylbenzene, polyethylene wax are added stainless steel cauldron, be warming up to 110 ± 5 ℃, begin to stir and add by weight urea, Potassium Persulphate, borax, zinc powder;
(2) then be warmed up to 180-195 ℃ with 50-60 ℃ of/hour speed;
(3) 1-2 hour stopped heating of reaction;
(4) will add by weight surplus stock and add stainless steel cauldron, after the mixing dissolving and get final product.
CN201210431180.XA 2012-11-01 2012-11-01 Metal rust inhibitor containing peregal O Expired - Fee Related CN102993817B (en)

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CN102993817B CN102993817B (en) 2014-07-02

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254796A (en) * 2013-04-17 2013-08-21 马鞍山拓锐金属表面技术有限公司 Anti-rust oil for automobile parts and preparation method thereof
CN103254981A (en) * 2013-04-17 2013-08-21 马鞍山拓锐金属表面技术有限公司 Anti-salt mist anti-rust oil and preparation method thereof
CN103469219A (en) * 2013-08-24 2013-12-25 天长市康和金属材料有限公司 Wiredrawing wire pickling additive
CN104178768A (en) * 2014-08-27 2014-12-03 江西瑞思博化工有限公司 Water-base antirust agent and preparation method thereof

Citations (4)

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US20080083435A1 (en) * 2006-10-06 2008-04-10 Myers Craig W Method of inhibiting corrosion in storage and transport vessels
CN101750914A (en) * 2008-12-05 2010-06-23 安集微电子(上海)有限公司 Photoresist detergent composition
EP2241591A1 (en) * 2009-04-07 2010-10-20 Research & Technology Petrochemical Company Hybrid organic-inorganic corrosion inhibitors for chromate-free corrosion resistant coatings
CN102676277A (en) * 2011-09-06 2012-09-19 安徽江南机械有限责任公司 Water soluble antirusting fluid, and preparation method and using method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080083435A1 (en) * 2006-10-06 2008-04-10 Myers Craig W Method of inhibiting corrosion in storage and transport vessels
CN101750914A (en) * 2008-12-05 2010-06-23 安集微电子(上海)有限公司 Photoresist detergent composition
EP2241591A1 (en) * 2009-04-07 2010-10-20 Research & Technology Petrochemical Company Hybrid organic-inorganic corrosion inhibitors for chromate-free corrosion resistant coatings
CN102676277A (en) * 2011-09-06 2012-09-19 安徽江南机械有限责任公司 Water soluble antirusting fluid, and preparation method and using method thereof

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Title
李国祥等: "金属材料除油防锈化学清洗剂的研制", 《内蒙古石油化工》, vol. 29, no. 3, 31 December 2003 (2003-12-31), pages 30 - 31 *
肖开学: "《实用金属防锈技术问答》", 31 August 1997, article "防锈材料与包装材料", pages: 13-36 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103254796A (en) * 2013-04-17 2013-08-21 马鞍山拓锐金属表面技术有限公司 Anti-rust oil for automobile parts and preparation method thereof
CN103254981A (en) * 2013-04-17 2013-08-21 马鞍山拓锐金属表面技术有限公司 Anti-salt mist anti-rust oil and preparation method thereof
CN103254796B (en) * 2013-04-17 2016-08-10 马鞍山拓锐金属表面技术有限公司 A kind of antirust oil for auto parts and components and preparation method thereof
CN103469219A (en) * 2013-08-24 2013-12-25 天长市康和金属材料有限公司 Wiredrawing wire pickling additive
CN103469219B (en) * 2013-08-24 2016-02-24 天长市康和金属材料有限公司 A kind of wiredrawing wire rod pickling additive
CN104178768A (en) * 2014-08-27 2014-12-03 江西瑞思博化工有限公司 Water-base antirust agent and preparation method thereof

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