CN103464418A - Semiconductor silicon chip degumming process - Google Patents

Semiconductor silicon chip degumming process Download PDF

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Publication number
CN103464418A
CN103464418A CN2013104319666A CN201310431966A CN103464418A CN 103464418 A CN103464418 A CN 103464418A CN 2013104319666 A CN2013104319666 A CN 2013104319666A CN 201310431966 A CN201310431966 A CN 201310431966A CN 103464418 A CN103464418 A CN 103464418A
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silicon chip
warm water
silicon chips
water
semi
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CN2013104319666A
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CN103464418B (en
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王少刚
邢玉军
范猛
王帅
张全红
李立伟
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Zhonghuan Leading Semiconductor Technology Co ltd
Tianjin Zhonghuan Advanced Material Technology Co Ltd
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Tianjin Huanou Semiconductor Material Technology Co Ltd
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Abstract

The invention provides a semiconductor silicon chip degumming process, which comprises the following steps that (1) cut monocrystalline silicon rods are reversely placed into a transfer car provided with a special clamp; (2) bubbling pre-cleaning is carried out, i.e. the monocrystalline silicon chips are placed into a groove full of tap water to be pre-cleaned by using a bubbling pipe for removing mortar on the surface of the silicon chips; (3) warm water is used for spraying the silicon chips; (4) the silicon chips are subjected to ultrasound pre-cleaning, i.e. the sprayed monocrystalline silicon chips are placed into ultrasound warm water to be soaked for removing mortar in gaps of the silicon chips; (5) warm water is used for soaking degumming; (6) warm water bubbling is carried out, and the monocrystalline silicon chips are disengaged from bonding strips; (7) warm water chip taking is carried out, i.e. the disengaged monocrystalline silicon chips are placed into the warm water, and residue glue on vertical surfaces of the silicon chips is wiped. The process overcomes the defect of high rejection rate of the semiconductor silicon chips caused by the existing degumming process, the automatic degumming technology after the cutting completion of the semiconductor monocrystalline silicon chips with different thicknesses is realized, and in addition, the surfaces of the silicon chips can be enabled not to generate defects of lace, broken edges, notches and the like.

Description

A kind of semi-conductor silicon chip degumming tech
Technical field
The present invention relates to monocrystalline silicon line cutting field, is to realize after the cutting of different-thickness semiconductor monocrystal silicon chip degumming technology automatically specifically.
Background technology
The semiconductor monocrystal silicon processing technique has obtained develop rapidly in recent years, develop into by initial interior (outward) circle cutting technique the multi-wire saw technology generally adopted at present, the semi-conductor silicon chip thickness that multi-line cutting machine has cut and diameter disunity, usually time changes larger with diameter variations different from thickness with the water temperature of coming unstuck.
Traditional degumming tech is generally manually-operated, technical process is for to be immersed in silicon chip in the hot water storgae more than 40 ℃, soak 50-130min, the rear surface flower sheet but the sheet surface washing totally can not cause coming unstuck, soak insufficient coming unstuck and can cause collapsing limit sliver etc., the employee operates very difficult standard simultaneously, random strong, silicon chip surface and integrality are caused to destruction in various degree, often cause later process sliver, collapse limit, contamination etc.Therefore degumming tech becomes the bottleneck of restriction production capacity and product quality.Therefore a kind of practicality technology of removing photoresist becomes the reduction fraction defective, reduces the semi-conductor silicon chip surface impurity and stains, and improves the key technology of yield.
Patent 102225406A discloses a kind of cleaning method of silicon wafer cut by diamond wire, but its solution is the low problem of pyramid coverage rate, reflectivity and battery efficiency of silicon chip alkali making herbs into wool, what be that this patent will solve with the difference of the art of this patent is that different-thickness, diameter semi-conductor silicon chip have cut rear degumming technology, improve come unstuck efficiency and yield ,Wei Hou road matting basis is provided.
Summary of the invention
The problem to be solved in the present invention is that to overcome the semi-conductor silicon chip fraction defective that existing degumming tech causes high, provides a kind of and realizes after the cutting of different-thickness semiconductor monocrystal silicon chip degumming technology automatically, and can guarantee that silicon chip surface, without the flower sheet, collapses limit, breach etc. bad.
Technical scheme of the present invention is as follows:
A kind of semi-conductor silicon chip degumming tech comprises the following steps:
1) will cut complete silicon single crystal rod is upside down in the transit wagon that particular jig is housed;
2) bubbling prerinse, soon monocrystalline silicon piece is placed in the groove of filling running water and utilizes bubbling pipe to carry out prerinse, to remove the silicon chip surface mortar;
3) use warm water to be sprayed silicon chip;
4) silicon chip is carried out to ultrasonic prerinse, soaked in will being placed on ultrasonic warm water through the monocrystalline silicon piece of spray, to remove the mortar in silicon chip gap;
5) use emerge in worm water to come unstuck;
6) warm water bubbling, will break away between monocrystalline silicon piece and adhesive strip;
7) warm water is got sheet, and the silicon chip that is about to break away from is placed in warm water, wiping silicon chip facade removing residual glue;
Further,
Above-mentioned steps 2) the prerinse condition in is: water temperature 15-25 ℃, bubbling TD 0.6-1.0cm, air pressure 0.3-0.5kp, time 300-500s;
Above-mentioned steps 3) the spray condition in is: spray is used 2-4 shower, reciprocal spray time 300-500s, and oscillation cycle 30-60s, water temperature is controlled between 25-45 ℃, hydraulic pressure 0.1-0.4MPa;
Above-mentioned steps 4) the ultrasonic prerinse condition in is: soak water temperature 30-50 ℃, and time 300-600s, supersonic frequency 25-40KHZ, in water, mixed volume is than the surfactant of 1-2%;
Above-mentioned steps 5) the immersion condition of coming unstuck in is: silicon chip is immersed in the hot water of 65-75 ℃, soaks in water and add 1-2% acid, this acid can be selected from a kind of in lactic acid, oxalic acid, citric acid, soak time 300-600s;
Above-mentioned steps 6) the warm water bubbling condition in is: silicon chip is placed on to warm water 35-50 ℃, soaks 300-500s, 35 ℃ of bubblings;
Above-mentioned steps 7) warm water in is got the sheet condition: water temperature 35-50 ℃.
It is 200um-1500um that above-mentioned semi-conductor silicon chip degumming tech is applicable to thickness, and the silicon chip that diameter is 57.5-200mm comes unstuck it smoothly, and can guarantee that silicon chip surface, without the flower sheet, collapses limit, breach etc. bad.
Advantage and good effect that the present invention has are: owing to adopting technique scheme, overcome the semi-conductor silicon chip fraction defective that existing degumming tech causes high, realized after different-thickness semiconductor monocrystal silicon chip cutting degumming technology automatically, and can guarantee that silicon chip surface, without the flower sheet, collapses limit, breach etc. bad.
The specific embodiment
A kind of semi-conductor silicon chip degumming tech comprises the following steps:
1) use the SIC of NTC442 line cutting machine 1500#, the steel wire of 0.14mm diameter, cut a diameter 150mm, length 270mm, and the monocrystalline of thickness 0.820mm, be upside down in monocrystal rod and material seat in the fixture of four-wheel transport vehicle after having cut.
2) again this monocrystalline silicon piece is placed in the tank of filling running water to 21 ℃ of water temperatures, bubbling pipe diameter 0.6mm, air pressure 0.3kPa, bubbling time 360s.
3) then use 35 ℃ of running water of working pressure 0.2MPa water temperature to be sprayed this monocrystalline, adopt 4 showers, every pipe is installed 4 shower nozzles, back and forth sprays 350s, oscillation cycle 40s.
4) will spray again complete monocrystalline silicon piece and be placed on and there is ultrasonic (supersonic frequency 28KHZ) in advance, in 40 ℃ of warm water, be soaked 400s, mix 1.0% oxalic acid in water.
5) again this silicon chip is immersed in the hot water of 70 ℃, adds 1% citric acid in water, soak time 420s,
6) again this silicon chip is placed in 35 ℃ of warm water and soaks 440s, open bubbling simultaneously and come unstuck silicon chip and bonding guide ribs are broken away from.
7) again this monocrystalline silicon piece and the material seat that separated are placed to 35 ℃ of warm water dollies and got sheet, and use scouring pad wiping silicon chip facade bar glue residual.
Above-mentioned semi-conductor silicon chip degumming tech can make silicon chip come unstuck smoothly, and can guarantee that silicon chip surface, without the flower sheet, collapses limit, breach etc. bad.
The above embodiment to invention has been described in detail, but described content is only preferred embodiment of the present invention, can not be considered to for limiting practical range of the present invention.All equalization variations of doing according to the present patent application scope and improvement etc., within all should still belonging to patent covering scope of the present invention.

Claims (8)

1. a semi-conductor silicon chip degumming tech is characterized in that: comprise the following steps:
1) will cut complete silicon single crystal rod is upside down in the transit wagon that particular jig is housed;
2) bubbling prerinse, soon monocrystalline silicon piece is placed in the groove of filling running water and utilizes bubbling pipe to carry out prerinse, to remove the silicon chip surface mortar;
3) use warm water to be sprayed silicon chip;
4) silicon chip is carried out to ultrasonic prerinse, soaked in will being placed on ultrasonic warm water through the monocrystalline silicon piece of spray, to remove the mortar in silicon chip gap;
5) use emerge in worm water to come unstuck;
6) warm water bubbling, will break away between monocrystalline silicon piece and adhesive strip;
7) warm water is got sheet, and the silicon chip that is about to break away from is placed in warm water, wiping silicon chip facade removing residual glue.
2. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the prerinse condition described step 2) is: water temperature 15-25 ℃, bubbling TD 0.6-1.0cm, air pressure 0.3-0.5kp, time 300-500s.
3. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the spray condition in described step 3) is: spray is used 2-4 shower, reciprocal spray time 300-500s, oscillation cycle 30-60s, water temperature is controlled between 25-45 ℃, hydraulic pressure 0.1-0.4MPa.
4. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the ultrasonic prerinse condition in described step 4) is: soak water temperature 30-50 ℃, time 300-600s, supersonic frequency 25-40KHZ, in water, mixed volume is than the surfactant of 1-2%.
5. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the immersion condition of coming unstuck in described step 5) is: silicon chip is immersed in the hot water of 65-75 ℃, soak in water and add 1-2% acid, this acid can be selected from a kind of in lactic acid, oxalic acid, citric acid, soak time 300-600s.
6. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the warm water bubbling condition in described step 6) is: silicon chip is placed on to warm water 35-50 ℃, soaks 300-500s, 35 ℃ of bubblings.
7. a kind of semi-conductor silicon chip degumming tech according to claim 1, it is characterized in that: the warm water in described step 7) is got the sheet condition and is: water temperature 35-50 ℃.
8. to be applicable to thickness be 200um-1500um to a kind of semi-conductor silicon chip degumming tech claimed in claim 1, the silicon chip that diameter is 57.5-200mm.
CN201310431966.6A 2013-09-18 2013-09-18 A kind of semi-conductor silicon chip degumming tech Active CN103464418B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104668231A (en) * 2015-02-13 2015-06-03 江西赛维Ldk太阳能高科技有限公司 Degumming method for pallet for linear cutting and pallet degumming solution
CN105855213A (en) * 2016-03-31 2016-08-17 苏州晶樱光电科技有限公司 Silicon wafer degumming process
CN106409972A (en) * 2016-09-27 2017-02-15 张家港市港威超声电子有限公司 Degumming tool for silicon wafer after multi-wire cutting
CN106816497A (en) * 2017-02-22 2017-06-09 邢台晶龙电子材料有限公司 A kind of silicon wafer stripping cleaning method and device
CN107473331A (en) * 2017-08-17 2017-12-15 隆基绿能科技股份有限公司 Concentrated water treatment method and silicon wafer stripping method
CN108372149A (en) * 2018-03-10 2018-08-07 中锗科技有限公司 A kind of Degumming method of wire cutting solar energy germanium wafer
CN108711547A (en) * 2018-05-03 2018-10-26 浙江海顺新能源有限公司 A kind of silicon wafer stripping technique
CN109979799A (en) * 2017-12-27 2019-07-05 东莞新科技术研究开发有限公司 The Degumming method of semiconductor wafer
CN111921945A (en) * 2020-07-14 2020-11-13 海盐得胜化工设备有限公司 Cleaning process for polycrystalline silicon structured packing
CN114247682A (en) * 2021-11-25 2022-03-29 安徽微芯长江半导体材料有限公司 Special post-cutting cleaning device and cleaning method for silicon carbide wafer

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US20030110803A1 (en) * 2001-09-04 2003-06-19 Nippon Sheet Glass Co., Ltd. Method of manufacturing glass substrate for magnetic disks, and glass substrate for magnetic disks
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104668231A (en) * 2015-02-13 2015-06-03 江西赛维Ldk太阳能高科技有限公司 Degumming method for pallet for linear cutting and pallet degumming solution
CN105855213A (en) * 2016-03-31 2016-08-17 苏州晶樱光电科技有限公司 Silicon wafer degumming process
CN106409972A (en) * 2016-09-27 2017-02-15 张家港市港威超声电子有限公司 Degumming tool for silicon wafer after multi-wire cutting
CN106816497A (en) * 2017-02-22 2017-06-09 邢台晶龙电子材料有限公司 A kind of silicon wafer stripping cleaning method and device
CN107473331A (en) * 2017-08-17 2017-12-15 隆基绿能科技股份有限公司 Concentrated water treatment method and silicon wafer stripping method
CN107473331B (en) * 2017-08-17 2021-03-09 隆基绿能科技股份有限公司 Concentrated water treatment method and silicon wafer degumming method
CN109979799A (en) * 2017-12-27 2019-07-05 东莞新科技术研究开发有限公司 The Degumming method of semiconductor wafer
CN108372149A (en) * 2018-03-10 2018-08-07 中锗科技有限公司 A kind of Degumming method of wire cutting solar energy germanium wafer
CN108711547A (en) * 2018-05-03 2018-10-26 浙江海顺新能源有限公司 A kind of silicon wafer stripping technique
CN108711547B (en) * 2018-05-03 2020-09-29 浙江海顺新能源有限公司 Silicon wafer degumming process
CN111921945A (en) * 2020-07-14 2020-11-13 海盐得胜化工设备有限公司 Cleaning process for polycrystalline silicon structured packing
CN114247682A (en) * 2021-11-25 2022-03-29 安徽微芯长江半导体材料有限公司 Special post-cutting cleaning device and cleaning method for silicon carbide wafer

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